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In the past several years, CH₃NH₃PbI₃ perovskite material has been extensively evaluated as an absorber layer of perovskite solar cells due to its excellent structural and optical properties, and greater than 22% conversion efficiency. However, improvement and future commercialization of solar cells based on CH₃NH₃PbI₃ encountered restrictions due to toxicity and instability of the lead element. Recently, studies on properties of lead-free and mixture of lead with other cations perovskite thin films as light absorber materials have been reported. The purpose of this paper was the fabrication of CH₃NH₃Sn₁-xPbxI₃ thin films with different SnI₂ concentrations in ambient condition, and study on the structural, morphological, optical, and photovoltaic performance of the studied solar cells. The X-ray diffraction studies revealed the formation of both CH₃NH₃PbI₃ and CH₃NH₃SnI₃ phases with increasing the Sn concentration, and improvement in crystallinity and morphology was also observed. All perovskite layers had a relatively high absorption coefficient >104 cm⁻¹ in the visible wavelengths, and the bandgap values varied in the range from 1.46 to 1.63 eV. Perovskite solar cells based on these thin films have been fabricated, and device performance was investigated. Results showed that photo-conversion efficiency (PCE) for the pure CH₃NH₃PbI₃sample was 1.20%. With adding SnI₂, PCE was increased to 4.48%.

In this work, the author mixed tin and lead with different percentages in the perovskite thin film. Also, the preparation of these layers and also other layers to fabricate solar cells based on them were conducted in an open and non-glove box environment. Finally, the effect of [Sn/Pb] ratio in the CH₃NH₃Sn₁-xPbxI₃ layers on the structural, morphological, optical, electrical and photovoltaic performance have been investigated.

CH₃NH₃Sn₁-xPbxI₃ (x = 0.0, 0.25, 0.50, 0.75, 1.0) perovskite thin films have been grown by a spin-coating technique. It was found that as tin concentration increases, the X-ray diffraction and FESEM images studies revealed the formation of both CH₃NH₃PbI₃ and CH₃NH₃SnI₃ phases, and improvement in crystallinity, and morphology; all thin films had high absorption coefficient values close to 104 cm⁻¹ in the visible region, and the direct optical bandgap in the layers decreases from 1.63 eV in pure CH₃NH₃SnI₃ to 1.46 eV for CH₃NH₃Sn0.0.25Pb0.75I3 samples; all thin films had p-type conductivity, and mobility and carrier density increased; perovskite solar cells based on these thin films have been fabricated, and device performance was investigated. Results showed that photo-conversion efficiency (PCE) for the pure CH₃NH₃PbI₃sample was 1.20%. With adding SnI2, PCE was increased to 4.48%.

The preparation method seems to be interesting as it is in an ambient environment without the protection of nitrogen or argon gas.

The purpose of this paper is to synthesize anticorrosion pigments of the perovskite type, YXO₃, where X = Ti, Zr, Mn or Al and Y = Ca, Sr, La or Fe, for coating materials intended for corrosion protection of metals. Also, to synthesize pigments containing hexavalent Mo and W (double perovskites).

The anticorrosion pigments were synthesized from oxides or carbonates by a high-temperature process. The following pigments were synthesized: CaTiO₃, SrTiO₃, CaZrO₃, SrZrO₃, LaTiO₃, LaMnO₃, CaMnO₃, SrMnO₃, LaFe₂O₃, SrFe₂O₃, LaAlO₃, Ca₂ZnWO₆ and Ca₂ZnMoO₆. The pigments were characterized by the physico-chemical properties of the powders, by X-ray diffraction analysis and by scanning electron microscopy. Epoxy-ester coating materials containing the pigments at a volume concentration PVC = 10 per cent were prepared and subjected to tests examining their physico-mechanical properties and tests in simulated corrosion atmospheres.

The perovskite structure was identified in the majority of the pigments. The pigments were found to impart good corrosion inhibiting properties to coating materials. The highest calculated anticorrosion efficiency was found for paints containing CaMnO₃ or SrMnO₃ as the pigments.

