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Article
Publication date: 1 August 2023

Veysi Ökten, Reşit Yıldız and Gökmen Sığırcık

This study aims to prevent mild steel (MS) against corrosion in 0.5 M HCl solution, 2-amino-4-methoxy-6-methyl-1,3,5-triazine was used. The effectiveness of the compound as a…

Abstract

Purpose

This study aims to prevent mild steel (MS) against corrosion in 0.5 M HCl solution, 2-amino-4-methoxy-6-methyl-1,3,5-triazine was used. The effectiveness of the compound as a corrosion inhibitor was studied via electrochemical, surface and theoretical calculation techniques.

Design/methodology/approach

For concentrations ranging from 0.5 to 10.0 mM, almost similar polarization resistances were obtained from electrochemical impedance spectroscopy (EIS) and linear polarization resistance tests. It also investigated inhibitive activity of 2-amino-4-methoxy-6-methyl-1,3,5-triazine on the steel surface using scanning electron and atomic force microscope instruments. Langmuir adsorption is the best matched isotherm for the adsorption of the inhibitor to the steel surface.

Findings

EIS method was used to determine inhibition efficiency, which was determined to be 95.7% for 10.0 mM inhibitor containing acid solution. Density functional theory’s predictions for quantum chemistry agreed well with the other experimental results.

Originality/value

The methods used in this study are effective and applicable; the used organic inhibitor is 2-amino-4-methoxy-6-methyl-1,3,5-triazine; and protective effectiveness is important, which is crucial for the task of MS corrosion prevention.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 5 October 2023

Minakshi Koundal, Ajay Kumar Singh and Chhaya Sharma

This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.

Abstract

Purpose

This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.

Design/methodology/approach

The mild steel 1010 coupon was considered for the current study. Weight loss and the electrochemical methods were used to evaluate the inhibitory effects of neodymium chloride (NdCl3) and NdTar on mild steel in NaCl solution. Scanning electron microscopy, energy-dispersive X-ray analysis and attenuated total reflectance-Fourier transform infrared spectroscopy measurements were carried out to study the morphology and composition of the film, nature of deposits and corrosion products formed in test media on the corroded steel, with the objective of further analyzing the observed behavior of the two inhibitors.

Findings

Of the two, NdTar performs better than NdCl3 because it shields mild steel surfaces for longer. According to the results, when NdCl3 is present in a corrosive solution, the protective film only comprises Nd/Fe oxide/hydroxide/carbonate. However, when neodymium is coupled with the tartrate group (an organic group) and then added to the NaCl solution, the inhibitor film comprises both bimetallic complexes (Fe-Tar-Nd) and metal oxide/hydroxide/carbonate, which results in a more compact film and has higher inhibition efficiency.

Originality/value

This study evaluated the combined effects of inorganic and organic inhibitors with those of an inorganic inhibitor used alone for mild steel in NaCl solution.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 5 April 2024

Kryzelle M. Atienza, Apollo E. Malabanan, Ariel Miguel M. Aragoncillo, Carmina B. Borja, Marish S. Madlangbayan and Emel Ken D. Benito

Existing deterministic models that predict the capacity of corroded reinforced concrete (RC) beams have limited applicability because they were based on accelerated tests that…

Abstract

Purpose

Existing deterministic models that predict the capacity of corroded reinforced concrete (RC) beams have limited applicability because they were based on accelerated tests that induce general corrosion. This research gap was addressed by performing a combined numerical and statistical analysis on RC beams, subjected to natural corrosion, to achieve a much better forecast.

Design/methodology/approach

Data of 42 naturally corroded beams were collected from the literature and analyzed numerically. Four constitutive models and their combinations were considered: the elastic-semi-plastic and elastic-perfectly-plastic models for steel, and two tensile models for concrete with and without the post-cracking stresses. Meanwhile, Popovics’ model was used to describe the behavior of concrete under compression. Corrosion coefficients were developed as functions of corrosion degree and beam parameters through linear regression analysis to fit the theoretical moment capacities with test data. The performance of the coefficients derived from different combinations of constitutive laws was then compared and validated.

