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In this special feature details are given of those British paints which can be described as corrosion‐resistant primers, both one‐ and two‐pack. The materials are generally classified according to the base or pigment which actively prevents corrosion—e.g. metallic zinc in zinc/epoxy formulations— or by the base which produces a barrier action against corrosion, e.g. bitumen in bituminous paints. Exceptions to this are the etching primers, which are separately classified. About 300 primers are described, the manufacturers' names and addresses being cross‐indexed and listed separately on page 48.

In this second part of the article we learn something more of the conditions in which corrosion of galvanizing can or cannot flourish and of the measures necessary for its prevention. Statistics are listed of experimental work on the life of hot‐dip galvanized coatings and related to different atmospheres.

INHIBITORS. Effect of additives on protective properties of effluent of coke by‐product It was found that the waste water or effluent of a coke by‐products factory contains substances having protective properties in neutral media. Inhibitors such as the Russian KKh (coke over by‐product) have been prepared from such. In the present work the effect of various additives has been investigated. Test samples used were of carbon and low‐carbon steels. They were thoroughly degreased and polished with emery paper, then placed in a desiccator with sulphuric acid for some days. The tests were made at room temperature in media of pH 5 to 8. Rate of corrosion was determined by the weight method; in addition to which the adsorption of ions at the surface of the corroding metal was also studied with the use of radioactive isotopes, P32, S35 and Ca45. The results are recorded and tabulated under the headings: effect of certain passivators, of carbon dioxide, of various chemical additives and of ion adsorption. Carbon dioxide was found to be a very effective additive; also zinc sulphate. It is proposed therefore that, in order to reduce boiler scale and corrosion, the KKh‐1 (effluent) should be treated with carbon dioxide and used as return water in water‐cooling systems of coke by‐product factories. Nine references.—(N. G. Chen, Zh. prikl. Khim., 1961, (5), 1081–1086.)

Sprayed metal coatings have a characteristic structure which greatly influences their behaviour in corrosion processes. The coatings are built up from tiny particles of metal, of the order of 20 microns diameter, produced by atomising molten metal in a stream of compressed air. The metal is supplied to the spraying pistol either as a wire or a powder and is melted in an oxygen‐fuel gas flame. The metals of low melting point, including zinc and aluminium, are also applied by a pistol which receives molten metal from a heated reservoir.

This study aims to study the effect of Sn on the corrosion behavior of weathering steel (WS) in a simulated tropical marine atmosphere.

Indoor alternate immersion tests, electrochemical measurements and real-time current-monitoring technology based on the galvanic corrosion principle were used and the scanning electron microscope, X-ray diffraction, X-ray photoelectron spectroscopy and electron probe microanalyzer were used to analyze the morphology and component of the rust layer.

The results indicated that Sn has a positive influence on the corrosion process. Sn participated in the composition of the rust layer in the form of SnO₂ and is enriched in the inner rust layer. SnO₂ participated in the coprecipitation process with iron oxides and oxyhydroxides, which promoted further transformation of γ-FeOOH to α-FeOOH. As a result, the rust layer of Sn-containing steel was continuous, compact and effectively blocked the invasion of aggressive Cl⁻. Therefore, the additive of Sn enhanced the corrosion resistance of WS in a simulated tropical marine atmosphere.

The corrosion behaviors of WS were researched by the real-time current-monitoring technology which was rarely used.

The anticorrosion coatings used in marine and atmospheric environment are subjected to many environmental factors. And the aging failure has been puzzling researchers. The purpose of this study is to find the correlation between the initial aging of epoxy coatings and the typical marine atmospheric environmental factors.

The epoxy coatings were subjected to a one-year exposure in three typical marine atmospheres. Meanwhile, principal component analysis, linear regression and Spearman and gray correlation analysis were applied to quantify the environmental characteristics and establish correlations with the coating aging.

