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This paper aims to evaluate the antibacterial properties of pigment printed fabric loaded with nano-sized silver and zinc.

The pigment printing paste was mixed with nano-sized silver/zinc particles and applied to the cotton fabrics by the hand screen-printing technique. The nano-sized particles, distribution on the fabric surface, were analysed by scanning electron microscopy and energy-dispersive X-ray spectroscopy. The ASTM E2149-01 test method was used to determine the bacteriodynamic activity of the treated fabrics. The wash and light fastness properties of the treated fabrics were investigated.

The experimental results of the study showed that antibacterial properties could be obtained by loading with nano-size silver/zinc particles on pigment printed cotton fabrics. There is no negative or positive effect of the addition of nano silver/zinc particles to the printing paste on fastness properties.

The nano-sized metal particles and pigment printing paste should be well mixed to achieve uniform distribution on the printed surface.

The described process marks the introduction of a nano-technological aspect to pigment printing by its application to cotton fabrics.

The novelty/originality of the study lies in the new application process of nano-size silver/zinc particles to the textile pigment printing for antibacterial properties.

The purpose of this paper is to improve anti-corrosion, self-cleaning, hydrophily and sterilization properties of aluminum (Al) alloy.

A multifunctional coating for medical external application on Al alloy had been prepared by anodic oxidation, electrolytic coloring silver (Ag) and sealed in boiling water with nano-sized titanium dioxide (TiO₂) particles. The multifunctional coating was characterized by X-ray diffraction, scanning electron microscope and energy dispersive spectroscopy. Other properties such as corrosion-resistance, wipe-resistance, hydrophilicity, photochemical decomposition and bactericidal antiseptic effect were also investigated.

The results demonstrate that a golden film with multi-function had been obtained for medical external application. The main phase of coating is amorphous Al₂O₃, and nano-sized silver particle is electrodeposited in bottom of film hole, while nano-sized TiO₂ is sealed on the external surface of coating. The properties of film, such as anti-corrosion, self-cleaning, hydrophily, sterilization are better than those of Al alloy substrate.

Considering about this usage for medical external application, a multifunctional coating which has the properties such as decoration, anti-corrosion, sterilize and self-cleaning has been first prepared on Al alloy surface in the study. This coating would meet the requirements of medical external using and provide theoretical and practical foundation about Al alloy for medical use.

Multiple fillers are adopted to study the filler influences on electrical and mechanical properties of the conductive adhesives. The performances of the developed nano-enhanced interconnect materials in printing process are also evaluated. The paper aims to discuss these issues.

Micron-sized silver flakes are used as the basic fillers, and submicro- and nano-sized silver spheres and carbon nanotubes (CNTs) are adopted to obtain conductive adhesives with multiple fillers. Differential scanning calorimetry measurement is carried out to characterize the curing behavior of the samples with different fillers, four-probe method is used to obtain the bulk resistivity, shear test is conducted for adhesive strength, and environmental loading test is also involved. Furthermore, printing trials with different patterns have been carried out.

The electrical resistivity of the adhesives with submicro-sized silver spheres does not monotonically change with the increasing sphere proportion, and there exists an optimized value for the ratio of silver flakes to spheres. Samples with relatively small amount of CNT additives show improved electrical properties, while their mechanical strengths tend to decrease. For the printing application, the adhesives with 18.3 volume% filler content behave much better than those with lower filler content of 6 percent. The presence of the nano-particles makes a slight improvement in the printing results.

More detailed printing performance and reliability test of the samples need to be carried out in the future.

The conductive adhesives as interconnect materials exhibit some improved properties with optimized bimodal or trimodal fillers. The additive of the nano-fillers affects slightly on the printing quality of the bimodal conductive adhesives.

Nano-sized silver particles at a concentration of 1620 ppm were prepared using hydroxypropyl starch (HPS) as a reductant of silver nitrate and a stabilizer for silver nanoparticles. A solution containing 1620 ppm silver nanoparticles was diluted to 50 ppm and 100 ppm. The diluted solution was applied to cotton fabrics in the presence and absence of a binder to impart antibacterial properties to the fabrics. The solution containing 50 ppm silver nanoparticles with 1% binder (Printofix® Binder MTB EG liquid) induces excellent and durable bactericidal activity in cotton fabrics. The finished fabrics were examined for morphological features and surface characteristics by making use of the SEM. The SEM pictures reveal that silver nanoparticles are deposited on the surface of fibrils (fabric fibres).

