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1 – 10 of 171
Article
Publication date: 5 December 2023

Huihong Feng, Jianxiang Zhao, Jiarui Hou and Huixia Feng

This study aims to investigate the influence of polyepoxysuccinic acid sodium (PESA), a green antiscalant, on the nucleation, crystallization and precipitation of magnesium…

Abstract

Purpose

This study aims to investigate the influence of polyepoxysuccinic acid sodium (PESA), a green antiscalant, on the nucleation, crystallization and precipitation of magnesium phosphate.

Design/methodology/approach

The conductivity method was used to investigate the maximum relative supersaturation of magnesium phosphate across various PESA dosages. Subsequently, a magnesium phosphate scale was prepared using the static scale inhibition method (GB/T16632-1996) and then analyzed via scanning electron microscopy.

Findings

The findings showed that PESA extends the induction period of magnesium phosphate crystallization, reduces crystal growth rate and elevates the solution’s relative supersaturation. Notably, PESA exerts a low dosage effect on inhibition of the magnesium phosphate scale, with the optimal dosage identified at 10 mL. Scanning electron microscopy revealed that PESA dispenses a dispersing effect on the magnesium phosphate scale, generating numerous concave, convex and deeper pores on the scale particles’ surface, and thereby significantly enhancing the surface area, especially when using an antiscalant with variable dosages.

Originality/value

This study sheds new light on the impact of PESA, a green antiscalant, on the crystallization and precipitation of magnesium phosphate, thus paving the way for the development of enhanced and eco-friendly scale inhibition strategies in future applications.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 18 October 2022

Reza Amini and Pooneh Kardar

This paper aims to achieve phosphating via optimal features of Mg metal as a suitable base coating, which is considered for other properties such as barrier properties against the…

Abstract

Purpose

This paper aims to achieve phosphating via optimal features of Mg metal as a suitable base coating, which is considered for other properties such as barrier properties against the passage of several factors.

Design/methodology/approach

In this research, in the phosphate bath, immersion time, temperature and the content of sodium nitrite as an accelerator were changed.

Findings

As a result, increasing the immersion time of AZ31 Mg alloy samples in the phosphating bath as well as increasing the ratio of sodium dodecyl sulfate (SDS) concentration to sodium nitrite concentration in the phosphating bath formulation increase the mass of phosphating formed per unit area of the Mg alloy. The results of the scanning electron microscope test showed phosphating is not completely formed in short immersion times, which is a thin and uneven layer.

Research limitations/implications

Mg and its alloys are sensitive to galvanic corrosion, which would lead to generating several holes in the metal. As such, it causes a decrease in mechanical stability as well as an unfavorable appearance.

Practical implications

Mg is used in several industries such as automobile and computer parts, mobile phones, astronaut compounds, sports goods and home appliances.

Social implications

Nevertheless, Mg has high chemical reactivity, so an oxide-hydroxide layer is formed on its surface, which has a harmful effect on the adhesion and uniformity of the coating applied on Mg.

Originality/value

By increasing the ratio of SDS concentration to sodium nitrite concentration in the phosphating bath, the corrosion resistance of the phosphating increases.

Details

Pigment & Resin Technology, vol. 53 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 6 November 2023

Xiao Xu and Yimin Zhang

This study aims to form composite solid lubricant coatings on the surface of bearing steel, which can significantly improve the tribological properties of thrust cylindrical…

Abstract

Purpose

This study aims to form composite solid lubricant coatings on the surface of bearing steel, which can significantly improve the tribological properties of thrust cylindrical roller bearings (TCRBs). Phosphating films possess microscopic porosity that typically needs to be sealed with oil, grease or wax. Due to its unique crystal structure, the phosphating film itself also exhibits a certain degree of lubricity. In this study, solid lubricants are used to fill the pores of the phosphating film. By combining the phosphating film with solid lubricants, lubrication and wear reduction can be achieved.

Design/methodology/approach

In this study, the surfaces of the shaft washer (WS) and seat washer (GS) were treated with zinc-phosphating. Subsequently, a solid lubricant solution (polytetrafluoroethylene [PTFE], MoS2 and graphite) was sprayed onto the phosphated samples at concentrations of 1 , 2  and 3 g/L. The porous and adsorptive nature of the phosphating film was used to embed the solid lubricant particles into the film, thus forming a composite lubrication layer containing solid lubricants on the surface of the bearing steel.

Findings

The addition of solid lubricant materials has shown significant potential in reducing wear losses compared with phosphated samples without such additives. Increasing the amount of solid lubricant added can facilitate the formation of a transfer film, which further enhances the protective properties. However, it is important to note that excessive amounts of solid lubricant material can contribute to seizure, leading to increased wear losses of the cage and a higher average coefficient of friction (ACOF).By spraying a PTFE solution with a concentration of 2 g/L, the lowest ACOF and cage wear loss were achieved, resulting in reductions of 60.5% for the ACOF and 89.4% for the cage wear loss. Similarly, when spraying a graphite solution with a concentration of 3 g/L, the lowest wear losses for GS and WS were observed, with reductions of 51.7% for GS wear loss and 38.9% for WS wear loss.

