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Phase change energy storage is an important solution for overcoming human energy crisis. This study aims to present an evaluation for the thermal performances of a phase change material (PCM) and a PCM–metal foam composite. Effects of pore size, pore density, thermal conductivity of solid structure and mushy region on the thermal storage process are examined.

In this paper, temperature, flow field and solid–liquid interface of a PCM with or without porous media were theoretically assessed. The influences of basic parameters on the melting process were analyzed. A PCM thermal storage device with a metal foam composite is designed and a thermodynamic analysis for it is conducted. The optimal PCM temperature and the optimal HTF temperature in the metal foam-enhanced thermal storage device are derived.

The results show that the solid–liquid interface of pure PCM is a line area and that of the mixture PCM is a mushy area. The natural convection in the melting liquid is intensive for a PCM without porous medium. The porous medium weakens the natural convection and makes the temperature field, flow field and solid–liquid interface distribution more homogeneous. The metal foam can greatly improve the heat storage rate of a PCM.

Thermal storage rate of a PCM is compared with that of a PCM–metal foam composite. A thermal analysis is performed on the multi-layered parallel-plate thermal storage device with a PCM embedded in a highly conductive porous medium, and an optimal melting temperature is obtained with the exergy optimization. The heat transfer enhancement with metal foams proved to be necessary for the thermal storage application.

There is a requirement to match selective laser melting (SLM) technologies to a wider range of polymeric materials, as the existing market for SLM powders is dominated by polyamide PA12. Drivers include the tailoring of physical properties to individual applications or cost reduction. Polypropylene (PP) currently has limited use in SLM; so, this paper aims to explore the potential use of PP materials of varying molecular weight (Mw).

PP polymers of differing Mw were characterised using a range of analytical techniques, including differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), rotational rheometry and real-time hot-stage (optical) microscopy.

The techniques are sufficiently sensitive to distinguish Mw effects, notably in terms of material viscosity. The stable sintering region for SLM has been defined clearly. Some success was achieved in melting parts using all grades of PP, including higher Mw grades, which potentially offer improved mechanical performance.

The range of techniques (DSC, oxidative induction time and TGA) form an effective analytical package with which to consider new polymeric materials for SLM.

High-Mw PP polymers, in tape or powder form, have potential use in SLM processes, providing scope to enhance part properties in future.

This is believed to be the first in-depth study noting the influence of PP Mw on important physical performance in a proprietary SLM process, using holographic beam manipulation.

This study aims to focus on understanding how different jet angles and Reynolds numbers influence the phase change materials’ (PCMs) melting process and their capacity to store energy. This approach is intended to offer novel insights into enhancing thermal energy storage systems, particularly for applications where heat transfer efficiency and energy storage are critical.

The research involved an experimental and numerical analysis of PCM with a melting temperature range of 22 °C–26°C under various conditions. Three different jet angles (45°, 90° and 135°) and two container angles (45° and 90°) were tested. Additionally, two different Reynolds numbers (2,235 and 4,470) were used to explore the effects of jet outlet velocities on PCM melting behaviour. The study used a circular container and analysed the melting process using the hot air inclined jet impingement (HAIJI) method.

The obtained results showed that the average temperature for the last time step at Ф = 90° and Re = 4,470 is 6.26% higher for Ф = 135° and 14.23% higher for Ф = 90° compared with the 45° jet angle. It is also observed that the jet angle, especially for Ф = 90°, is a much more important factor in energy storage than the Reynolds number. In other words, the jet angle can be used as a passive control parameter for energy storage.

This study offers a novel perspective on the effective storage of waste heat transferred with air, such as exhaust gases. It provides valuable insights into the role of jet inclination angles and Reynolds numbers in optimizing the melting and energy storage performance of PCMs, which can be crucial for enhancing the efficiency of thermal energy storage systems.

The purpose of this paper is the study of the electro-vortex flow (EVF) as well as heating and melting processes for mini industrial direct current electric arc furnace (DC EAF).

A mini DC EAF was designed, manufactured and installed to study the industrial processes of heating and melting a small amount of melt, being 4.6 kg of steel in the case under study. Numerical modelling of metal melting was performed using the enthalpy and porosity approach at equal values and non-equal values of the solidus and liquidus temperatures of the metal. The EVF of the liquid phase of metal was computed using the large eddy simulation model of turbulence. Melt temperature measurements were made using an infrared camera and a probe with a thermocouple sensor. The melt speed was estimated by observing the movement of particles at the top surface of melt.

