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Article
Publication date: 26 August 2014

Driss Chebabe, Ahmed Dermaj, Hamid Erramli and Najat Hajjaji

The purpose of this study is to study corrosion inhibition of Bronze alloy B66 by 4-amino-3-methyl-1,2,4-triazole-5-thione (MTSNH) in 3 per cent NaCl solution…

Abstract

Purpose

The purpose of this study is to study corrosion inhibition of Bronze alloy B66 by 4-amino-3-methyl-1,2,4-triazole-5-thione (MTSNH) in 3 per cent NaCl solution. Archaeological bronze artefacts often are stored or displayed in uncontrolled conditions and may suffer from dangerous active corrosion processes that can lead to their destruction. The most dangerous form of archaeological bronze degradation is due to a cyclic reaction that involves copper from the pure alloy and chlorine as a pathogenic agent. A protection treatment can be used to protect them from the corrosion environment and stabilise them to avoid further degradation during exhibition or storage. Starting from its initial assessment as a corrosion inhibitor for pure copper, nowadays benzotriazole (BTA) is in widespread use for the conservation of copper-based artefacts, but unfortunately, BTA is toxic and a suspected carcinogen. The development of new and safe protection systems would offer a choice of alternative products to conservation-restoration professionals for the effective and safe stabilization and protection of metal artefacts. In this investigation, a new organic compound, namely, MTSNH, was synthesized, characterized and tested as a corrosion inhibitor for Bronze B66 (similar to archaeological bronze) in 3 per cent NaCl solution using potentiodynamic polarization studies and electrochemical impedance spectroscopy (EIS) at room temperature. It has been observed from the corrosion rate that the inhibition efficiency increased with increasing concentration of MTSNH. Potentiodynamic polarisation results revealed that the compound acted as a mixed-type inhibitor. Impedance studies indicated that protection occurs through adsorption of the inhibitor on the metal surface, with important modification to the mechanism of corrosion. Surface analysis was carried out using scanning electron microscopy scanning electron microscopy (SEM)/energy dispersive spectrometry (EDX) techniques to verify the electrochemical results.

Design/methodology/approach

The inhibition efficiency of MTSNH is investigated by potentiodynamic polarization, EIS and surface analysis.

Findings

The synthesized MTSNH act a good inhibitor in 3 per cent NaCl and inhibition efficiency increases with inhibitor concentration. Polarisation curves showed that the inhibitor is mixed. The EIS measurements showed that the inhibitor acted throughout the formation of film at the bronze surface. The surface analysis confirms this result.

Originality/value

The adsorption of the MTSNH on the metal surface can markedly change the corrosion resisting property of metal. Therefore, the study of the relation between adsorption and corrosion inhibiting is of a great importance.

Details

Anti-Corrosion Methods and Materials, vol. 61 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

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Article
Publication date: 13 September 2011

Fatima Bensajjay, Saliha Alehyen, Mohammed El Achouri, Najat Hajjaji, Abdelkbir Bellaouchou, Lourdes Perez and Maria Rosa Infante

The purpose of this investigation is the evaluation of the inhibitive performance of a new “gemini” surfactant in the series of bis‐quat: N, N, N′, N″, N″‐pentamethyl…

Abstract

Purpose

The purpose of this investigation is the evaluation of the inhibitive performance of a new “gemini” surfactant in the series of bis‐quat: N, N, N′, N″, N″‐pentamethyl diethyleneamine‐N, N″‐di‐[tetradecylammonium bromide] on the corrosion of iron in 1 M HCl by gravimetric, potentiodynamic and electrochemical impedance measurements. The effect of the temperature on the corrosion behavior of iron in 1 M HCl without and with inhibitor is studied in the temperature range (298‐333 K). This work also attempts to correlate thermodynamic and kinetic parameters with the inhibition effect.

Design/methodology/approach

The inhibition efficiency of gemini synthesized is investigated by weight loss, potentiodynamic polarization and impedance spectroscopy methods.

Findings

The synthesized gemini bis‐quat acted as a good inhibitor in 1 M HCl, and inhibition efficiency increased with inhibitor concentration and temperature. Polarization curves showed that the surfactant was a mixed‐type inhibitor in hydrochloric acid. Impedance spectroscopy measurements showed that the inhibitor acted through the formation of a multilayer film at the iron surface. The adsorption of inhibitor on the iron surface obeyed the Langmuir adsorption isotherm equation. The inhibition effect was satisfactorily explained by both thermodynamic and kinetic parameters.

Originality/value

The adsorption of surfactants in the metal surface can markedly change the corrosion resisting property of the metal. So the study of the relation between the adsorption and corrosion inhibition is of a great importance. This was the first attempt to study the inhibition properties of gemini surfactants at the host laboratory.

Details

Anti-Corrosion Methods and Materials, vol. 58 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

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