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Article
Publication date: 29 June 2010

Z. Abdel Hamid and A. Abdel Aal

The purpose of this paper is to investigate the deposition of uniform, adherent and crack‐free Ni‐P thin films on carbon fibres using the electroless deposition technique.

Abstract

Purpose

The purpose of this paper is to investigate the deposition of uniform, adherent and crack‐free Ni‐P thin films on carbon fibres using the electroless deposition technique.

Design/methodology/approach

Before applying the electroless process, the carbon fibre surfaces must be subjected to several treatment processes to remove the organic binder, etching and surface metallization. The surface morphology of the Ni‐P coatings was assessed using a scanning electron microscope (SEM). The chemical compositions of Ni‐P layers were identified by energy dispersive X‐ray analysis (EDS). The bond strength of the coated layer was determined by measuring the electrical resistance at the fibre/coating interface. The magnetic properties of the fibres were estimated using a hysteresis diagram. The tensile performance of single fibres coated by Ni‐P has been investigated with respect to coating thickness.

Findings

Pre‐treatment processes are used to improve the adhesion of Ni‐P layers and to obtain homogeneous coatings. The influence of plating parameters (temperature, pH and time) on the coating thickness of the Ni‐P layer was investigated. It was found that the coating thickness increased as the pH value, plating time and the temperature of the bath increased. The results revealed that a complete and uniform Ni‐P coating on fibre could be obtained at optimum conditions 85°C, pH 6, for 60 min, and the results indicated that the P content in the electroless deposit is approximately 3.4 wt%. The tensile strength values are improved significantly after coating and increased by 3‐5 times with increasing of coating thickness from 0.3 to 2 μm.

Originality/value

The results presented in this work are an insight into understanding of the deposition and adherence of Ni‐P thin films on carbon fibre using the electroless technique and behaviour of the coated fibre.

Details

Anti-Corrosion Methods and Materials, vol. 57 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 March 1999

Paul T. Vianco

An overview has been presented on the topic of alternative surface finishes for package I/Os and circuit board features. Aspects of processability and solder joint reliability…

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Abstract

An overview has been presented on the topic of alternative surface finishes for package I/Os and circuit board features. Aspects of processability and solder joint reliability were described for the following coatings: baseline hot‐dipped, plated, and plated‐and‐fused 100Sn and Sn‐Pb coatings; Ni/Au; Pd, Ni/Pd, and Ni/Pd/Au finishes; and the recently marketed immersion Ag coatings. The Ni/Au coatings appear to provide the all‐around best options in terms of solderability protection and wire bondability. Nickel/Pd finishes offer a slightly reduced level of performance in these areas which is most likely due to variable Pd surface conditions. It is necessary to minimize dissolved Au or Pd contents in the solder material to prevent solder joint embrittlement. Ancillary aspects that include thickness measurement techniques; the importance of finish compatibility with conformal coatings and conductive adhesives; and the need for alternative finishes for the processing of non‐Pb bearing solders are discussed.

Details

Circuit World, vol. 25 no. 1
Type: Research Article
ISSN: 0305-6120

Keywords

Article
Publication date: 13 November 2007

Yingwu Yao

This paper aims to study the effect of SiO2 nano‐particulates on the corrosion behaviour of Ni‐W/SiO2 nanocomposite coatings.

Abstract

Purpose

This paper aims to study the effect of SiO2 nano‐particulates on the corrosion behaviour of Ni‐W/SiO2 nanocomposite coatings.

Design/methodology/approach

Weight loss measurements, electrochemical measurements and scanning electron microscope were used to study the corrosion behaviour of Ni‐W/SiO2 nanocomposite coatings in NaCl solution.

Findings

The incorporation of SiO2 nano‐particulates into the Ni‐W alloy matrix significantly increased the corrosion resistance. The improvement in corrosion resistance was due to the SiO2 nano‐particulates acting as physical barriers to the corrosion process by filling in crevices, gaps and microscopic holes on the surface of the Ni‐W alloy.

Originality/value

This study highlights the use of nano‐particulates for the control of Ni‐W alloy coating corrosion and opens a new route for industry in the anti‐corrosion field.