Findings

The results showed that the highest accuracy (R2 = 0.90) was achieved when the tensile response of concrete was modeled without the residual stresses after cracking and the steel was analyzed as an elastic-perfectly-plastic material. The proposed procedure and regression model also showed reasonable agreement with experimental data, even performing better than the current models derived from accelerated tests and traditional procedures.

Originality/value

This study presents a simple but reliable approach for quantifying the capacity of RC beams under more realistic conditions than previously reported. This method is simple and requires only a few variables to be employed. Civil engineers can use it to obtain a quick and rough estimate of the structural condition of corroding RC beams.

Details

International Journal of Structural Integrity, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1757-9864

Keywords

Article
Publication date: 10 August 2023

Clément Génin, Marc Jeannin, Anne-Marie Grolleau and Philippe Refait

The purpose of this study is to investigate cathodic protection (CP) efficiency in the tidal zone and its associated processes.

Abstract

Purpose

The purpose of this study is to investigate cathodic protection (CP) efficiency in the tidal zone and its associated processes.

Design/methodology/approach

Specific features of CP in the tidal zone, that is, persistence of a thin seawater film and insufficient cathodic potential due to ohmic drop, were addressed. In this preliminary study, carbon steel electrodes were polarized at two cathodic potentials (correct or insufficient protection) while immersed in 1 mm or 5 mm thick natural seawater layers. After CP interruption, the protective ability of the layers covering the steel electrodes was studied using various electrochemical methods, including electrochemical impedance spectroscopy. The layers were characterized by XRD.

Findings

The protective ability of calcareous deposits was increased in thin seawater films. Insufficient CP could promote protective aragonite/corrosion products layer.

Originality/value

The combined effects of thin seawater film and applied potential were never addressed, and the conclusions drawn from this preliminary study give new insight on the efficiency of CP in the tidal zone.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 21 February 2024

Shuliu Wang, Qianqian Liu, Jin Wang, Nana Chen, JunHang Chen, Jialiang Song, Xin Zhang and Kui Xiao

This study aims to investigate the role of aluminium (Al) in marine environment and the corrosion mechanism of galvalume coatings by conducting accelerated experiments and data…

Abstract

Purpose

This study aims to investigate the role of aluminium (Al) in marine environment and the corrosion mechanism of galvalume coatings by conducting accelerated experiments and data analysis.

Design/methodology/approach

Samples were subjected to accelerated corrosion for 136 days via salt spray tests to simulate the natural conditions of marine environment and consequently accelerate the experiments. Subsequently, the samples were examined using various test methods, such as EDS, scanning electron microscopy (SEM), X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS), and the obtained data were analysed.

Findings

Galvalume coatings comprised interdigitated zinc (Zn)-rich and dendritic Al-rich phases. Corrosion was observed to begin with a Zn-rich phase. The primary components of the corrosion product film were Al2O3 and Zn5(OH)8Cl2·H2O. It was confirmed that the role of Al was to form a dense protective film, thereby successfully blocking the entry of corrosive media and protecting the iron substrate.

Originality/value

This study provides a clearer understanding of the corrosion mechanism and kinetics of galvalume coatings in a simulated marine environment. In addition, the role of Al, which is rarely mentioned in the literature, was investigated.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Open Access
Article
Publication date: 18 January 2024

Puyu Yang and Giovanni Colavizza

Wikipedia's inclusive editorial policy permits unrestricted participation, enabling individuals to contribute and disseminate their expertise while drawing upon a multitude of…

Abstract

Purpose

Wikipedia's inclusive editorial policy permits unrestricted participation, enabling individuals to contribute and disseminate their expertise while drawing upon a multitude of external sources. News media outlets constitute nearly one-third of all citations within Wikipedia. However, embracing such a radically open approach also poses the challenge of the potential introduction of biased content or viewpoints into Wikipedia. The authors conduct an investigation into the integrity of knowledge within Wikipedia, focusing on the dimensions of source political polarization and trustworthiness. Specifically, the authors delve into the conceivable presence of political polarization within the news media citations on Wikipedia, identify the factors that may influence such polarization within the Wikipedia ecosystem and scrutinize the correlation between political polarization in news media sources and the factual reliability of Wikipedia's content.