This study aims to address a comprehensive and integrated investigations pertaining to the preparation of AgNPs with well-defined nano-sized scale using the aforementioned poly (meth acrylic acid [MAA])–chitosan graft copolymer, which is cheap, nontoxic, biodegradable and biocompatible agent as a substitute for the traditionally used toxic reducing agents.

AgNPs are prepared under a range of conditions, containing silver nitrate and poly (MAA)–chitosan graft copolymer concentrations, time, temperature and pH of the preparation medium. To classify AgNPs obtained under the various conditions, ultraviolet–visible spectroscopy spectra and transmission electron microscopy images are used for characterization of AgNPs instrumentally in addition to the visual color change throughout the work. The work was further extended to study the application of the so prepared AgNPs on cotton fabric to see their suitability as antibacterial agent as well as their durability after certain washing cycles.

According to the current investigation, the optimal conditions for AgNPs formation of nearly 3–15 nm in size are 5 g/l, poly (MAA)–chitosan graft copolymer and 300 ppm AgNO₃ in addition to carrying out the reaction at 60°C for 30 min at pH 12. Besides, the application of the so prepared AgNPs on cotton fabric displayed a substantial reduction in antibacterial efficiency against gram-positive and gram-negative bacteria estimated even after 10 washing cycles in comparison with untreated one.

To the best of the authors’ information, no comprehensive study of the synthesis of AgNPs using poly (MAA)–chitosan graft copolymer with a graft yield of 48% has been identified in the literature.

This paper aims to propose a simple, eco-friendly method for obtaining colloidal solutions of silver nanoparticles (Ag NPs) by using of contact non-equilibrium low-temperature plasma in presents polysorbate-80 and to assess their antibacterial activity in composite materials (beads) for water treatment process.

Silver nanoparticles were prepared in aqueous AgNO3 solution by using of contact non-equilibrium low-temperature plasma in the present of nonionic surfactant polysorbate-80 (Tween 80) as capping agent. Ultraviolet–visible (UV) spectroscopy, X-ray diffraction and zeta potential analysis were used to study the formation and properties of silver nanoparticles.

The formation of silver colloidal solutions in the presence of capping agent under plasma discharge is characterized by the presence of peak λmax = 380 – 402 nm in the spectra. The addition of sodium alginate into the reaction mixture allows synthesizing stable colloidal silver solutions. The average size of formed silver particles is up to 50 nm. Ag NPs exhibited an excellent bactericidal activity against both gram-positive and gram- negative bacteria. Composite beads prepared using nonionic surfactant were found to be effective in disinfecting the Staphylococcus aureus to different extents.

Further studies are necessary for confirmation of the practical application, especially of the toxicity of Ag NPs, as well as the sorption properties of the alginate beads with Ag NPs.

The method provides a simple and practical solution to improving the synthesis of colloidal solutions of Ag NPs for water treatment process.

Contact nonequilibrium low-temperature plasma can be used as an effective technique for synthesis of nanomaterials.

The purpose of this paper is to discuss the use of epoxy‐based conducting adhesives in z‐axis interconnections.

A variety of conductive adhesives with particle sizes ranging from 80 nm to 15 μm were laminated into printed wiring board substrates. SEM and optical microscopy were used to investigate the micro‐structures, conducting mechanism and path. The mechanical strength of the various adhesives was characterized by 90° peel test and measurement of tensile strength. Reliability of the adhesives was ascertained by IR‐reflow, thermal cycling, pressure cooker test (PCT), and solder shock. Change in tensile strength of adhesives was within 10 percent after 1,000 cycles of deep thermal cycling (DTC) between −55 and 125°C.

The volume resistivity of copper, silver and low‐melting point (LMP) alloy based paste were 5 × 10⁻⁴, 5 × 10⁻⁵ and 2 × 10⁻⁵ Ω cm, respectively. Volume resistivity decreased with increasing curing temperature. Adhesives exhibited peel strength with Gould's JTC‐treated Cu as high as 2.75 lbs/in. for silver, and as low as 1.00 lb/in. for LMP alloy. Similarly, tensile strength for silver, copper and LMP alloy were 3,370, 2,056 and 600 ψ, respectively. There was no delamination for silver, copper and LMP alloy samples after 3X IR‐reflow, PCT, and solder shock. Among all, silver‐based adhesives showed the lowest volume resistivity and highest mechanical strength. It was found that with increasing curing temperature, the volume resistivity of the silver‐filled paste decreased due to sintering of metal particles.