Details

Anti-Corrosion Methods and Materials, vol. 54 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 3 April 2019

Jashanpreet Singh, Satish Kumar and S.K. Mohapatra

This study/paper aims to investigate the erosion wear performance of Ni-based coatings [Ni-Cr-O and NiCrBSiFe-WC(Co)] under sand-water slurry conditions.

Abstract

Purpose

This study/paper aims to investigate the erosion wear performance of Ni-based coatings [Ni-Cr-O and NiCrBSiFe-WC(Co)] under sand-water slurry conditions.

Design/methodology/approach

A high-velocity oxy-fuel (HVOF) process was used to deposit the Ni-based coatings [Ni-Cr-O and NiCrBSiFe-WC(Co)] on the surface of stainless steel (SS 316L) substrate. A Ducom TR-41 erosion tester was used to conduct the tribological experiments on bare/HVOF coated SS 316L. The erosion wear experiments were carried out for different time durations (1.30-3.00 h) at different impact angles (0-60°) by running the pot tester at different rotational speeds (600-1,500 rev/min). The solid concentration of sand slurry was taken in the range of 30-60 Wt.%. The surface roughness of Ni-based coated surfaces was also measured along the transverse length of the specimens.

Findings

Results show the arithmetic mean roughness (Ra) values of Ni-Cr-O and NiCrBSiFe-WC coated SS-316L were 7.04 and 6.67 µm, respectively. The erosion wear SS-316L was almost 3.5 ± 1.5 times greater than that of the NiCrBSiFe-WC coatings. NiBCrSi-WC(Co) sprayed SS-316L showed lower erosion wear than Ni-Cr-O sprayed SS-316L. Microscopically, the eroded Ni-Cr-O coating underwent plowing, microcutting and craters. Ni-Cr-O coating have shown the ductile nature of erosion wear mechanism. NiBCrSi-WC(Co) surface underwent craters, plowing, carbide/boride pullout, fractures and intact. Erosion wear mechanisms on the eroded surface of NiBCrSi-WC(Co) were neither purely ductile nor brittle.

Practical implications

It is a useful technique to estimate the erosion wear of hydraulic machinery coated with Ni-based coatings imposed under mining conditions.

Originality/value

The erosion wear performance of HVOF-sprayed Ni-Cr-O and NiCrBSiFe-WC(Co) powders was investigated through extensive experimentation, and the results are well supported by scanning electron micrographs and 3D topology.

Details

Industrial Lubrication and Tribology, vol. 71 no. 4
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 29 June 2023

He Chuang, Wang Fan, Liu Zhicheng and Kong Dejun

The purpose of this study is to investigate the effect of laser scanning speed (LSS) on the corrosive-tribological performance of Ni-60%WC coating in Wusu mine water, which was…

Abstract

Purpose

The purpose of this study is to investigate the effect of laser scanning speed (LSS) on the corrosive-tribological performance of Ni-60%WC coating in Wusu mine water, which was beneficial to improve the friction–wear performance of cylinder liner on water injection pump.

Design/methodology/approach

Ni-60%WC coatings were fabricated on 45 steel by laser cladding, and the microstructure and tribological performance was analyzed using a super depth of field microscope and ball-on-plate friction tester, and the wear mechanism was also discussed.

Findings

At room temperature (RT, 25 ± 2 °C), the average coefficients of friction of substrate and Ni-60%WC coatings fabricated at the LSS of 6, 10, 12 and 14 mm/s are 0.48 ± 0.08, 0.23 ± 0.01, 0.21 ± 0.05, 0.22 ± 0.02 and 0.25 ± 0.04, respectively, and the corresponding wear rates are 8.755 × 104, 4.525 × 103, 1.539 × 103, 1.957 × 103 and 2.743 × 103 µm3·s–1·N–1, respectively, showing that the coating fabricated at the LSS of 10 mm/s has best friction reduction and wear resistance. The wear mechanism of Ni-60%WC coating is abrasive wear, fatigue wear and oxidative wear, which is resulted from the WC particles with the high-hardness.

