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1 – 10 of 86Nor Salwani Hashim and Fatimah De’nan
It is generally known that the perforated section such as the castellated section is good to sustain distributed loads but inadequate to sustain highly concentrated loads…
Abstract
Purpose
It is generally known that the perforated section such as the castellated section is good to sustain distributed loads but inadequate to sustain highly concentrated loads. Therefore, it is possible to design the opening in a different arrangement of web opening to achieve section efficiency, thus improving the strength and torsional behaviour of the section with web opening. This study aims to focus on the finite element analysis of I-beam with and without openings in steel section dominated to lateral-torsional buckling behaviour.
Design/methodology/approach
In this work, the analysis of different sizes, shapes and arrangements of web opening is performed by using LUSAS application to conduct numerical analysis on lateral-torsional buckling behaviour. This involves three diameter sizes of web opening, five types of opening shapes and two criteria of the model.
Findings
The section with c-hexagon web opening was placed about 200-mm centre to centre and 100-mm edge distance, contribute to 7.26% increase of buckling capacity. For the section with 150-mm centre to centre and 50-mm edge distance, the occurrence of local buckling contributes to decrease of lateral buckling section capacity to 19.943 kNm, where pure lateral-torsional buckling mostly occurred because of prevented section. Besides that, the web opening diameter was also analysed. The web crippling was observed because of the increase of opening diameter from 0.67 to 0.80 D.
Originality/value
This contributes to a decrease in buckling capacity as figured in the contour of the deformed shape. For Model 1, an increase of buckling capacity (31.46%) is observed when the opening diameter are changed from 0.67 to 0.80 D.
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Minakshi Koundal, Ajay Kumar Singh and Chhaya Sharma
This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.
Abstract
Purpose
This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.
Design/methodology/approach
The mild steel 1010 coupon was considered for the current study. Weight loss and the electrochemical methods were used to evaluate the inhibitory effects of neodymium chloride (NdCl3) and NdTar on mild steel in NaCl solution. Scanning electron microscopy, energy-dispersive X-ray analysis and attenuated total reflectance-Fourier transform infrared spectroscopy measurements were carried out to study the morphology and composition of the film, nature of deposits and corrosion products formed in test media on the corroded steel, with the objective of further analyzing the observed behavior of the two inhibitors.
Findings
Of the two, NdTar performs better than NdCl3 because it shields mild steel surfaces for longer. According to the results, when NdCl3 is present in a corrosive solution, the protective film only comprises Nd/Fe oxide/hydroxide/carbonate. However, when neodymium is coupled with the tartrate group (an organic group) and then added to the NaCl solution, the inhibitor film comprises both bimetallic complexes (Fe-Tar-Nd) and metal oxide/hydroxide/carbonate, which results in a more compact film and has higher inhibition efficiency.
Originality/value
This study evaluated the combined effects of inorganic and organic inhibitors with those of an inorganic inhibitor used alone for mild steel in NaCl solution.
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Liang Ma, Qiang Wang, Haini Yang, Da Quan Zhang and Wei Wu
The aim of this paper is to solve the toxic and harmful problems caused by traditional volatile corrosion inhibitor (VCI) and to analyze the effect of the layered structure on the…
Abstract
Purpose
The aim of this paper is to solve the toxic and harmful problems caused by traditional volatile corrosion inhibitor (VCI) and to analyze the effect of the layered structure on the enhancement of the volatile corrosion inhibition prevention performance of amino acids.
Design/methodology/approach
The carbon dots-montmorillonite (DMT) hybrid material is prepared via hydrothermal process. The effect of the DMT-modified alanine as VCI for mild steel is investigated by volatile inhibition sieve test, volatile corrosion inhibition ability test, electrochemical measurement and surface analysis technology. It demonstrates that the DMT hybrid materials can improve the ability of alanine to protect mild steel against atmospheric corrosion effectively. The presence of carbon dots enlarges the interlamellar spacing of montmorillonite and allows better dispersion of alanine. The DMT-modified alanine has higher volatilization ability and an excellent corrosion inhibition of 85.3% for mild steel.