Originality/value

The combination of the phosphating film and solid lubricants aims to achieve lubrication and wear reduction, providing a new approach to wear-resistant technology for TCRBs.

Peer review

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-07-2023-0231/

Details

Industrial Lubrication and Tribology, vol. 75 no. 10
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 27 June 2023

Bin Wang, Wanbin Chen, Shan Gao and Dezhi Wang

This paper aims to prepare a composite film on LY12 aluminum (Al) alloy by immersing in dodecyl phosphate and cerium nitrate solution by self-assembling methods. The effect of…

Abstract

Purpose

This paper aims to prepare a composite film on LY12 aluminum (Al) alloy by immersing in dodecyl phosphate and cerium nitrate solution by self-assembling methods. The effect of dipping sequence in dodecyl phosphate and cerium nitrate solution on the corrosion resistance of the composite film is studied.

Design/methodology/approach

The corrosion resistance of the dodecyl phosphate/cerium composite film is investigated by electrochemical measurement and film composition analysis.

Findings

The dipping sequence in dodecyl phosphate and cerium nitrate solutions has a significant impact on the corrosion resistance of the composite film. It shows best corrosion resistance by first dipping in dodecyl phosphate and then dipping in cerium nitrate solution.

Originality/value

The research shown in this work lays a scientific basis of the film preparation for industrial applications in the future.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Expert briefing
Publication date: 16 August 2023

Prices stayed in the USD100-200 per tonne range in the 2010s, before rising due to China’s imposition of export tariffs, Moscow’s export ban and Russia’s invasion of Ukraine. The…

Details

DOI: 10.1108/OXAN-DB281263

ISSN: 2633-304X

Keywords

Geographic
Topical
Article
Publication date: 2 November 2023

Mohabbat Amirnejad, Mohammad Rajabi and Roohollah Jamaati

This study aims to investigate the effect of electrodeposition parameters (i.e. time and voltage) on the properties of hydroxyapatite (HA) coating fabricated on Ti6Al4V surface.

21

Abstract

Purpose

This study aims to investigate the effect of electrodeposition parameters (i.e. time and voltage) on the properties of hydroxyapatite (HA) coating fabricated on Ti6Al4V surface.

Design/methodology/approach

A full factorial design along with response surface methodology was utilized to evaluate the main effect of independent variables and their relative interactions on response variables. The effect of electrodeposition voltage and deposition time on HA coatings Ca/P molar ratio and the size of deposited HA crystals were examined by structural equation modeling (SEM). The formation of plate-like and needle-like HA crystals was observed for all experiments.

Findings

The results obtained showed that the higher electrodeposition voltage leads to lower Ca/P values for HA coatings. This is more significant at lower deposition times, where at a 20-minute deposition time, the voltage increased from 2 to 3 V and the Ca/P decreased from 2.27 to 1.52. Full factorial design results showed that electrodeposition voltage has a more significant effect on the size of the deposited HA crystal. With increasing the voltage from 2 to 3 V at a deposition time of 20 min, the HA crystal size varied from 99 to 36 µm.

Originality/value

The investigation delved into the impact of two critical parameters, deposition time and voltage, within the electrodeposition process on two paramount properties of HA coatings. Analyzing the alterations in coating characteristics relative to variations in these process parameters can serve as a foundational guide for subsequent research in the domain of calcium-phosphate deposition for implants.

Details

Engineering Computations, vol. 40 no. 9/10
Type: Research Article
ISSN: 0264-4401

Keywords

Open Access
Article
Publication date: 14 November 2023

Laith F. Lazem

Using a combination of the geographical information system (GIS) and the Canadian water quality index (WQI), the current study sought to provide a long-term general assessment of…

Abstract

Purpose

Using a combination of the geographical information system (GIS) and the Canadian water quality index (WQI), the current study sought to provide a long-term general assessment of the water quality of the Shatt Al-Arab River (SAAR), focusing on its suitability for living organisms. Likewise, SPSS statistics was used to develop a nonlinear WQI regression model for the study area.

Design/methodology/approach

The study required four decades of data collection on some environmental characteristics of river water. After that, calculate the WQI and conduct the spatial analysis. Eight variables in total, including water temperature, dissolved oxygen, potential hydrogen ions, electrical conductivity (EC), biological oxygen demand, turbidity, nitrate and phosphate, were chosen to calculate the WQI.

Findings

Throughout the study periods, the WQI values varied from 55.2 to 79.83, falling into the categories of four (marginal) and three (fair), with the sixth period (2007–2008) showing the most decline. The present research demonstrated that the high concentration of phosphates, the high EC values, and minor changes in the other environmental factors are the major causes of the decline in water quality. The variations in ecological variables' overlap are a senior contributor to changes in water quality in general. Notably, using GIS in conjunction with the WQI has shown to be very effective in reducing the time and effort spent on investigating water quality while obtaining precise findings and information at the lowest possible expense. Calibration and validation of the developed model showed that this model had a perfect estimate of the WQI value. Due to its flexibility and impartiality, this study recommends using the proposed model to estimate and predict the WQI in the study area.

