Search results

The purpose of this paper is to obtain liquid acrylate oligomers containing carboxyl groups as excellent toughening agents for epoxy resins.

Liquid acrylate oligomers containing carboxyl groups were synthesised by the solution polymerisation of butyl acrylate (BA), acrylic acid (AA) and acrylonitrile (AN) as monomers. The liquid acrylate oligomers were used as the toughening agents for epoxy resins. The chemical structure of the oligomers was characterised by ¹³C nuclear magnetic resonance (NMR) spectroscope. The morphology of modified epoxy networks was analysed by scanning electron microscope (SEM). The mechanical and thermodynamic properties were measured by universal testing machine and dynamic mechanical analyser (DMA).

The results show that AA and oligomer concentrations have great influence on the morphology, mechanical and thermodynamic properties of the modified epoxy networks. When the 10 wt percent oligomer containing BA and AN and AA in the ratio of 75/20/5 is used to modify the epoxy resin, the increase in impact strength of the modified epoxy network is 291.5 percent over the unmodified epoxy network due to addition of the oligomers without a sacrifice in heat‐resistance properties. Fracture surface analysis by SEM indicates the presence of a two‐phase microstructure.

The modified epoxy networks can be used as high performance materials such as adhesives, sealants and matrices of composites.

The liquid acrylate oligomers containing carboxyl and nitrile groups which were synthesised with BA, AA and AN as monomers by the solution polymerisation are novel and can greatly increase the toughness of epoxy resins without loss of thermal resistance.

In order to obtain functionalized core-shell nanoparticles (CSNPs) as excellent toughening agents for epoxy resins. The paper aims to discuss these issues.

Functionalized CSNPs containing epoxy groups on the surface were synthesized by emulsion polymerization with butyl acrylate as the core and methyl methacrylate copolymerizing with glycidyl methacrylate (GMA) as the shell. CSNPs were used as toughening agents for epoxy resins and their chemical structure was characterized by FT-IR. The morphology of modified epoxy networks (MEPN) was analyzed by SEM and TEM. Both the mechanical properties and thermodynamic properties were studied.

The results show that nearly spherical CSNPs with the particle size of 50-100 nm are obtained. A certain amount of CSNPs are uniformly dispersed in epoxy resins by the grinding method and the MEPN shows the ductile fracture feature. The miscibility between CSNPs and epoxy matrix increases with the increase of GMA concentration which makes more bonds form between them. Epoxy resins toughened with 10 wt% CSNPs containing 10 wt% GMA show the best mechanical properties and the increase in tensile strength and impact strength of the MEPN is 13.5 and 59.7 percent, respectively, over the unmodified epoxy networks. And the improvement in impact strength is not accompanied with loss of thermal resistance.

The MEPN can be used as high-performance materials such as adhesives, sealants and matrixes of composites.

The functionalized CSNPs are novel and it can greatly increase the toughness of epoxy resins without loss of thermal resistance.

The purpose of this paper is to study the inter-element coupling effect of membrane and plate components between two adjacent shells occurring on the common boundary.

In this paper, three triangular flat shells developed by combining an excellent membrane element (OPT) with three outstanding plate bending elements (DKT, RDKTM and DST-BK), respectively, are used to study this phenomenon. Benchmark tests are implemented to evaluate the performance of three selected plate elements and the formulated flat shells.

The inter-element coupling effect of membrane and plate components belonging, respectively, to two adjacent shells deteriorate the performance of shells. Therefore, a shell’s performance cannot be guaranteed certainly by the superimposed membrane and plate behaviors.

The “order matching” criterion is proposed to explain this phenomenon and it is concluded that the flat shell that follows this criterion explicitly may alleviate or even overcome the inter-element coupling effect.

Previous studies mainly focus on formulation of high-performance membrane and plate elements. However, the inter-element coupling effect of membrane and plate components between two adjacent shells occurring on the common boundary, has attracted less attention. Thorough benchmark tests for three flat shells are implemented to investigate the phenomenon. The results shows that the inter-element coupling effect deteriorates the performance of shells. And the “order matching” criterion is proposed to explain this phenomenon and it is concluded that the flat shell that follows this criterion explicitly may alleviate or even overcome the inter-element coupling effect.

Engineering composite laminates/structures are usually subjected to complex and variable loads, which result in interlayer delamination damage. However, damaged laminate may cause the whole structure to fail before reaching the design level. Therefore, the purpose of this paper is to develop an equivalent model to effectively evaluate compressive residual strength.

