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1 – 10 of 44Yingshuang Liu, Ran Liu, Dalei Zhang, Shaohua Xing, Xiaohui Dou, Xinwei Zhang and Zonghao He
The corrosion behaviour of titanium alloy surface when fluid with different flow rates flows through welded joints with different residual heights was explored.
Abstract
Purpose
The corrosion behaviour of titanium alloy surface when fluid with different flow rates flows through welded joints with different residual heights was explored.
Design/methodology/approach
The experiment uses a combination of array electrodes and simulation.
Findings
It is found that when the weld reinforcement exists, the corrosion tendency of both ends of the weld metal is greater than that of other parts of the welded joint due to the influence of high turbulence kinetic energy and shear stress. The presence of weld reinforcement heights makes the fluid behind it fluctuate greatly. The passivation films of both the base metal (BM) at the rear and the heat-affected zone (HAZ) are more prone to corrosion than those of the front BM and HAZ, and the passivation film is rougher.
Originality/value
The combination of test and simulation was used to explore the influence of electrochemical and hydrodynamic factors on the corrosion behaviour of titanium alloy-welded joints when welding residual height existed.
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Junyu Shi, Shengli Ling, Yinjie Kuang, Yonggang Tong, Yongle Hu and Dunying Deng
The purpose of this paper is to reveal the effect of microstructure on the corrosion behavior of CoCrNi alloy in 3.5 Wt.% NaCl solution.
Abstract
Purpose
The purpose of this paper is to reveal the effect of microstructure on the corrosion behavior of CoCrNi alloy in 3.5 Wt.% NaCl solution.
Design/methodology/approach
The as-cast CoCrNi alloy was prepared by arc melting, and the cold-rolled and annealed alloys were prepared by processing the as-cast alloy.
Findings
The experimental results showed that a protective passivation film was formed on the surfaces of these CoCrNi MEA, and the stability and compactness of alloys increased in the sequence of cold-rolled, as-cast and annealed CoCrNi alloys. The annealed CoCrNi alloys had the best pitting resistance.
Originality/value
This study proposes the effect of the microstructure of CoCrNi alloy on corrosion resistance.
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Sixian Rao, Changwei Zhang, Fei Zhao, Lei Bao and Xiaoyi Wang
This paper aims to explore the influence of corrosion-deformation interactions (CDI) on the corrosion behavior and mechanisms of 316LN under applied tensile stresses.
Abstract
Purpose
This paper aims to explore the influence of corrosion-deformation interactions (CDI) on the corrosion behavior and mechanisms of 316LN under applied tensile stresses.
Design/methodology/approach
Corrosion of metals would be aggravated by CDI under applied stress. Notably, the presence of nitrogen in 316LN austenitic stainless steel (SS) would enhance the corrosion resistance compared to the nitrogen-absent 316L SS. To clarify the CDI behaviors, electrochemical corrosion experiments were performed on 316LN specimens under different applied stress levels. Complementary analyses, including three-dimensional morphological examinations by KH-7700 digital microscope and scanning electron microscopy coupled with energy dispersive spectroscopy, were conducted to investigate the macroscopic and microscopic corrosion morphology and to characterize the composition of corrosion products within pits. Furthermore, ion chromatography was used to analyze the solution composition variations after immersion corrosion tests of 316LN in a 6 wt.% FeCl3 solution compared to original FeCl3 solution. Electrochemical experiment results revealed the linear decrease in free corrosion potential with increasing applied stress. Electrochemical impedance spectroscopy results indicated that high tensile stress level damaged the integrity of passivation film, as evidenced by the remarkable reduction in electrochemical impedance. Ion chromatography analyses proved the concentrations increase of NO3− and NH4+ ion concentrations in the corrosion media after corrosion tests.
Findings
The enhanced corrosion resistance of 316LN SS is attributable to the presence of nitrogen.
Research limitations/implications
The scope of this study is confined to the influence of tensile stress on the electrochemical corrosion of 316LN at ambient temperatures; it does not encompass the potential effects of elevated temperatures or compressive stress.
Practical implications
The resistance to stress electrochemical corrosion in SS may be enhanced through nitrogen alloying.
Originality/value
This paper presents a systematic investigation into the stress electrochemical corrosion of 316LN, marking the inaugural study of its impact on corrosion behaviors and underlying mechanisms.
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Zhaozhi Li, Changfu Zhang, Hairong Zhang, Haihui Liu, Zhao Zhu and Liucheng Wang
This study aims to apply an electrochemical grinding (ECG) technology to improve the material removal rate (MRR) under the premise of certain surface roughness in machining U71Mn…
Abstract
Purpose
This study aims to apply an electrochemical grinding (ECG) technology to improve the material removal rate (MRR) under the premise of certain surface roughness in machining U71Mn alloy.