Originality/value

Even though the water quality of the SAAR has been the subject of numerous studies, this is the only long-term investigation that has been done to evaluate and predict its water quality.

Details

Arab Gulf Journal of Scientific Research, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1985-9899

Keywords

Article
Publication date: 8 May 2023

Mengmeng Li, Jian Chen, Jingtao Sun, Long Hao, Di Wu, Jianqiu Wang and Wei Ke

The purpose of this study is to investigate the initial corrosion behavior of pure Mg, AZ31 and AZ91 alloys in phosphate buffer solution (PBS) and to characterize the features in…

Abstract

Purpose

The purpose of this study is to investigate the initial corrosion behavior of pure Mg, AZ31 and AZ91 alloys in phosphate buffer solution (PBS) and to characterize the features in corrosion type and resistance of the corrosion product layer.

Design/methodology/approach

The scanning electron microscopy, equipped with energy-dispersive spectroscopy, X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy have been used to characterize the as-corroded samples. Besides, the Mg2+ concentration in PBSs has been determined by inductively coupled plasma atomic emission spectrum.

Findings

It has been found that pure Mg suffers pit corrosion, and AZ31 initially undergoes pit corrosion and then uniform corrosion dominates with an extended immersion duration. However, AZ91 exhibits the uniform corrosion with the highest corrosion rate among the three materials. Besides, the corrosion product layer on AZ31 has the best compactness and corrosion resistance.

Originality/value

The findings add depth in understanding the corrosion of pure Mg and its alloys in PBS and also have guiding significance in exploring the effects by alloyed elements to develop new biomaterials with better performance.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Open Access
Article
Publication date: 1 March 2024

Priyajit Mondal, Dhritishree Ghosh, Madhupa Seth and Subhra Kanti Mukhopadhyay

The purpose of this article is to provide information about interactions between pink-pigmented facultative methylotroph (PPFM) organisms and plants, their molecular mechanisms of…

Abstract

Purpose

The purpose of this article is to provide information about interactions between pink-pigmented facultative methylotroph (PPFM) organisms and plants, their molecular mechanisms of methylotrophic metabolism, application of PPFMs in agriculture, biotechnology and bioremediation and also to explore lacuna in PPFMs research and direction for future research.

Design/methodology/approach

Research findings on PPFM organisms as potent plant growth promoting organisms are discussed in the light of reports published by various workers. Unexplored field of PPFM research are detected and their application as a new group of biofertilizer that also help host plants to overcome draught stress in poorly irrigated crop field is suggested.

Findings

PPFMs are used as plant growth promoters for improved crop yield, seed germination capacity, resistance against pathogens and tolerance against drought stress. Anti-oxidant and UV resistant properties of PPFM pigments protect the host plants from strong sunshine. PPFMs have excellent draught ameliorating capacity.

Originality/value

To meet the ever increasing world population, more and more barren, less irrigated land has to be utilized for agriculture and horticulture purpose and use of PPFM group of organisms due to their draught ameliorating properties in addition to their plant growth promoting characters will be extremely useful. PPFMs are also promising candidates for the production of various industrially and medicinally important enzymes and other value-added products. Wider application of this ecofriendly group of bacteria will reduce crop production cost thus improving economy of the farmers and will be a greener alternative of hazardous chemical fertilizers and fungicides.

Graphicalabstract:

Details

Arab Gulf Journal of Scientific Research, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1985-9899

Keywords

Article
Publication date: 1 March 2024

Asif Ur Rehman, Pedro Navarrete-Segado, Metin U. Salamci, Christine Frances, Mallorie Tourbin and David Grossin

The consolidation process and morphology evolution in ceramics-based additive manufacturing (AM) are still not well-understood. As a way to better understand the ceramic selective…

Abstract

Purpose

The consolidation process and morphology evolution in ceramics-based additive manufacturing (AM) are still not well-understood. As a way to better understand the ceramic selective laser sintering (SLS), a dynamic three-dimensional computational model was developed to forecast thermal behavior of hydroxyapatite (HA) bioceramic.

Design/methodology/approach

AM has revolutionized automotive, biomedical and aerospace industries, among many others. AM provides design and geometric freedom, rapid product customization and manufacturing flexibility through its layer-by-layer technique. However, a very limited number of materials are printable because of rapid melting and solidification hysteresis. Melting-solidification dynamics in powder bed fusion are usually correlated with welding, often ignoring the intrinsic properties of the laser irradiation; unsurprisingly, the printable materials are mostly the well-known weldable materials.

Findings

The consolidation mechanism of HA was identified during its processing in a ceramic SLS device, then the effect of the laser energy density was studied to see how it affects the processing window. Premature sintering and sintering regimes were revealed and elaborated in detail. The full consolidation beyond sintering was also revealed along with its interaction to baseplate.

Originality/value

These findings provide important insight into the consolidation mechanism of HA ceramics, which will be the cornerstone for extending the range of materials in laser powder bed fusion of ceramics.

Details

Rapid Prototyping Journal, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1355-2546

Keywords

1 – 10 of 171