Search results
1 – 10 of 955Won-Hyuk Lee, Tae-Wook Na, Kyung-Woo Yi, Seung-Min Yang, Jang-Won Kang, Hyung Giun Kim and Hyung-Ki Park
When a pure titanium component is fabricated in a selective laser melting (SLM) process using titanium powder, the oxygen concentration of the SLM sample increases compared to the…
Abstract
Purpose
When a pure titanium component is fabricated in a selective laser melting (SLM) process using titanium powder, the oxygen concentration of the SLM sample increases compared to the initial powder. The purpose of this paper is to study the reason for increasing oxygen concentration after SLM.
Design/methodology/approach
To understand this phenomenon, the authors analyzed the oxidation behavior during the SLM process thermodynamically.
Findings
Based on the laser parameters used in this study, the temperature of the Ti melt during the SLM process was expected to rise to 2,150°C. Based on the thermodynamic analysis, the equilibrium oxygen partial pressure for oxidation was 2.32 × 10−19 atm at 2,150°C when the dissolved oxygen concentration in the titanium is 0.2 wt.%. However, the oxygen partial pressure inside the SLM chamber was 1 × 10−3 atm, which is much higher than the equilibrium oxygen partial pressure. Therefore, oxidation occurred during the SLM process, and the oxygen concentration of the SLM sample increased compared to the initial powder.
Originality/value
Most studies on fabricating Ti components using additive manufacturing (AM) have been focused on how the changes in the microstructures and mechanical properties depend on the process parameters. However, there are a few studies that analyzed the oxygen concentration change of Ti during the AM process and its causes. In this study, the authors analyzed the oxidation behavior during the SLM process thermodynamically.
Details
Keywords
F. Rotman, D. Navarro and S. Mellul
This paper reports the results of development work conducted on nitrogen‐based atmospheres in order to improve the firing of copper thick film systems through continuous furnaces…
Abstract
This paper reports the results of development work conducted on nitrogen‐based atmospheres in order to improve the firing of copper thick film systems through continuous furnaces. The proposed solution is particularly suitable for industrial production conditions since it allows variations of the material quantity processed per unit time, resulting not only in an improvement in quality but also in productivity. Such improvements have been achieved by using a new gas distribution system which provides both zone control and regulation of oxygen additions in the nitrogen furnace atmosphere. An efficient set‐up of this system has become possible thanks to precise control of the oxygen profile in relation to the temperature cycle, taking into account various inks' characterisation, and owing to an extensive study of the effects of oxygen additions on copper thick film properties. The solution was tested in a muffle‐lined belt furnace with several commercial dielectric and copper inks, and for increasing oxygen additions into the furnace preheat zone. Different sample patterns were designed to test both monolayer and multilayer systems. The test programme includes measurements of resistivity, bondability, solderability, dielectric breakdown voltage and adhesion of copper films on alumina and on dielectric layers before and after ageing. Ink characterisation by thermogravimetry and by several gas analyses has confirmed that the organic vehicle removal mechanism under nitrogen atmospheres doped with oxygen is a burnout. Indeed, significant oxygen consumption occurs within the temperature range of the removal, as a function of the amount of ink processed. Oxygen additions in the furnace burnout zone greatly improve both the dielectric breakdown voltage and the adhesion of copper on alumina and on dielectric (especially after ageing), while sheet resistivity, wire bondability and soft solderability are not altered below a defined O2 level. It is therefore possible to determine an optimum oxygen addition range for which the thick films fired under such conditions will have the best characteristics. This optimum oxygen window is achieved thanks to a new regulation system which operates whenever variations occur in the quantity of paste processed.
Chinmay Roy, Aparna Ghosh and Suman Chatterjee
This paper aims to estimate the relationship between defect structure with gas concentration for use as a gas sensor. The change in defect concentration caused a shift in the…
Abstract
Purpose
This paper aims to estimate the relationship between defect structure with gas concentration for use as a gas sensor. The change in defect concentration caused a shift in the Fermi level, which in turn changed the surface potential, which is manifested as the potentiometric response of the sensing element.
Design/methodology/approach
A new theoretical concept based on defect chemistry and band structure was used to explain the experimental gas response of a sensor. The theoretically simulated response was compared with experimental results.
Findings
Understanding the origin of potentiometric response, through the generation of defects and a corresponding shift in Fermi level of sensing surface, by the adsorption of gas. Through this understanding, the design of a sensor with improved selectivity and stability to a gas can be achieved by the study of defect structure and subsequent band analysis.
Research limitations/implications
This paper provides information about various types of surface defects and numerical simulation of material with defect structure. The Fermi energy of the simulated value is correlated with the potentiometric sensor response.
