Search results
1 – 10 of 168Abstract
Details
Keywords
Suhendrayatna, Muhammad Zaki, Annisa Delima Habdani Harahap and Fitriani Verantika
Purpose – In this study, the possibility of the application of rice husks for adsorbing Mn(II) ion in the water phase has been studied.Design/Methodology/Approach – Experimental…
Abstract
Purpose – In this study, the possibility of the application of rice husks for adsorbing Mn(II) ion in the water phase has been studied.
Design/Methodology/Approach – Experimental studies have been initiated by preparing activated carbon from rice husks. The activation of rice husks was done using both physical and chemical treatment methods through heating at 110 °C and washing with citric acid activator at 0.2 M, 0.4 M, and 0.6 M. The adsorption tests were conducted as two part tests: preliminary and primary. The preliminary test was conducted to choose the best condition of four independent variables, i.e., contact time (0–120 minutes), activator concentrations (0.2, 0.4, and 0.6 M), initial Mn(II) concentrations (10, 20, 50, 100, 200, and 400 mg/L), and adsorption temperatures (30, 47, and 67 °C).
Findings – By identifying the substituted groups using Fourier Transform Infrared Spectroscopy after activation with citric acid, it was found that the highest transmittance percentage was present in activated carbon with 0.2 M of citric acid. The best adsorption capacity and efficiency was 13.87 mg/g and 79.60%, respectively, which were obtained at 200 mg/L initial concentration with a 0.2 M citric acid concentration for 120 min contact time at 47 °C. These results lead to a conclusion that rice husks after activation with citric acid can be applied as an adsorbent for Mn(II) adsorption in the water phase.
Research Limitations/Implications – The activated carbon produced was only applicable for the adsorption of Mn(II) ions from the water phase, but not applicable for the adsorption of other heavy metals ions.
Practical Implications – Rice husks were potentially prepared as an adsorbent for Mn(II) ion adsorption in the water phase that was low cost, environmental friendly, and easy to prepare.
Originality/Value – Activated carbon prepared from biomass was mostly carried out using acids at high concentrations while the study was conducted using weak acids (citric acid) at low concentrations.
Details
Keywords
Purpose – The purpose of this paper to immobilization provides biosorbent particle with density and mechanichal strength, immobilization can save the cost of separating from…
Abstract
Purpose – The purpose of this paper to immobilization provides biosorbent particle with density and mechanichal strength, immobilization can save the cost of separating from biomass, can be regeneration and to increase adsorption capacity for metal ions.
Design/Methodology/Approach – The parameters affecting the adsorption, such as initial metal ion concentration, pH, contact time, and temperature, were studied. The analysis of biosorbent functional group was carried out by Fourier Transform Infrared Spectroscopy, SEM-EDX, for elemental analysis.
Findings – Optimum pH condition for biosorption Cd(II) was pH 5, contact time was 45 min, and initial concentration was 250 mg/L. Biosorbent analysis was characterized using SEM-EDX and FTIR analysis. Kinetics adsorption was studied and analyzed in terms of the pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetics models. The result showed that the biosorption for Cd(II) ion followed the pseudo-second-order kinetic model. Biosorption data of Cd(II) ion at 300°K, 308°K, and 318°K was analyzed with Temkin, Langmuir, and Freundlich isotherms. Biosorption of Cd(II) by durian seed immobilization in alginate according to the Langmuir isotherm equation provided a coefficient correlation of r2 = 0.939 and maximum capacity biosorption of 25.05 mg/g.
Details
Keywords
Kamaruzzaman Yunus, M.A. Zuraidah and Akbar John
This study aims to examine the metal pollution in coastal sediment in the Peninsular Malaysia.
Abstract
Purpose
This study aims to examine the metal pollution in coastal sediment in the Peninsular Malaysia.
Design/methodology/approach
Approximately 141 published studies were screened from 1,285 documents and reviewed to determine the existing pollution status in the coastal areas of Peninsular Malaysia and the metals under review were Pb, Hg, Cd, Ar, Cu, Zn, Cr and Ni. Sources of pollutants and their effect on biological systems, marine organisms and human health were addressed in this review as well as recommendation of heavy metal removal or remedies in short. Emphasis is placed on marine pollution, particularly on the toxic metal accumulation in biota.
Findings
This study has revealed the different concentrations of pollutants, low, moderately, and chronically contaminated areas from heavy metals and the consequences to aquatic ecosystem and indirectly to human health, since an increasing in the coastal developments in Peninsular Malaysia.
Originality/value
This study has revealed the different concentrations of pollutants, low, moderately, and chronically contaminated areas from heavy metals and the consequences to aquatic ecosystem and indirectly to human health, since an increasing in the coastal developments in Peninsular Malaysia.
Details
Keywords
Jiahe Wang, Huajian Li, Chengxian Ma, Chaoxun Cai, Zhonglai Yi and Jiaxuan Wang
This study aims to analyze the factors, evaluation techniques of the durability of existing railway engineering.
Abstract
Purpose
This study aims to analyze the factors, evaluation techniques of the durability of existing railway engineering.