Findings
The DMT hybrid material provides a good template for the distribution of VCI, which can effectively improve the vapor-phase antirust property of VCI.
Research limitations/implications
The increased volatilization rate also means increased VCI consumption and higher costs.
Practical implications
Provides a new way of thinking to replace the traditional toxic and harmful VCI.
Originality/value
For the first time, amino acids are combined with nano laminar structures, which are used to solve the problem of difficult volatilization of amino acids.
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Veysi Ökten, Reşit Yıldız and Gökmen Sığırcık
This study aims to prevent mild steel (MS) against corrosion in 0.5 M HCl solution, 2-amino-4-methoxy-6-methyl-1,3,5-triazine was used. The effectiveness of the compound as a…
Abstract
Purpose
This study aims to prevent mild steel (MS) against corrosion in 0.5 M HCl solution, 2-amino-4-methoxy-6-methyl-1,3,5-triazine was used. The effectiveness of the compound as a corrosion inhibitor was studied via electrochemical, surface and theoretical calculation techniques.
Design/methodology/approach
For concentrations ranging from 0.5 to 10.0 mM, almost similar polarization resistances were obtained from electrochemical impedance spectroscopy (EIS) and linear polarization resistance tests. It also investigated inhibitive activity of 2-amino-4-methoxy-6-methyl-1,3,5-triazine on the steel surface using scanning electron and atomic force microscope instruments. Langmuir adsorption is the best matched isotherm for the adsorption of the inhibitor to the steel surface.
Findings
EIS method was used to determine inhibition efficiency, which was determined to be 95.7% for 10.0 mM inhibitor containing acid solution. Density functional theory’s predictions for quantum chemistry agreed well with the other experimental results.
Originality/value
The methods used in this study are effective and applicable; the used organic inhibitor is 2-amino-4-methoxy-6-methyl-1,3,5-triazine; and protective effectiveness is important, which is crucial for the task of MS corrosion prevention.
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Akhil Khajuria, Anurag Misra and S. Shiva
An experimental investigation for developing structure-property correlations of hot-rolled E410 steels with different carbon contents, i.e. 0.04wt.%C and 0.17wt.%C metal active…
Abstract
Purpose
An experimental investigation for developing structure-property correlations of hot-rolled E410 steels with different carbon contents, i.e. 0.04wt.%C and 0.17wt.%C metal active gas (MAG) and cold metal transfer (CMT)-MAG weldments was undertaken.
Design/methodology/approach
Mechanical properties and microstructure of MAG and CMT-MAG weldments of two E410 steels with varying content of carbon were compared using standardized mechanical testing procedures, and conventional microscopy.
Findings
0.04wt.%C steel had strained ferritic and cementite sub-structures in blocky shape and large dislocation density, while 0.17wt.%C steel consisted of pearlite and polygonal ductile ferrite. This effected yield strength (YS), and microhardness being larger in 0.04wt.%C steel, %elongation being larger in 0.17wt.%C steel. Weldments of both E410 steels obtained with CMT-MAG performed better than MAG in terms of YS, ultimate tensile strength (UTS), %elongation, and toughness. It was due to low heat input of CMT-MAG that resulted in refinement of weld metal, and subzones of heat affected zone (HAZ).
Originality/value
A substantial improvement in YS (∼9%), %elongation (∼38%), and room temperature impact toughness (∼29%) of 0.04wt.%C E410 steel is achieved with CMT-MAG over MAG welding. Almost ∼10, ∼12.5, and ∼16% increment in YS, %elongation, and toughness of 0.17wt.%C E410 steel is observed with CMT-MAG. Relatively low heat input of CMT-MAG leads to development of fine Widmanstätten and acicular ferrite in weld metal and microstructural refinement in HAZ subzones with nearly similar characteristics of base metal.
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Takumi Yamaguchi and Fuminobu Ozaki
The main purpose of this study was to evaluate the tensile strengths of JIS G3549 super high-strength steel strand wire ropes (1,570 MPa-class high-carbon steels) and wire rope…
Abstract
Purpose
The main purpose of this study was to evaluate the tensile strengths of JIS G3549 super high-strength steel strand wire ropes (1,570 MPa-class high-carbon steels) and wire rope open swaged socket connections at fire and post fire.