The pigments synthesized can be used with advantage in paints intended for corrosion protection of the substrate metals.

The use of the above pigments in anticorrosion coating materials to protect metals is new. Especially beneficial are the uses and procedures for the synthesis of anticorrosion pigments which do not contain heavy metals and are acceptable from the environmental protection aspect.

The purpose of this paper is to investigate the magnetic properties and the ground state phase diagrams of the double perovskite La₂NiMnO₆ using the Monte Carlo simulations (MCS).

In this work, the authors propose a Hamiltonian modeling this compound, described by an Ising model, with different exchange coupling interactions J11, J12 and J22 between the only magnetic atoms Ni and Mn.

Starting with the ground state phase diagrams, the authors present and discuss the stable configurations in different physical parameter planes. On the other hand, the authors present the investigation of the magnetic properties and the magnetization behaviors of the magnetic susceptibilities, as a function of temperature, crystal field, the exchange coupling interactions and the Zeeman energy. To complete this study, the authors illustrate the dependency of the total magnetizations for the hysteresis loops of the double perovskite La₂NiMnO₆ compound. This study is done for fixed values of temperature, the exchange coupling interactions and crystal field.

The authors modeled the different physical parameters of the double perovskite La₂NiMnO with a Hamiltonian describing the system. At T=0K, the authors discussed the ground state phase diagrams of different physical parameters planes. For non-null temperature values, the authors studied the magnetic behavior of the double perovskite La₂NiMnO using MCS under the metropolis algorithm. The authors expect that the results of these simulations can provide some important keys for the experimental research and technology applications of the double perovskite La₂NiMnO₆ in the future.

The purpose of this article is to evaluate the role of mineralisers on the formation of perovskite structure, optimise the amounts of chromium content, soaking time and finally the ratio of fuel (citric acid) to oxidiser (metal nitrate) and investigation of the physical properties of resulted pigments.

A red pigment based on perovskite structure (YAl_1-yCr_yO₃, y = (0.01-0.1) was synthesised by solution combustion method with various mineralisers, like NaF, MgF₂ and Li₂CO₃. Thermal decomposition of the resulting nitrate-citrate gels and the phase evolution of calcined powders were investigated and the microstructure and colorimetry of the emerging products were characterised.

The most effective mineraliser system for the formation of YAlO₃ perovskite was NaF:MgF₂:Li₂CO₃ (3:2:1 by weight). Furthermore, desirable pigments were obtained by firing the samples at 1,400°C for 4 hours. The highest redness parameter (a*) and reflectance value were obtained when y was 0.03 and 0.01, respectively. Increasing the fuel: oxidiser ratio led to an increase in the a* parameter. Use of the optimum prepared red pigment in the low and high firing temperature glazes gave a high chemical and thermal stability.

Only citric acid was used as fuel. Other fuels and different ratios of fuel to oxidiser could also be studied.

The method developed provided a new approach for preparation to nontoxic, high-temperature, ceramic red pigment compared to the solid-state method.

The methods for synthesis of pigment based on perovskite structure with different chromium contents and for evaluation of thermal stability of pigment in glaze were novel.

The purpose of this paper is to synthesise X₂TiO₄ spinel‐type anticorrosion pigments and YTiO₃, perovskite‐type anticorrosion pigments, where X = Zn, Mg, Ca, Sr; Y = Ca for metal protective paints.

Anticorrosion pigments were synthesised from oxides or carbonates at high temperature. The following pigments were synthesised: TiO₂ · ZnO, 2TiO₂ · ZnO, TiO₂ · 2ZnO, TiO₂ · MgO, TiO₂ · CaO, TiO₂ · ZnO · MgO, and TiO₂ · ZnO · SrO. The pigments obtained were characterised by means of X‐ray diffraction analysis, measurement of particle sizes and scanning electron microscopy. The anticorrosion pigments synthesised were used to produce epoxy coatings with PVC = 10 per cent for each synthesised pigment. The coatings were tested for physical‐mechanical properties and in corrosion atmospheres. The corrosion test results were compared with those of alumino zinc phosphomolybdate.

