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Article
Publication date: 1 May 2010

S.F. Ibrahim, N.A El-Zaher and M.N. Micheal

Recently, much attention has been focused on using physical treatments for improving functional properties of polymeric fabrics since they have several useful advantages, such as…

Abstract

Recently, much attention has been focused on using physical treatments for improving functional properties of polymeric fabrics since they have several useful advantages, such as non toxicity, soil release, improving physical properties and chemical reactivity of fabrics, avoiding environmental pollution resulting from chemical modification, etc. Hence, this article discusses the feasiblity and characterization of using UV/ozone treatments as a source of surface modification on the surface and bulk characteristics of various polymeric fabrics. Thus, pure cotton, pure polyester, and blend (cotton/polyester) fabrics are treated with UV/ozone for different periods of time (1,3,5,10,15, 20 and 60 minutes). The treated samples are examined and evaluated through various measurements involving the Fourier transform infrared spectra (FTIR) that provides evidence for the changes in the peak intensity values of different functional groups characterizing each fabric ,whiteness and yellowness indices, tensile strength, percentage elongation, and Young's modulus values, which are inversely related to the elacticity of the fabric. Moreover, the efficiency of this treatment process is tested by evaluating the dyeing characteristics by using two different dye classes which involve measuring dye up-take (K/S) values and light fastness assessments.

Article
Publication date: 28 May 2021

Quratulain Mohtashim, Muriel Rigout and Sheraz Hussain Siddique Hussain Yousfani

Sulphur dyes provide an inexpensive medium to dye cellulosic fibres with heavy shade depths. They offer moderate to good fastness to light and wet treatments. However, owing to…

Abstract

Purpose

Sulphur dyes provide an inexpensive medium to dye cellulosic fibres with heavy shade depths. They offer moderate to good fastness to light and wet treatments. However, owing to the environmental hazard produced by the use of sodium sulphide, the practical implication of these dyes is steadily decreasing. Moreover, these dyes are prone to oxidation causing pronounced fading on exposure to laundering. This paper aims to present the green processing of sulphur dyes by using a biodegradable reducing agent in place of sodium sulphide to dye cotton fabrics. The study also proposes after-treatments with tannin to improve the fastness properties of the dyeings.

Design/methodology/approach

In this study, dyeings were produced on cotton fabric with a range of C.I. Leuco Sulphur dyes, which were reduced with sodium sulphide and glucose. Sulphur dyeings were after-treated with an environment-friendly tannin-based product (Bayprotect CL (BP)); subsequently, the after-treated samples were evaluated for colour strength, wash, light and rubbing fastness.

Findings

A novel after-treatment method was developed, which substantially improved the wash fastness of C.I. Leuco Sulphur Black 1 dyeing to ISO 105 C06/C09 washing. However, the degree of this improvement varied for the other sulphur dyes used. The surface morphology and the possible mechanisms for the improved fastness properties were also discussed.

Research limitations/implications

The effect of after-treatment was significant for improving the wash fastness of sulphur black dyeings in particular, while the effect on other colours was minor. Significant improvements were observed for light and wet rub fastness for most of the dyeings, which signifies the importance of tannins as a finishing agent.

Practical implications

It is observed that the tannin-based product, BP, is found to provide the photoprotective effect by improving the lightfastness of the dyeings. Future research may involve the exploration of various tannins as a finishing agent to sulphur dyeings.

Originality/value

This novel finishing technique is found significant for improving the wash fastness of sulphur black 1 dyeings for both the reducing systems. Improvements were also observed for light and wet rub fastnesses for most of the dyeings.

Details

Pigment & Resin Technology, vol. 51 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 June 2020

Quratulain Mohtashim, Muriel Rigout and Sheraz Hussain Siddique

Sulphur dyes are the most highly consumed colourants for cellulosic substrates owing to their reasonable cost and acceptable fastness. However, the use of noxious conventional…

Abstract

Purpose

Sulphur dyes are the most highly consumed colourants for cellulosic substrates owing to their reasonable cost and acceptable fastness. However, the use of noxious conventional reducing agent, sodium sulphide and impaired wash fastness against oxidative bleaching is gradually decreasing the market of these dyes. As the need for “Green” goods and services is raising public awareness, this paper aims to use a glucose-based biodegradable reducing agent in place of sodium sulphide to dye cotton fabrics with a range of commercial sulphur dyes. The study also proposes an aftertreatment method to improve the fastness properties of the dyeing.

