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The impact of climate change towards water surface resources is crucial, particularly in developing and non-developing countries. Groundwater as a main water resource is thus an essential. However, contamination due to hydrocarbon spills affects the groundwater as a water resource, especially as a main source of drinking water. This chapter investigates the light non-aqueous phase liquid (LNAPL) penetrations in double-porosity soil with different moisture contents and with or without vibration impact. It also explains the LNAPL penetration phenomena by employing image analysis. The physical laboratory experiments were implemented using an acrylic cylinder, a mirror, toluene and a Nikon D90 DSLR digital camera. Prepared soil was poured in an acrylic cylinder and compressed with compressor until it became 10 cm in height. LNAPL was then poured instantaneously onto the acrylic cylinder that was filled with soil sample. The LNAPL penetration patterns were recorded and monitored using a Nikon D90 DSLR digital camera. The processing technique was conducted at predetermined time intervals using Surfer software and Matlab routine to plot the LNAPL pattern. The results showed that a higher penetration rate of LNAPL occurred with higher moisture content and without vibration impact. The penetration time for LNAPL to reach the bottom of the soil sample was found to be longer for the soil that had low moisture content and with vibration impact.

Textile industry is considered to be one of the largest consumers of water. There needs to be an alternative for water in textile wet processing. Solvent dyeing can be an approach to replace the use of water in dyeing for water conservation.

In this study, the dyeing of polyester was carried out using conventional and solvent dyeing methods. The solvent used was non-aqueous, deep eutectic solvent (DES) prepared using choline chloride and urea. Dyeing parameters such as time, temperature and pH were optimized for a concentration of dye using the solvent and were compared with the conventional dyeing.

The prepared solvent was characterized in terms of Fourier-transform infrared resonance and ¹H and ¹³C nuclear magnetic resonance to analyze the reaction between choline chloride and urea. Dyeing performance in terms of K/S and fastness properties of dyed fabrics were evaluated and found to be at par against conventional dyeing.

Use of DES as a dyeing medium is a novel approach in the textile industry.

The evolution in developed countries has taken a role in global warming and natural disasters such as flash flood, El-Nino, earthquake and groundwater contamination. The underground storage tank leakage problems and spillage of hydrocarbon liquid leading to the contamination of non-aqueous phase liquids (NAPLs) into the groundwater could reduce the quality of groundwater. This chapter is intended to investigate the behaviour and the pattern of NAPL migrations in double-porosity soil under vibration and intact conditions. The experimental model is developed by using kaolin soil type S300 and toluene as NAPLs. The kaolin soil was mixed with 25% of moisture content to produce kaolin granules in the soil column and vibrate under 0.98 Hz of frequency within 60 seconds. As a result, both specimen liquids completely migrated to the bottom of soil column: sample 1 has higher permeability compared to sample 2. This is due to the fracture in double-porosity soil under vibration effect and loosened the soil structure in sample 1 compared to good intact soil sample 2 with stronger and compact soil structure. In conclusion, this study proves that the dangerous hydrocarbon NAPL migration in fractured double-porosity soil has very harmful effect on the environment and groundwater resources.

This series of articles is based on the new 64pp booklet prepared by the author, aided by many of his colleagues in Tioxide International Ltd, and published last month under the title “Dispersion of Tioxide Pigments in Non‐Aqueous Media”. The book describes the principles of dispersion and gives practical advice to help coatings chemists disperse Tioxide pigments in the most efficient and economical manner possible. Section A defines dispersion and gives a brief explanation of mechanisms that may be concerned in the production of a stable dispersed system. It presents an outline scheme for the formulation of millbases that can be applied to all combinations of titanium dioxide pigments and resins. The effects of resins, solvents, and “dispersing aids” are also considered. Section B describes the types of paintmaking machine used in the industry today. The sections of the original book to be ommitted from the series of articles to be published in the journal are those that it is considered have already been adequately covered in the literature.

Acrylic resins are formulated into protective coatings in several ways. Most important volumewise are waterborne formulations based either on pure acrylics or on acrylic‐vinyl copolymers. Second most important are solvent‐based enamels and lacquers widely used for product finishes particularly in the automotive and appliance industries. An innovation of a decade or so ago is proving popular in this area, namely two component coatings based on hydroxyl‐containing acrylics and di‐ or polyisocyanates. These combine many of the good features of acrylics and urethanes and provide hard thermoset coatings. Yet they cure at temperatures as low as ambient.

There are many methods by which the state of dispersion of pigments may be studied, either in the liquid paint or in the dried film. They range from essentially practical methods useful for production control to sophisticated laboratory techniques capable of providing quantitative data on the number, size, and type of particles present in a dispersion.

Of the mass production industries, the Automobile Industry is perhaps the leader in demanding a high standard of finish appearance and finish performance for its product. This is to be expected, considering the prestigious nature of the product and cost of the motor car, and the increasing impact of consumerism in all the major markets of the world.