Design/methodology/approach
Steady-state tests from ambient temperature (20 °C) to 800 °C, transient-state tests under the allowable design tensile force and tensile tests in an ambient temperature environment after heating (heating temperatures of 200–800 °C) were conducted.
Findings
The tensile strengths of the wire rope and end-connection specimens at both fire and post fire were obtained. The steel wire rope specimens possessed larger reduction factors than general hot-rolled mild steels (JIS SS400) and high-strength steel bolts (JIS F10T). The end-connection specimens with sufficient socket lengths exhibited ductile fracture of the wire rope part at both fire and post fire; however, those with short socket lengths experienced a pull-out fracture at the socket.
Originality/value
The fundamental and important tensile test results of the super high-strength steel strand wire ropes (1,570 MPa-class high-carbon steels) and wire rope open swaged socket connections were accumulated at fire and post fire, and the fracture modes were clarified. The obtained test results contribute to fire resistance performance-based design of cable steel structures at fire and fire-damage investigations to consider their reusability post fire.
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Varun Sabu Sam, M.S. Adarsh, Garry Robson Lyngdoh, Garry Wegara K. Marak, N. Anand, Khalifa Al-Jabri and Diana Andrushia
The capability of steel columns to support their design loads is highly affected by the time of exposure and temperature magnitude, which causes deterioration of mechanical…
Abstract
Purpose
The capability of steel columns to support their design loads is highly affected by the time of exposure and temperature magnitude, which causes deterioration of mechanical properties of steel under fire conditions. It is known that structural steel loses strength and stiffness as temperature increases, particularly above 400 °C. The duration of time in which steel is exposed to high temperatures also has an impact on how much strength it loses. The time-dependent response of steel is critical when estimating load carrying capacity of steel columns exposed to fire. Thus, investigating the structural response of cold-formed steel (CFS) columns is gaining more interest due to the nature of such structural elements.
Design/methodology/approach
In this study, experiments were conducted on two CFS configurations: back-to-back (B-B) channel and toe-to-toe (T-T) channel sections. All CFS column specimens were exposed to different temperatures following the standard fire curve and cooled by air or water. A total of 14 tests were conducted to evaluate the capacity of the CFS sections. The axial resistance and yield deformation were noted for both section types at elevated temperatures. The CFS column sections were modelled to simulate the section's behaviour under various temperature exposures using the general-purpose finite element (FE) program ABAQUS. The results from FE modelling agreed well with the experimental results. Ultimate load of experiment and finite element model (FEM) are compared with each other. The difference in percentage and ratio between both are presented.
Findings
The results showed that B-B configuration showed better performance for all the investigated parameters than T-T sections. A noticeable loss in the ultimate strength of 34.5 and 65.6% was observed at 90 min (986℃) for B-B specimens cooled using air and water, respectively. However, the reduction was 29.9 and 46% in the T-T configuration, respectively.
Originality/value
This research paper focusses on assessing the buckling strength of heated CFS sections to analyse the mode of failure of CFS sections with B-B and T-T design configurations under the effect of elevated temperature.
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Evrim Baran Aydın, Eyüp Başaran, Sevgi Ateş and Reşit Çakmak
The aim of this study was to investigate the activity of 4-((4-((2-hydroxyethyl)(methyl)amino)benzylidene) amino)-1,5-dimethyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one (HEMAP), a…
Abstract
Purpose
The aim of this study was to investigate the activity of 4-((4-((2-hydroxyethyl)(methyl)amino)benzylidene) amino)-1,5-dimethyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one (HEMAP), a Schiff base synthesized and characterized for the first time, to the authors’ knowledge, as a novel inhibitor against corrosion of mild steel (MS) in hydrochloric acid solution.
