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Article
Publication date: 5 December 2016

Evangelia K. Karaxi, Ioannis A. Kartsonakis and Costas A. Charitidis

Magnesium-aluminum layered double hydroxides (LDH) with a platelet-like morphology were synthesized through a modified co-precipitation method. The purpose of this paper is to…

Abstract

Purpose

Magnesium-aluminum layered double hydroxides (LDH) with a platelet-like morphology were synthesized through a modified co-precipitation method. The purpose of this paper is to investigate calcined Mg-Al-CO3 LDH (CLDH) as chloride ion traps.

Design/methodology/approach

The morphology and chemical composition of the synthesized materials were studied through UHR-SEM, EDS, FT-IR and XRD. The chloride ion adsorption was confirmed by XRD; the characteristic diffraction peaks of the reconstructed LDH structure were revealed, similar to the one before the thermal treatment process. The effect of varying the experimental conditions on the chloride ion adsorption, such as the initial target-ion concentration, the adsorbent material dosage, the solution temperature and the solution pH was also investigated.

Findings

The experimental data fitting revealed that the Langmuir equation is a better model on the basis of correlation coefficients (R2) and that the pseudo-second kinetic model can satisfactorily describe the chloride ion uptake.

Originality/value

The ability of Mg-Al CLDH to recover their layered structure upon exposure to aqueous sodium chloride solutions with concentrations up to 0.3 M (10,636 mg/L) through the chloride adsorption and the simultaneous rehydration process is clearly demonstrated.

Details

International Journal of Structural Integrity, vol. 7 no. 6
Type: Research Article
ISSN: 1757-9864

Keywords

Article
Publication date: 4 November 2020

Liliya Frolova and Tatyana Butyrina

The purpose of this paper is to study the patterns of formation of anti-corrosion properties, the development of compositions for pigments by using the method of co-precipitation…

Abstract

Purpose

The purpose of this paper is to study the patterns of formation of anti-corrosion properties, the development of compositions for pigments by using the method of co-precipitation and subsequent heat treatment.

Design/methodology/approach

To obtain co-precipitated hydroxides, aqueous solutions of salts were used. The conditions of synthesis varied according to the following parameters: the nature of the starting salts of metals; and the ratio of metal cations. The anticorrosive activity of the pigments was evaluated by the potentiodynamic method, by comparing the anodic and cathodic polarization curves, and calculated potentials and corrosion currents on the basis of regions of Tafel on curves. Polarization curves were obtained by using Potentiostat/Galvanostat/ZRA Gamry, which connected to the PC, and by using the program Gamry Framework. The measurement results were processed by using the method of simplex-lattice planning. X-ray diffractograms of pigments were recorded on a DRON – 2.0 diffractometer (monochromatic copper radiation with a nickel filter).

Findings

The paper deals with the results of research the dependence of colour characteristics and anticorrosion properties of synthesized compositions on their nature and composition. The presence of aluminium cations leads to the formation of solid solutions of ferrum and aluminium oxyhydroxides.

Originality/value

The main technological properties of pigments are determined by the anionic and cationic composition. Colour characteristics are determined by the cation-chromophore. The anti-corrosive properties of non-calcined pigments are determined to a greater extent by the presence of the formed hydroxyl ions and the composition of the compounds. The greatest protective effect is observed when using double compounds of metals, the dissociation constants of which differ significantly. The protective effect is mainly determined by the slowdown of the anode process. Anions containing aluminium atoms accelerate the corrosion processes.

Details

Pigment & Resin Technology, vol. 50 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 October 2018

F.F.M Shaikh, T.D. Dongale and R.K. Kamat

The overall purpose of this research paper largely depends on developing an easy method to synthesis a material suitable for supercapacitor application. This paper includes the…

Abstract

Purpose

The overall purpose of this research paper largely depends on developing an easy method to synthesis a material suitable for supercapacitor application. This paper includes the synthesis of, α-Co(OH)2, its structural, elemental and morphological properties and its supercapacitor properties.

