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The purpose of this paper is to investigate the performance of natural Jordanian zeolite tuff to remove ammonia from aqueous solutions using a laboratory batch method and fixed-bed column apparatus. Equilibrium data were fitted to Langmuir and Freundlich models.

Column experiments were conducted in packed bed column. The used apparatus consisted of a bench-mounted glass column of 2.5 cm inside diameter and 100 cm height (column volume = 490 cm3). The column was packed with a certain amount of zeolite to give the desired bed height. The feeding solution was supplied from a 30 liter plastic container at the beginning of each experiment and fed to the column down-flow through a glass flow meter having a working range of 10-280ml/min.

Ammonium ion exchange by natural Jordanian zeolite data were fitted by Langmuir and Freundlich isotherms. Continuous sorption of ammonium ions by natural Jordanian zeolite tuff has proven to be effective in decreasing concentrations ranging from 15-50 mg NH₄-N/L down to levels below 1 mg/l. Breakthrough time increased by increasing the bed depth as well as decreasing zeolite particle size, solution flow-rate, initial NH₄+ concentration and pH. Sorption of ammonium by the zeolite under the tested conditions gave the sorption capacity of 28 mg NH₄-N/L at 20°C, and 32 mg NH₄-N/L at 30°C.

This research investigates the performance of natural Jordanian zeolite tuff to remove ammonia from aqueous solutions using a laboratory batch method and fixed-bed column apparatus. The equilibrium data of the sorption of Ammonia were plotted by using the Langmuir and Freundlich isotherms, then the experimental data were compared to the predictions of the above equilibrium isotherm models. It is clear that the NH₄+ ion exchange data fitted better with Langmuir isotherm than with Freundlich model and gave an adequate correlation coefficient value.

This paper aims to formulate and prepare a series of alkyd paints with new anticorrosive pigments, eco-friendly to the environment, based on a natural zeolitic rock modified by ion exchange to incorporate passivating cations.

The electrochemical characterization of the painted steel was carried out by conductivity measurements, linear polarization tests, measurements of the corrosion potential and electrochemical noise measurements. Besides, accelerated tests in standard environmental chambers were also carried out.

The results show that clinoptilolite–mordenite-based pigments incorporated in the paint provide acceptable anticorrosive properties, taking into account their low environmental impact and the use of a natural resource of low cost. The inhibitory efficiency of ZLa is higher than 80% and of ZPr is close to 70%. The electrochemical assays of the coated panels with the alkyd paints ZLa and ZPr shows similar behavior.

In this work, good results were obtained with an alkyd resin, but other resins could be tested. Paints could also be formulated with modified zeolites as a complement to others traditional anticorrosive pigments.

These paints could be used for the protection of metal structures in low corrosive environments.

There are not many published works using zeolites as anticorrosive pigments.

Modern construction methods have been developed with the goal of reducing construction time as much as possible, which results in some situations during construction and within the first few days after it, when concrete is subjected to exceptionally high loads. The precast concrete, which is the concrete in very early ages, may result in severe cracks or damages. In conventional construction projects, sometimes working with concrete, which had not reached its ultimate strength, is an unavoidable matter of fact. This paper aims to discuss these issues.

Researchers in the field of construction materials have done their best to make some changes in the different parts of the concrete in order to bring about reforms, based on the existing needs, and achieve new quality and primacy from concrete. One kind of concrete, the emergence of which dates back to many years ago, is self-compacting concrete. Thanks to its high efficiency for the parts with complex forms of high-density steel, this kind of concrete suggests new prospects.