Design/methodology/approach
HEMAP was characterized by some spectroscopic methods including High-Resolution Mass Spectrometry (HRMS), Proton Nuclear Magnetic Resonance (1H NMR), Carbon-13 (C13) nuclear magnetic resonance (13C NMR) and Fourier Transform Infrared Spectroscopy (FT-IR). Then, the inhibition efficiency of HEMAP on MS in a hydrochloric acid solution was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). To explain the inhibition mechanism, the surface charge, adsorption isotherms and thermodynamic parameters of MS in the inhibitor solution were studied.
Findings
EIS tests displayed that the highest inhibition efficiency was calculated approximately as 99.5% for 5 × 10−2 M HEMAP in 1 M HCl solution. The adsorption of HEMAP on the MS surface was found to be compatible with the Langmuir model isotherm. The thermodynamic parameter results showed that the standard free energy of adsorption of HEMAP on the MS surface was found to be more chemical than physical.
Originality/value
This study is important in terms of demonstrating the performance of the first synthesized HEMAP molecule as an inhibitor against the corrosion of MS in acidic media. EIS tests displayed that the highest inhibition efficiency was calculated approximately as 99.5% for 5 × 10−2 M HEMAP in 1 M HCl solution.
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Kei Kimura, Takeshi Onogi and Fuminobu Ozaki
This work examines the effects of strain rate on the effective yield strength of high-strength steel at elevated temperatures, through tensile coupon tests at various strain…
Abstract
Purpose
This work examines the effects of strain rate on the effective yield strength of high-strength steel at elevated temperatures, through tensile coupon tests at various strain rates, to propose appropriate reduction factors considering the strain rate effect.
Design/methodology/approach
The stress–strain relationships of 385 N/mm2, 440 N/mm2 and 630 N/mm2-class steel plates at elevated temperatures are examined at three strain rate values (0.3%/min, 3.0%/min and 7.5%/min), and the reduction factors for the effective yield strength at elevated temperatures are evaluated from the results. A differential evolution-based optimization is used to produce the reduction-factor curves.
Findings
The strain rate effect enhances with an increase in the standard design value of the yield point. The effective yield strength and standard design value of the yield point exhibit high linearity between 600 and 700 °C. In addition to effectively evaluating the test results, the proposed reduction-factor curves can also help determine the ultimate strength of a steel member at collapse.
Originality/value
The novelty of this study is the quantitative evaluation of the relationship between the standard design value of yield point at ambient temperature and the strain-rate effect at elevated temperatures. It has been observed that the effect of the strain rate at elevated temperatures increases with the increase in the standard design value of the yield point for various steel strength grades.
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Huimin Yang, Chunlin Ye, Yi Li and Songwei Zhang
This study aims to probe the applicability of 2-mercaptobenzothiazole (MBT) functionalized ionic liquids (ILs) as additives in lithium complex grease (LCG) by researching the…
Abstract
Purpose
This study aims to probe the applicability of 2-mercaptobenzothiazole (MBT) functionalized ionic liquids (ILs) as additives in lithium complex grease (LCG) by researching the corrosion inhibiting, rheological and tribological performances.
Design/methodology/approach
Electrochemical tests such as electrochemical impedance spectroscopy and potentiodynamic polarization curves were used on Gamry electrochemical workstation to research the corrosion inhibition properties of ILs in 1.0 M HCl corrosive solution. The rheological properties of different grease samples were tested on a rheometer. The tribological properties were investigated on SRV-V oscillating reciprocating friction and wear tester. Scanning electron microscope, X-ray spectrometer and X-ray photoelectron spectrometer were used to characterize the lubricating mechanism.
Findings
The 2-MBT functionalized ILs have excellent corrosion inhibition properties. When used as additives in LCG, they both exhibited enhancing effects on thermostability, colloid stability and structural recoverability, and furthermore, outstanding friction-reducing and antiwear properties were also obtained. Surface analysis indicated that the superior lubricating performances of 2-MBT functionalized ILs were mainly ascribed to the formation of tribochemical products on wear tracks, including organic compounds with C–O bond, Fe2O3 and FeS2.
Originality/value
The 2-MBT-based ILs synthesized in this study were multifunctional additives with excellent corrosion inhibiting and tribological properties, which would have a very broad application prospect in lubricating grease industry.
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