As a case study, an example of silver‐filled conductive adhesives as a z‐axis interconnect construction for a flip‐chip plastic ball grid array package with a 150 μm die pad pitch is given.

A high‐performance Z‐interconnect package can be provided which meets or exceeds JEDEC level requirements if specific materials, design, and manufacturing process requirements are met, resulting in an excellent package that can be used in single and multi‐chip applications. The processes and materials used to achieve smaller feature dimensions, satisfy stringent registration requirements, and achieve robust electrical interconnections are discussed.

Natural convection in finite enclosures is a common phenomenon in various thermal applications. To provide the thermal design guidelines, this study aims to numerically explore the potential of using internal baffles and nanofluids to either enhance or suppress heat transport in a vertical annulus. Furthermore, the annular-shaped enclosure is filled with aqueous-silver nanofluid and the effects of five distinct nanoparticle shapes are examined. In addition, the influence of baffle design parameters, including baffle position, thickness and length, is thoroughly analyzed.

The finite difference method is used in conjunction with the alternating direction implicit and successive line over relaxation techniques to solve nonlinear and coupled partial differential equations. The single phase model is used for nanofluid which is considered as a homogeneous fluid with improved thermal properties. The independence tests are carried out for assessing the sufficiency of grid size and time step for obtaining results accurately.

The baffle dimension parameters and nanoparticle shape exhibit significant impact on the convective flow and heat transfer characteristics, leading to the following results: sphere- and blade-shaped nanoparticles demonstrate around 30% enhancement in the heat transport capability compared with platelet-shaped nanoparticles, which exhibit the least. When considering the baffle design parameter, either a decrease in the baffle length and thickness or an increase in baffle height leads to an improvement in heat transport rate. Consequently, a threefold increase in baffle height yields a 40% improvement in thermal performance.

Understanding the impact of nanoparticle shapes and baffle design parameters on flow and thermal behavior will enable engineers to provide valuable insight on thermal management and overall system efficiency. Therefore, the current work focuses on exploring buoyant nanofluid flow and thermal mechanism in a baffled annular-shaped enclosure. Specifically, an internal baffle that exhibits conductive heat transfer through it is considered, and the impact of baffle dimensions (thickness, length and position) on the fluid flow behavior and thermal characteristics is investigated. In addition, the current study also addresses the influence of five distinct nanoparticle shapes (e.g. spherical, cylindrical, platelet, blade and brick) on the flow and thermal behavior in the baffled annular geometry. In addition to deepening the understanding of nanofluid behavior in a baffled vertical annulus, the current study contributes to the ongoing advancements in thermal applications by providing certain guidelines to design application-specific enclosures.

This paper aims to synthesize silver nanoparticles using atmospheric discharge plasma in contact with liquid at different pressure in reactor and to assess their catalytical properties for reducing 4-nanoparticles (NP).

The Ag colloidal NPs was rapidly synthesized as a result of non-equilibrium low-temperature plasma formation between an electrode and the surface of AgNO₃ solution for 5 min at different pressure in reactor. Synthesized Ag NPs were characterized with common analytical techniques. Ultraviolet–visible (UV) spectroscopy, dynamic light scattering, scanning microcopy analysis were used to study the formation and characteristics of silver nanoparticles.

The formation of silver colloidal solutions under plasma discharge at different pressure in reactor is characterized by the presence of surface resonance peak in the spectra. Scanning electron microscope (SEM) images confirmed the formation of spherical particles having a size distribution in the range of 15-26 nm. The AgNPs solution showed excellent rapid catalytic activity for the complete degradation of toxic 4-nitrophenol (4-NPh) into non-toxic 4-aminophenol (4-APh) within 18 min.

Further studies are necessary for confirmation of the practical application, especially of deposition Ag NPs on TiO₂.

The method provides a simple and practical solution to improving the synthesis of colloidal solutions of Ag NPs for degradation of organic pollutants (4-NPh) in water and wasters water.

Atmospheric discharge plasma in contact with liquid at different pressure can be used as an effective technique for synthesis of nanomaterials with catalytic properties.