Practical implications
Gas sensors are an integral part of vehicular and industrial pollution control. The theory developed shows the origin of response which can help in identifying the best sensing material and its optimum temperature of operation.
Social implications
Low-cost, reliable and highly sensitive gas sensors are highly demanded which is fulfilled by potentiometric sensors.
Originality/value
The operating principle of potentiometric sensors is analyzed through electron band structure analysis. With the change in measured gas concentration, the oxygen partial pressure changes. This results in a change in defect concentration in the sensing surface. Band structure analysis shows that change in defect concentration is associated with a shift in Fermi level. This is the origin of the potentiometric response.
Details
Keywords
Sai Nikhil Subraveti, V. Vinod Kumar, Harish Pothukuchi, P.S.T. Sai and B.S.V. Patnaik
Better membrane oxygenators need to be developed to enable efficient gas exchange between venous blood and air.
Abstract
Purpose
Better membrane oxygenators need to be developed to enable efficient gas exchange between venous blood and air.
Design/methodology/approach
Optimal design and analysis of such devices are achieved through mathematical modeling tools such as computational fluid dynamics (CFD). In this study, a control volume-based one-dimensional (1D) sub-channel analysis code is developed to analyze the gas exchange between the hollow fiber bundle and the venous blood. DIANA computer code, which is popular with the thermal hydraulic analysis of sub-channels in nuclear reactors, was suitably modified to solve the conservation equations for the blood oxygenators. The gas exchange between the tube-side fluid and the shell-side venous blood is modeled by solving mass, momentum and species conservation equations.
Findings
Simulations using sub-channel analysis are performed for the first time. As the DIANA-based approach is well known in rod bundle heat transfer, it is applied to membrane oxygenators. After detailed validations, the artificial membrane oxygenator is analyzed for different bundle sizes (L/W) and bundle porosity (epsilon) values, and oxygen saturation levels are predicted along the bundle. The present sub-channel analysis is found to be reasonably accurate and computationally efficient when compared to conventional CFD calculations.
Research limitations/implications
This approach is promising and has far-reaching ramifications to connect and extend a well-known rod bundle heat transfer algorithm to a membrane oxygenator community. As a variety of devices need to be analyzed, simplified approaches will be attractive. Although the 1D nature of the simulations facilitates handling complexity, it cannot easily compete with expensive and detailed CFD calculations.
Practical implications
This work has high practical value and impacts the design community directly. Detailed numerical simulations can be validated and benchmarked for future membrane oxygenator designs.
Social implications
Future membrane oxygenators can be designed and analyzed easily and efficiently.
Originality/value
The DIANA algorithm is popularly used in sub-channel analysis codes in rod bundle heat transfer. This efficient approach is being implemented into membrane oxygenator community for the first time.
Details
Keywords
Mayu Muramatsu, Keiji Yashiro, Tatsuya Kawada and Kenjiro Tarada
The purpose of this study is to develop a simulation method to calculate non-stationary distributions of the chemical potential of oxygen in a solid oxide fuel cell (SOFC) under…
Abstract
Purpose
The purpose of this study is to develop a simulation method to calculate non-stationary distributions of the chemical potential of oxygen in a solid oxide fuel cell (SOFC) under operation.
Design/methodology/approach
The initial-boundary value problem was appropriately formulated and the appropriate boundary conditions were implemented so that the problem of non-stationary behavior of SOFC can be solved in accordance with actual operational and typical experimental conditions. The dependencies of the material properties on the temperature and partial pressure of oxygen were also elaborately introduced to realize actual material responses. The capability of the proposed simulation method was demonstrated under arbitrary operating conditions.
Findings
The steady state calculated with the open circuit voltage condition was conformable with the analytical solution. In addition, the transient states of the spatial distributions of potentials and currents under the voltage- and current-controlled conditions were successfully differentiated, even though they eventually became the same steady state. Furthermore, the effects of dense materials assumed for interconnects and current collectors were found to not be influential. It is thus safe to conclude that the proposed method enables us to simulate any type of transient simulations regardless of controlling conditions.
Practical implications
Although only uniaxial models were tested in the numerical examples in this paper, the proposed method is applicable for arbitrary shapes of SOFC cells.
Originality/value
The value of this paper is that adequate numerical simulations by the proposed method properly captured the electrochemical transient transport phenomena in SOFC under various operational conditions, and that the applicability was confirmed by some numerical examples.
Details
Keywords
THE partial pressure of the oxygen content in the atmosphere decreases directly with the atmospheric pressure, i.e., with the altitude, the proportion of oxygen in the atmosphere…
Abstract
THE partial pressure of the oxygen content in the atmosphere decreases directly with the atmospheric pressure, i.e., with the altitude, the proportion of oxygen in the atmosphere (about 20·9 per cent) remaining practically constant in the substratosphere.
