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1 – 10 of 191The purpose of this study is to prepare a new adsorbent activated carbon immobilized on polystyrene (ACPS) for uranium (VI) and thorium (IV) removal from an aqueous solution…
Abstract
Purpose
The purpose of this study is to prepare a new adsorbent activated carbon immobilized on polystyrene (ACPS) for uranium (VI) and thorium (IV) removal from an aqueous solution. Activated carbon (AC) was derived from biochar material by chemical activation to increase the active sites on its surface and enhance the adsorption capacity. Activated carbon (AC) was immobilized on polystyrene (PS) to improve the physical properties and facilitate separation from the working solution. A feasibility study for the adsorption of uranium (VI) and thorium (IV) on the new adsorbent (ACPS) has been achieved. Adsorption kinetics, isotherms, and thermodynamics models of the adsorption process were used to describe the reaction mechanism.
Design/methodology/approach
Activated carbon was synthesized from biochar charcoal by 2 M H2SO4. Activated carbon was immobilized on the pretreatment polystyrene by hydrothermal process forming new adsorbent (ACPS). Characterization studies were carried out by scanning electron microscope, energy-dispersive X-ray spectrometer, infrared spectroscopy and X-ray diffraction techniques. Different factors affect the adsorption process as pH, contact time, solid/liquid ratio, initial concentration and temperature. The adsorption mechanism was explained according to kinetic, isothermal and thermodynamic studies. Also, the regeneration of spent ACPS was studied.
Findings
The experimental results showed that pH and equilibrium time of the best adsorption were 6.0 and 60 min for U(VI), 4.0 and 90 min for Th(IV), (pHPZC = 3.4). The experimental results fit well with pseudo-second order, Freundlich and Dubinin–Radushkevich models proving the chemisorption and heterogenous adsorption reaction. Adsorption thermodynamics demonstrated that the adsorption process is exothermic and has random nature of the solid/liquid interface. In addition, the regeneration of spent ACPS research showed that the adsorbent has good chemical stability. According to the comparative study, ACPS shows higher adsorption capacities of U(VI) and Th(IV) than other previous bio-adsorbents.
Originality/value
This study was conducted to improve the chemical and physical properties of bio-charcoal purchased from the local market to activated carbon by hydrothermal method. Activated carbon was immobilized on polystyrene forming new adsorbent ACPS for eliminating U(VI) and Th(IV) from aqueous solutions.
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Chigoziri N. Njoku, Temple Uzoma Maduoma, Wilfred Emori, Rita Emmanuel Odey, Beshel M. Unimke, Emmanuel Yakubu, Cyril C. Anorondu, Daniel I. Udunwa, Onyinyechi C. Njoku and Kechinyere B. Oyoh
Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to…
Abstract
Purpose
Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to protect metals from deterioration in corrosive environments. Moreover, the toxic nature, non-biodegradability and price of most conventional corrosion inhibitors have encouraged the application of greener and more sustainable options, with natural and synthetic drugs being major actors. Hence, this paper aims to stress the capability of natural and synthetic drugs as manageable and sustainable, environmentally friendly solutions to the problem of metal corrosion.
Design/methodology/approach
In this review, the recent developments in the use of natural and synthetic drugs as corrosion inhibitors are explored in detail to highlight the key advancements and drawbacks towards the advantageous utilization of drugs as corrosion inhibitors.
Findings
Corrosion is a critical issue in numerous modern applications, and conventional strategies of corrosion inhibition include the use of toxic and environmentally harmful chemicals. As greener alternatives, natural compounds like plant extracts, essential oils and biopolymers, as well as synthetic drugs, are highlighted in this review. In addition, the advantages and disadvantages of these compounds, as well as their effectiveness in preventing corrosion, are discussed in the review.
Originality/value
This survey stresses on the most recent abilities of natural and synthetic drugs as viable and sustainable, environmentally friendly solutions to the problem of metal corrosion, thus expanding the general knowledge of green corrosion inhibitors.
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M. Hassanein, M. Abd El Rahm, H. M. Abd El Bary and H. Abd El-Wahab
This paper aims to study the physical and chemical characteristics of inkjet titanium dioxide inks for cotton fabric digital printing.