Design/methodology/approach
China has built a railway network of over 150,000 km. Ensuring the safety of the existing railway engineering is of great significance for maintaining normal railway operation order. However, railway engineering is a strip structure that crosses multiple complex environments. And railway engineering will withstand high-frequency impact loads from trains. The above factors have led to differences in the deterioration characteristics and maintenance strategies of railway engineering compared to conventional concrete structures. Therefore, it is very important to analyze the key factors that affect the durability of railway structures and propose technologies for durability evaluation.
Findings
The factors that affect the durability and reliability of railway engineering are mainly divided into three categories: material factors, environmental factors and load factors. Among them, material factors also include influencing factors, such as raw materials, mix proportions and so on. Environmental factors vary depending on the service environment of railway engineering, and the durability and deterioration of concrete have different failure mechanisms. Load factors include static load and train dynamic load. The on-site rapid detection methods for five common diseases in railway engineering are also proposed in this paper. These methods can quickly evaluate the durability of existing railway engineering concrete.
Originality/value
The research can provide some new evaluation techniques and methods for the durability of existing railway engineering.
Details
Keywords
Karima Derdour, Chafia Bouchelta, Amina Khorief Naser-Eddine, Mohamed Salah Medjram and Pierre Magri
The purpose of this paper is to focus on the removal of hexavalent chromium [Cr(VI)] from wastewater by using activated carbon-supported Fe catalysts derived from walnut shell…
Abstract
Purpose
The purpose of this paper is to focus on the removal of hexavalent chromium [Cr(VI)] from wastewater by using activated carbon-supported Fe catalysts derived from walnut shell prepared using a wetness impregnation process. The different conditions of preparation such as impregnation rate and calcination conditions (temperature and time) were optimized to determine their effects on the catalyst’s characteristics.
Design/methodology/approach
The catalyst samples were characterized using thermogravimetric analysis, scanning electron microscopy and Fourier transform infrared spectroscopy. The adsorption of Cr(VI) by using using activated carbon supported Fe catalysts derived from walnut shell as an adsorbent and catalyst was investigated under different adsorption conditions. The parameters studied were contact time, adsorbent dose, solution pH and initial concentrations.
Findings
Results showed that higher adsorption capacity and rapid kinetics were obtained when the activated walnut shell was impregnated with Fe at 5 per cent and calcined under N2 flow at 400°C for 2 h. The adsorption isotherms data were analyzed with Langmuir and Freundlich models. The better fit is obtained with the Langmuir model with a maximum adsorption capacity of 29.67 mg/g for Cr(VI) on Fe5-AWS at pH 2.0.
Originality/value
A comparison of two kinetic models shows that the adsorption isotherms system is better described by the pseudo-first-order kinetic model.
Details
Keywords
Abstract
Details
Keywords
Agnishwar Girigoswami, Poornima Govindharaj, Mahashweta Mitra Ghosh and Koyeli Girigoswami
Abstract
Purpose
In addition to agriculture, energy production, and industries, potable water plays a significant role in many fields, further increasing the demand for potable water. Purification and desalination play a major role in meeting the need for clean drinking water. Clean water is necessary in different areas, such as agriculture, industry, food industries, energy generation and in everyday chores.
Design/methodology/approach
The authors have used the different search engines like Google Scholar, Web of Science, Scopus and PubMed to find the relevant articles and prepared this mini review.
Findings
The various stages of water purification include coagulation and flocculation, coagulation, sedimentation and disinfection, which have been discussed in this mini review. Using nanotechnology in wastewater purification plants can minimize the cost of wastewater treatment plants by combining several conventional procedures into a single package.
Social implications
In society, we need to avail clean water to meet our everyday, industrial and agricultural needs. Purification of grey water can meet the clean water scarcity and make the environment sustainable.
Originality/value
This mini review will encourage the researchers to find out ways in water remediation to meet the need of pure water in our planet and maintain sustainability.
Details
Keywords
Kiranmai Uppuluri and Dorota Szwagierczak
The purpose of this work was to characterize NiMn2O4 spinel-based thermistor powder, to use it in screen printing technology to fabricate temperature sensors, to study their…
Abstract
Purpose
The purpose of this work was to characterize NiMn2O4 spinel-based thermistor powder, to use it in screen printing technology to fabricate temperature sensors, to study their performance for different sintering temperatures of thermistor layer, with and without insulative cover, as well as to investigate stability of the fabricated thermistors and their applicability in water quality monitoring.
Design/methodology/approach
After the characterization of starting NiMn2O4 spinel-based thermistor powder, it was converted to thick film paste which was screen printed on alumina substrate. Thermistor layers were sintered at four different sintering temperatures: 980°C, 1050°C, 1150°C and 1290°C. An interdigitated pattern of Ag-Pd conductive layer was used to reduce the resistance. Temperature-resistance characteristics were investigated in air and water, with and without insulative cover atop the thermistor layer. Stability of the fabricated thermistors after aging at 120°C for 300 h was also examined.
Findings
Thick film NiMn2O4 spinel thermistors, prepared by screen printing and sintering in the temperature range 980°C–1290°C, exhibited good negative temperature coefficient (NTC) characteristics in the temperature range −30°C to 145°C, including high temperature coefficient of resistance, good stability and applicability in water.
Originality/value
This study explores the range of sintering temperature that can be applied for NiMn2O4 thermistor thick films without compromising on the temperature sensing performance in air and water, as well as stability of the thermistors after aging at elevated temperatures.
Details