Design/methodology/approach

Firstly, the electrolyte is prepared using binder free method, then electrodeposition is used to synthesize α-Co(OH)2 at 2 V. X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscope (SEM) are used to study the structural, elemental and morphological characteristics. The supercapacitor properties are investigated by using cyclic voltammetry, charging-discharging graph, stability test and electrochemical impedance spectroscopy (EIS).

Findings

Synthesis of α-Co(OH)2 is a tedious job as the temperature and use of weak base plays an important role. However, throughout electrodeposition, temperature is maintained using a water bath and weak base as the precursor. The presence of nitrate anions shows more interlayer space than that of ß-Co(OH)2 because of which free diffusion of the electrolyte is possible. Sheets structures are more visible in SEM images. Nanosheet like structure is observed in the film and such kind of structure provide higher surface area and higher specific capacitance. Usually, the surface morphology of cobalt hydroxide shows flower-like, spherical and nanocubes particles. The cross-section of the deposited film and it is found to be approximately 100 µm. In the forward and backward scan, oxidation and reduction peaks are clearly visible. However, such a behavior is reported as stable because of no further peaks of oxidation.

Originality/value

XRD and EDS confirms the growth of α-Co(OH)2. SEM images shows the porous nature of the film. Specific capacitance and energy density has been estimated at 5 mV s−1 is 780 F g−1 and 82 W h kg−1, respectively. The film was stable for 600 cycles showing 75 per cent capacitance retention. The voltage drop is 0.02 V for 0.5 A cm−2, indicating low resistance and good conductivity of the film. The specific power is estimated to be 15 W kg−1 for 1 A cm−2. The value of RESR, RCT, CDL and W is 4.83 Ohm, 1.273 Ohm, 0.00233 C and 0.717, respectively. Thus indicating α-Co(OH)2 to be better candidate for supercapacitor applications.

Details

Microelectronics International, vol. 35 no. 4
Type: Research Article
ISSN: 1356-5362

Keywords

Article
Publication date: 19 January 2024

Zhengwei Song, Zhi-Hui Xie, Lifeng Ding and Shengjian Zhang

This paper aims to comprehensively review the preparation methods of superhydrophobic surfaces (SHPS) for corrosion protection of Mg alloy in recent years.

Abstract

Purpose

This paper aims to comprehensively review the preparation methods of superhydrophobic surfaces (SHPS) for corrosion protection of Mg alloy in recent years.

Design/methodology/approach

The preparation methods, wettability and corrosion resistance of SHPS on Mg alloy in the past three years are systematically described in this paper.

Findings

Two types of SHPS, including single-layer and multilayer coatings for corrosion protection of Mg alloy are summarized. Preparing multilayered coatings with multifunction is the current trend in developing SHPS on Mg alloy.

Originality/value

This paper reviewed the preparation methods and corrosion resistance of SHPS on Mg alloys. It provides a valuable reference for researchers to develop highly durable SHPS with excellent corrosion resistance for Mg alloys.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 24 January 2024

Dexin Chen, Hongyuan He, Zhixin Kang and Wei Li

This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.

Abstract

Purpose

This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.

Design/methodology/approach

One-step electrodeposition is a versatile and simple technology to prepare superhydrophobic coatings on metal surfaces.

Findings

Preparing superhydrophobic coatings by one-step electrodeposition is an efficient method to protect metal surfaces.

Originality/value

Even though there are several technologies, one-step electrodeposition still plays a significant role in producing superhydrophobic coatings.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 30 August 2019

Liliya Frolova

The purpose of this paper is to study the process of coprecipitation of polyhydroxocomplexes of nickel and aluminum from solutions of nickel (Ni) (II) sulfate and aluminum (Al…

Abstract

Purpose

The purpose of this paper is to study the process of coprecipitation of polyhydroxocomplexes of nickel and aluminum from solutions of nickel (Ni) (II) sulfate and aluminum (Al) (III) sulfate with caustic soda and to study the conversion process to nickel aluminate and to check its properties.

