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1 – 10 of over 4000Omar Alejandro Valdés-Saucedo, Liliana Judith Vázquez-Rodríguez, Brenda López-Zárate, Lorena Garza-Tovar, Nora Aleyda García-Gómez, Alfredo Artigas, Alberto Monsalve, Javier H. Humberto Ramírez-Ramírez, Francisco Aurelio Pérez-González, Rafael Colás and Nelson Federico Garza-Montes-de-Oca
This paper aims to analyse the surface evolution of pure recycled titanium subjected to isothermal and cyclic oxidation conditions using dry air as oxidant gas. It is important to…
Abstract
Purpose
This paper aims to analyse the surface evolution of pure recycled titanium subjected to isothermal and cyclic oxidation conditions using dry air as oxidant gas. It is important to mention that the cyclic oxidation behaviour of pure titanium is a process that has been barely studied.
Design/methodology/approach
An isothermal and cyclic oxidation reactor was built for these purposes. This installation allows the oxidation of material under the action of any atmosphere and for temperatures up to 1,200°C. For this study, the oxidation behaviour of the material was studied at 850°C and 950°C.
Findings
Oxide growth under isothermal oxidation conditions in air follows a parabolic behaviour with an activation energy of 118 kJ/mol, and the oxide phase formed on the surface of the metal was rutile. The cyclic oxidation of the material indicates that oxide is spalled from the surface following linear behaviours; this phenomenon is controlled by the thermal stresses experienced by the samples during heating and cooling cycles.
Originality/value
The material is obtained from the production of electrolytic copper, and during its reprocessing practices at high temperature, it was thought that it could experience some abnormal oxidation. In addition, given that pure titanium is currently used for biomedical application, some surface degree can be given by means of oxidation and subsequent spallation process situation that is found during the cyclic oxidation experiments, which could be a low-cost method to engineer a surface for these purposes.
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Khushdeep Goyal, Hazoor Singh and Rakesh Bhatia
Molten sulphate-vanadate induced hot corrosion is the main reason of failure of boiler tubes used at high temperatures in thermal power plants. The hot corrosion can be…
Abstract
Purpose
Molten sulphate-vanadate induced hot corrosion is the main reason of failure of boiler tubes used at high temperatures in thermal power plants. The hot corrosion can be encountered by applying thermal spray coatings on the alloy steels. In this perspective, this paper aims to attempt to investigate the effect of carbon nanotubes reinforcement on Cr2O3 composite coatings on hot corrosion behaviour of ASTM-SA213-T22 steel in a corrosive environment of Na2SO4 – 60%V2O5 at 900°C for 50 cycles.
Design/methodology/approach
The coatings have been deposited with high velocity oxy fuel process. The samples were exposed to hot corrosion in a Silicon tube furnace at 900°C for 50 cycles. The kinetics of corrosion behaviour were analysed by the weight gain measurements after each cycle. Corrosion products were analysed with X-ray diffraction, scanning electron microscopy, energy dispersive and cross-sectional analysis techniques.
Findings
During investigations, the carbon nanotubes (CNT) reinforced Cr2O3 composite coatings on T22 steel were found to provide better corrosion resistance in the molten salt environment at 900°C. The coatings showed lower weight gain along with formation of protective oxide scales during the experiment. Improvement in protection against hot corrosion was observed with increase in CNT content in the coating matrix.
Research limitations/implications
The addition of CNT has resulted in reduction in porosity by filling the voids in chromium oxide coating, with interlocking of particle and has blocked the penetration of corroding species to enhance the corrosion resistance of the composite coatings. The corrosion rate was found to be decreasing with increase in CNT content in coating matrix.
Originality/value
It must be mentioned here that high temperature corrosion behaviour of thermally sprayed CNT-Cr2O3 composite coatings has never been studied, and it is not available in the literature. Hence, present investigation can provide valuable information for application of CNT-reinforced coatings in high temperature fuel combustion environments.
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Sandeep Kumar, Rakesh Bhatia and Hazoor Singh
In Indian thermal power plants, the main cause of boiler tube failure is the presence of molten sulphates and vanadates, which deteriorate the tube material at high temperatures…
Abstract
Purpose
In Indian thermal power plants, the main cause of boiler tube failure is the presence of molten sulphates and vanadates, which deteriorate the tube material at high temperatures. To combat the hot corrosion failure of metals, thermal spray technology is adopted. This study aims to investigate and study the effect of hot corrosion behaviour of carbon nanotube (CNT)-reinforced ZrO2-Y2O3 composite coatings on T-91 boiler tube steel in a molten salt environment at 900 °C for 50 cycles.