The results indicate that the coating will undergo macroscopic fading and chalking upon exposure to the marine atmosphere, while microscopic examination reveals holes, cracks and partial peeling. The adhesion performance and electrochemical properties of the coating deteriorated with prolonged exposure, coating aging mainly occurs with the generation of O-H bonds and the breakage of molecular chains such as C-N and C-O-C. The coating was most deeply aged after exposure to the Xisha, followed by Zhoushan and finally Qingdao. Environmental factors affect the photooxidative aging and hydrolytic degradation processes of coatings and thus coating aging. To further demonstrate the correlation between environmental factors and coating aging, principal component analysis was used. The correlation model between environmental factors and coating aging was subsequently obtained. The correlation model between the rate of coating adhesion loss (E) and the comprehensive evaluation parameter of environmental factors (Z) is expressed as E = 0.142 + 0.028Z. Meanwhile, the Spearman correlation analysis and gray correlation method were used to investigate the impact of each environmental factor on coating aging. Solar irradiation, relative humidity and wetting time have the highest correlation with coating aging, which are all above 0.8 and have the greatest influence on coating aging; wind speed and temperature have the smallest correlation with coating aging, which are about 0.6 and have the least influence on coating aging.

This paper establishes a correlation between typical marine environmental factors and coating aging performance, which is crucial for predicting the service life of other coatings in diverse environments.

Marine corrosion is one of those generic titles that many understand but very few can define. Basically it is corrosion due to sea‐water but, in fact, the worse corrosion is experienced when the sea‐water is present in the form of a mist. Any consideration of marine corrosion must, in consequence, be based on the corrosivity of sea‐water, sea‐water‐laden atmospheres, and mixtures of these.

In this article a resume is given of the principal obsevations made during the course of exposure in a natural atmosphere during some twenty years, while choosing the most characteristic examples. The following points will be examined: Resistance to spray and mist of aluminium‐magnesium, aluminium‐magnesium‐silicon, aluminium‐ zinc‐magnesium, and aluminium‐copper magnesium rolled alloys, and of cast alloys; Behaviour of welds, and of contacts with steel and cement; Behaviour during immersion in the sea, and corrosion by differential aeration; Protection by anodisation. These observations have been made during exposure at the experimental stations of the Pechiney Group, in marine atmospheres at Salin‐de‐Giraud (Mediterranean), Saint‐Jean‐de‐Luz, Biarritz and Ostend, and in an industrial atmosphere at Aubervilliers.

In the present work, the protective properties of inhibitive pigments in two epoxy‐primers against corrosion of the aluminium alloy 2024T3 in marine atmosphere were investigated, the first containing SrCrO₄ and the second Zn₃(PO₄)₂. Potentiostatic polarisation and impedance measurement methods were utilised to evaluate, both the spontaneous onset of defects on coated samples and the propagation of a small artificial defect of known dimension applied since the beginning of the test on each sample, during 24 months of exposure to the marine atmosphere. These techniques enabled a quantitative evaluation of the protective efficiency of the two primers to be made, and for the effects of the surface pre‐treatments of the metallic substrate to be investigated.

The purpose of this paper is to explore the environment around the rail track at different sites in Nile Delta region, Egypt, through the measurements of the air pollutants and corrosive ionic species present in surface soil and also to investigate the impact of the existing contaminants on the composition of iron rust formed on the rail head surface at these sites and then the durability of rail itself.

The soil characterization was studied by means of sieve shakers, pH meter, conductivity meter and ion chromatography instrument. Scanning electron microscopy, energy dispersive spectrometry, Fourier transform infrared spectroscopy and X-ray diffraction were used to characterize the rust layer formed on the rail head surface.

The results showed the relation between the contaminants and the composition of the rust layer. Magnetite and goethite were the major phases identified in the rust layers. Akaganeite was detected in the marine atmosphere. Iron sulfide and iron oxide nitrate hydroxide were detected in environments rich in H₂S and NO₂ gases, respectively. The appearance of phases like FeCl₂ and FeOCl only at marine atmospheres reflects that the corrosive species in suspended particulate matter like chloride ion have a higher effect on the rust composition of the rail head surface than that in surface soil layer.

This paper revealed the impact of air and soil contaminants on the composition of rust layer on the rail head surface and may provide guidance for the durability of rails and the necessity for their preservation.