Abstract
Purpose
This paper aims to study the physical and chemical characteristics of inkjet titanium dioxide inks for cotton fabric digital printing.
Design/methodology/approach
Different dispersing agents through the reaction of glycerol monooleate and toluene diisocyanate were prepared and then performed by using three different polyols (succinic anhydride-modified polyethylene glycol PEG 600, EO/PO Polyether Monoamine and p-chloro aniline Polyether Monoamine), to obtain three different dispersing agents for water-based titanium dioxide inkjet inks. The prepared dispersants were characterized using FTIR to monitor the reaction progress. Then the prepared dispersants were formulated in titanium dioxide inkjet inks formulation and characterized by particle size, dynamic surface tension, transmission electron microscopy, viscosity and zeta potential against commercial dispersants. Also, the study was extended to evaluate the printed polyester by using the prepared inks according to washing and crock fastness.
Findings
The obtained results showed that p-chloro aniline Polyether Monoamine (J) and succinic anhydride modified polyethylene glycol PEG 600 (H) dispersants provided optimum performance as compared to commercial standards especially, particle size distribution data while EO/PO Polyether Monoamine based on dispersant was against and then failed with the wettability and dispersion stability tests.
Practical implications
These ink formulations could be used for printing on cotton fabric by DTG technique of printing and can be used for other types of fabrics.
Originality/value
The newly prepared ink formulation for digital textile printing based on synthesized polyurethane prepolymers has the potential to be promising in this type of printing inks, to prevent clogging of nozzles on the printhead and to improve the print quality on the textile fiber.
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Roma G. Elfadel, Hala M. Refat, H. Abdelwahab, Salem S. Salem, Mohamed A. Awad and M.A.M. Abdel Reheim
This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.
Abstract
Purpose
This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.
Design/methodology/approach
Salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid were prepared and used as new sources of polyol and dibasic acid for PEA and alkyd resins, then confirmed by: acid value, FT-IR and 1H-NMR. The coating performance of the resins was determined using measurements of physico-mechanical properties. The biological and insecticide activities of the prepared resins were investigated.
Findings
The tests carried out revealed that the modified PEA and alkyd enhanced both phyisco-mechanical and chemical properties in addition to the biological and insecticide activities. The results of this paper illustrate that the introduction of salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid within the resin structure improved the film performance and enhanced the antimicrobial activity performance of PEA and alkyd resins.
Research limitations/implications
The modified alkyd and PEA organic resins can be used as biocidal binders when incorporated into paint formulations for multiple surface applications, especially those that are exposed to several organisms.
Originality/value
Modified alkyd and PEA resins based on newly synthesized modifiers have a significant potential to be promising in the production and development of antimicrobial and insecticide paints, allowing them to function to restrict the spread of insects and microbial infection.
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Walid E. Elgammal, Essam M. Eliwa, Hosni A. Goomaa, Medhat E. Owda and H. Abd El-Wahab
This paper aims to focus on the synthesis of the macrocyclic complexes (Cu and Zn) and their applications as anticorrosive materials in epoxy paint formulation for surface coating…
Abstract
Purpose
This paper aims to focus on the synthesis of the macrocyclic complexes (Cu and Zn) and their applications as anticorrosive materials in epoxy paint formulation for surface coating application.
Design/methodology/approach
A selected macrocyclic Cu(II) and Zn(II) complexes were prepared via template synthesis and characterized using Fourier transform infrared, thermal gravimetric analysis, scanning electron microscope, flexibility, hardness and adhesion of coating films prepared using epoxy paint.
Findings
The corrosion resistance of the epoxy-painted films was improved due to the incorporation of the Zn and Cu complexes into the formulation.
Originality/value
It was found that the metal complex-based formulation with Cu(II) and Zn(II) had outperformed the sample blank.
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Heba Tolla El Sayed Abo El Naga and Manar Yahia Ismail Abd El-Aziz
Synthetic materials have many drawbacks in high-performance garments because they absorb less moisture and cause allergies to sensitive individuals. Cotton materials cannot…
Abstract
Purpose
Synthetic materials have many drawbacks in high-performance garments because they absorb less moisture and cause allergies to sensitive individuals. Cotton materials cannot satisfy all the requirements and cannot provide the required high performance. This study aims to use eco-friendly materials with a common structure to analyse their suitability for high-performance garment application.
