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1 – 10 of 15M. Viková, R.M. Christie and M. Vik
In this article, a unique concept for a device that conducts photochromic measurement in the reflectance mode together with the methodology described has been patented in the…
Abstract
In this article, a unique concept for a device that conducts photochromic measurement in the reflectance mode together with the methodology described has been patented in the Czech Republic in the author's name. This unique device allows measurements of colorimetric and spectral characteristics of photochromic textiles as photochromic sensors and also as a fatigue tester for the control of color change stability. The measurement of colorimetric and spectral parameters in comparison together with the intensity of UV irradiation allows the dependence of color change on intensity of irradiation to determined, and a scale for individual visual observation to be developed, as well as the risks of UV irradiation to be evaluated.
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Our previous papers (Viková & Vik, 2005) described a unique device, now patented in the Czech Republic in the author's name, for photochromic measurement in a reflectance mode…
Abstract
Our previous papers (Viková & Vik, 2005) described a unique device, now patented in the Czech Republic in the author's name, for photochromic measurement in a reflectance mode together with a methodology. This device allows photochromic sensors to test the colorimetric and spectral characteristics of photochromic textiles, and also fatigue tests for control of colour change stability. This concept of colorimetric and spectral parameters also finds the dependence of colour change on the intensity of UV irradiation and temperature. In this paper, we would like to describe the dependence of colour change on temperature for the photochromic Photopia AQ Ink system (Blue, Purple and Yellow) produced by Matsui Shikiso Chemical Co.Ltd.
It is known that the reversion of photochromic compounds from coloured to colourless is promoted thermally. The photochromic structure can achieve a lower level of saturated absorbance at higher temperatures when thermo reversible photochromic systems, such as spirooxazines and chromenes, increase the rate of thermal bleaching reaction and thus decrease light stimulated coloration.
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S. Lam Po Tang and G. K. Stylios
The paper aims to provide an overview of the area of smart textiles.
Abstract
Purpose
The paper aims to provide an overview of the area of smart textiles.
Design/methodology/approach
The paper describes and discusses new and developing materials and technologies used in the textile industries.
Findings
Significant progress has been achieved in the area of technical textiles. Fibres, yarns, fabrics and other structures with added‐value functionality have been successfully developed for technical and/or high performance end‐uses. The basic building blocks are already in place in the field of smart textiles and clothing.
Practical implications
As progress in science and engineering research advances, and as the gap between designers and scientists narrows, the area of smart clothing is likely to keep on expanding for the foreseeable future. Growth is predicted to occur in two distinct directions: performance‐driven smart clothing and fashion‐driven smart clothing. There are challenges that have to be addressed.
Originality/value
The paper provides information of value to those interested in the future directions of the textile industry.
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Rithin Kumar N.B., Vincent Crasta and B M Praveen
The purpose of this paper is to explore the synthesis, preparation and investigation of micro structural, optical and mechanical studies of polyvinyl alcohol (PVA) doped with…
Abstract
Purpose
The purpose of this paper is to explore the synthesis, preparation and investigation of micro structural, optical and mechanical studies of polyvinyl alcohol (PVA) doped with tungsten oxide (WO3) nanocomposites films. These films were prepared by simple solvent casting method is further characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), UV-visible spectroscopy, universal testing machine (UTM), scanning electron microscope (SEM), energy-dispersive analysis of X-rays (EDAX) and atomic force microscope (AFM) techniques to determine the enhancement in structural, optical and mechanical properties with increase in dopant concentration.
Design/methodology/approach
The present paper deals with the synthesis of WO3 nanoparticles using precipitation method and doping into PVA matrix to prepare a polymer nanocomposite film using coagulation and solvent casting method. The FTIR explores the interaction of dopants with PVA matrix. The XRD spectra investigate the variation of crystallinity. The UV/Vis-spectra reveals the information of optical energy band gap and the Urbach Energy for different doping concentrations. The mechanical properties of the nanocomposites were exposed using UTM. The phase homogeneity, film topography, chemical composition of nanocomposites is analyzed using SEM, EDAX and AFM techniques supporting the above results.