Design/methodology/approach
The effects of machining parameters (electrolyte type, grinding wheel granularity, applied voltage, grinding wheel speed and machining time) on the MRR and surface roughness are investigated with experiments.
Findings
The experiment results show that an electroplated diamond grinding wheel of 46# and 15 Wt.% NaNO3 + 10 Wt.% NaCl electrolyte is more suitable to be applied in U71Mn ECG. And the MRR and surface roughness are affected by machining parameters such as applied voltage, grinding wheel speed and machining time. In addition, the maximum MRR of 0.194 g/min is obtained with the 15 Wt.% NaCl electrolyte, 17 V applied voltage, 1,500 rpm grinding wheel speed and 60 s machining time. The minimum surface roughness of Ra 0.312 µm is obtained by the 15 Wt.% NaNO3 + 10 Wt.% NaCl electrolyte, 13 V applied voltage, 2,000 rpm grinding wheel speed and 60 s machining time.
Originality/value
Under the electrolyte scouring effect, the products and the heat generated in the machining can be better discharged. ECG has the potential to improve MRR and reduce surface roughness in machining U71Mn.
Peer review
The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-10-2023-0341/
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Yuchen Xi, Qinying Wang, Yafei Wu, Xingshou Zhang, Lijin Dong, ShuLin Bai and Yi Yang
The purpose of this study is to investigate the crevice corrosion behavior and mechanism of laser additive manufacturing (LAM) nickel-based alloy under wedge-shaped crevice.
Abstract
Purpose
The purpose of this study is to investigate the crevice corrosion behavior and mechanism of laser additive manufacturing (LAM) nickel-based alloy under wedge-shaped crevice.
Design/methodology/approach
First, the opening size of the wedge-shaped crevice was designed to 0.1, 0.3 and 0.5 mm by controlling the thickness of silicon rubber and the double-side adhesive tape. Then, one side of the glass sheet was stuck on the silicon strip and keep the electrodes of Rows 1 and 2 outside the crevice as a reference, and the opposite side was stuck to the wire beam electrode by silica gel.
Findings
The current density with a maximum value of 5.7 × 10−6 A/cm2 was observed at the crevice opening of 0.5 mm, while the lowest value of 9.2 × 10−7 A/cm2 was found at the crevice opening of 0.1 mm. In addition, the corrosion resistance at the inside of the crevice is higher than that at the outside and the middle of the crevice. It means that the internal width of the wedge-shaped crevice tends toward 0, which hinders the migration of ions in the corrosive medium. The generation of corrosive products further reduce the crevice size to cause the inhibition of corrosion at the inside of the crevice as well.
Originality/value
The multilayer and multipath LAM component is prepared to show the complex microstructure, which made the corrosion behavior and mechanism at wedge-shaped crevice nondeterminacy.
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Dongyang Li, Guanghu Yao, Yuyuan Guan, Yaolei Han, Linya Zhao, Lining Xu and Lijie Qiao
In this paper, the authors aim to study the effect of hydrogen on the pitting corrosion behavior of Incoloy 825, a commonly used material for heat exchanger tubes in hydrogenated…
Abstract
Purpose
In this paper, the authors aim to study the effect of hydrogen on the pitting corrosion behavior of Incoloy 825, a commonly used material for heat exchanger tubes in hydrogenated heat exchangers.
Design/methodology/approach
The pitting initiation and propagation behaviors were investigated by electrochemical and chemical immersion experiments and observed and analyzed by scanning electron microscope and energy dispersive spectrometer methods.
Findings
The results show that hydrogen significantly affects the electrochemical behavior of Incoloy 825; the self-corrosion potential decreased from −197 mV before hydrogen charging to −263 mV, −270 mV and −657 mV after hydrogen charging, and the corrosion current density increased from 0.049 µA/cm2 before hydrogen charging to 2.490 µA/cm2, 2.560 µA/cm2 and 2.780 µA/cm2 after hydrogen charging. The pitting susceptibility of the material increases.
Originality/value
Hydrogen is enriched on the precipitate, and the pitting corrosion also initiates at that location. The synergistic effect of hydrogen and precipitate destroys the passive film on the metal surface and promotes pitting initiation.
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Meigui Yin, Lei Zhang and Longxiang Huang
The purpose of this paper is to study the effect of surface salt spray duration on the fretting wear and electrochemical corrosion behaviors of Inconel 690 alloy.
Abstract
Purpose
The purpose of this paper is to study the effect of surface salt spray duration on the fretting wear and electrochemical corrosion behaviors of Inconel 690 alloy.
Design/methodology/approach
A high-temperature steam generator was applied to salt spray test samples, a fretting wear rig was used to realize the damage behavior tests, an electrochemical workstation was applied to analysis the changes of each sample’s corrosion dynamic response before and after fretting wear.