Design/methodology/approach
This study used two eco-friendly yarns (bamboo, modal and bamboo: modal 50:50) and yarns per needle (two- and four-ply yarns). with a single jersey knit construction and gauge of 7. The physical, mechanical, appearance, comfort, thermal and ultraviolet protection factor (UPF) protection characteristics were evaluated using 15 tests.
Findings
The produced knitted fabrics showed high performance for use as garments with physical, mechanical, appearance, comfort, thermal and UPF protection characteristics that were achieved, tested and analysed. The highest-achieved samples with a good UPF (<15) were made from bamboo material, which has other high-performance characteristics such as antibacterial characteristics, a soft surface, thermal insulation and others.
Research limitations/implications
The single jersey structure was used for producing fabrics as it is the common structure in the garment. Also, only gauge 7 was used for its economics and ease of production.
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Amal Mohamed El-Moursy, Zeinab Mohmed Abdel Mageid, Manar Yahia Ismail Abd El-Aziz, Nour Asser and Osama Hakeim
Wearing clothes requires specifications for feeling comfortable, derived from the fibres, fabrics and finishing properties. This study aims to deal with the effect of economic…
Abstract
Purpose
Wearing clothes requires specifications for feeling comfortable, derived from the fibres, fabrics and finishing properties. This study aims to deal with the effect of economic blends containing hollow fibres, bamboo and cotton/polyester waste on the mechanical properties of the produced fabrics and the appropriate end use.
Design/methodology/approach
This research included two blends: one consisted of cotton/polyester wastes blended with bamboo and the other to which Chorisia fibres were added. Two weft counts 10,6/1 Ne were made from each blend, which were used to produce four fabric samples (S1 Chorisia-free and S2 with Chorisia); additionally, another two samples were dyed that contain Chorisia (S3) from each count. The six samples were tested by Kawabata Evaluation System (KES).
Findings
The samples gave a good total hand value (THV) for use as men's winter suits, where the thicker count 6/1, with and without Chorisia had better properties, also both counts 6, 10/1 with dye. The hollow fibres affected the fabrics’ properties, including thickness, shear, bending, thermal conductivity and weight. Both blends had a positive effect on THV.
Research limitations/implications
Cotton/polyester waste, Chorisia and bamboo fibres were tested, and 2% Remazol Yellow GNL dye was used.
Practical implications
The ratio of blending, weft counts and dye affected the fabric’s properties, with consequences for the use of the Kawabata system and its applications.
Social implications
The fabrics used in this research may be considered to be economical and have good THV.
Originality/value
The study proved the usefulness of fabrics made of two blends. The Chorisia component may be seen as a good alternative to cotton fibres to reduce the cost of producing high-consumption winter suit fabrics.
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Haider Jouma Touma, Muhamad Mansor, Muhamad Safwan Abd Rahman, Yong Jia Ying and Hazlie Mokhlis
This study aims to investigate the feasibility of proposed microgrid (MG) that comprises photovoltaic, wind turbines, battery energy storage and diesel generator to supply a…
Abstract
Purpose
This study aims to investigate the feasibility of proposed microgrid (MG) that comprises photovoltaic, wind turbines, battery energy storage and diesel generator to supply a residential building in Grindelwald which is chosen as the test location.
Design/methodology/approach
Three operational configurations were used to run the proposed MG. In the first configuration, the electric energy can be vended and procured utterly between the main-grid and MG. In the second configuration, the energy trade was performed within 15 kWh as the maximum allowable limit of energy to purchase and sell. In the third configuration, the system performance in the stand-alone operation mode was investigated. A whale optimization technique is used to determine the optimal size of MG in all proposed configurations. The cost of energy (COE) and other measures are used to evaluate the system performance.
Findings
The obtained results revealed that the first configuration is the most beneficial with COE of 0.253$/KWh and reliable 100%. Furthermore, the whale optimization algorithm is sufficiently feasible as compared to other techniques to apply in the applications of MG.
Originality/value
The value of the proposed research is to investigate to what extend the integration between MG and main-grid is beneficial economically and technically. As opposed to previous research studies that have focused predominantly only on the optimal size of MG.