Findings
The films characterized by FTIR spectroscopy explores the irregular shift in the bands of pure and doped PVA can be understood on the basis of intra/inter molecular hydrogen bonding with the adjacent OH group of PVA backbone. The XRD result reconnoiters that the particle size and crystallinity increases whereas microstructural strain and dislocation density decreases with increase in dopant concentration. Further the drastic decrease in optical energy band gap E g =0.94 eV for doping concentration x=15 wt% and the increase in values of Urbach Energy (E u ) with doping concentrations were investigated by UV/Vis spectra. Also the extinction coefficient was high in the wavelength range of 250-400 nm and low in the wavelength range of 400-1,200 nm. The mechanical studies indicates that the addition of the WO3 with weight percentage concentration x=15 percent increases the tensile strength and Young’s modulus. The phase homogeneity, the particle size of the dopants and chemical composition of nanocomposites is analyzed using SEM and EDAX. The film topography of the nanocomposites is analyzed using AFM techniques supporting the above results.
Originality/value
The investigation of synthesis, preparation and investigation of micro structural, optical and mechanical studies of PVA doped with WO3 nanocomposites films as been done. The results prove that these nanocomposites having good mechanical strength with crystalline nature and also very low optical energy gap value that could find possible applications in industries.
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Gobikannan Tamilmani, Venkhatesan D., Santhosh P., Tamilselvan M., Suryappa Jayappa Pawar and Amin Hirenbhai Navinbhai
This paper aims to study the combination of photochromic microcapsules, which use the ultraviolet (UV) rays for colour changing phenomena, and titanium oxide (TiO2) nanoparticles…
Abstract
Purpose
This paper aims to study the combination of photochromic microcapsules, which use the ultraviolet (UV) rays for colour changing phenomena, and titanium oxide (TiO2) nanoparticles (NPs), which block the UV rays by their photocatalytic activity in the sunlight on the cotton fabric.
Design/methodology/approach
The TiO2 NPs mixed with photochromic printing paste are used for coating on cotton fabric and further curing is performed in a one-step process. The photochromic pigment printed fabric impregnated in a liquid solution is processed in a two-step process with two variables such as 1% TiO2 and 2% TiO2. The characterization of samples was done with a UV transmittance analyser, surface contact angle, antimicrobial test and fabric physical properties.
Findings
The UV protection of TiO2-treated photochromic printed fabric was high and gives the ultraviolet protection factor rating of 2,000 which denotes almost maximum blocking of UV rays. The antibacterial activity of the one-step samples shows the highest 36 mm zone of inhibition (ZOI) against S. aureus (gram-positive) and 32 mm ZOI against E. coli (gram-negative) bacteria. The one-step sample shows the highest static water contact angle of 118.6° representing more hydrophobicity, whereas the untreated fabric is fully wetted (0.4°). In two-step processes, as the concentration of TiO2 increased, the antibacterial activity, UV blocking and hydrophobicity became better.
Originality/value
This work achieves the multifunctional finishes by using photochromic microcapsules and NPs in a single process as a first attempt. The results inferred that one-step sample has achieved higher values in most of the tests conducted when compared to all other sample.
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Examines the seventeenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects…
Abstract
Examines the seventeenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.
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Asim Kumar Roy Choudhury and Biswapati Chatterjee
The purpose of this paper is to compare light fastness assessments by exposure of fabric dyes with various dyes in daylight and an artificial xenon arc lamp.
Abstract
Purpose
The purpose of this paper is to compare light fastness assessments by exposure of fabric dyes with various dyes in daylight and an artificial xenon arc lamp.
Design/methodology/approach
Cotton fabric dyed with 66 reactive, vat, azoic and direct dyes dyed in different depths were exposed to daylight and Xenon arc lamp for assessment of light fastness by standard methods. The light fastness rating and fading hours by the two methods were analysed and compared statistically.
Findings
The correlation between the corresponding light fastness rating (LFR) measured in Xenotest and daylight is quite high (0.93). The logarithmic correlation coefficients between fading hour (FH) and LFR in Xenotest and daylight are 0.95 and 0.88, respectively. For Xenotest, the assessed LFRs are same as those predicted from geometric progression up to LFR of 5.5, and thereafter, the former is higher. On the other hand, in the case of daylight, the assessed LFR is lower. Assessments for three successive seasons showed high repeatability in case of Xenotest and moderate repeatability in case of daylight. Assessments for three successive seasons showed high repeatability in case of Xenotest and moderate repeatability in case of daylight.