Design/methodology/approach
A plasma spray technique was used for development of the coatings. The samples were exposed to hot corrosion in a silicon tube furnace at 900 °C for 50 cycles. After testing, the test coupons were analysed by X-ray diffraction, scanning electron microscopy/energy dispersive spectroscopy and cross-sectional analysis techniques to aid understanding the kinetics of the corrosion reaction.
Findings
CNT-based reinforced coatings showed lower weight gain along with the formation of protective oxide scales during the experimentation. Improvement in protection against hot corrosion was observed with increase in CNT content in the coating matrix.
Originality/value
It is pertinent to mention here that the high temperature behaviour of CNT-reinforced ZrO2-Y2O3 composite on T-91 steel at 900°C temperature in molten salt environment has never been studied. Thus, the present research was conducted to provide useful results for the application of CNT-reinforced composite coatings at elevated temperature.
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J.A. von Fraunhofer and G.A. Pickup
THE variation in weight gains of the binary (and ternary) iron alloys with change in the atmosphere composition clearly demonstrates the sensitivity of oxidation behaviour to…
Abstract
THE variation in weight gains of the binary (and ternary) iron alloys with change in the atmosphere composition clearly demonstrates the sensitivity of oxidation behaviour to conditions. In particular it can be seen from Figs. 3 and 4 that the presence of atmospheric pollutants (sulphur and nitrogen oxides, water vapour) markedly increases the oxidation rate in air. This is supported by the further marked increase in oxidation in flue gases produced by the presence of sulphur oxides. Oxidation in flue gases at 700°C is far greater than in air, Figs. 7 and 10 and Table 3. This is due to the formation of wustite which was not present in air‐formed oxide scales.
A.U. Malik, Rais Ahmad, Sharif Ahmad and Sultan Ahmad
Nickel aluminide coatings on mild steel have been prepared by pack cementation process. The high temperature oxidation behaviour of the coatings have been studied at 750°, 800…
Abstract
Nickel aluminide coatings on mild steel have been prepared by pack cementation process. The high temperature oxidation behaviour of the coatings have been studied at 750°, 800° and 850° in flowing air. The influence of different rare earth oxide addition on the oxidation rates of nickel aluminide coating on mild steel has also been investigated. The kinetic of the oxidation of nickel aluminide coating on mild steel, with or without addition of RE2O3 proceeds by a diffusion controlled mechanism as revealed by the parabolic nature of weight gain Vs time plots. At higher temperatures the oxidation rates of the nickel aluminide coatings are lowered down markedly irrespective of rare earth oxide concentration. The oxidation rates are significantly affected by the morphology of the oxide scales, in cases where the structure of oxide scales is not seriously disrupted due to decarburization, the oxidation rates are significantly reduced.
M.A. Quraishi and Hariom K. Sharma
Stainless steel 316 was coated with CeO2 and Y2O3 modified aluminide and titanium aluminide coatings. The coatings were prepared by the pack cementation method and the high…
Abstract
Stainless steel 316 was coated with CeO2 and Y2O3 modified aluminide and titanium aluminide coatings. The coatings were prepared by the pack cementation method and the high temperature oxidation behaviour of the coatings was investigated in an atmosphere containing a limited supply of air. The performance of the coatings was studied by measuring oxidation kinetics, and by scanning electron microscopic techniques. The oxidation rates of these coatings were reduced in the presence of CeO2 and Y2O3 due to better adherence of their oxide scales.
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Cleaning plays an extremely important part in the manufacture of metal components which are ultimately to be given a protective coating, since the presence of the smallest amount…
Abstract
Cleaning plays an extremely important part in the manufacture of metal components which are ultimately to be given a protective coating, since the presence of the smallest amount of scale, oxide, grease or dirt could cause poor adhesion, and corrosion can occur under the coat. Before the final finishing, most metal components undergo four processes—firstly, preliminary cleaning or decreasing to remove the heavy oils, greases and soils; secondly, pickling and bright dipping for the removal of oxide and scale; thirdly, polishing and mechanical finishing; fourthly, there is normally a hot alkali cleaning process, which must again be followed by an acid dip to ensure that any oxide is removed.
M. Adam Khan, S. Sundarrajan and S. Natarajan
The aim of this paper is to study the hot corrosion behaviour of super 304H stainless steel for marine applications.