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Mona Saied, Abeer Reffaee, Shimaa Hamieda, Salwa L. Abd- El- Messieh and Emad S. Shafik
This study aims to get rid of non-degradable polyvinyl chloride (PVC) waste as well as sunflower seed cake (SSC) waste by preparing eco-friendly composites from both in different…
Abstract
Purpose
This study aims to get rid of non-degradable polyvinyl chloride (PVC) waste as well as sunflower seed cake (SSC) waste by preparing eco-friendly composites from both in different proportions to reach good mechanical and insulating properties for antimicrobial and antistatic applications.
Design/methodology/approach
Eco-friendly composite films based on waste polyvinylchloride (WPVC) and SSC of concentrations (0, 10, 20, 30 and 40 Wt.%) were prepared using solution casting method. Further, the effect of sunflower seed oil (SSO) on the biophysical properties of the prepared composites is also investigated. Fourier transform infrared spectroscopy, X-ray diffraction (XRD), scanning electron microscope, mechanical, thermal, dielectric properties were assessed. Besides, the antimicrobial and biodegradation tests were also studied.
Findings
The crystallinity increases by rising SSC concentration as revealed by XRD results. Additionally, the permittivity (ε′) increases by increasing SSC filler and SSO as well. A remarkable increase in dc conductivity was attained after the addition of SSO. While raw WPVC has very low bacterial activity. The composite films are found to be very effective against staphylococcus epidermidis, staphylococcus aureus bacteria and against candida albicans as well. On the other hand, the weight loss of WPVC increases by adding of SSC and SSO, as disclosed by biodegradation studies.
Originality/value
The study aims to reach the optimum method for safe and beneficial disposal of PVC waste as well as SSC for antistatic and antimicrobial application.
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Mohamed Moshreh Ali Ahmed, Dina Kamal Abd El Salam Ali Hassan and Nourhan Hesham Ahmed Magar
The purpose of this paper is to investigate whether audit committee characteristics, in particular audit committee size, audit committee activity and audit committee gender…
Abstract
Purpose
The purpose of this paper is to investigate whether audit committee characteristics, in particular audit committee size, audit committee activity and audit committee gender diversity, are associated with financial performance in Egyptian banks. The second purpose of this paper is to explore the moderating role of board gender diversity on the relationship between audit committee characteristics and financial performance.
Design/methodology/approach
A multiple regression analysis is used to estimate the moderating role of board gender diversity on the relationship between audit committee characteristics and financial performance of a sample of Egyptian banks during the period between 2018 and 2022.
Findings
The results indicate that audit committee size has a negative and insignificant effect impact on return on assets (ROA) and return on equity (ROE), respectively. The results also indicate that the audit committee gender diversity has a significant positive impact on ROA and ROE, respectively. Regarding audit committee activity, the number of board meetings has a negative and insignificant effect on ROA and ROE, respectively. Regarding gender diversity as a moderating variable, in general there is a positive effect of gender diversity on the relationship between audit committee characteristics and financial performance.
Research limitations/implications
The study was limited to 20 banks in one country, but it sets the tone for future empirical research on this subject matter. The study also relied on one moderating variable, which is board gender diversity. This study provides an avenue for future research in the area of corporate governance and financial performance in other emerging countries, especially other African countries.
Practical implications
This study provides useful insights for managers and policymakers to better understand which audit committee characteristics can best encourage a company to improve financial performance. Furthermore, regulators should ensure that banks strictly adhere to corporate governance principles to build a strong banking industry capable of achieving economic development.
Social implications
Banks will benefit equally from valuable qualities across demographic groupings in society by having females on the audit committee and appropriate audit committee meetings. Additionally, if audit committee members are correctly selected, banks with more females in audit committee and suitable audit committee meetings can successfully contribute to strengthening financial performance and social welfare of diverse segments of society. A culture of good banking governance must emerge to improve bank financial stability and, as a result, greater stability and economic growth.
Originality/value
To the best of the authors’ knowledge, the study is, perhaps, the first to examine the moderating role of board gender diversity on the relationship between audit committee characteristics and financial performance in Egyptian banks. This study adds to the literature by investigating such an issue in a developing economy that operates in a different context than those in developed countries.
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