Design/methodology/approach

For the thermodynamic analysis of the precipitation process, the software package MEDUSA was used. The dependences of the electrical conductivity, pH and residual concentrations as functions of the OH/Me ratio were obtained. Using X-ray phase analysis, spectroscopic analysis and derivatographic analysis, the properties of the products obtained were studied. The effects of OH/Me ratio and molar ratio cation of reagents on the physicochemical properties of the products were analyzed.

Findings

The paper deals with the results of theoretical and experimental research on the synthesis pigments of blue and green colors based on Ni-Al spinel. The influence of the molar ratio cation content on optical and color characterise of pigments were studied.

Originality/value

The original complex method of studying the processes of co-precipitation of cations in the form of hydroxides is proposed. pH precipitation of aluminum hydroxide and nickel are different. It is interesting to study their co-precipitation. The resulting single-phase product is a precursor of nickel aluminate over a wide range of cation ratios. The dependences of the electrical conductivity, pH and residual concentrations as functions of the OH/Me ratio were obtained.

Details

Pigment & Resin Technology, vol. 48 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 September 2017

Xueping Hu, Pengfei Tang, Yanfei Wang and Jing Liu

Water-based graphite lubricants have good lubricity in the process of metal forming, especially for hot-rolling seamless pipe. Although the use of water as a working fluid system…

173

Abstract

Purpose

Water-based graphite lubricants have good lubricity in the process of metal forming, especially for hot-rolling seamless pipe. Although the use of water as a working fluid system instead of conventional mineral oil has many advantages for the fuel consumption, post cleaning and a new type of lubricant, the graphite contaminated the machine and workers for its physical properties. From the global environmental protection viewpoint, it is urgent to develop a kind of benign material.

Design/methodology/approach

Magnesium hydroxide which has the average particle size of 10 μm was chosen as a base material without further modification and pretreatments. On the HT-1000 high-temperature tribometer, the influence of temperature and lubricant materials on the friction coefficient was studied. The tribological performance at 900°C provided evidence under high temperature for exploring a new lubricant material.

Findings

Tap water-based brucite lubricant will open a new chapter in the industrial lubrication, effectively avoiding many unfavorable factors caused by graphite lubrication, such as conductivity, pollution and energy loss. Meanwhile, it expanded the application of brucite as flame-retardant agent, catalyst, water treatment agent and so on.

Originality/value

It is a new and environmental lubricant to tap water-based brucite lubricant. And specially, the preparation process of lubricant is simple and economical.

Details

Industrial Lubrication and Tribology, vol. 69 no. 5
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 14 December 2023

Yajun Chen, Zehuan Sui and Juan Du

This paper aims to focus on the research progress of intelligent self-healing anti-corrosion coatings in the aviation field in the past few years. The paper provides certain…

Abstract

Purpose

This paper aims to focus on the research progress of intelligent self-healing anti-corrosion coatings in the aviation field in the past few years. The paper provides certain literature review supports and development direction suggestions for future research on intelligent self-healing coatings in aviation.

Design/methodology/approach

This mini-review uses a systematic literature review process to provide a comprehensive and up-to-date review of intelligent self-healing anti-corrosion coatings that have been researched and applied in the field of aviation in recent years. In total, 64 articles published in journals in this field in the last few years were analysed in this paper.

Findings

The authors conclude that the incorporation of multiple external stimulus-response mechanisms makes the coatings smarter in addition to their original self-healing corrosion protection function. In the future, further research is still needed in the research and development of new coating materials, the synergistic release of multiple self-healing mechanisms, coating preparation technology and corrosion monitoring technology.