In this paper, taking carbon fiber reinforced composite T300/69 specimens as the study object, first, the compressive residual strength under different impact energy is obtained. Then, zero-thickness cohesive elements, Hashin failure criteria and Camanho nonlinear degradation scheme are used to simulate the full-process simulation for compression after edge impact (CAEI). Lastly, based on an improved Whitney–Nuismer criterion, the equation of edge hole stress distribution, characteristic length and compressive residual strength is used to verify the correctness of the equivalent model.

An equivalent relationship between the compressive residual strength of damaged laminates and laminates with edge hole is established. For T300/69 laminates with a thickness of 2.4 mm, the compressive residual strength after damage under an impact energy of 3 J is equivalent to that when the hole aperture R = 2.25 mm and the hole aperture R = 9.18 mm when impact energy is 6 J. Besides, the relationship under the same size and different thickness is obtained.

The value of this study is to provide a reference for the equivalent behavior of damaged laminates. An equivalent model proposed in this paper will contribute to the research of compressive residual strength and provide a theoretical basis for practical engineering application.

The special structure of the vortex pump contributes to its complex internal flow pattern. A type of horizontal 150WX-200-20 vortex pump is taken as a research subject to deeply study the progression and distribution of flow pattern in its channel. To explain the mechanism of flow in this pump, numerical analysis of the whole flow and experiment have been conducted.

The authors studied and analyzed the distribution and evolution of flow pattern under different flow, such as circulating-flow, through-flow and other forms. Finally, a model of flow pattern in the vortex pump has been built, which has more perfectly fit the reality.

They are through-flow affected by circulating-flow, main and subsidiary circulating-flow, vortices between vanes and other vortices (or liquid impingement) in volute. Entering the pump, part of the flow stays in vanes and turn into vortices while the other goes into the front chamber. The flow that runs into the front chamber will be divided into two parts. One part will be collected by viscosity into a vortex rope when it passing through the interface between the impeller and the vaneless chamber, which closely relates to the circulating-flow, and the rest directly goes out of the field through the diffuser. Besides, a fraction of circulating-flow joins the through-flow when it goes through the section V and leaves the pump.

The research results build a theoretical foundation for working out the flow mechanism of the vortex pump, improving its efficiency and optimizing its hydraulic design.

The stress state near the notch affects fatigue damage directly, but quantifying the stress field is difficult. The purpose of this study is to provide a mathematical description method of the stress field near the notch to achieve a reliable assessment of the fatigue life of notched specimens.

Firstly, the stress distribution of notched specimens of different materials and shapes under different stress levels is investigated, and a method for calculating the stress gradient impact factor is presented. Then, the newly defined stress gradient impact factor is used to describe the stress field near the notch, and an expression for the stress at any point along a specified path is developed. Furthermore, by combining the mathematical expressions for the stress field near the notch, a multiaxial fatigue life prediction model for notched shaft specimens is established based on the damage mechanics theory and closed solution method.

The stress gradient factor for notched specimens with higher stress concentration factors (V60-notch, V90-notch) varies to a certain extent when the external load and material change, but for notched specimens with relatively lower stress concentration factors (C-notch, U-notch, stepped shaft), the stress gradient factor hardly varies with the change in load and material, indicating that the shape of the notch has a greater influence on the stress gradient. It is also found that the effect of size on the stress gradient factor is not obvious for notched specimens with different shapes, there is an obvious positive correlation between the normal stress gradient factor and the normal stress concentration factor compared with the relationship between the shear stress gradient factor and the stress concentration factor. Moreover, the predicted results of the proposed model are in better agreement with the experimental results of five kinds of materials compared with the FS model, the SWT model, and the Manson–Coffin equation.

In this paper, a new stress gradient factor is defined based on the stress distribution of a smooth specimen. Then, a mathematical description of the stress field near the notch is provided, which contains the nominal stress, notch size, and stress concentration factor which is calculated by the finite element method (FEM). In addition, a multiaxial fatigue life prediction model for shaft specimens with different notch shapes is established with the newly established expressions based on the theory of damage mechanics and the closed solution method.

In practical engineering, oil filters often work under asymmetric cyclic loading. In order to improve the prediction accuracy of fatigue life of the oil filters under asymmetric cyclic loading, the effect of strain ratio and low cycle fatigue plastic deformation on fatigue life need to be considered. This paper aims to discuss the aforementioned objective.

First, strain-controlled fatigue tests with strain ratios of 0, 0.5 and −1 were carried out on the oil filter material 2A70-T6 aluminum alloy, and the test data were used to obtain strain fatigue life curves at three strain ratios. Then, based on the idea of the constant life curve method, the average value of the ratio of the strain amplitude corresponding to different strain ratios under the same partial life was defined as the strain ratio factor. Finally, the elastic-plastic factor was modified by the strain ratio factor, and a new fatigue life prediction model considering the effect of strain ratio was proposed.