Originality/value

Ni-60%WC coatings were first applied for cylinder liner, and the effect of laser scanning speed on its tribological performance was investigated.

Details

Industrial Lubrication and Tribology, vol. 75 no. 6
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 11 April 2023

Ronnarit Khuengpukheiw, Anurat Wisitsoraat and Charnnarong Saikaew

This paper aims to compare the wear behavior, surface roughness, friction coefficient and volume loss of high-velocity oxy-fuel (HVOF) sprayed WC–Co and WC–Cr3C2Ni coatings on…

Abstract

Purpose

This paper aims to compare the wear behavior, surface roughness, friction coefficient and volume loss of high-velocity oxy-fuel (HVOF) sprayed WC–Co and WC–Cr3C2Ni coatings on AISI 1095 steel with spraying times of 10 and 15 s.

Design/methodology/approach

In this study, the pin-on-disc testing technique was used to evaluate the wear characteristics at a speed of 0.24 m/s, load of 40 N and test time of 60 min under dry conditions at room temperature. The wear characteristics were examined and analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy. The surface roughness of a coated surface was measured, and microhardness measurements were performed on the cross-sectioned and polished surfaces of the coating.

Findings

Spraying time and powder material affected the hardness of HVOF coatings due to differences in the porosity of the coated layers. The average hardness of the WC–Cr3C2Ni coating with a spaying time of 15 s was approximately 14% higher than that of the WC–Cr3C2Ni coating with a spraying time of 10 s. Under an applied load of 40 N, the WC–Co coating with a spraying time of 15 s had the lowest variation in the friction coefficient compared with the other coatings. The WC–Co coating with a spraying time of 10 s had the lowest average and variation in volume loss compared to the other coatings. The WC–Cr3C2Ni coating with a spraying time of 10 s exhibited the highest average volume loss. The wear features changed slightly with the spraying time owing to variations in the hardness and friction coefficient.

Originality/value

This study investigated tribological performance of WC–Co; WC-Cr3C2-Ni coatings with spraying times of 10 and 15 s using pin-on-disc tribometer by rotating the relatively soft pin (C45 steel) against hard coated substrate (disc).

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 19 July 2018

Chaolei Ban, Shuqin Zhu, Jie Ma, Fangreng Wang, Zhengfeng Jia and Jie Wang

Ni coating was electroplated on carbon steel substrate to protect carbon steel.

Abstract

Purpose

Ni coating was electroplated on carbon steel substrate to protect carbon steel.

Design/methodology/approach

During electroplating, the ultrasonic irradiation (UI) (1 kHz) action was in situ used with different frequency. The influence of UI on the microstructure, mechanical and electrochemical performance of the coating was studied with scanning electron microscopy, X-ray diffraction, microhardness measurement, polarization curves and electrochemical impedance spectroscopy.

Findings

The results show that comparing that without UI imposition, UI during electroplating can refine the coating grain and decrease the micro-pores in the coating, resulting in improvement of the coating corrosion and hardness.

Originality/value

The imposition of UI action during electroplating Ni coating can remove intrinsic pores in the coating and compact the coating. The potential bimetallic cell between substrate and plating layer can be insulated to enhance the corrosion resistance of Ni coating. The imposition of UI action during electroplating Ni coating can refine Ni coating grain size and improve the coating haredness.

Details

Anti-Corrosion Methods and Materials, vol. 65 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 10 November 2020

Refaie Omar, Elsayed Oraby, Yasser Abdelrhman and Mohammed Aboraia

The ability to produce a uniform composition, high corrosion resistance with a hard coating layer during the electroless coating techniques are mainly based on the plating bath…

Abstract

Purpose

The ability to produce a uniform composition, high corrosion resistance with a hard coating layer during the electroless coating techniques are mainly based on the plating bath composition. The complexing agent is one of the most important components that control the coating layer properties. This paper aims to investigate the effect of the glycine as a complex agent on the surface and corrosion properties of Ni-P and Ni-P/Al2O3 electroless coating.

