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To investigate the effect of halide ions on the corrosion inhibition of mild steel using polyvinyl alcohol (PVA) in H₂SO₄ at 30‐60°C and to study the mechanism of action.

The corrosion rates were determined using the gravimetric (weight loss) and gasometric (hydrogen evolution) techniques. The results obtained in the absence and presence of PVA, halides, PVA – halides combination were used to calculate the inhibition efficiency (%I), degree of surface coverage and to propose the mechanism of inhibition and type of adsorption.

Results obtained showed that inhibition efficiency (%I) increased with the increase in concentration of PVA, on the addition of halides and with the increase in temperature. Phenomenon of chemical adsorption was proposed and PVA was found to obey Langmuir, Flory‐Huggins and Freundlich adsorption isotherms. The synergism parameter, S₁, evaluated was found to be greater than unity and the values of E_a, ΔH°, ΔS° and ΔG° obtained revealed that the adsorption process was spontaneous.

Electrochemical studies such as polarization and AC impedance spectra will enlighten more on the mechanistic aspects of the corrosion inhibition and more polymers need to be evaluated as corrosion inhibitors.

PVA can be used as corrosion inhibitor and the addition of halides to PVA improves the inhibition efficiency considerably.

This paper provides new information on the effects of halides on the corrosion inhibition using PVA as an inhibitor for mild steel in acidic medium. Such a study had not been reported elsewhere.

The purpose of this study is to investigate starch mucor (SM) in potassium iodide (KI) as corrosion inhibitor of aluminium in hydrochloric acid (HCl) medium.

The SM in KI was characterized by gravimetric, scanning electron microscopy, electrochemical impedance spectroscopy measurements, potentiodynamic polarization and gas chromatography-mass spectrometer techniques. The inhibition efficiency was optimized using response surface methodology.

The result revealed that the inhibitor inhibited corrosion at a low concentration with the rate of inhibition increasing as the concentration of the inhibitor increased. The inhibition efficiency increases as the temperature was increased with slight incorporation of the inhibitor (SM in KI). This indicates that the corrosion control is both inhibitor (SM in KI) and temperature dependent.

The research results can provide the basis for using SM in KI as corrosion inhibitor of aluminium in HCL medium. Mixed-type inhibitor nature of SM was proved by cathodic and anodic nature of the polarization curves.

To investigate the inhibitive effect of gum arabic (GA) for the corrosion of aluminium in alkaline (NaOH) medium and determine its adsorption characteristics. The present work is another trial to find a cheap and environmentally safe inhibitor for aluminium corrosion.

The inhibition efficiency (%I) has been evaluated using the hydrogen evolution (via the gasometric assembly) and the thermometric methods at 30 and 40°C. The concentrations of GA (inhibitor) used were 0.1‐0.5 g/l and the concentrations of NaOH (the corrodent) were 0.1‐2.5 M. The mechanism of adsorption inhibition and type of adsorption isotherms were proposed from the trend of inhibition efficiency with temperature, E_a, ΔG_ads and Q_ads values.

GA inhibited the corrosion of aluminium in NaOH solutions. The inhibition efficiency increased with increase in GA concentration and with increase in temperature. Phenomenon of chemical adsorption is proposed for the inhibition and the process followed the Langmuir and Freundlich adsorption isotherms. The results obtained in this study for the %I were comparable for the two methods used and were corroborated by kinetic and thermodynamic parameters evaluated from the experimental data.

Further investigations involving electrochemical studies such as polarization method will enlighten more on the mechanistic aspect of the corrosion inhibition.

This paper provides new information on the possible application of GA as an environmentally friendly corrosion inhibitor even in highly aggressive alkaline environments. It has not been published elsewhere.

The paper aims to investigate the effectiveness of hydroxypropyl methylcellulose (HPMC) as corrosion inhibitor for aluminium in 0.5 M H₂SO₄ solution.

