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This paper aims to propose a modified full-additive method (MFAM) to fabricate fine copper lines for high density interconnection (HDI) printed circuit boards (PCBs). In addition, the surface of the fine copper lines is treated with a brown oxidation process to obtain good adhesion between the copper and the dielectric resin.

Fine copper lines fabricated by MFAM were observed to evaluate the undercut quality, in comparison to undercut quality of copper lines fabricated by the semi-additive method and the subtractive method. The effect of the thickness of the dry film on the quality of the copper plating was investigated to obtain the regular shape of fine lines. The fine copper lines treated with the brown oxidation process were also examined to generate a coarse surface microstructure to improve the adhesion between the copper and the dielectric resin. The cross section and surface of as-fabricated fine copper lines were characterized using an optical microscope, a scanning electron microscope and an atomic force microscope.

MFAM has the potential to fabricate high-performance fine copper lines for HDI PCBs. Undercut of as-fabricated fine copper lines could be prevented to meet the design requirement of impedance. In addition, fine copper lines exhibit enough adhesive force to laminate with dielectric resin after the brown oxidation process.

MFAM, with the advantages of high efficiency and being a facile process, is developed to fabricate high-quality fine copper lines for industrial HDI PCB manufacture.

The purpose of this paper is to study an electrolytic etching method to prepare fine lines on printed circuit board (PCB). And the influence of organics on the side corrosion protection of PCB fine lines during electrolytic etching is studied in detail.

In this paper, the etching factor of PCB fine lines produced by new method and the traditional method was analyzed by the metallographic microscope. In addition, field emission scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used to study the inhibition of undercut of the four organometallic corrosion inhibitors with 2,5-dimercapto-1,3,4-thiadiazole, benzotriazole, l-phenylalanine and l-tryptophan in the electrolytic etching process.

The SEM results show that corrosion inhibitors can greatly inhibit undercut of PCB fine lines during electrolytic etching process. XPS results indicate that N and S atoms on corrosion inhibitors can form covalent bonds with copper during electrolytic etching process, which can be adsorbed on sidewall of PCB fine lines to form a dense protective film, thereby inhibiting undercut of PCB fine lines. Quantum chemical calculations show that four corrosion inhibitor molecules tend to be parallel to copper surface and adsorb on copper surface in an optimal form. COMSOL Multiphysics simulation revealed that there is a significant difference in the amount of corrosion inhibitor adsorbed on sidewall of the fine line and the etching area.

As a clean production technology, electrolytic etching method has a good development indicator for the production of high-quality fine lines in PCB industry in the future. And it is of great significance in saving resources and reducing environmental pollution.

There has been increasing interest in the development of printable electronics to meet the growing demand for low‐cost, large‐area, miniaturized, flexible and lightweight devices. The purpose of this paper is to discuss the electronic applications of novel printable materials.

The paper addresses the utilization of polymer nanocomposites as it relates to printable and flexible technology for electronic packaging. Printable technology such as screen‐printing, ink‐jet printing, and microcontact printing provides a fully additive, non‐contacting deposition method that is suitable for flexible production.

A variety of printable nanomaterials for electronic packaging have been developed. This includes nanocapacitors and resistors as embedded passives, nanolaser materials, optical materials, etc. Materials can provide high‐capacitance densities, ranging from 5 to 25 nF/in², depending on composition, particle size, and film thickness. The electrical properties of capacitors fabricated from BaTiO₃‐epoxy nanocomposites showed a stable dielectric constant and low loss over a frequency range from 1 to 1,000 MHz. A variety of printable discrete resistors with different sheet resistances, ranging from ohm to Mohm, processed on large panels (19.5×24 inches) have been fabricated. Low‐resistivity materials, with volume resistivity in the range of 10⁻⁴‐10⁻⁶ ohm cm, depending on composition, particle size, and loading, can be used as conductive joints for high‐frequency and high‐density interconnect applications. Thermosetting polymers modified with ceramics or organics can produce low k and lower loss dielectrics. Reliability of the materials was ascertained by (Infrared; IR‐reflow), thermal cycling, pressure cooker test (PCT) and solder shock testing. The change in capacitance after 3× IR‐reflow and after 1,000 cycles of deep thermal cycling between −55°C and +125°C was within 5 per cent. Most of the materials in the test vehicle were stable after IR‐reflow, PCT, and solder shock.

The electronic applications of printable, high‐performance nanocomposite materials such as adhesives (both conductive and non‐conductive), interlayer dielectrics (low‐k, low‐loss dielectrics), embedded passives (capacitors and resistors), and circuits, etc.. are discussed. Also addressed are investigations of printable optically/magnetically active nanocomposite and polymeric materials for fabrication of devices such as inductors, embedded lasers, and optical interconnects.

A thin film printable technology was developed to manufacture large‐area microelectronics with embedded passives, Z‐interconnects and optical waveguides, etc. The overall approach lends itself to package miniaturization because multiple materials and devices can be printed in the same layer to increase functionality.

As printed wiring boards move to thin laminate structures, there is growing interest in the use of photoimageable coatings to serve as dielectric. Shipley has developed a liquid photoimageable dielectric which combines liquid coating, imaging and plateability. This paper presents work using this material to produce electrolessly plated lines and blind vias, along with initial adhesion data. Some of the interesting properties of this material are: low dielectric constant, low moisture absorption and good compliance to stress. The material can be processed to provide a high Tg and high plated adhesion can be obtained using conventional swell and etch techniques. It can be imaged and processed using conventional printed circuit coating and imaging techniques. This material will offer a relatively low cost alternative to thin clad laminates and may find use for adding one or two layers to a conventional multilayer board or in providing surface topography for surface mount devices. The paper describes recent developments related to this dielectric and its use.

Today's and, to a greater extent, tomorrow's technologies in the Printed Circuit Industry need — besides very stringent challenges on quality — a very careful, precise and cost effective selection of valuable materials and sophisticated techniques in order to achieve optimal relationships between the costs and benefits of each technology. A survey of materials, their costs, technical requirements and also of alternative methods is given — today's and tomorrow's state‐of‐the‐art.

This event, organised by the Institute of Metal Finishing, will take place at The Post House Hotel, Leicester, on 20 March 1985. The Conference language will be English and details of the technical programme are as follows:

This paper describes recent printed board applications in circuit manufacturing on novel non‐laminate substrates. It specifically discusses properties pertinent to metal core, thermal plastics, and new processing conditions for circuitising the new substrates. Techniques explored are intended to provide rigidity, flatness, dimensional stability and improved thermal management.

In September 1998 six European companies involved in PCB manufacturing and electronic packaging started collaborating in a development project known as “PRIME”. The “Program for Re‐engineering and Innovating (PCB) Manufacturing and Equipment” project lost one of its original members in late 1999, and Coates Circuit Products joined as the dielectric supplier. The project is now approaching the mid‐term assessment (MTA), where alternative production scenarios will be discussed and the most attractive carried forward to fabricate test vehicles and ultimately demonstrator patterns. Some essential features of the project have already been demonstrated and these initial results will be presented.

This paper briefly reviews the impact that tape automated bonding systems are having in the semiconductor industry and describes a recent development of a bumped testable TAB system suitable for direct assembly to PWBs. The impact that such a system will have on PWB technology is discussed.