Search results

This paper aims to provide an overview of the strategies and techniques being used and developed for the fabrication of nanoscale devices.

This paper discusses various nanofabrication technologies and strategies and highlights their merits and limitations. It concludes with a consideration of longer‐term possibilities.

It is shown that top‐down nanofabrication frequently uses lithographic and other techniques derived from the microtechnology industry but recent research appears to have identified a limit to its capabilities. Bottom‐up nanofabrication is less well‐developed but techniques such as molecular mechanosynthesis may offer unique capabilities in the longer‐term.

The paper provides a timely review of the rapidly developing field of nanofabrication technology.

As the last link of product remanufacturing, reassembly process is of great importance in increasing the utilization of remanufactured parts as well as decreasing the production cost for remanufacturing enterprises. It is a common problem that a large amount of remanufactured part/reused part which past the dimension standard have been scrapped, which have increased the production cost of remanufacturing enterprises to a large extent. With the aim to improve the utilization of remanufacturing parts with qualified quality attributes but exceed dimension, the purpose of this paper is to put forward a reassembly classification selection method based on the Markov Chain.

To begin with, a classification standard of reassembly parts is proposed. With the thinking of traditional ABC analysis, a classification management method of reassembly parts for remanufactured engine is proposed. Then, a homogeneous Markov Chain of reassembly process is built after grading the matching dimension of reassembly parts with different variety. And the reassembly parts selection model is constructed based on the Markov Chain. Besides, the reassembly classification selection model and its flow chart are proposed by combining the researches above. Finally, the assembly process of remanufactured crankshaft is adopted as a representative example for illustrating the feasibility and the effectiveness of the method proposed.

The reassembly classification selection method based on the Markov Chain is an effective method in improving the utilization of remanufacturing parts/reused parts. The average utilization of remanufactured crankcase has increased from 35.7 to 80.1 per cent and the average utilization of reused crankcase has increased from 4.2 to 14 per cent as shown in the representative example.

The reassembly classification selection method based on the Markov Chain is of great importance in enhancing the economic benefit for remanufacturing enterprises by improving the utilization of remanufactured parts/reused parts.

The stimulus of the successful semiconductor device miniaturisation programmes coupled to recent progress in synthetic chemistry and molecular engineering has led to the emergence of a new inter‐disciplinary activity—molecular electronics—which holds long‐term promise for a new range of electronic materials and devices. From very speculative origins the field has begun to generate important applications based on photoresists, Langmuir‐Blodgett films, electroactive polymers and photochromic materials. A selection of topics ranging from molecular switches, memories, sensors, and the biological interface to prospects for a molecular computer are discussed with special emphasis on features such as stability, self‐organisation and self‐assembly which are unique to molecular systems.

This paper aims to evaluate the inhibitive effect and adsorption behavior of the 2-amino-5-thiol-1,3,4-thiadiazole vanillin (A) on copper in 3 per cent NaCl solution.

A thiazole Schiff bases were synthesized, named, 2-amino-5-thiol-1,3,4-thiadiazole vanillin (A), which was fabricated respectively on copper surface by the molecular self-assembled. Evaluation was carried out by electrochemical measurement and surface analysis techniques. Measurement of static friction coefficient scanning electron microscopy and Contact angle analysis were applied, and it is finally confirmed the existence of the adsorbed film. The inhibitive mechanism of A was evaluated by means of quantitative calculation and molecular dynamics simulation.

The electrochemical measurement indicated that the self-assembled molecular film can effectively inhibit the corrosion of copper sheet, when the concentration was 15 mmol⋅L⁻¹ and the assembly time was 6 h, the corrosion inhibition effect was the best, reaching as high as 97.5 per cent. Scanning electron microscopy results showed that the Schiff base compound forms a protective film on the surface of the copper, which effectively blocks the transfer of corrosion particles to the metal substrate, thereby inhibiting the occurrence of corrosion. Adsorption behavior of A followed the Langmuir’s adsorption isotherm and attributed to mixed-type adsorption. The results of Quantitative calculation and molecular dynamics simulation showed that A was adsorbed on Cu (111) surface in parallel.

In this study, the corrosion inhibition properties of Schiff base film were investigated by combining theory with experiment. Theoretical calculation is helpful to guide the synthesis of efficient and environmentally friendly corrosion inhibitors.

The damage caused by metal corrosion is great. The self-assembled Schiff base membrane synthesized in this paper is simple and compact, and the corrosion inhibition efficiency of copper in 3 per cent NaCl solution is 97.5 per cent.

Inhibition of metal corrosion can better save energy and reduce economic losses.

The synthesized Schiff base was prepared on the copper surface by the molecular self-assembled. The Schiff base membrane has a good corrosion inhibition effect on copper in 3 per cent NaCl solution, and the corrosion inhibition efficiency is up to 97.5 per cent.