This study aims at evaluating the effect of early loads on the 28-day compressive strength of concretes with zeolite and limestone powder under different curing conditions (wet or dry). In this regard, two self-compacting concrete mix designs with the same ratio of water to cementations materials and 0.4 percent and 10 percent zeolite have been considered; therefore, concrete cube samples with zeolite and limestone powder in different curing conditions at ages of three, one and seven days under preloading with 80–90 percent of compressive strength are damaged, and after curing in different conditions, their 28-day compressive strength is measured. According to the results, the recovery of the 28-day compressive strength of damaged samples, compared to that of intact samples, is possible in all curing conditions. The experiments that have been performed on concrete samples under dry and wet curing conditions show that the full recovery of compressive strength of damaged samples compared to that of intact ones happened only in preloaded samples at the age of one days, and in other ages (three and seven days) the 28-day strength reduction has occurred in damaged samples compared to the that in intact samples. The results of concrete samples with zeolite and without limestone powder at the age of one day indicate the greatest impact on other samples on the 28-day compressive strength of damaged samples compared to that of intact ones, occurring under dry condition.

This research analyzed and studied the influence under wet and dry curing conditions and the presence of limestone powder and zeolite fillers in recovering of the 28-day compressive strength of preloaded concrete samples at early stages (one, three and seven days) after the construction of the concrete.

This study aims to use porous concrete and mineral adsorbents (additives) for reducing the quantity and improving the quality of urban runoff.

The effects of adding mineral adsorbents and fine grains to porous concrete is tested for increasing its performance in improving the quality of urban runoff. Two levels of sand (10 and 20 per cent) and 5, 10 and 15 per cent of zeolite, perlite, LECA and pumice were added to the porous concrete. Unconfined compressive strength, hydraulic conductivity (permeability) and porosity of the porous concrete specimens were measured. Some of the best specimens were selected for testing the improvement of runoff quality. A rainfall simulator was designed and the quality of the runoff was investigated for changes in electrical conductivity (EC), total suspended solids (TSS), total dissolved solids (TDS) and chemical oxygen demand (COD).

The results of this study showed that compressive strength of the porous concrete was increased by adding fine grains to the concrete mixture. Fine grains decreased the permeability and porosity of the samples. Zeolite had the highest compressive strength. Samples having pumice own maximum permeability. Samples which had perlite, had the least compressive strength and permeability. Because of the fast flow of runoff water in the porous slab and its low thickness, sufficient time was not provided for effective functioning of the additives, and the removal percentage of the pollution parameters was low.

Porous concrete can ameliorate both quantity and quality of the urban runoff.

The purpose of this paper is to provide an investigation on a new kind of adsorbent materials, namely, the Prussian blue analog (PBA)-loaded albite-base porous ceramic foam, which can effectively adsorb the heavy metal ion in the wastewater.

The natural zeolite powder has been used as the primary raw material to make a sort of porous ceramic foam by impregnating polymer foam in slurry and then sintering. Adjusting the technological parameters could control the bulk density of the ceramic product, which could float on water with the bulk density less than 1 g/cm³ and also sink in water with the bulk density higher than 1 g/cm³. After desilicating the porous ceramic foam, an Al-Fe type PBA with a strong function of ion exchange was loaded on the ceramic surface by directly yielding.

The adsorption performance for harmful metal ions was greatly improved by combining together the high adsorption capability of the PB analog and the efficient high specific surface area of the porous ceramic foam.

This work presents a PBA-loaded albite-base porous ceramic foam that can effectively adsorb the harmful substance in water, and the adsorption efficiency for some typical harmful ions, i.e., Cd²⁺, Cs⁺ and As(V), was examined under different conditions of the experimental period, the pH value and the ion concentration in the tested solution.

The purpose of this study is to prepare Polystyrene grafted with Zeolite Y (Zeosty) for Uranyl ion [U(VI)] adsorption from aqueous solution. The adsorption mechanism has been explained by studying kinetic, isothermal and thermodynamic models.

Polystyrene was grafted with Zeosty by a simple hydrothermal technique. Zeosty was characterized by different techniques such as X-ray diffraction, scanning electron microscope, energy dispersive X-ray and Infrared spectroscopy to confirm its structure and its molecular composition. Zeosty was used for U(VI) adsorption from an aqueous solution in a series of batch experiments. The effects of pH, contact time, initial U(VI) concentration and temperature on the adsorption process were investigated.