Design/methodology/approach

The authors conduct a descriptive and regression analysis, relying on Wikipedia Citations, a large-scale open dataset of nearly 30 million citations from English Wikipedia. Additionally, this dataset has been augmented with information obtained from the Media Bias Monitor (MBM) and the Media Bias Fact Check (MBFC).

Findings

The authors find a moderate yet significant liberal bias in the choice of news media sources across Wikipedia. Furthermore, the authors show that this effect persists when accounting for the factual reliability of the news media.

Originality/value

The results contribute to Wikipedia’s knowledge integrity agenda in suggesting that a systematic effort would help to better map potential biases in Wikipedia and find means to strengthen its neutral point of view policy.

Details

Online Information Review, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1468-4527

Keywords

Article
Publication date: 6 December 2023

Labeeba Kothur and Vidushi Pandey

This paper aims to investigate the mechanisms through which social media news consumption across different platforms leads to opinion polarization in society. To this end, the…

Abstract

Purpose

This paper aims to investigate the mechanisms through which social media news consumption across different platforms leads to opinion polarization in society. To this end, the authors draw from cultivation theory to examine whether social media news consumption imparts a mainstreaming or resonance effect. Media consumption imparts a mainstreaming effect if frequent users, regardless of their social identity, develop homogenous attitudes about issues, whereas resonance is at play if there is a differing cultivation effect on various social groups depending on their relatability of life experiences.

Design/methodology/approach

The authors conduct the study in the developing context of India, using a population survey dataset from 2019. Regression-based mediation and moderation analyses were carried out to test the hypotheses.

Findings

The findings reveal that resonance is the most prominent mechanism through which social media news consumption cultivates opinion polarization, contrary to the mainstreaming effect imparted by television. Further, WhatsApp use was found to strengthen the polarizing effect of overall social media news consumption, while YouTube use weakened the cultivation of polarization.

Research limitations/implications

The paper unearths how social media news consumption influences the opinion polarization of various social groups differently. The authors also find the differential effect of specific platform use. These findings have the potential to inform policymakers and developers about how to mitigate the detrimental effects of platform-based political persuasion.

Originality/value

This study offers significant contributions. First, the authors explain social media-induced polarization using the novel theoretical lens of cultivation. Second, the authors find that social media and television news consumption differ in their polarizing effects. Third, the authors find that while WhatsApp use amplifies the polarizing effect of social media news consumption, YouTube use weakens it.

Details

Information Technology & People, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0959-3845

Keywords

Article
Publication date: 9 May 2023

Mohamed Elkattan and Aladin H. Kamel

The purpose of this study is to develop an efficient model to solve the electromagnetic forward problem using a novel semi-analytical approach to compute the electromagnetic…

26

Abstract

Purpose

The purpose of this study is to develop an efficient model to solve the electromagnetic forward problem using a novel semi-analytical approach to compute the electromagnetic fields because of the presence of a scatterer.

Design/methodology/approach

The proposed model involves a novel formulation of a complete orthonormal set of radiating/nonradiating polarization currents. Furthermore, an integral equation-based representation is derived, and the appropriate boundary conditions are imposed to get the scattered electromagnetic field. An error term is introduced to evaluate the obtained results.

Findings

The proposed model was tested using several examples at different frequencies. The results of this study show that the novel representation exhibits fast convergence behavior and achieves highly accurate results, when compared to the results provided by the transmission line method.