Design/methodology/approach

The paper investigated the impact of a newly developed aftertreatment method on the fastness properties of dyeing. This involved the sequential application of a cationic fixing agent (Tinofix ECO) and tannin (Bayprotect CL) on the coloured fabrics and subsequent evaluation of colour strength, washing, light and rubbing fastness.

Findings

The effect of aftertreating the dyed cotton was found to significantly improve the light and wet rub fastness. The surface morphology of the dyeing remained unaffected as depicted by the absence of any finish residues.

Research limitations/implications

The protective effect of the cation–tannin aftertreatments was examined with a view to providing the necessary commercial performance; however, it was established that the dry rub fastness was either reduced or remained unaffected and the wash fastness to International Organization for Standardization 105 C09 was also marginal.

Originality/value

This finishing technique is novel and can be found useful for manufacturing sulphur-dyed products with the improved light and wet rub fastness.

Details

Pigment & Resin Technology, vol. 49 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 5 August 2020

Akshita Agrawal and Sheetal Chopra

This paper aims to extract the dye colourant from teak leaves using different aqueous mediums (Alkaline, Neutral and Acidic); to characterize the dye in terms of yield %; ash…

232

Abstract

Purpose

This paper aims to extract the dye colourant from teak leaves using different aqueous mediums (Alkaline, Neutral and Acidic); to characterize the dye in terms of yield %; ash content and moisture content; to standardize the conditions of application of dye extracted from teak leaves on selected natural and synthetic fabrics using selected natural and chemical mordants; to assess the colour value (K/S, L*, c*/ h*, a*, b*) and fastness properties of the dyed samples in terms of wash, rub, light and perspiration fastness; and to develop dyed and printed designs using combinations of mordant and extracted dye.

Design/methodology/approach

Stage 1 – Extraction of dye from teak leaves; and characterization of dye: yield% ash content and moisture content. Stage 2 – Preparation of fabrics for dyeing; optimization of mordanting parameters using pre mordanting method followed by post mordanting; and optimization of dyeing parameters. Stage 3 – Testing of dyed fabric – Colour Measurement; K/S L*a*b*/L*c*h*; fastness properties; wash fastness done in the Laundrometer using ISO 2 standard test method; crock fastness done by Crockmeter using AATCC 116–1995 test method; perspiration fastness tested by perspirometer using AATCC 15– 2007 test method; and light fastness assessment in Mercury Bulb Tungsten Filament (MBTF) light fastness tester using AATCC Test Method 16–2004.

Findings

The findings of the study show that waste teak leaves can be used as an effective dye for natural as well as synthetic fabrics giving a wide range of colours on wool, silk and nylon. The maximum relative colour strength of the extracted dye on unmordanted dyed samples was found to be at pH 5 on wool and silk and at pH 7 on nylon. A range of shades was obtained with the use of different mordants. The extracted dye showed moderate to good fastness properties in terms of light, wash, rub and perspiration on wool and silk and excellent on nylon. Fastness properties were found to improve with the application of mordants both as pre and post method. Various combinations of mordants and dye result in obtaining pleasing and harmonious colours which were used aesthetically for printing.

Research limitations/implications

Due to time constrains, extraction in an organic medium could not be done, which could be a further scope for study.

Practical implications

Dyeing using teak leaves is a step towards sustainability and effective waste utilization with promising potential for application on natural as well as synthetic fabrics. Good colour with added properties will provide excellent solutions for eco-friendly methods of dyeing.

Social implications

This paper demonstrates the new possibilities offered by innovative uses of by-products of the timber industry and open good prospects for alternatives to synthetic colourants and new markets for the textile industry. It offers a new tool for the development of slow fashion.

Originality/value

It is a common practice to prune the tree branches to improve wood quality; thus, leaves are easily available as by product from pruning and also from wood harvesting. In the present study, waste teak leaves (Tectona grandis L.) were used for the extraction of dye.