Design/methodology/approach

In this study, the effect of glycine as a complexing agent on the final surface and corrosion properties of the Ni-P and Ni-P/Al2O3 coatings has been investigated. The surface morphology and composition of the coated samples were investigated by scanning electron microscope (SEM) imaging and energy dispersive x-ray spectroscopy (EDS) analysis. Linear polarization scan and electrochemical impedance spectroscopy techniques were used to investigate the corrosion properties of the coating layer.

Findings

The results clarify that, glycine has a remarkable effect on the porosity content of Ni-P and Ni-P/Al2O3. It was found that increasing of glycine concentration results in higher porosity content in the coating layers. Also, the porosity in the coating layers minimizes the protectability of the coating against corrosion. The results also show that adding nano-alumina (Al2O3) to the coating path has improved the corrosion properties by decreasing the porosity in the coating layer. The scanning electron microscope (SEM) images showed that the concentration of glycine affects the content and distribution of alumina nanoparticles embedded in the coating layer. Also, it was observed that using a high concentration of glycine (0.4 M glycine), the alumina tends to agglomerate and the final alumina content in the coating was decreased.

Originality/value

The present study reveals that the quality of the final coating plays a major role in the corrosion performance of the steel substrate. The coating quality can by improve remarkably by optimization of the complexing agent used in the plating bath, to minimize the porosity involve in the coating layer.

Details

Anti-Corrosion Methods and Materials, vol. 67 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 8 July 2022

Haiqiang Yu, Quanzhong Guo, Keqin Du, Dongyun Li, Chuan Wang and Yong Wang

The purpose of this paper is to investigate the interfacial conductivity and corrosion resistance of the Ni–P/Ti4O7 composite coating that is deposited on a carbon steel substrate…

Abstract

Purpose

The purpose of this paper is to investigate the interfacial conductivity and corrosion resistance of the Ni–P/Ti4O7 composite coating that is deposited on a carbon steel substrate as bipolar plates for proton exchange membrane fuel cells.

Design/methodology/approach

The Ni–P/Ti4O7 coating was prepared by electroless plating. Scanning electron microscopy, white light interference, energy dispersive spectrometry and X-ray diffraction were used, respectively, to study the surface morphology, chemical composition and phase composition of coated samples. Electrochemical impedance spectroscopy, potentiodynamic and potentiostatic polarization were used to test the electrochemical performance and corrosion behavior. The interfacial contact resistance (ICR) was measured via the standard method.

Findings

The surface of the Ni–P/Ti4O7 coating is complete and dense and without obvious defects. The electrochemical test results show that the Ni–P/Ti4O7 coating provides better corrosion resistance than the Ni–P coating and substrate. Compared with the Ni–P coating, the ICR of the Ni–P/Ti4O7 coating is lower by about 82.7%. This is because the coating has more conductive contact points. The more exciting thing is that the ICR of the Ni–P/Ti4O7 coating only increases to 12.38 mΩ·cm2 after 5 h of polarization.

Originality/value

This paper provides a method for achieving surface modification of metal bipolar plates. Introducing Ti4O7 particles in the Ni–P layer reduces the contact resistance before and after polarization while ensuring good corrosion resistance.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 17 July 2018

Yan Baoxu and Kong Dejun

The amorphous Al-Ni-Fe-Gd coatings were fabricated to improve anti-corrosion performance of offshore platforms.

Abstract

Purpose

The amorphous Al-Ni-Fe-Gd coatings were fabricated to improve anti-corrosion performance of offshore platforms.

Design/methodology/approach

The amorphous Al-Ni-Fe-Gd coatings were first fabricated on S355 steel using the laser thermal spraying.

Findings

The amorphous forming capability and corrosion resistance increases with the laser powers increasing.

Research Limitations/implications

The amorphous Al-Ni-Fe-Gd coatings were applied on S355 steel of offshore platforms to increase its long-term heavy and anti-corrosion protection.

Originality/value

The amorphous Al-Ni-Fe-Gd coatings were first fabricated using a laser thermal spraying, improving its anti-corrosion.

Details

Anti-Corrosion Methods and Materials, vol. 65 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

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