The thermal flux for metal heating and melting, which is supplied through an arc spot at the top surface of metal, is estimated using the thermal balance of the furnace at melting point. The melting time was estimated using numerical modelling of heating and melting of metal. The process started at room temperature and finished once whole volume of metal was molten. The evolution of the solid/melt phase boundary as well as evolution of EVF patterns of the melt was studied.

Numerical studies of heating and melting processes in metal were performed in the case of intensive liquid phase turbulent circulation due to the Lorentz force in the melt, which results from the interaction of electrical current with a self-magnetic field.

During the thermal processing of thin films in which low intensity line heat sources are used, extended processing times are often required to reach steady state (˜15 sec). In addition, the melting of the film may occur some time after processing has begun, and therefore there is no initial melting condition within the film. In such cases, computer simulations may become very time consuming, and the development of an efficient computational method which incorporates the initial formation of the melt during processing is necessary. A general technique was developed to accurately model two‐dimensional heat conduction in a multilayer film structure with one‐dimensional phase change in one of the thin films. These conditions frequently exist in thin film thermal processing when the thermal gradient through the thickness of the melting film can be considered negligible. The method involves an implicit formulation of the modified enthalpy method. The solid/liquid interface energy‐balance equation is taken into account which allows the exact location of the interface to be tracked within a control volume. A comparison is made between the explicit and implicit modified methods to test efficiency and accuracy. The implicit method is then applied to the zone‐melting recrystallization of a silicon thin film in a multilayer structure.

A model study of laser heating process including phase change and molten flow in the melt pool gives physical insight into the process and provides useful information on the influence of melting parameters. In addition, the predictions reduce the experimental cost and minimize the experimental time. Consequently, investigation into laser control melting of the titanium alloy becomes essential. The purpose of this paper is to do this.

Laser repetitive pulse heating of titanium surface is investigated and temperature field as well as Marangoni flow in the melt pool is predicted using finite volume approach. The influence of laser scanning speed and laser pulse parameter (defining the laser pulse intensity distribution at the workpiece surface) on temperature distribution and melt size is examined. The experiment is carried out to validate temperature predictions for two consecutive laser pulses.

The influence of laser scanning speed is significant on the melt pool geometry, which is more pronounced for the laser pulse parameter β=0. Temperature predictions agree with the thermocouple data obtained from the experiment.

Although temperature dependent properties are used in the simulations, isotropy in properties may limit the simulations. The laser canning speed is limited to 0.3 m/s, which is good for surface treatment process, but it may slow for annealing treatments.

The results are very useful to capture insight into the melting process. In addition, the influence of laser scanning speed and laser pulse intensity distribution on the melt formation in the surface vicinity is well presented, which will be useful for those working on laser surface treatment process.

The work is original and findings are new, which demonstrate the influence of laser parameters on the melt pool formation and resulting Marangoni flow.

A transient, three‐dimensional mathematical model of a single‐pass laser surface alloying process has been developed to examine the macroscopic heat, momentum and species transport during the process. A numerical study is performed in a co‐ordinate system moving with the laser at a constant scanning speed. A fixed grid enthalpy‐porosity approach is used, which predicts the evolutionary development of the laser‐melted pool. It is observed that the melting of the added alloying element is not instantaneous in case its melting temperature is higher as compared to that of the base metal. As a result, the addition of alloying element at the top surface cannot be accurately modelled as a mass flux boundary condition at that surface. To resolve this situation, the addition of alloying elements is formulated by devising a species generation term for the solute transport equation. By employing a particle‐tracking algorithm and a simultaneous particle‐melting consideration, the species source term is estimated by the amount of fusion of a spherical particle as it passes through a particular control volume. Numerical simulations are performed for Ni as alloying element on Al base metal. It is revealed that the present model makes a distinctly different prediction of composition variation within the resolidified microstructure, as compared to a model that does not incorporate any considerations of distributed melting.

The purpose of this paper is to solve the problem of a three-dimensional computational analysis for an elliptic-shaped cavity in a pipe under constant temperature.

The three-dimensional computational solution of governing equations was performed by using finite volume method with different temperature difference.