Originality/value

The derived formulations presented in this study are significant in the electromagnetic forward modelling field because of the meaningful physical representation they provide. This is an important aspect that leads to precise calculation of electromagnetic fields for various applications.

Details

COMPEL - The international journal for computation and mathematics in electrical and electronic engineering , vol. 42 no. 6
Type: Research Article
ISSN: 0332-1649

Keywords

Article
Publication date: 5 January 2024

Hafte Gebreselassie Gebrihet and Martin Limbikani Mwale

The purpose of this study is to examine the effect of polarisation on trust in government.

Abstract

Purpose

The purpose of this study is to examine the effect of polarisation on trust in government.

Design/methodology/approach

The authors use the ordered probit technique to model trust as a function of polarisation and various control variables. The authors apply the instrumental variables approach to address potential endogeneity in polarisation, using ethnic diversity as an instrument.

Findings

The results reveal that an increase in polarisation reduces trust in central government. However, trust in local government is non-responsive to this polarisation. The estimations controlled for government performance, and the authors found a positive association between government performance and trust in government, which, however, does not alter the relationship between polarisation and trust in government.

Practical implications

In ethnically polarised nations, policymakers should consider decentralisation measures. This can help sustain trust and development support, particularly in regions where citizens prioritise ethnicity over nationality.

Social implications

The social implications of this research underscore the importance of promoting trust in government to foster social cohesion and stability, particularly in ethnically diverse societies.

Originality/value

The authors find that increased ethnic polarisation reduces trust in the central government, particularly among those prioritising their ethnicity over nationality. This adds a non-performance dimension to government trust literature, suggesting that policies focusing solely on performance may yield limited results. The research extends beyond central government trust to include local governments. Unlike central government, local government trust remains tied to performance attributes unaffected by polarisation. Hence, investing resources through local governments is a viable strategy for enhancing citizen support while mitigating polarisation’s adverse effects.

Details

Transforming Government: People, Process and Policy, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1750-6166

Keywords

Article
Publication date: 3 August 2023

Yandong Hou, Zhengbo Wu, Xinghua Ren, Kaiwen Liu and Zhengquan Chen

High-resolution remote sensing images possess a wealth of semantic information. However, these images often contain objects of different sizes and distributions, which make the…

Abstract

Purpose

High-resolution remote sensing images possess a wealth of semantic information. However, these images often contain objects of different sizes and distributions, which make the semantic segmentation task challenging. In this paper, a bidirectional feature fusion network (BFFNet) is designed to address this challenge, which aims at increasing the accurate recognition of surface objects in order to effectively classify special features.

Design/methodology/approach

There are two main crucial elements in BFFNet. Firstly, the mean-weighted module (MWM) is used to obtain the key features in the main network. Secondly, the proposed polarization enhanced branch network performs feature extraction simultaneously with the main network to obtain different feature information. The authors then fuse these two features in both directions while applying a cross-entropy loss function to monitor the network training process. Finally, BFFNet is validated on two publicly available datasets, Potsdam and Vaihingen.

Findings

In this paper, a quantitative analysis method is used to illustrate that the proposed network achieves superior performance of 2–6%, respectively, compared to other mainstream segmentation networks from experimental results on two datasets. Complete ablation experiments are also conducted to demonstrate the effectiveness of the elements in the network. In summary, BFFNet has proven to be effective in achieving accurate identification of small objects and in reducing the effect of shadows on the segmentation process.

Originality/value

The originality of the paper is the proposal of a BFFNet based on multi-scale and multi-attention strategies to improve the ability to accurately segment high-resolution and complex remote sensing images, especially for small objects and shadow-obscured objects.

Details

International Journal of Intelligent Computing and Cybernetics, vol. 17 no. 1
Type: Research Article
ISSN: 1756-378X

Keywords

1 – 10 of 128