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This study aims to investigate the morphology and physicochemical properties of BiOBr/Polyvinylidene fluoride (PVDF) composite membranes and the differences in the properties of BiOBr/PVDF composite membranes made by adding different precursor ratios during the casting process.

In this paper, sodium bromide and Bi(NO3)3 were used as precursors for the preparation of BiOBr photocatalysts, and PVDF membranes were modified by using the phase conversion method in conjunction with the in situ deposition method to produce BiOBr/PVDF hydrophilic composite membranes with both membrane separation and photocatalytic capabilities.

The characterization results confirmed that the composites were successfully and homogeneously co-mingled in the PVDF membranes. The related performance of the composite membrane was tested, and it was found that the composite membrane with the optimal precursor incorporation ratio had good photocatalytic efficiency and antipollution ability; the removal efficiencies of methyl orange, rhodamine B and methylene blue were 80.43%, 85.02% and 86.94%, respectively, in 2.5 h. The photocatalytic efficiency of composite membranes with different precursor ratios increased and then decreased with the increase of the precursor addition ratio.

The composite membrane is prepared by phase conversion method with in situ deposition method, and the BiOBr material has unique advantages for the degradation of organic dyes. The comprehensive experimental data can be known that the composite membrane prepared in this paper has high degradation efficiency and good durability for organic dyes.

The aim of this paper is to synthesize graphene-modified titanium dioxide (GR-TiO₂) nanorod arrays nanocomposite films, so that these can enhance the photocatalytic properties of titanium dioxide and overcome the problem of difficult separation and recovery of photocatalysts.

The GR-TiO₂ nanocomposite films were synthesized via hydrothermal method and spin-coating. The obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), ultraviolet–visible (UV-Vis) diffuse reflectance spectrum and Raman spectrum. The photocatalytic performance of the GR-TiO₂ nanocomposite films for degrading Rhodamin B under ultraviolet (UV) was studied by a UV-Vis spectrophotometer. The photocatalytic enhancement mechanism of graphene was studied by photoelectrochemical analysis.

The introduction of graphene expanded the range of the optical response of TiO₂ nanorod arrays, improving the separation efficiency of the photogenerated electron-hole pairs, and thus dramatically increasing its photocatalytic performance.

A simple and novel way for synthesizing GR-TiO₂ nanocomposite films has enhanced the photocatalytic performance of TiO₂.

The photocatalyst synthesized is easy to separate and recycle in the process of photocatalytic reaction, so it is possible to achieve industrialization.

The purpose of this paper is to provide an investigation on a new kind of photocatalytic material, namely, the porous ceramic foam loading titanium dioxide, which can make an effective photocatalytic degradation of the methyl orange (MO) solution in the wastewater.

The natural zeolite powder has been used as the primary raw material to produce a sort of lightweight porous ceramic foam by impregnating polymer foam in slurry and then sintering. With the sol-gel method, a kind of open-cell reticular porous ceramic foam loading TiO₂ film was obtained having a good photocatalytic action, and the resultant porous composite product presents the bulk density of 0.3~0.6 g/cm³ to be able to float on water.

The MO could tend to be completely degraded in the solution with a certain concentration by the TiO₂-loaded ceramic foam irradiated with ultraviolet light, and this composite foam was found to have high degradation efficiency for the MO solution in a wide range of pH.

This work presents a TiO₂-loaded ceramic foam that can effectively photo-catalyze to degrade the MO in water, and the degradation efficiency were examined under different conditions of the MO solution with various pH values.

This paper aims to investigate the reusability of metal/metal oxide-coupled ZnO nanorods (ZnO NRs) to degrade rhodamine B (RhB).

ZnO NRs particles were synthesized by precipitation method and used to remove various types of metal ions such as Cu²⁺, Ag⁺, Mn²⁺, Ni²⁺, Pb²⁺, Cd²⁺ and Cr²⁺ ions under UV illumination. The metal/metal oxide-coupled ZnO NRs were characterized by scanning electron microscope, X-ray diffraction and UV-Vis diffuse reflectance. The photodegradation of RhB dye by these metal/metal oxide-coupled ZnO NRs under UV exposure was assessed.

The metal/metal oxide-coupled ZnO NRs were successfully reused to remove RhB dye in which more than >90% of RhB dye was degraded under UV exposure. Furthermore, the coupling of Ag, CuO, MnO₂, Cd and Ni particles onto the surface of ZnO NRs even enhanced the degradation of dye. The dominant reactive species involved in the degradation of RhB dye were ^•OH- and ^•O₂⁻-free radicals.

The coupling of metal/metal oxide onto the surface of ZnO NRs after metal ions removal could affect the photocatalytic performance of ZnO NRs in the degradation of organic pollutants in subsequent stage.

A good reusability performance of metal/metal oxide-coupled ZnO NRs make ZnO NRs become a desirable photocatalyst material for the treatment of wastewater, which consists of both heavy metal ions and organic dyes.

Metal/metal oxide coupling onto the surface of ZnO NRs particles improved subsequent UV-assisted photocatalytic degradation of RhB dye.

This paper aims to investigate the photocatalytic activity of zinc doped MAO-TiO₂ films under the optimum MAO treatment condition.

The coating was prepared by micro arc oxidation, and the influence of doping on the properties of the coating was also investigated.