Details

Research Journal of Textile and Apparel, vol. 24 no. 4
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 1 December 1982

M.A. Rabah, A.A. Aboukhashaba and M.S. Aly

The European association of pigment and dye manufacturers established a method for the estimation of heat and light fastness of organic pigments. In such method, pigments were…

Abstract

The European association of pigment and dye manufacturers established a method for the estimation of heat and light fastness of organic pigments. In such method, pigments were dispersed in partially dried linseed oil whereby prints were made on standard writing paper. Degraded prints were visually estimated after comparing with a freshly prepared standard scale of 8 grades. A sample similar to scale 5 or more was considered to be of good or excellent fastness. Practically, it became familiar with controversial personnel estimations, especially in regard to the critical level of 4–5. Furthermore, the specific side effect interference of the linseed oil resin could not be avoided. It becomes reasonable to put forward a method depending on instrumental measurements. In the light of this method, heat and light fastness of organic pigments can be colourimetrically determined. The pigment is pasted in water containing 2–3% weight of sodium silicate as binding agent. Thin film prints are then made on a transparent non‐porous standard paper 80 g/m2. Prints are dried over P2O5 in a desicator placed in a cool and dark place. The dried prints are striped in 2cm width. Some of these stripes are taken for the colourimetric determination of the colour density with the help of a colour densitometer. Other stripes are subjected for 72 hours to daylight (not to direct sun rays) or placed in a drying oven maintained at the required temperature for the same duration. For colour density measurements, prints are underlined with 100 g/m2 white standard paper. Peak heights obtained with certain light wave‐length are computed with reference to the peak of the undergraded sample. It has been shown that a change in heat or light fastness as low as 2% can be determined with an accuracy range of 0.5% compared to 12.5% and 3.5% for the European method respectively.

Details

Pigment & Resin Technology, vol. 11 no. 12
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 December 2004

George K. Stylios

Examines the tenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects…

3545

Abstract

Examines the tenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.

Details

International Journal of Clothing Science and Technology, vol. 16 no. 6
Type: Research Article
ISSN: 0955-6222

Keywords

Article
Publication date: 6 June 2016

F.A. Faiz, J.S.K. Ngo and K.B. Bujang

This study aims to improve the natural dyeing recipe with better light fastness using ascorbic acid (vitamin C) with pulverised plant dyes.

Abstract

Purpose

This study aims to improve the natural dyeing recipe with better light fastness using ascorbic acid (vitamin C) with pulverised plant dyes.

Design/methodology/approach

Silk fabrics pre-mordanted with alum (aluminium ammonium sulphate) were dyed using six types of plant dyes available in Sarawak, Malaysia, namely, Engkerabai leaves (Psychotria viridiflora), Ketapang leaves (Terminalia catappa), mangrove bark (Ceriops tagal), Sepang wood (Caesalpinia sappan), mangosteen husk (Garcinia mangostana) and onion skin (Allium cepa). Then, the dyed samples were immersed in vitamin C. The dyed and vitamin C-treated silk samples were exposed to direct sunlight for 40 h to test whether vitamin C had any effect on the light fastness of the dyed samples.

Findings

It was found that the fabric samples using vitamin C for after-treatment, particularly Engkerabai, Ketapang, mangrove and mangosteen, exhibited better light fastness. The colours of the four samples changed and looked darker when compared to the non-treated fabric samples. However, it was observed that vitamin C had a reverse effect on Sepang wood and onion skin. The acidic aqueous solution of vitamin C discharged the dyed samples instead.

Originality/value

In conclusion, depending on the plant types, vitamin C can be used to improve the light fastness of natural dyes or as a reducing agent for natural dyes.

Article
Publication date: 29 January 2020

Jiyoung Park and Youngmi Park

Equisetum arvense L. (Equisetum) is a weed that is very difficult to remove because of its deep roots. The purpose of this paper is to examine the dyeability and antioxidant…

Abstract

Purpose

Equisetum arvense L. (Equisetum) is a weed that is very difficult to remove because of its deep roots. The purpose of this paper is to examine the dyeability and antioxidant activity of Equisetum extracted from hot water.

Design/methodology/approach

Dry Equisetum was extracted at 100°C for 2 h, and its dyeability according to time, temperature and repetition cycle, and the mordant effect by skim milk powder were confirmed. The color change according to the K/S, fastness to rubbing, light, sweat and washing, UV protection rate and antioxidant activity were evaluated.

