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Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to protect metals from deterioration in corrosive environments. Moreover, the toxic nature, non-biodegradability and price of most conventional corrosion inhibitors have encouraged the application of greener and more sustainable options, with natural and synthetic drugs being major actors. Hence, this paper aims to stress the capability of natural and synthetic drugs as manageable and sustainable, environmentally friendly solutions to the problem of metal corrosion.

In this review, the recent developments in the use of natural and synthetic drugs as corrosion inhibitors are explored in detail to highlight the key advancements and drawbacks towards the advantageous utilization of drugs as corrosion inhibitors.

Corrosion is a critical issue in numerous modern applications, and conventional strategies of corrosion inhibition include the use of toxic and environmentally harmful chemicals. As greener alternatives, natural compounds like plant extracts, essential oils and biopolymers, as well as synthetic drugs, are highlighted in this review. In addition, the advantages and disadvantages of these compounds, as well as their effectiveness in preventing corrosion, are discussed in the review.

This survey stresses on the most recent abilities of natural and synthetic drugs as viable and sustainable, environmentally friendly solutions to the problem of metal corrosion, thus expanding the general knowledge of green corrosion inhibitors.

The purpose of this review is to comprehensively consider the material properties and processing of additive titanium alloy and provide a new perspective for the robotic grinding and polishing of additive titanium alloy blades to ensure the surface integrity and machining accuracy of the blades.

At present, robot grinding and polishing are mainstream processing methods in blade automatic processing. This review systematically summarizes the processing characteristics and processing methods of additive manufacturing (AM) titanium alloy blades. On the one hand, the unique manufacturing process and thermal effect of AM have created the unique processing characteristics of additive titanium alloy blades. On the other hand, the robot grinding and polishing process needs to incorporate the material removal model into the traditional processing flow according to the processing characteristics of the additive titanium alloy.

Robot belt grinding can solve the processing problem of additive titanium alloy blades. The complex surface of the blade generates a robot grinding trajectory through trajectory planning. The trajectory planning of the robot profoundly affects the machining accuracy and surface quality of the blade. Subsequent research is needed to solve the problems of high machining accuracy of blade profiles, complex surface material removal models and uneven distribution of blade machining allowance. In the process parameters of the robot, the grinding parameters, trajectory planning and error compensation affect the surface quality of the blade through the material removal method, grinding force and grinding temperature. The machining accuracy of the blade surface is affected by robot vibration and stiffness.

This review systematically summarizes the processing characteristics and processing methods of aviation titanium alloy blades manufactured by AM. Combined with the material properties of additive titanium alloy, it provides a new idea for robot grinding and polishing of aviation titanium alloy blades manufactured by AM.

This paper aims to optimize the single-point incremental forming process variables for realizing higher formability in Inconel 625 components and to plot the forming limit diagram for Inconel 625 aviation-grade superalloy.

The formability of Inconel 625 components has been measured in terms of major strain, minor strain and minimum sheet thickness. Response surface methodology with desirability function analysis has been used to achieve maximum formability. The finite element analysis has been conducted at optimal parametric setting.

The derived forming limit diagram proves that the maximum forming limit for Inconel 625 is 57.5° at the optimal parametric setting, achieved with desirability of 0.995. The outcomes of finite element analysis conducted at optimal parametric setting show excellent agreement with confirmation experiment results.

Inconel 625 superalloy is frequently used in aircraft and other high-performance applications for its superior strength.

It has been suggested that to enhance formability, higher tool rotation speed, minimum step-size, larger tooltip diameter and higher wall angle must be used. Wall angle is the governing parameter among all the parameters.

This paper aims to design a novel TiC/GTD222 nickel-based high-temperature alloy with excellent hot corrosion resistance by incorporating appropriate amounts of C, Al and Ti elements into GTD222 alloy.

The composite material was prepared using the selective laser melting (SLM) technology, followed by a hot isostatic pressing (HIP) treatment. Subsequently, the composite underwent a hot corrosion test in a 75% Na₂SO₄ + 25% NaCl mixed salt environment at 900 °C.

The HIP-SLMed TiC/GTD222 composite exhibits a relatively low weight loss rate. First, the addition of alloying elements facilitates the formation of multiple protective oxide films rich in Al, Ti and Cr. These oxide films play a crucial role in enhancing the material’s resistance to hot corrosion. Second, the HIP treatment results in a reduction of grain size in the composite and an increased number of grain boundaries, which further promote the formation of protective films.