The results show that the BET surface area is 78.25±0.03m²/g, total pore area is 76.32 ± 0.04m²/g, and the total pore volume is 0.2135 ± 0.0004cm³/g. The degradation ratio of the film electrode with Zn-doped in methyl orange solution is up to 94%. When the react circles is 10 times, the degradation ratio is up to more than 85% and remains steady. With the different reaction conditions, these kinetics of the reactions show some different formulas.

A kinetic equation for photocatalytic activity is established.

The purpose of this paper is to improve the degradation efficiency of Rhodamine B (RhB) by new photocatalytic materials.

Binary Z-scheme g-C₃N₄/Bi₂WO₆ photocatalytic material was synthesized by the one-step hydrothermal reaction. The construction of Z-scheme heterojunction led to the rapid separation of photogenerated electrons and holes, which would degrade RhB into small molecular substances to achieve the purpose of degradation.

It was found that Bi₂WO₆/25%g-C₃N₄ displayed the highest photocatalytic activity, which was about 1.44 and 1.34 times higher than that of pure Bi₂WO₆ and g-C₃N₄, respectively. According to the trapping experiments, the superoxide radical (·O²⁻) was the major active species of the RhB decomposition in Bi₂WO₆/g-C₃N₄ catalysts.

The successful synthesis of Z-scheme Bi₂WO₆/g-C₃N₄ provides new ideas and references for the design of catalysts with high photocatalytic activity, which should have wide applications in the future.

Using only zinc nitrate, ferric nitrate and sodium hydroxide as reactants, rod-like and flower-like α-Fe₂O₃/ZnO composites were prepared via a simple and rapid solution route by controlling the composition of precursor solution. The products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and UV-vis diffuse reflectance spectra (UV-vis DRS). Photocatalytic activity of the as-prepared α-Fe₂O₃/ZnO composites was evaluated by degradation of methyl orange (MO) under simulated solar light. The results indicated that both α-Fe₂O₃/ZnO composites possess higher photocatalytic activity than commercial P25 TiO₂. In addition, possible reasons why α-Fe₂O₃/ZnO composites have excellent photocatalytic performance were discussed.

Three-dimensional (3D) printing is popular for many applications including the production of photocatalysts. This paper aims to focus on developing of 3D-printed photocatalyst-nano composite lattice structure. Digital light processing (DLP) 3D printing of photocatalyst composites was performed using photosensitive resin mixed with 0.5% Wt. of TiO₂ powder and varying amounts (0.025% Wt. to 0.2% Wt.) of graphene nanoplatelet powder. The photocatalytic efficiency of DLP 3D-printed photocatalyst TiO₂ composite was investigated, and the effects of nano graphite powder incorporation on the photocatalytic activity, thermal and mechanical properties were investigated.

Methods involve 3D computer-aided design modeling, printing parameters and comprehensive characterization techniques such as structural equation modeling, X-ray diffraction, thermogravimetric analysis, Fourier-transform infrared (FTIR) and mechanical testing.

Results highlight successful dispersion and characteristics of TiO₂ and graphene nanoplatelet (GNP) powders, intricate designs of 3D-printed lattice structures, and the influence of GNPs on thermal behavior and mechanical properties.

The study suggests applicability in wastewater treatment and environmental remediation, showcasing the adaptability of 3 D printing in designing effective photocatalysts. Future research should focus on practical applications and the long-term durability of these 3D-printed composites.

This paper aims to report a novel preparation method of titanium dioxide (TiO₂)/zinc oxide (ZnO) composites with different mole ratios of TiO₂:ZnO and their photocatalytic activity.

TiO₂/ZnO composites are prepared by a facile route. X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and ultra-violet–visible diffuse reflectance spectra (UV-vis DRS) are used to characterize the products. Photocatalytic activity of the samples is evaluated by degradation of persistent organic pollutant pentachlorophenol under ultra-violet (UV) irradiation.

It is found that all the as-prepared TiO₂/ZnO composites not only have good catalytic activity under UV light irradiation, but also have excellent circulation stability. The optimal mole ratio of TiO₂:ZnO is 0.75:1.

This report presents a simple and rapid method for the preparation of TiO₂/ZnO composites with excellent photocatalytic activity. Experimental results could provide useful reference for the treatment of chlorophenols in the future.

The purpose of this paper is to study the effect of synthesis conditions on properties of TiO₂ nanoparticles to be used for photocatalysis and also producing TiO₂ using a low temperature method.

TiO₂ nanoparticles were synthesised via a sol‐gel method at low temperature and the effect of parameters such as: synthesis temperature, HNO₃ concentration, calcination temperature and synthesis time on properties of TiO₂ were studied. The effects of the physico‐chemical properties of TiO₂, its concentration and light intensity on photocatalytic properties of TiO₂ nanoparticles were investigated also.

The results showed that TiO₂ with Anatase phase were formed at 80‐100°C by using proper HNO₃ concentration, synthesis time and calcinations temperature. Calcinations programme and temperature and also the synthesis time affect the formation of TiO₂ crystalline phase (i.e. Rutile and Brookite), their surface area and crystallite size. To evaluate the photocatalytic properties of TiO₂ nanoparticles, fluorescein was used as a model molecule. Results showed that degradation of fluorescein could be described by pseudo‐first order kinetics. The effect of TiO₂ concentration and light intensity on photocatalytic activity showed that increasing concentration of TiO₂ and the light intensity would increase the degradation of fluorescein.

The method used in this work to prepare TiO₂ nanoparticles is an economic method for low temperature synthesis of TiO₂ nanoparticles with high photocatalytic activity, which could find numerous applications in coating technology.