A spinel or perovskite structure was found in the pigments synthesised. High anticorrosion efficiency was identified in all the synthesised pigments, the highest efficiency being demonstrated in the TiO₂ · ZnO pigment of spinel structure and in the TiO₂ · CaO pigment of perovskite structure.

The pigments synthesised can be conveniently used to protect metal bases from corrosion.

The use of pigments synthesised in anticorrosion coatings for metal protection presents a new approach. Its benefits are the use and the method of synthesising the anticorrosion pigments that do not contain heavy metals and that are acceptable for the environment.

This paper aims to combine the results of magnetic measurements with high temperature series expansions to determine the magnetic phase diagram of SrMn_1−xFe_xO₃ 0≤x≤1 perovskites materials.

The authors have found antiferromagnetic ordering for lightly and heavily Fe‐substituted material, while intermediate substitution leads to spin‐glass behavior. Near the SrMn_0.5Fe_0.5O₃ composition these two types of ordering are found to coexist and affect one another.

The spin glass behavior may be caused by competing ferromagnetic and antiferromagnetic interactions among Mn⁴⁺ and observed Fe³⁺ and Fe⁵⁺ ions.

The magnetic perovskites materials are several application in industrial applications (spintronics, magnetic random‐access memory (MRAM), …).

The aim of the present work was the characterization of a group of compounds with the perovskite‐type structure in respect of their applicability as thermistor materials.

Four compositions: La_0.7Sr_0.3Zr_0.5Co_0.2²⁺Co_0.3³⁺O₃, La_0.8Sr_0.2Ti_0.5Co_0.3²⁺Co_0.2³⁺O₃, La_0.4Sr_0.6Ti_0.3Fe_0.7O₃ and CaTi_0.8Co_0.2O₃ were synthesized by solid‐state reaction. Ceramic thermistor materials were sintered in the temperature range 1,300‐1,400°C. The synthesized powders were used for fabrication of thick film pastes and thermistors fired at 1,100‐1,250°C. Resistance‐temperature characteristics of the ceramic samples were studied in the range −55 to 800°C for the ceramic samples and 20‐600°C for thick films. Endurance tests at 300°C for 500 h were performed.

The developed NTC materials exhibited high temperature coefficients of resistivity, dense microstructure and good stability. The most advantageous characteristics have been shown by La_0.7Sr_0.3Zr_0.5Co_0.2²⁺Co_0.3³⁺O₃ and La_0.8Sr_0.2Ti_0.5Co_0.3²⁺Co_0.2³⁺O₃ thermistors. The highest Temperature coefficient of resistances for the ceramics were found in the temperature range from −55 to 180°C (−10.7 to −2.9 per cent/°C) and for the thick films in the temperature range 40‐300°C (−5.6 to −1.5 per cent/°C).

This work has been focused on preliminary choice of compositions appropriate for practical thermistor thick film applications. Elucidation of conduction mechanism of the investigated materials needs further complex studies of conductivity, nonstoichiometry, thermoelectric power, etc. as a function of temperature and oxygen partial pressure.

In this work, an attempt has been made to extend the typical range of NTC compositions and to fulfil the demand for improved stability of bulk and thick film thermistors at elevated temperatures.

To synthesise calcium titanate with a perovskite structure as an anticorrosion pigment for metal protecting paints.

Calcium titanate was synthesised from titanium dioxide and calcium carbonate at high temperature. The pigment obtained was characterised by means of X‐ray diffraction, particle size distribution measurement and scanning electron microscopy. The pigment obtained was further characterised with regard to the parameters required for paint formulation; its specific mass was determined by oil consumption and critical pigment volume concentration. The synthesised calcium titanate was used to prepare epoxy coatings with varying contents of the anticorrosion pigment. The coating was tested for physical‐mechanical properties and in corrosive atmospheres. The results were compared with titanium dioxide that served as a starting material for calcium titanate preparation.