Findings
The thickness of the oxide film that formed on sample surface was increased with the salt spray duration, and somewhat it could act as lubrication during the fretting wear process; however, the corrosive chloride would accelerate the fretting mechanical damage behavior.
Originality/value
In a salt steam spray condition, the fretting tribo-corrosion behaviors of Inconel 690 alloy surface was studied.
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Hairui Jiang, Jianjun Guan, Yan Zhao, Yanhong Yang and Jinglong Qu
The purpose of this study is to investigate the corrosion resistance of superalloys subjected to ultrasonic impact treatment (UIT). The passive film growth on the superalloys’…
Abstract
Purpose
The purpose of this study is to investigate the corrosion resistance of superalloys subjected to ultrasonic impact treatment (UIT). The passive film growth on the superalloys’ surface is analyzed to illustrate the corrosion mechanism.
Design/methodology/approach
Electrochemical tests were used to investigated the corrosion resistance of GH4738 superalloys with different UIT densities. The microstructure was compared before and after the corrosion tests. The passive film characterization was described by electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS) tests.
Findings
The compressive residual stress and corrosion resistance of the specimens significantly increased after UIT. The order of corrosion resistance is related to the UIT densities, i.e. 1.96 s/mm2 > 1.71 s/mm2 > 0.98 s/mm2 > as-cast. The predominant constituents of the passive films are TiO2, Cr2O3, MoO3 and NiO. The passive film on the specimen with 1.96 s/mm2 UIT density has the highest volume fraction of Cr2O3 and MoO3, which is the main reason for its superior corrosion resistance.
Originality/value
This study provides quantitative corrosion data for GH4738 superalloys treated by ultrasonic impact. The corrosion mechanism is explained by the passive film’s characterization.
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Zhengwei Song, Shengjian Zhang, Lifeng Ding, Xuejing Wu and Ning Long
The purpose of this paper was prepared a Ni-based superhydrophobic coating on the surface of copper to enhence its corrosion resistance. The superhydrophobic coating (SHPC) has…
Abstract
Purpose
The purpose of this paper was prepared a Ni-based superhydrophobic coating on the surface of copper to enhence its corrosion resistance. The superhydrophobic coating (SHPC) has proven to be an effective surface treatment in corrosion protection. In this paper, a Ni-based SHPC was prepared on the surface of copper (Cu) to enhance its corrosion resistance.
Design/methodology/approach
The coating was prepared through a two-step electrodeposition process. The first step involves the formation of a micro-nano structure Ni layer formed by an electrodeposition process. Subsequently, the polysiloxane layer was deposited on the Ni surface to create an SHPC. The morphology, composition, structure, wettability and corrosion resistance of the coating were characterized and discussed.
Findings
The results show that the water contact angle of the as-prepared coating reaches 155.5°±1.0°. The corrosion current density (icorr = 3.90 × 10−9 A·cm−2) decreased by three orders of magnitude compared to the substrate, whereas |Z|f = 0.01 Hz (2.40 × 106 Ω·cm2) increased by three orders of magnitude. It indicated that the prepared coating has excellent superhydrophobicity and high corrosion resistance, which can provide better protection for the substrate.
Originality/value
The prepared coating provides long-lasting protection for Cu and other metals and offers valuable data for developing SHPCs.
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Yuchen Xi, Qinying Wang, Xiaofang Luo, Xingshou Zhang, Tingyao Liu, Huaibei Zheng, Lijin Dong, Jie Wang and Jin Zhang
The purpose of this paper is to investigate the effect Ti on stress corrosion cracking (SCC) and flow accelerated stress corrosion cracking (FA-SCC) behavior and mechanisms of…
Abstract
Purpose
The purpose of this paper is to investigate the effect Ti on stress corrosion cracking (SCC) and flow accelerated stress corrosion cracking (FA-SCC) behavior and mechanisms of Monel K500 alloy.
Design/methodology/approach
Monel K500 alloy with different Ti contents was designed. A metallurgical microscope (XJP-3C) and scanning electron microscopy (EV0 MA15 Zeiss) with an energy dispersive spectroscopy were used to analyze the microstructure of the Monel K500 alloy. In situ electrochemical tests were carried out in static and flowing seawater to study FA-SCC behavior.
Findings
The number of TiCN particles in the alloy increased as the increase of Ti content. The static corrosion and SCC of Monel K500 alloy are reduced as the content of Ti increases. Generally, the SCC of alloys was caused by the synergistic effect of the anodic dissolution at exposed metal matrix and the pit corrosion of metal matrix adjacent to TiCN particles, which was further accelerated by flowing.
Originality/value
The corrosion behavior and mechanism of Monel K500 alloy with different Ti contents in a complex flowing seawater environment are still unclear, which remain systematic study to insure the safe service of the alloy.
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