Ancient and Modern The ability of zeolite granules to act as a molecular sieve has been known to science for many years: now NGL have adapted this age‐old process and by…
Abstract
Ancient and Modern The ability of zeolite granules to act as a molecular sieve has been known to science for many years: now NGL have adapted this age‐old process and by harnessing it to modern electronic technology have created a new concept in aircraft Life Support systems.
The purpose of this study is to improve the performance of hollow fiber membrane and improve the separation efficiency.
Abstract
Purpose
The purpose of this study is to improve the performance of hollow fiber membrane and improve the separation efficiency.
Design/methodology/approach
By establishing a mathematical model of hollow fiber membrane gas separation, the influences of parameters such as pressure difference between the inside and outside of the filament, initial oxygen concentration of intake air, intake air flow rate and back pressure outside the filament on the polarization coefficient were analyzed, so as to explore the degree of influence of operating parameters on the concentration polarization, and put forward a technical scheme to reduce the concentration polarization.
Findings
Factors such as pressure difference between the inside and outside of the filament, initial oxygen concentration of intake air, intake air flow rate and back pressure outside the filament have a certain effect on the polarization coefficient. Among them, the polarization coefficient is positively correlated with pressure difference inside and outside the filament, initial oxygen concentration of intake air and back pressure outside the filament, and is negatively correlated with intake air flow.
Practical implications
Negative pressure suction on the permeation side can be used to increase the membrane permeation flow rate and reduce the concentration polarization.
Originality/value
The influence of concentration polarization on membrane performance is reduced by controlling various factors.
Details
Keywords
Determining the variation law of the oxygen concentration in the ullage space of the fuel tank is the key to the design of the inert system. Among various factors affecting the…
Abstract
Purpose
Determining the variation law of the oxygen concentration in the ullage space of the fuel tank is the key to the design of the inert system. Among various factors affecting the oxygen concentration in the ullage space of the fuel tank, the temperature difference between day and night shows particular importance while relevant analysis and calculation are scarce.
Design/methodology/approach
This study establishes a theoretical simulation model of the central wing fuel tank of an aircraft according to the relevant provisions of day-night temperature variation in FAR25 airworthiness regulations, verifies the model with the existing experimental data and discusses the corresponding relationship between the oxygen concentration in the ullage space of the fuel tank and the day-night temperature difference. The influence of day and night temperature difference, fuel type, fuel load rate, initial oxygen concentration, dissolved oxygen evolution and other factors on the oxygen concentration in the ullage space of the fuel tank were analyzed, and the limit of initial oxygen concentration of the fuel tank before the shutdown at night meeting the requirements of the airworthiness provisions was proposed.
Findings
The results show that the temperature difference between day and night, fuel load rate, initial oxygen concentration and other factors have different effects on the oxygen concentration in the ullage space of fuel tank. The initial oxygen concentration limit before shutdown shall be 2% below the 12% oxygen concentration stipulated by FAA.
Research limitations/implications
The research results in this paper will be of good reference value to the design of the inert system and the calculation of the flammability exposure evaluation time. This paper aims to be good reference of the design of the inert system and the calculation of the flammability exposure evaluation time.
Originality/value
The research results of this paper can provide practical guidance for the current civil airworthiness certification work.
Details
Keywords
Lei Shao, Shiyu Feng, Chaoyue Li, Weihua Liu and Xuying Huang
This paper aims to improve the previous fuel scrubbing model and find out the relationship between bubble diameter and scrubbing efficiency (ƞ).
Abstract
Purpose
This paper aims to improve the previous fuel scrubbing model and find out the relationship between bubble diameter and scrubbing efficiency (ƞ).
Design/methodology/approach
A fuel tank scrubbing test bench was established to verify the accuracy of this model. Ullage and dissolved oxygen concentration were measured, and images of bubble size and distribution were collected and analyzed using image analysis software.
Findings
The bubble diameter has a great influence on ullage and dissolved oxygen concentration during the fuel scrubbing process. The scrubbing efficiency (ƞ) has an exponential relationship with bubble diameter and decreases rapidly as the bubble diameter increases.
Practical implications
The variation of the ullage and dissolved oxygen concentration predicted by this model is more accurate than that of the previous model. In addition, the study of bubble size can provide a guidance for the design of fuel scrubber.
Originality/value
This study not only improves the previous fuel scrubbing model but also develops a method to calculate scrubbing efficiency (ƞ) based on bubble diameter. In addition, a series of tests and analyses were conducted, including numerical calculation, experiment and image analysis.
Details