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The idea of this paper is to present optical and microwave systems making use of new materials. Materials science as an interdisciplinary field has pushed on the development of revolutionary technologies such as polymer, semiconductors and nanomaterials. A brief introduction to optical and related microwave transmission systems was given; pure-optical, fiber-optic, Radar, WLAN and hybrid transmission systems have been taken into account. Principle operations and first promising experimental results in telecom and automotive applications have been shown. Also using Radar techniques we presented a Matlab/Simulink model of a correlation method for speed measurement allowing a variation of all known parameters.