The results showed that the adsorption of U(VI) on the prepared reached equilibrium at pH 6 with a removal efficiency of 98.9%. Adsorption kinetics and isotherms models are studied on the experimental data to estimate the mechanism of the adsorption reaction was chemisorption and homogenous reaction. The activity of Zeosty increased at high temperatures, resulting in the adsorption capacity increase. Thermodynamic parameters ΔGo, ΔHo and ΔSo indicate that the adsorption processes are spontaneous and endothermic. Zeosty has an effective surface and could be considered a valuable adsorbent for U(VI) removal from aqueous waste. A comparison study proves that the new adsorbent has high effective behavior in the adsorption process, and it is considered a new reliable adsorbent for U(VI) removal from wastewater.

This study is complementary to the previous study using the same technique to prove that the effective fine particle adsorbents need solid support to enhance their absorption capacities.

This paper aims to evaluate the efficacy of a zeolite-filled silane sol–gel coating as protective layer on pretreated AZ31 magnesium alloy substrates.

Anti-corrosion properties of a silane–zeolite composite coating, at various zeolite content, have been investigated on AZ31 magnesium substrates subjected to different surface pretreatment procedures before coating deposition. A short time etching by hydrofluoric acid (HF) and an anodic polarization in NaOH solution were used as surface pretreatments.

High hydrophobicity and good adhesion performances of coatings have been observed. Corrosion protection performance, during immersion in 3.5 per cent NaCl solution, was evaluated by means of electrochemical impedance spectroscopy tests. All coating formulations evidenced good barrier properties. Better durability properties have been shown by coating obtained on HF pretreated magnesium substrate and with a 60 per cent of zeolite content.

High electrochemical reactivity of magnesium alloys represents the mayor limit of its application in many different fields. In this concern, zeolite-based coatings are emerging as potentially effective environmentally friendly coating for metallic substrates. Despite aluminum and stainless steel substrates, in the literature, only expensive direct synthesis zeolite coating was investigated for its application on magnesium alloys protection. For this reason, this paper fulfills the need to assess the adhesion and anti-corrosion behavior of sol–gel silane–zeolite coating in magnesium alloy substrates.

The purpose of this paper is to provide an investigation on a new kind of photocatalytic material, namely, the porous ceramic foam loading titanium dioxide, which can make an effective photocatalytic degradation of the methyl orange (MO) solution in the wastewater.

The natural zeolite powder has been used as the primary raw material to produce a sort of lightweight porous ceramic foam by impregnating polymer foam in slurry and then sintering. With the sol-gel method, a kind of open-cell reticular porous ceramic foam loading TiO₂ film was obtained having a good photocatalytic action, and the resultant porous composite product presents the bulk density of 0.3~0.6 g/cm³ to be able to float on water.

The MO could tend to be completely degraded in the solution with a certain concentration by the TiO₂-loaded ceramic foam irradiated with ultraviolet light, and this composite foam was found to have high degradation efficiency for the MO solution in a wide range of pH.

This work presents a TiO₂-loaded ceramic foam that can effectively photo-catalyze to degrade the MO in water, and the degradation efficiency were examined under different conditions of the MO solution with various pH values.

Introduction How old is concrete? 150 years, 2,000 years or 9,000 years? Since the invention of Portland cement by Aspdin in the early 19th century, concrete has become the most widely used construction material in the world. Yet, concrete durability can pose severe constraints on the concrete engineer and designer. In the search for materials which are more cost‐effective or more efficient, cement replacement materials such as natural pozzolans, calcined clays, shale and soils, slags, rice husk ash or pulverised fuel ash are attracting much interest. Are these cheap replacement materials not compromising on quality and long‐term durability? A first optimistic answer is given in this paper which will be especially useful for practising civil and structural engineers, materials technologists, engineers and designers.

Ancient and Modern The ability of zeolite granules to act as a molecular sieve has been known to science for many years: now NGL have adapted this age‐old process and by harnessing it to modern electronic technology have created a new concept in aircraft Life Support systems.