The proposed model was validated, respectively, by fatigue test data of 2A70-T6 aluminum alloy, 2124-T851 aluminum alloy and oil filter and the results of the proposed model were compared with the Coffin–Manson equation, Morrow model and Smith–Watson–Topper (SWT) model, showing that the proposed model had higher applicability and accuracy.

In this work, a strain ratio factor is established based on the idea of the constant life curve method, and the strain ratio factor is used to modify the introduced elastic-plastic factor, and then a new fatigue life prediction model considering the influence of strain ratio and low cycle fatigue plastic deformation on material fatigue damage accumulation is proposed. The results show that the prediction results of the proposed model are in good agreement with the experimental data, and the proposed model has good fatigue life prediction ability considering the influence of strain ratio and lays a foundation for the fatigue life prediction of the oil filter.

With the growing concern of various sectors of society regarding environmental issues and the promotion of sustainable development, green technology innovation is generally considered to be conducive to the long-term development of enterprises. However, because of the existence of agency problems, managers may have shortsighted behaviors. Then how will managers' shortsighted behaviors affect enterprises' green technology innovation?

This paper uses machine learning-based text analysis methods to construct a manager myopia index based on the data from A-share listed companies on the Shanghai and Shenzhen Stock Exchanges from 2015 to 2020. We examine the impact of manager myopia on green technology innovation in companies.

Our study finds that manager myopia significantly inhibits green technology innovation in companies. However, when multiple large shareholders coexist and the proportion of institutional investors' holdings is high, it can alleviate the inhibitory effect of manager myopia on green innovation. Heterogeneity tests show that the impact of manager myopia on green technology innovation is relatively significant in non-state-owned and manufacturing companies, as well as in the electricity industry. Robustness tests demonstrate that our conclusions remain valid after using propensity score matching to eliminate endogeneity problems.

From the perspective of corporate governance, this paper incorporates managers' shortsightedness, multiple large shareholders and institutional investors' shareholding ratios into the same logical framework, analyzes their internal mechanisms, helps improve corporate governance, enhances green innovation capabilities and has strong implications for the implementation of national innovation-driven development strategies and the achievement of “carbon peak” and “carbon neutrality” targets.

Due to the limitation of experimental conditions and budget, fatigue data of mechanical components are often scarce in practical engineering, which leads to low reliability of fatigue data and reduces the accuracy of fatigue life prediction. Therefore, this study aims to expand the available fatigue data and verify its reliability, enabling the achievement of life prediction analysis at different stress levels.

First, the principle of fatigue life probability percentiles consistency and the perturbation optimization technique is used to realize the equivalent conversion of small samples fatigue life test data at different stress levels. Meanwhile, checking failure model by fitting the goodness of fit test and proposing a Monte Carlo method based on the data distribution characteristics and a numerical simulation strategy of directional sampling is used to extend equivalent data. Furthermore, the relationship between effective stress and characteristic life is analyzed using a combination of the Weibull distribution and the Stromeyer equation. An iterative sequence is established to obtain predicted life.

The TC4–DT titanium alloy is selected to assess the accuracy and reliability of the proposed method and the results show that predicted life obtained with the proposed method is within the double dispersion band, indicating high accuracy.

The purpose of this study is to provide a reference for the expansion of small sample fatigue test data, verification of data reliability and prediction of fatigue life data. In addition, the proposed method provides a theoretical basis for engineering applications.

This paper aims to investigate how to improve new product performance in turbulent circumstances of emerging economies.

This paper used regression analysis to examine the performance impact of customer relationship management (CRM) and product development management (PDM) concentration strategy in new product development (NPD). A detailed contingent analysis of the market and institutional environments in emerging economies is also conducted based on a survey of 114 Chinese high-tech manufacturers.

The research findings show that PDM has a stronger positive effect on new product performance than CRM in emerging economies and that the contingent effects of the market and institutional environment vary. More specifically, technological turbulence and enforcement inefficiency can positively moderate the relationship between CRM and new product performance, whereas the moderating effect of market turbulence on CRM is negative. Meanwhile, enforcement inefficiency negatively moderates the effect of PDM on new product performance, while the moderating effect of market turbulence on PDM is positive.

This paper is limited to a survey of high-tech manufacturing enterprises in China. Further research should continues to explore and document the strategic issue about NPD in emerging economies by longitudinal study.

This paper contributed to theoretical and practical initiatives on the strategic issue of NPD and provided firms a further understanding of how to select the right NPD strategy in emerging economies to improve new product performance.