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The purpose of this paper is to study the tribology behavior of steel–steel contact under the lubrication of water-based drilling mud with different oleic acid-filled microcapsules as lubricant additives.

A ball-on-disc tribometer was used to evaluate the lubrication properties of the steel–steel contact. The wear tracks of the worn surfaces were observed by a scanning electron microscope.

Results show that the dependence of both friction and wear on the category of additives shares a consistent pattern. In contrast to oleic acid and empty microcapsules, oleic acid-filled microcapsules achieve the best tribological performance which is related to the lubricant effect of oleic acid and the isolation and rolling abilities of microcapsules.

This study provides a helpful method of encapsulated lubricant additives to prolong lubrication performance for steel–steel contact.

This study has applied microcapsules to improve the tribological properties of drilling mud.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-08-2019-0320/

WO₃ particles were prepared by the sol-gel method. Tetraethyl silicate (TEOS) was used to obtain a SiO₂-coated WO₃ nanoparticle. Quantum chemical parameters of oleic acid, triethanolamine, glycerol and methyl pentane as dispersants were theoretically calculated. Tribological properties of SiO₂/WO₃ nanocomposite lubricant were carried out on an MRS-10A four-ball friction and wear tester.

The purpose of this study is to investigate the preparation and tribological properties of SiO₂/WO₃ nanocomposite lubricant.

The obtained SiO₂-coated WO₃ nanoparticle (nano-SiO₂/WO₃) with a particle size of about 70 nm. The calculated adsorption energy of triethanolamine on the surface of the steel ball is 554.6 eV, and triethanolamine is selected as the dispersant. The dispersion effect of SiO₂/WO₃ nanocomposite lubricant is good, which shows that triethanolamine oleate plays a good dispersion role in the preparation of lubricant, which is consistent with the calculation results of the adsorption capacity of dispersant. As a good auxiliary lubricant, SiO₂ can improve the tribological properties and wear resistance of WO₃.

Nanocomposite lubricants have been the focus of research in recent years, which could greatly reduce energy consumption. And the SiO₂/WO₃ exhibited excellent lubrication performance as a lubricant additive. The lubrication mechanism of SiO₂/WO₃ nanocomposite lubricant is the synergistic lubrication mechanism of friction film lubrication and antifriction bearing. This study could provide a certain reference for the practical application of nanocomposite lubricants.

The purpose of this paper is to understand the impacts of oleoyl glycine on biodegradation, friction and wear performances of a mineral lubricating oil.

The biodegradabilities of a neat oil and its formulations with oleoyl glycine were evaluated on a biodegradation tester and the microbial characters in the biodegradation sewage observed through a microscope. Also, the friction and wear performances of neat oil and the formulated oil were determined on a four‐ball tribometer. The morphologies and tribochemical features of the worn surfaces were analyzed by scanning electron microscopy and X‐ray photoelectron spectroscopy.

Oleoyl glycine markedly enhanced biodegradation of unreadily biodegradable mineral oil and effectively improved its anti‐wear and friction‐reducing abilities. The enhancement of biodegradability of the mineral oil was preliminarily ascribed to the increment of microbial populations in the biodegradation processes, while the improvement of anti‐wear and friction‐reducing abilities was mainly attributed to the formation of a boundary adsorption film of oleoyl glycine on the friction surfaces.

Oleoyl glycine is a biodegradable and low eco‐toxic compound. The authors' work has shown that oleoyl glycine is effective in improving biodegradability and tribological performances of mineral lubricants. Enhancing biodegradability of petroleum‐based lubricants by additives is a new attempt. The paper has significance for improving ecological and tribological performances of mineral lubricants, even for developing petroleum‐based biodegradable lubricants.

Although this series was concluded in our August issue, by the following further contribution has been received from Mr. Griffiths. This article can be read independently from the previous four, but nevertheless, we think should be included in the series.

This paper aims to formulate a new metal working fluid (MWF) composition including some eco-friendly emulsifiers, corrosion inhibitor, biocide, and non- edible vegetable oil (castor oil) as the base oil. To achieve this aim, five MWFs with different hydrophilic–lipophilic balance (HLB) value as 10, 9.5, 9, 8.5 and 8 were prepared to identify the optimum HLB value that gives a highly stable oil-in-water emulsion. The performance of castor oil based MWF was evaluated using tool chip tribometer and drill dynamometer. The surface morphology of steel disc and friction pin was performed using scanning electron microscope (SEM) and 3D profilometer. The results revealed that the use of the prepared cutting fluid (E1) caused the cutting force to decrease from 500 N for dry high-speed steel sample to 280N, while the same value for a commercial cutting fluid (COM) was recorded as 340 N at drilling speed and cutting feed force as 1120 rpm and 4 mm/min., respectively.

A castor oil-based metalworking fluid was prepared using nonionic surfactants. The composition of the metalworking fluid was further optimized by adding performance-enhancing additives. The performance of castor oil based MWF was analyzed using Tool chip tribometer and Drill dynamometer. The surface morphology of steel ball and a disc was done using 3D profilometer and SEM.

Studies revealed that castor oil-based MWF having Monoethanolamine (MEA) as corrosion inhibitor was found to be highly stable. The drilling dynamometer and tool chip tribometer studies showed that castor oil-based MWF performance was comparable to that of commercial MWF.

This study aims to explore the performance of the castor oil based metalworking fluid (MWF) using tool chip tribometer and drill dynamometer.

The conventional MWFs are petroleum derives and are unsustainable. Use of non-edible plant-based oils for preparing the MWF will not only be conserved environment but also add value addition to agricultural crops.

The social Implications is aiming to decrease the environmental impact that results from the using of mineral cutting fluids.