The hot corrosion behavior of the TiC/GTD222 nickel-based composite material prepared through SLM and HIP processing has not been previously studied. This research provides a new approach for designing nickel-based superalloys with excellent hot corrosion resistance.

This present research aims to identify the optimum process parameters for enhancing geometric accuracy in single-point incremental forming of aviation-grade superalloy 625.

The geometric accuracy has been measured in terms of half-cone-angle, concentricity, roundness and wall-straightness errors. The Taguchi Orthogonal-Array L9 with desirability-function-analysis has been used to achieve improved accuracy.

To achieve maximum geometric accuracy, the optimum setting having a tooltip diameter of 10 mm, a step-size of 0.2 mm and a tool rotation speed (TRS) of 900 RPM has been derived. With this setting, the half-cone-angle accuracy increases by 42.96%, the concentricity errors decrease by 47.36%, the roundness errors decline by 45.2% and the wall straightness errors reduce by 1.06%.

Superalloy 625 is a widespread nickel-based alloy, finding enormous applications in aerospace, marine and chemical industries.

It has been recommended to increase TRS, reduce step-size and use moderate size tooltip diameter to enhance geometric accuracy. Step-size has been found to be the governing parameter among all the parameters.

Modeling of material behavior by physically or microstructure-based models helps in understanding the relationships between its properties and microstructure. However, the majority of the numerical investigations on the prediction of the deformation behavior of AA2024 alloy are limited to the use of phenomenological or empirical constitutive models, which fail to take into account the actual microscopic-level mechanisms (i.e. crystallographic slip) causing plastic deformation. In order to achieve accurate predictions, the microstructure-based constitutive models involving the underlying physical deformation mechanisms are more reliable. Therefore, the aim of this work is to predict the mechanical response of AA2024-T3 alloy subjected to uniaxial tension at different strain rates, using a dislocation density-based crystal plasticity model in conjunction with computational homogenization.

A dislocation density-based crystal plasticity (CP) model along with computational homogenization is presented here for predicting the mechanical behavior of aluminium alloy AA2024-T3 under uniaxial tension at different strain rates. A representative volume element (RVE) containing 400 grains subjected to periodic boundary conditions has been used for simulations. The effect of mesh discretization on the mechanical response is investigated by considering different meshing resolutions for the RVE. Material parameters of the CP model have been calibrated by fitting the experimental data. Along with the CP model, Johnson–Cook (JC) model is also used for examining the stress-strain behavior of the alloy at various strain rates. Validation of the predictions of CP and JC models is done with the experimental results where the CP model has more accurately captured the deformation behavior of the aluminium alloy.

The CP model is able to predict the mechanical response of AA2024-T3 alloy over a wide range of strain rates with a single set of material parameters. Furthermore, it is observed that the inhomogeneity in stress-strain fields at the grain level is linked to both the orientation of the grains as well as their interactions with one another. The flow and hardening rule parameters influencing the stress-strain curve and capturing the strain rate dependency are also identified.

Computational homogenization-based CP modeling and simulation of deformation behavior of polycrystalline alloy AA2024-T3 alloy at various strain rates is not available in the literature. Therefore, the present computational homogenization-based CP model can be used for predicting the deformation behavior of AA2024-T3 alloy more accurately at both micro and macro scales, under different strain rates.

As an advanced manufacturing method, additive manufacturing (AM) technology provides new possibilities for efficient production and design of parts. However, with the continuous expansion of the application of AM materials, subtractive processing has become one of the necessary steps to improve the accuracy and performance of parts. In this paper, the processing process of AM materials is discussed in depth, and the surface integrity problem caused by it is discussed.

Firstly, we listed and analyzed the characterization parameters of metal surface integrity and its influence on the performance of parts and then introduced the application of integrated processing of metal adding and subtracting materials and the influence of different processing forms on the surface integrity of parts. The surface of the trial-cut material is detected and analyzed, and the surface of the integrated processing of adding and subtracting materials is compared with that of the pure processing of reducing materials, so that the corresponding conclusions are obtained.

In this process, we also found some surface integrity problems, such as knife marks, residual stress and thermal effects. These problems may have a potential negative impact on the performance of the final parts. In processing, we can try to use other integrated processing technologies of adding and subtracting materials, try to combine various integrated processing technologies of adding and subtracting materials, or consider exploring more efficient AM technology to improve processing efficiency. We can also consider adopting production process optimization measures to reduce the processing cost of adding and subtracting materials.