This study was carried out using weight loss and electrochemical techniques. Inhibition efficiency was determined by comparing the corrosion rates in the absence and presence of inhibitor system. Quantum chemical computations were performed using density functional theory to assess the parameters responsible for the inhibition process and also to analyse the local reactivity of the molecule.

HPMC inhibited aluminium corrosion in the acidic environment. The inhibition efficiency was found to depend on concentration of the inhibitor. Impedance results reveal that HPMC is adsorbed on the corroding metal surface. Polarization results show that the dissolution reaction is due to destabilization of the passive oxide film on the Al surface. Adsorption of the inhibitor is approximated by Freundlich adsorption isotherm and the calculated standard free energy of adsorption indicates weak physical interaction between the inhibitor molecules and aluminium surface. This can be attributed to preferential interaction of the active sites with the passive oxide layer. The calculated quantum chemical parameters show good correlation with the inhibition efficiency.

HPMC could find possible application as a polymeric thickener and additive to improve corrosion resistance and barrier properties of anticorrosion paints.

This paper provides novel information on the inhibitive characteristics of HPMC under the stated conditions. The inhibitor systems provide an effective means for suppressing aluminium corrosion even in highly aggressive acidic environments.

To determine the inhibition efficiency and adsorption characteristics of two water soluble polymers namely polyvinyl alcohol (PVA) and polyethyleneglycol (PGE) as corrosion inhibitors of mild steel in H₂SO₄.

The inhibition efficiencies of PVA and PEG were evaluated using the weight loss and hydrogen evolution techniques at 30‐60°C.

The inhibition efficiency (I per cent) of the inhibitors increased with increase in concentration and temperature. The inhibitors (PVA and PEG) were found to obey Temkin, Freundlich and Langmuir adsorption isotherms from the fit of the experimental data at all concentrations and temperatures studied. The phenomenon of chemical adsorption is proposed from the activation parameters obtained. PEG was found to be a better inhibitor than PVA.

The mechanistic aspect of the corrosion inhibition can be better understood using electrochemical studies such as polarization and AC impedance spectra.

The findings may be useful in cooling water systems in industries under simulated conditions.

This paper provides additional new information on the inhibiting characteristics of PVA and PEG as promising corrosion inhibitors.

The purpose of this paper is to investigate the effect of polyethylene glycol (PEG), polyvinylpyrrolidone (PVP) and blended formulations on the corrosion inhibition of aluminium in HCl solutions at 30-60°C and to study the mechanism of action.

The inhibitive effect of the homopolymers and polymer blend was assessed using weight loss and hydrogen evolution methods at 30 and 60°C. The morphology of the corroding aluminium surface without and with the additives was visualized using atomic force microscopy. The trend of inhibition efficiency with temperature was used to propose the mechanism of inhibition and type of adsorption.

Results obtained show that inhibition efficiency (η%) increases with increase in concentration of the polymers but decreases with increase in temperature. The inhibition efficiency of the homopolymers and their blends decreased with rise in temperature. Inhibition efficiency was found to be synergistically enhanced on blending the two homopolymers with highest inhibition efficiency obtained for (PEG:PVP) blending ratio of 1:3. The phenomenon of physical adsorption is proposed from the trend of inhibition efficiency with temperature.

The mechanistic aspect of the corrosion inhibition can be better understood using electrochemical studies such as potentiodynamic polarization and electrochemical impedance spectroscopy.

Studies involving the use of polymer blends/mixtures as corrosion inhibitor for metals in corrosive environments are scarce. The results suggest that the mixture could find practical application in corrosion control in aqueous acidic environment. The data obtained would form part of database on the use of polymer–polymer mixtures to control acid-induced corrosion of metal.

In the “dry” state, pigment particles are held together by attraction forces of various physical chemical natures including the van der Waals force and the “liquid bridge” force. These attraction forces must be overcome in order to disperse pigment particles into liquid media. Dispersion machinery is designed to generate energy required to overcome, to various extents, such attraction forces. On the other hand, the efficiency of dispersion operation is significantly dependent upon the effectiveness of the transfer of energy from the dispersion tools/dispersion charges to the oversized pigment particles, as a result of the presence of the adhesion and cohesion within the dispersion system. This paper explores the nature and the significance of various forces between pigment particles and of the adhesion and cohesion phenomena associated with pigment dispersion, from a practical point of view. Principles relevant to improving the efficiency of pigment dispersion via minimisation of the adhesion between pigment particles and via maximisation of the adhesion and cohesion within the dispersion system are also discussed.

