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This paper aims to improve the corrosion resistance performance and stability of PbO₂ electrodes in chloride wastewater.

The morphology of PbO₂-ZrO₂ nanocomposite electrodes was observed by scanning electron microscopy (SEM). The open circuit potential (OCP) curves, anodic polarization curves, electrochemical impedance spectra, accelerated life tests, weight-loss tests and reusability tests were used to study the corrosion resistance properties and stability of PbO₂-ZrO₂ nanocomposite electrodes in NaCl solution.

SEM showed that the surface morphology of PbO₂-ZrO₂ nanocomposite electrodes became compacted and smooth. Electrochemical tests showed that ZrO₂ nanoparticles could increase the OCP, corrosion potential and charge transfer resistance, and decrease the corrosion current density in 3.5 Wt. per cent NaCl electrolyte solution. Besides, PbO₂-ZrO₂ nanocomposite electrodes showed high reusability for acetamiprid degradation, the accelerated service life could reach 146 h, which was almost 3.3 times longer than that of PbO₂ electrodes (44 h), weight-loss tests showed that the corrosion resistance for PbO₂-ZrO₂ nanocomposite electrodes was 2.3 times as compared to PbO₂ electrodes.

By the codeposition of ZrO₂ nanoparticles, the corrosion resistance performance and stability of PbO₂ electrodes in NaCl electrolyte were improved.