Abstract
Purpose
The aim of this paper is to study the hot corrosion behaviour of super 304H stainless steel for marine applications.
Design/methodology/approach
The investigation was carried out with three different combinations of salt mixture (Na2SO4, NaCl and V2O5) at two different temperatures (800 and 900°C).
Findings
The spalling and growth of oxide layer was observed more with the presence of V2O5 in the salt mixture at 900°C during experimentation than what was observed in 800°C. The mass change per unit area is calculated to study the corrosion kinetics and also the influence of salt mixture. Further, the samples are analysed through materials characterisation techniques using optical image, scanning electron microscope (SEM), energy dispersive X-ray (EDAX) and X-ray diffraction (XRD) analysis. The presence of V2O5 in the salt mixture was the most important influencing species for accelerating hot corrosion.
Originality/value
SEM, EDAX and XRD analysis confirmed the formation of Fe2O3 and Cr2O3 at 900°C showing contribution in corrosion protection.
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Somrerk Chandra-Ambhorn, Sompong Chueaprakha and Thamrongsin Siripongsakul
The dissimilar welds between AISI 304L and Fe-15.6Cr-8.5Mn were investigated on oxidation at 700°C with the effects of dissolved nitrogen in the welds. This paper aims to clarify…
Abstract
Purpose
The dissimilar welds between AISI 304L and Fe-15.6Cr-8.5Mn were investigated on oxidation at 700°C with the effects of dissolved nitrogen in the welds. This paper aims to clarify the oxidation behaviors to expand the range of application for Fe-Cr-Mn stainless steel.
Design/methodology/approach
Dissimilar welds between AISI 304L and Fe-15.6Cr-8.5Mn were fabricated using gas tungsten arc welding to investigate the oxidation behavior of the welds at 700°C. Pure Ar and Ar-4%N2 shielding gases were used to evaluate the effects of nitrogen gas. The welds were introduced to the cyclic oxidation test. In each cycle, the furnace was heated up to 700°C, and the temperature was kept at 700°C for 8 h, then the mass gain because of oxidation was examined. The scales after oxidation test were investigated by using scanning electron microscopy with EDX and X-ray diffraction analysis.
Findings
Addition of 4 per cent nitrogen to Ar shielding gas reduced delta-ferrite content in the weld. Ar-4%N2 shielding gas resulted in dissolved nitrogen which helped increase the diffusivities of chromium or oxygen vacancies in the oxide to facilitate the chromia formation at the inner part near the steel substrate. This protective layer can help reduce the Fe outward diffusion, thus reducing mass gain because of iron oxide formation.
Originality/value
The oxidation behavior of dissimilar welds between AISI 304L and Fe-15.6Cr-8.5Mn were investigated at 700°C. The evaluation is beneficial for expanding the range of application of Fe-Cr-Mn stainless steel at high temperature.
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Alejandro Garza-Caballero, Gina Idárraga-Ospina, Nora A. García-Gomez, Francisco Aurelio Pérez-González, Maribel De-la-Garza-Garza, Alfredo Artigas, Alberto Monsalve, Rafael Colás and Nelson Federico Garza-Montes-de-Oca
High silicon amorphous steels are gaining preference as the material of choice for the fabrication of the core of low and medium power electrical transformers because they present…
Abstract
Purpose
High silicon amorphous steels are gaining preference as the material of choice for the fabrication of the core of low and medium power electrical transformers because they present a better electromagnetic behaviour compared to that offered by common grain-oriented and non-oriented high silicon steels. This study aims to investigate the effects that the environmental conditions present during the high temperature annealing of cores exert on the surface oxidation and electromagnetic changes experienced by a commercial amorphous steel alloy.
Design/methodology/approach
The effect of environmental impact on the correct development of annealing practices during the manufacture process of amorphous steel cores used in distribution transformers was studied by the development of an oxidation reactor. With this installation, it was possible to simulate environmental conditions that could affect the surface of magnetic cores made from amorphous steel.
Findings
It was found that: the surface oxidation of amorphous steels affects their electromagnetic behaviour, environmentally induced surface degradation can be modelled at laboratory scale and oxide formation does not affect the amorphous condition of the alloy.
Originality/value
The effect of surface oxidation induced by the existence of water vapour in the annealing process of cores made from amorphous steels and its impact on the electromagnetic behavior of these alloys has been barely studied.
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