With the gradual improvement of the requirements for the surface quality of parts in the production process and the in-depth implementation of sustainable manufacturing, the demand for integrated processing of metal addition and subtraction materials is likely to continue to grow in the future. By deeply understanding and studying the problems of material reduction and surface integrity of AM materials, we can better meet the challenges in the manufacturing process and improve the quality and performance of parts. This research is very important for promoting the development of manufacturing technology and achieving success in practical application.

An experimental investigation for developing structure-property correlations of hot-rolled E410 steels with different carbon contents, i.e. 0.04wt.%C and 0.17wt.%C metal active gas (MAG) and cold metal transfer (CMT)-MAG weldments was undertaken.

Mechanical properties and microstructure of MAG and CMT-MAG weldments of two E410 steels with varying content of carbon were compared using standardized mechanical testing procedures, and conventional microscopy.

0.04wt.%C steel had strained ferritic and cementite sub-structures in blocky shape and large dislocation density, while 0.17wt.%C steel consisted of pearlite and polygonal ductile ferrite. This effected yield strength (YS), and microhardness being larger in 0.04wt.%C steel, %elongation being larger in 0.17wt.%C steel. Weldments of both E410 steels obtained with CMT-MAG performed better than MAG in terms of YS, ultimate tensile strength (UTS), %elongation, and toughness. It was due to low heat input of CMT-MAG that resulted in refinement of weld metal, and subzones of heat affected zone (HAZ).

A substantial improvement in YS (∼9%), %elongation (∼38%), and room temperature impact toughness (∼29%) of 0.04wt.%C E410 steel is achieved with CMT-MAG over MAG welding. Almost ∼10, ∼12.5, and ∼16% increment in YS, %elongation, and toughness of 0.17wt.%C E410 steel is observed with CMT-MAG. Relatively low heat input of CMT-MAG leads to development of fine Widmanstätten and acicular ferrite in weld metal and microstructural refinement in HAZ subzones with nearly similar characteristics of base metal.

Gallic acid is a substance that is widely found in nature. Initially, it was only used as a corrosion inhibitor to retard the rate of corrosion of metals. In recent years, with intensive research by scholars, the modification of coatings containing gallic acid has become a hot topic in the field of metal protection. This study aims to summarize the various preparation methods of gallic acid and its research progress in corrosion inhibitors and coatings, as well as related studies using quantum chemical methods to assess the predicted corrosion inhibition effects and to systematically describe the prospects and current status of gallic acid applications in the field of metal corrosion inhibition and protection.

First, the various methods of preparation of gallic acid in industry are understood. Second, the corrosion inhibition principles and research progress of gallic acid as a metal corrosion inhibitor are presented. Then, the corrosion inhibition principles and research progress of gallic acid involved in the synthesis and modification of various rust conversion coatings, nano-coatings and organic resin coatings are described. After that, studies related to the evaluation and prediction of gallic acid corrosion inhibition on metals by quantum chemical methods are presented. Finally, new research ideas on gallic acid in the field of corrosion inhibition and protection of metals are summarized.

Gallic acid can be used as a corrosion inhibitor or coating in metal protection.

There is a lack of research on the synergistic improvement of gallic acid and other substances.

The specific application of gallic acid in the field of metal protection was summarized, and the future research focus was put forward.

To the best of the authors’ knowledge, this paper systematically expounds on the research progress of gallic acid in the field of metal protection for the first time and provides new ideas and directions for future research.

This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.

The mild steel 1010 coupon was considered for the current study. Weight loss and the electrochemical methods were used to evaluate the inhibitory effects of neodymium chloride (NdCl₃) and NdTar on mild steel in NaCl solution. Scanning electron microscopy, energy-dispersive X-ray analysis and attenuated total reflectance-Fourier transform infrared spectroscopy measurements were carried out to study the morphology and composition of the film, nature of deposits and corrosion products formed in test media on the corroded steel, with the objective of further analyzing the observed behavior of the two inhibitors.

Of the two, NdTar performs better than NdCl₃ because it shields mild steel surfaces for longer. According to the results, when NdCl₃ is present in a corrosive solution, the protective film only comprises Nd/Fe oxide/hydroxide/carbonate. However, when neodymium is coupled with the tartrate group (an organic group) and then added to the NaCl solution, the inhibitor film comprises both bimetallic complexes (Fe-Tar-Nd) and metal oxide/hydroxide/carbonate, which results in a more compact film and has higher inhibition efficiency.

This study evaluated the combined effects of inorganic and organic inhibitors with those of an inorganic inhibitor used alone for mild steel in NaCl solution.