Research limitations/implications
The exposure conditions in daylight cannot be controlled or standardised, whereas the exposure in Xenon arc lamp in the accelerated fading instrument can be strictly controlled. These differences in exposure control may affect the repeatability of experimental findings.
Practical implications
Inconsistent ratings may be because of little deterioration of samples during storage, as well as seasonal variation of daylight.
Social implications
There are no direct social implications.
Originality/value
The researches on the comparison of the two light fastness assessment methods have not been reported in any recent publication to the best our knowledge.
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Abstract
Purpose
To develop a method based on urea/microwave treatment for improving the dyeability of the flax fibre.
Design/methodology/approach
The treatment was carried out under a variety of conditions in terms of the power of the microwave, the time of microwave treatment and the use of urea in the treatment solution. The physical chemical properties of the treated flax fibres were characterised using a variety of techniques including scanning electron microscopy (SEM), X‐ray diffractometry, spectrophotometric measurement and tensile measurement.
Findings
It was found that the treated flax fibres had significantly improved dyeability. The causes to the improvement of the dyeability of the flax fibre were found to be the increased absorption of dye on the fibre and the increased reaction probability between the dye and the fibre. The procedure for optimum modification appeared to be soaking the flax fabrics in 10 per cent urea solution; treating the fabrics with microwave at 350 W for 2.5 minutes; and treating the fabrics with microwave at 700 W for one minute.
Practical implications
The treatment method developed addressed a problem of great concern in textile coloration, i.e. poor dyeability of flax fibre. The method developed provided a practical and effective solution to such a problem.
Originality/value
The method of treatment of flax fibre, involving soaking in urea and baking in microwave, for the improvement of dyeability was novel. The method could be adapted for use in industrial scale flax dyeing with satisfactory levels of exhaustion and fixation.
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Abstract
Purpose
To identify the causes to the variation of shade of coloured acrylic sheets from one batch to another and to propose solution to alleviate such a phenomenon.
Design/methodology/approach
A number of analytical techniques, including spectrophotometric measurement, evaluation of dispersion stability, pigment particle size analysis, scanning electron microscopy and transmission electron microscopy, were employed to assess the degree of colour shade variation, the degree of dispersion and nature of the particles within the acrylic sheet formulations and the acrylic sheet products.
Findings
It was found that the variation of shade of the coloured acrylic sheets from one batch to another was mainly caused by the lack of dispersion stability of the pigment particles concerned over time.
Practical implications
The investigation found solutions to the variation of shade of the coloured acrylic sheets from one batch to another.
Originality/value
Colour and colour consistency are a key attribute of the coloured acrylic sheets. Although not frequently encountered, such imperfections were undesirable. The investigation identified the causes to such imperfections and found a way to eliminate such imperfections.
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Abstract
Purpose
The purpose of this paper is to investigate the effects of carbon nanotubes (CNTs) on the mechanical, thermal and colour properties of solvent-containing two-component polyurethane (PU) coating.
Design/methodology/approach
Fourier transform infrared spectroscopy and observation of dispersion stability were used to assess the effects of acid treatment on CNTs. The CNTs and PU composite coating was synthesised by in situ polymerisation and bending polymerisation, and the mechanical, thermal and colour appearance properties of coating were characterised.
Findings
It was found that desirable modifications to CNTs occurred after acid treatment; thus, mainly carboxylic acid groups were introduced onto the surface of CNTs. And the acid-treated CNTs could improve the mechanical and thermal properties of PU coating, and the properties of composite coating was improved more successfully by in situ polymerisation than by blending polymerisation.
Practical implications
The investigation established a method to synthesise CNTs and PU composite coating. The mechanical and thermal properties of PU coating could be improved by the inclusion of CNTs.
Originality/value
This study established a method to synthesise CNTs and PU composite coating by in situ polymerisation and blending polymerisation; the effects of CNTs on modifying mechanical, thermal and colour properties of PU coating were investigated and compared in detail.
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