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Long time ago, multistructured materials showed great interest being considered as the bridge between bulk and atomic materials. Core-shell particles are kind of composite materials that refer to multilayered structures with a core totally surrounded by shell(s) (onion-like structure). These new structures can offer an advantage of applying new adjustable parameters like shape, stoichiometry and chemical ordering, in addition to the opportunity of tailoring more complexed structures for different applications. Recently it was found that these structures can be tuned and taken for more advanced path with novel structures formed of core surrounded by multishells. The purpose of this study is to study the effect of the new anticorrosive pigments with its mutual shells and how each shell affects the performance of the pigment in protecting the metal and which shell will be more relevant in its effect.

The prepared pigments were characterized using X-ray fluorescence, X-ray diffraction, TEM and SEM/EDX to prove their core-shell structure, and then they were integrated in coating formulations to evaluate their anticorrosive activity using immersion test and electrochemical impedance spectroscopy (EIS).

The results showed that the prepared core-shell pigments possess a lot of unique characteristics and can offer improved anticorrosive performance in the generated coatings.

Core-mutual shells structured pigments were prepared for improving the corrosion resistivity of the organic coatings as a new trend in anticorrosive pigments.

This study aims to understand the current production scenario emphasizing the significance of green manufacturing in achieving economic and environmental sustainability goals to fulfil future needs; to determine the viability of particular strategies and actions performed to increase the process efficiency of electrical discharge machining; and to uphold the values of sustainability in the nonconventional manufacturing sector and to identify future works in this regard.

A thorough analysis of numerous experimental studies and findings is conducted. This prominent nontraditional machining process’s potential machinability and sustainability challenges are discussed, along with the current research to alleviate them. The focus is placed on modifications to the dielectric fluid, choosing affordable substitutes and treating consumable tool electrodes.

Trans-esterified vegetable oils, which are biodegradable and can be used as a substitute for conventional dielectric fluids, provide pollution-free machining with enhanced surface finish and material removal rates. Modifying the dielectric fluid with specific nanomaterials could increase the machining rate and demonstrate a decrease in machining flaws such as micropores, globules and microcracks. Tool electrodes subjected to cryogenic treatment have shown reduced tool metal consumption and downtime for the setup.

The findings suggested eco-friendly machining techniques and optimized control settings that reduce energy consumption, lowering operating expenses and carbon footprints. Using eco-friendly dielectrics, including vegetable oils or biodegradable dielectric fluids, might lessen the adverse effects of the electrical discharge machine operations on the environment. Adopting sustainable practices might enhance a business’s reputation with the public, shareholders and clients because sustainability is becoming increasingly significant across various industries.

A detailed general review of green nontraditional electrical discharge machining process is provided, from high-quality indexed journals. The findings and results contemplated in this review paper can lead the research community to collectively apply it in sustainable techniques to enhance machinability and reduce environmental effects.