Sinusoidal signals are often used as the inputs of the six degree of freedom (DOF) motion simulator platforms. The purpose of this paper is to propose a fuzzy incremental controller (FIC) to improve sinusoidal signal tracking performances of an electrohydraulic Gough-Stewart platform (GSP).

An FIC is proposed to control an electrohydraulic GSP without any model parameters. The FIC output can be self-organized by only using the hydraulic actuator position information. The control rules are determined by a systematic deterministic method.

Experimental results show that the proposed FIC is valid and can achieve better tracking performances compared with classical PID controller and a decoupling controller (a model-based controller).

An FIC using a systematic deterministic rule-base determination method is proposed to improve sinusoidal signal tracking performances of electrohydraulic GSP.

The purpose of this paper is to investigate the effect of Raphia hookeri exudate gum and halide ions on the corrosion inhibition of aluminium in HCl solutions at 30‐60°C and to study the mechanism of action.

The corrosion rates were determined using the gravimetric (weight loss), gasometric (hydrogen evolution) and thermometric techniques. The results obtained in the absence and presence of Raphia hookeri, halides and Raphia hookeri – halides combination were used to calculate the inhibition efficiency (%I), degree of surface coverage and to propose the mechanism of inhibition and type of adsorption.

Results obtained showed that the Raphia hookeri exudates gum acted as an inhibitor for aluminium corrosion in acidic environment. Inhibition efficiency (%I) increased with increase in concentration of the Raphia hookeri exudates gum and synergistically increased to a considerable extent on the addition of halide ions. The increase in inhibition efficiency (%I) and surface coverage (θ) in the presence of the halides was found to be in the order I⁻ > Br⁻ > Cl⁻ which indicates that the radii as well as electronegativity of the halide ions play a significant role in the adsorption process. Raphia hookeri exudates gum obeys Freundlich, Langmuir and Temkin adsorption isotherms. Phenomenon of physical adsorption is proposed from the values of kinetic/thermodynamic parameters obtained. The values of synergism parameter (S_I) obtained for the halides are greater than unity suggesting that the enhanced inhibition efficiency of the Raphia hookeri caused by the addition of the halide ions is only due to synergistic effect.

Electrochemical studies such as polarization and AC impedance spectra will throw more light on the mechanistic aspects of the corrosion inhibition and more exudate gums need to be evaluated as corrosion inhibitors.

Raphia hookeri exudate gum can be used as corrosion inhibitor and the addition of halides to it improves the inhibition efficiency considerably.

This paper provides new information on the use of exudate gums as corrosion inhibitors and addition of halides in acidic medium. This environmentally friendly inhibitor could find possible applications in metal surface anodizing and surface coatings.

The purpose of this paper is to study the inhibitive and adsorptive characteristics of ethanol extract of Gongronema latifolium (GL) as a corrosion inhibitor for mild steel in H₂SO₄.

The inhibition efficiencies were evaluated using thermometric and hydrogen evolution techniques.

The inhibition efficiency of ethanol extract of GL vary with concentration of the extract, period of immersion and with temperature. The extract acts as an inhibitor because of its phytochemical and amino acid composition. The extract is adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherm. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of some kinetic and thermodynamic parameters obtained.

The study provides information on the use of ethanol extract of GL as a corrosion inhibitor. Electrochemical studies such as polarisation and alternating current impedance spectra will throw more light on the mechanistic aspects of the corrosion inhibition.

Ethanol extract of GL can be used as an environmentally friendly inhibitor for the corrosion of mild steel in H₂SO₄.

This environmentally friendly inhibitor could find possible applications in metal surface anodising and surface coatings.