Findings

UV‒Vis spectroscopy showed that the Equisetum extract contained a flavonoid compound. The addition of Equisetum to artificial silk produced the greatest color difference when dyed at 60°C for 1 h, and the K/S value increased slightly after the pre-mordant treatment. In the fastness test, light and washing had no significant effect, but the fastness to rubbing was very good at Grades 4 and 5, and there was also a considerable improvement in the UV protection rate. The antioxidant activity of the extract was confirmed by an analysis of the radical scavenging ability through the DPPH (1,1-diphenyl 2-picryl-hydrazyl) and ABTS ([2,2’- azino-bis (3-ethylbenzothialzoline-6-sulfonic acid) diammonium salt]) tests.

Originality/value

These results revealed a new natural antioxidant-containing dyestuff, weed grass, which is easy to obtain, easy to use as a dyeing material and has excellent antioxidant activity in an extracted dye solution and dyeing fabric.

Details

International Journal of Clothing Science and Technology, vol. 32 no. 3
Type: Research Article
ISSN: 0955-6222

Keywords

Article
Publication date: 2 May 2017

Hatem E. Gaffer, Mohamed R. Elgohary, Hassan Ali Etman and Saad Shaaban

The purpose of this paper was to synthesize novel antibacterial reactive dyes for dyeing cotton fabrics.

Abstract

Purpose

The purpose of this paper was to synthesize novel antibacterial reactive dyes for dyeing cotton fabrics.

Design/methodology/approach

Four synthetic novel antibacterial reactive dyes based on sulfonamide (D1-D4) have been synthesized by the coupling reaction of sulfonamide diazonium salt with sulfonamido-cyanurated 7-amino-4-hydroxynaphthalene-2-sulfonic acid “j-acid”. The chemical structure of the synthesized dyes was secured by their spectral data [infra red (IR) and proton Nuclear magnetic Resonance (1HNMR)].

Findings

The prepared reactive dyes (D1-D4) were applied to cotton fabrics. Optimum conditions of the dying samples at sodium sulfate 100 g/l, liquor ratio (L.R.) 1:10, sodium carbonate 20 g/l at 80°C (D1, D2 and D4), 60°C (D3 for 60 min) were investigated. The fastness properties toward washing, perspiration, rubbing and light were evaluated. Dyed fabrics showed good light fastness property and good to very good washing and perspiration fastness properties according to the gray scale. Antimicrobial activities for synthesized dyes showed excellent activity against gram-negative organisms such as Pseudomonas aeruginosa and Proteus mirabilis faecalis, whereas very good activity against gram-positive organisms such as Staphylococcus aureus and Enterococcus faecalis with respect to the standard drugs ampicillin and chloramphenicol.

Originality/value

The principle advantages in this study were that the synthesis of novel synthesized dyes by introducing bisulfonamide-based moieties to increase the antimicrobial activity of the cellulose fabrics could be used as a medical textile, short reaction time and reaction procedure conducted in few steps, the work up is convenient and thus the starting material can be easily prepared.

Details

Pigment & Resin Technology, vol. 46 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 March 2015

G.H. Elgemeie, K.A. Ahmed, E.A. ahmed, M.H. helal and D.M. Masoud

– This paper aims to synthesise coumarine flourescent dyes from a cheap material in a very short time with a very high yield, and by using a clean green chemistry.

Abstract

Purpose

This paper aims to synthesise coumarine flourescent dyes from a cheap material in a very short time with a very high yield, and by using a clean green chemistry.

Design/methodology/approach

Efficient microwave synthesis for some novel iminocoumarins starts from the reaction of p-phenyl-enediamine and ethyl cyanoacetate followed by cyclocondensation with salicylaldehyde derivatives.

Findings

The synthesized iminocoumarine compounds were characterized by spectroscopic methods. Absorption and fluorescence spectra of the compounds were also recorded. All compounds were fluorescent in 1,4-dioxane solution, they all emitted blue light (440-460 nm). The printing properties were studied, and their applications on printing polyester and polyamide fabrics were studied by silk screen printing.

Originality/value

The authors designed efficient microwavel synthesis for some novel iminocoumarine derivatives; The novel procedure features short-reaction time, moderate yields and simple workup; All compounds were fluorescent in 1,4-dioxane solution, and they all emitted blue light; The authors studied their application in printing polyester and polyamide fabrics.

Details

Pigment & Resin Technology, vol. 44 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

1 – 10 of 358