Calcium titanate was prepared from materials that do not add any impurities to the anticorrosion properties of the pigment. It was identified that calcium titanate of perovskite structure is a highly efficient anticorrosion pigment for paints.

Calcium titanate can be utilised for the preparation of anticorrosion paints to protect metal bases from corrosion.

The method of synthesising calcium titanate as an anticorrosion pigment is new. The literature has not yet described the use of calcium titanate as a pigment with inhibitive properties in paints. From an ecologic standpoint, the application of a new anticorrosion pigment for paints presents a highly positive trend.

At first, the organic/inorganic and hybrid PV materials by their electrical model are described. Then the proposed converter topology, circuit analysis and various operating modes of converter according to on/off timing of switches are investigated. The current and voltage in the converter components are illustrated and the voltage gain and switching stress of proposed converter are presented. Finally, to show the effectiveness of the proposed converter, the power loss analysis is provided and the simulation is done in PSIM software. In the last section, the advantages of the proposed topology of higher efficiency by lower number of components in compare with other conventional topologies are presented.

In this paper, an improved topology of DC-DC converter based on VL technique is proposed for Perovskite Solar cells (PeSCs). The PeSCs attracted a lot of interest due to their potential in combining the advantages of both organic and inorganic components. The proposed converter by using fewer components and higher output voltage generation in compare with conventional ones could be a good candidate for PeSCs due to lower efficiency of this cells. The performance of converter is expressed in continuous conduction mode (CCM) and discontinuous conduction mode (DCM), and the boundary conditions for the proposed converter is presented.

By using VL technique, this converter is used to boost the lower output voltage levels of PeSCs for grid connection. The PV cell output voltage is increased from 24.5 V to 106 V by proposed converter topology. The step-by-step voltage increasing by charging and discharging of inductor and capacitor is used for boosting the input voltage. By comparing other converters, there is no design complexity in the proposed converter structure, and the power loss is much reduced which increases the converter efficiency. On the other hand, due to using lower number of elements of energy storage elements such as inductors and capacitors, the converter cost is also diminished. Therefore, the design topology simplicity which result simple control algorithm and lower number of components which diminish the system cost by appropriate voltage boosting capability are the main advantages of this proposed topology for new PeSCs which don’t have enough efficiency in compare with old Si PV cells.

In this paper, by using the lower number of components a new structure of DC-DC converter based on the VL technique is proposed. The advantages of this converter such as the simplicity, easier control and high voltage gain by lower power loss, could make this converter a good candidate for new PeSCs where the system whole efficiency will be a critical point to have the unique properties of this new materials in lower loss.

This paper aims to investigate different properties of synthesized perovskite Sm_0.9Sr_0.1CoO_3-δ and its potential for application in potentiometric oxygen sensors.

The powder was obtained through solid-state reaction method and characterized by thermogravimetric/differential thermal analyzer and X-ray diffraction. It was used for both making a paste and pressing into rods for sintering. The prepared paste was deposited on alumina and yttria-stabilized zirconia substrates, by screen printing. Thick film conductivity, bulk conductivity and Seebeck coefficient of sintered rods were measured as a function of temperature. An oxygen concentration cell was fabricated with the screen-printed perovskite material as electrodes.

Electrical conductivity of the bulk sample and thick film increases with the increase in temperature, showing semiconductor-like behavior, which is also indicated by relatively high values of the measured Seebeck coefficient. Estimated values of the activation energy for conduction are found to be of the same magnitude as those reported in the literature for similar composition. An investigation of Nernstian behavior of the fabricated cell confirmed that Sm_0.9Sr_0.1CoO_3-δ is a promising material for application in oxygen potentiometric sensors.

Gas sensor research is focused on the development of new sensitive materials. Although there is scarce information on SmCoO_3-δ in the literature, it is mostly investigated for fuel cell applications. Results of this study imply that Sr-doped SmCoO_3-δ is a good candidate material for oxygen potentiometric sensor.