Self-organization has been regarded as a tool for the synthesis of well-defined organic nanostructures. Heterocyclic annulated perylene diimides are the subjects of considerable current research studies. The purpose of this study is to reveal the photophysical property, electronic structure and solid-state packing of O-heterocyclic annulated perylene diimide.

Asymmetrically five-membered O-heterocyclic annulated perylene diimide (OAPDI) was synthesized. Structure and purity of OAPDI were confirmed by ¹H NMR, ¹³C NMR, IR and mass spectral techniques. Photophysical properties of OAPDI were studied using UV–vis absorption and fluorescence in both solution (CHCl₃) and solid state. Scanning electron microscopic and atomic force microscopy were used to characterize the surface morphology of OAPDI. Conducting properties of the OAPDI were evaluated by current–voltage measurements. The compounds geometries were also optimized at 6-31G* using density functional theory.

The UV–vis absorption and fluorescence spectra of OAPDI in solution are blue-shifted in comparison with that of unsubstituted perylene bisimide. Solid-state UV–vis measurements of OAPDI indicate that it is capable of forming highly ordered structure. The non-covalent interactions, electrostatic attraction and p-p stacking moieties of OAPDI synergistically guide assembly and domain growth while maintaining the interpenetrating network of nanofibers in the solid film. The OAPDI gave higher current at −2.0 V (0.68 µA) and 4.0 V (1.0 µA).

This study will be helpful for exploring feasible routes to acquire soluble perylene diimides and well-defined organic nanostructures. Furthermore, such molecular tailoring approach would be helpful for designing and synthesizing novel organic semiconductive materials with excellent charge-transporting and light-emitting capabilities.

Ultra-high molecular weight polyethylene (UHMWPE) is adopted in water-lubricated bearings for its excellent performance. This paper aims to investigate the tribological properties of UHMWPE with a molecular weight of 10.2 million (g mol^‐1) under different molding temperatures.

The UHMWPE samples were prepared by mold pressing under constant pressure and different molding temperatures (140°C, 160°C, 180°C, 200°C, 220°C). The friction and wear tests in water were conducted at the RTEC tribo-tester.

The friction coefficient and wear loss decreased first and rose later with the increasing molding temperature. The minimums of the friction coefficient and wear loss were found at the molding temperatures of 200°C. At low melting temperatures, the UHMWPE molecular chains could not unwrap thoroughly, leading to greater abrasive wear. On the other hand, high melting temperatures will cause the UHMWPE molecular chains to break up and decompose. The optimal molding temperatures for UHMWPE were found to be 200°C.

Findings are of great significance for the design of water-lubricated UHMWPE bearings.

This paper aims to prepare highly hydrophobic films on aluminum AA3003 using myristic acid (MA) and evaluate its corrosion protection efficiency in a low-chloride solution.

The aluminum surface was initially treated with boiling water to develop a porous nanostructure, and then surface modification was carried out in ethanolic solutions with different concentrations of MA. The surface morphology, wetting behavior and film composition were first characterized, and then, the corrosion behavior was evaluated with electrochemical techniques.

The best hydrophobicity and corrosion resistance were obtained with 50 mM of MA. For such concentration, a water contact angle of 140° and protective efficiency of 96% were achieved. A multilayer structure was revealed by scanning electron microscope and X-ray photoelectron spectroscopy.

The results of this work shed light on the anticorrosion performance of fatty acid self-assembled multilayers on the surface of Al–Mn alloys.

The purpose of this paper is to improve the generation efficiency of singlet oxygen of methylene blue molecules through finely controlling their aggregation states in drug carriers.

As a photosensitiser in photodynamic therapy, methylene blue (MB) was loaded on citrate-modified hydroxyapatite (HAp) through an electrostatic interaction and followed by encapsulation of coordination complexes of tannic acid (TA) and Fe(III) ions. Ultraviolet-visible absorption spectrum of the supernatant after incubation of samples was recorded at certain time interval to investigate the release behaviour of MB. Photodynamic activity of MB was determined by the oxidation reaction of uric acid by singlet oxygen generated by MB under illumination.

Almost all MB molecules were immediately released from HAp-MB, whilst an initial burst release of MB from HAp-MB@TA was followed by a sustainable and pH-sensitised release. In comparison with HAp-MB, photocatalystic reduction of HAp-MB@TA by titanium dioxide hardly occurred under illumination, indicating the stability against reduction to leukomethylene blue in vitro. Generation efficiency of singlet oxygen by MB released from HAp-MB@TA was significantly higher than that from HAp-MB because of the control of TA and Fe(III) ions complexes on molecular structures of released MB.

A facile method was herein demonstrated to optimise the generation efficiency of singlet oxygen by controlling aggregation states of PS molecules and improve PDT efficiency to damage tumour tissues.