The originality of this work is to replace the mineral oil and synthetic oil based cutting fluids with more eco-friendly alternatives one. In addition, the investigation will focus on developing functional additives required for cutting fluids which are environmentally benign.

A number of oleochemicals have found application in the formulation of metal processing lubricants. Calcium palmitate can act as a gelling inhibitor for lubricants for non‐chip metal forming, and diglyceryl oleate and sodium oleyl sulphate have been employed in chipless forming and machining lubricants. Glyceryl monooleate has been used together with paraffin wax and xylene for forming aluminium sheets, and isopropyl oleate has been blended into lubricants for cold forming of metal. Lubrication in cold forming of steel and aluminium alloys has been promoted by the use of sodium stearate and phosphating processes. Stearic acid has also been utlized in metal forming. Butyl butanamine stearamide is applicable in lubricants for non‐ferrous metal working, and coatings that can prevent galling when titanium is cold worked can be formed on the metal by the use of 0.5 grams of hydrofluoric acid, with 10 grams stearic acid in 100 ml. of a solvent, the process being accelerated by the inclusion of phosphoric acid at 0.85 grams. Calcium stearate has also been used in solvent‐based metalworking Iubricants, in acrylic electrophoretic lubricant coatings on metal, and in bentonite‐containing metalworking oils. Mixtures of cetyl alcohol and tricresyl phosphate have been cast into slabs and used on metalworking tools.

This paper aims to understand the influences of tris (2-hydroxyethyl) isocyanurate oleate and oleic acid tris (2-hydroxyethyl) isocyanurate phosphate ester on biodegradability and tribological performances of mineral lubricating oil.

Tris (2-hydroxyethyl) isocyanurate oleate and oleic acid tris (2-hydroxyethyl) isocyanurate phosphate ester were prepared and characterized by Fourier transform infrared spectrometer. The biodegradability and tribological properties of neat oil and its formulations were studied on a tester for fast evaluating biodegradability of lubricants and a four-ball tester, respectively. The worn surfaces were investigated by scanning electron microscope and X-ray photoelectron spectroscope.

Tris (2-hydroxyethyl) isocyanurate oleate and oleic acid tris (2-hydroxyethyl) isocyanurate phosphate ester both improved markedly the biodegradability, the anti-wear properties, friction-reducing properties and extreme pressure properties of base oil. The effect of oleic acid tris (2-hydroxyethyl) isocyanurate phosphate ester was better than tris (2-hydroxyethyl) isocyanurate oleate. The improvement of tribological performances was mainly ascribed to the formation of a complicated boundary lubrication film of tris (2-hydroxyethyl) isocyanurate oleate and oleic acid tris (2-hydroxyethyl) isocyanurate phosphate ester on the friction surfaces.

This paper has indicated that tris (2-hydroxyethyl) isocyanurate oleate and oleic acid tris (2-hydroxyethyl) isocyanurate phosphate ester effectively improve the biodegradability and tribological performances of mineral lubricating oil. Promoting biodegradation of mineral lubricant by additives is very significant for the development of petroleum-based biodegradable lubricants. These two additives not merely improve the tribological performances; more importantly, they improve the ecological performances.

Oleochemicals can be made from the components of renewable animal, marine and vegetable oils and fats. This oleochemical group of products is a large one, comprising fatty acids, glycerol and numerous derivatives of these including fatty alcohols, fatty esters, and nitrogen‐, phosphorus‐and sulphur‐containing materials. Polyoxyalkylated end products from the above, from heavy metal and water‐soluble soaps, epoxidised chemicals, polymer components, and the quarternary ammonium compounds are found. The oleochemicals of interest to the lubricants manufacturer are those which function in some specific manner. Anti‐corrosive, anti‐oxidant, anti‐squawk, anti‐stick, anti‐sludge, anti‐wear detergent, dispersant and oiliness agents, pour point depressants and viscosity modifying materials, are examples.

The purpose of this study is to synthesise and characterise surface-capped molybdenum sulphide (SCMS) nanoparticles using the solvothermal method and to investigate their tribological behaviour towards friction improver and wear reduction for bio-based lubricant oil additives.

The design of the experiment was to use freshly prepared molybdenum (II) acetate, thioacetamide, fatty acid and hexane as the solvent inside an autoclave vessel which is heated at high temperature and pressure. Various types of fatty acids were used as the capping agent, such as caproic, lauric, stearic and oleic acid. The SCMS nanoparticles formed were characterized by Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray diffractometry, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy and thermal gravimetric analysis. These nanoadditives were then blended into pentaerythrityl tetracaprylate/caprate ester at 0.05 Wt.% concentration. The formulated bio-based lubricant oil samples were tested for viscosity, viscosity index (VI) and density based on standard method ASTM D445 and ASTM D2270. A four-ball test was carried out for determination of coefficient of friction and wear scar diameter. The wear scar formed on the surface of the ball bearing was analysed using scanning electron microscopy.

The characterisation results showed that SCMS nanoparticles were successfully formed with amorphous ball-like structure, and the presence of the capping layer surrounding the nanoparticles was confirmed. Then, the formulated bio-based lubricant oil with addition of nanoadditives displays improved tribological properties in term of VI, antifriction and wear reduction.

This research provides a synthesis method of producing SCMS nanoparticles using the organomolybdenum complex as the chemical precursor through the solvothermal reaction approach. Besides that, it also gives an alternative antifriction and antiwear nanoadditive for formulation of the bio-based lubricant oil.

IN THE DIVISION of organic chemicals into aromatics (benzene derivatives) and aliphatics (methane derivatives or fatty compounds), it has been found with reference to the last‐named that oleic acid is the most widespread of all the natural fatty acids. This acid accounts for more than 30 per cent of total fatty acids found in combination in many fats and oils, while its presence has been noted in all the natural fats and oils known to man.