Originality/value

To the best of the authors’ knowledge, this is one of the few systematic literature reviews on intelligent self-healing anti-corrosion coatings in aviation. The authors provide a comprehensive overview of the topical issues of such coatings and present their views and opinions by discussing the opportunities and challenges that self-healing coatings will face in future development.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 March 2013

G.C. Kordas, A.C. Balaskas, I.A. Kartsonakis and E.K. Efthimiadou

The purpose of this paper is to study the release of corrosion inhibitor from nanocontainers and to show that it can be released due to reaction with the substrate induced by…

Abstract

Purpose

The purpose of this paper is to study the release of corrosion inhibitor from nanocontainers and to show that it can be released due to reaction with the substrate induced by corrosion. This is called self‐healing of corrosion. Raman spectroscopy was used to show that reaction after scratching of the surface and corrosion of the substrate.

Design/methodology/approach

TiO2 nanocontainers loaded with 8‐hydroxyquinoline (8‐HQ) were placed onto a copper substrate and wetted with in 0.05 M NaCl solution. The Raman spectrum of the modified copper surface was attributed to the Cu(8‐Q)2 compound. The incorporation of loaded nanocontainers into epoxy coatings showed enhanced protection against corrosion. Artificial defects were formed on the coatings in order to evaluate the corrosion process and the possible self‐healing effect. The Raman spectra in the scratch tentatively assigned to Cu(8‐Q)2 compound. This result shows that the enhanced anti‐corrosive properties of the films with loaded nanocontainers can be attributed to the released inhibitor from the nanocontainer.

Findings

The authors found that the corrosion of copper substrate induces the release of hydroxyquinoline and formation of a chelate. This is the self‐healing phenomenon.

Practical implications

This can be employed for self‐healing in all structures, such as mechanical properties of bridges, etc.

Social implications

Damage occurs in all structures: the cost is immense – millions of dollars. Damage also occurs after an earthquake, accidents, etc. Self‐repairing is the key issue in modern science, therefore this article is of great importance.

Originality/value

The originality is that the authors showed, with Raman spectroscopy, that the chemicals in the nanocontainers in the coatings are released by the corrosion induced in the metal. This is the first spectroscopic proof of self‐healing.

Details

International Journal of Structural Integrity, vol. 4 no. 1
Type: Research Article
ISSN: 1757-9864

Keywords

Article
Publication date: 6 September 2023

Donghui Hu, Shenyou Song, Zongxing Zhang and Linfeng Wang

This paper aims to figure out the conundrum that the corrosion resistance longevity of steel wires for bridge cables was arduous to meet the requirements.

Abstract

Purpose

This paper aims to figure out the conundrum that the corrosion resistance longevity of steel wires for bridge cables was arduous to meet the requirements.

Design/methodology/approach

The “two-step” hot-dip coating process for cable steel wires was developed, which involved first hot-dip galvanizing and then hot-dip galvanizing of aluminum magnesium alloy. The corrosion rate, polarization curve and impedance of Zn–6Al–1Mg and Zn–10Al–3Mg alloy-coated steel wires were compared through acetate spray test and electrochemical test, and the corrosion mechanism of Zn–Al–Mg alloy-coated steel wires was revealed.

Findings

The corrosion resistance of Zn–10Al–3Mg alloy-coated steel wires had the best corrosion resistance, which was more than seven times that of pure zinc-coated steel wires. The corrosion current of Zn–10Al–3Mg alloy-coated steel wires was lower than that of Zn–6Al–1Mg alloy-coated steel wires, whereas the capacitive arc and impedance value of the former were higher than that of the latter, making it clear that the corrosion resistance of Zn–10Al–3Mg was better than that of Zn–6Al–1Mg alloy coating. Moreover, the Zn–Al–Mg alloy-coated steel wires for bridge cables had the function of coating “self-repairing.”

Originality/value

Controlling the temperature and time of the hot dip galvanizing stage can reduce the thickness of transition layer and solve the problem of easy cracking of the transition layer in the Zn–Al–Mg alloy coating due to the Sandelin effect.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

1 – 10 of 424