The parafin wax was chosen as a phase change material (PCM), and melting fraction, streamlines and isotherms are formed for different time step. It is found that position B give better results than that of position A, and temperature difference effects the duration of melting of PCM.

The three-dimensional analysis of melting in an ellipsoidal pipe with inner pipe with higher temperature is the main originality of this work.

This study aims to study the impact of intermetallic compound on microstructure, mechanical characteristics and thermal behavior of the melt-spun Bi-Ag high-temperature lead-free solder.

In this paper, a new group of lead-free high-temperature Pb-free solder bearing alloys with five weight percentages of different silver additions, Bi-Ag_x (x = 3.0, 3.5, 4.0, 4.5 and 5.0 Wt.%) have been developed by rapidly solidification processing (RSP) using melt-spun technique as a promising candidate for the replacement of conventional Sn-37Pb common solder. The effect of the addition of a small amount of Ag on the structure, microstructure, thermal and properties of Bi-Ag solder was analyzed by means of X-ray diffractometer, scanning electron microscopy, differential scanning calorimetry and Vickers hardness technique. Applying the RSP commonly results in departures from conventional microstructures, giving an improvement of grain refinement. Furthermore, the grain size of rhombohedral hexagonal phase Bi solid solution and cubic IMC Bi_0.97Ag_0.03 phase is refined by Ag addition. Microstructure analysis of the as soldered revealed that relatively uniform distribution, equiaxed refined grains of secondary IMC Bi_0.97Ag_0.03 particles about 10 µm for Bi-Ag_4.5 dispersed in a Bi matrix. The addition of trace Ag led to a decrease in the solidus and liquidus temperatures of solder, meanwhile, the mushy zone is about 11.4°C and the melting of Sn-Ag_4.5 solder was found to be 261.42°C which is lower compared with the Sn-Ag₃ solder 263.60°C. This means that the silver additions into Bi enhance the melting point. The results indicate that an obvious change in electrical resistivity (?) at room temperature was noticed by the Ag addition. It was also observed that the Vickers microhardness (H_v) was increased with Ag increasing from 118 to 152 MPa. This study recommended the use of the Bi-Ag lead-free solder alloys for higher temperature applications.

Silver content is very important for the soldering process and solder joint reliability. Based on the present investigations described in this study, several conclusions were found regarding an evaluation of microstructural and mechanical deformation behavior of various Bi-Ag solders. The effect of Ag and rapid solidification on the melting characteristics, and microstructure of Bi-Ag alloys were studied. In addition, the mechanical properties of Bi with different low silver were investigated. From the present experimental study, the following conclusions can be drawn. The addition of Ag had a marked effect on the melting temperature of the lead-free solder alloys, it decreases the melting temperature of the alloy from 263.6 to 261.42°C. Bi-Ag solders are comprised of rhombohedral Hex. Bi solid solution and cubic Ag_0.97Bi_0.03 IMC is formed in the Bi matrix. The alloying of Ag could refine the primary Bi phase and the Bi_0.97Ag_0.03 IMC. With increasing Ag content, the microstructure of the Bi-Ag gradually changes from large dimples into tiny dimple-like structures. The refinement of IMC grains was restrained after silver particles were added into the matrix. The inhibition effect on the growth of IMC grains was most conspicuous when solder was doped with Ag particles. As a result, the Vickers microhardness of the Bi-Ag lead-free solder alloys was enhanced by more than 100% ranging from 118.34 to 252.95 MPa. Bi-Ag high-temperature lead-free solders are a potential candidate for replacing the tin-lead solder (Sn-37Pb) materials which are toxic to human and the environment and has already been banned.

This study recommended the use of the Bi-Ag lead-free solder alloys for high-temperature applications.

A numerical study is conducted for natural convection dominated melting inside discretely heated rectangular enclosures. This study finds applications in the design and operation of thermal energy storage units and the cooling of electric equipment. Results show the benefits of discrete heating over uniform heating for optimizing the melting process. For enclosures of high aspect ratios (A ∼> 4), configurations leading to well controlled heat source temperatures and long melting times are obtained. For cavities of low aspect ratios (A ∼< 4), it is found that the source span η is the most influential parameter. For η ∼ < 0.45, the melting times are shorter and the heat source temperatures remain equal and moderate during the entire melting process. A map for determining the cavity size and the source distribution that optimizes the melting process is presented.