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Purpose – The purpose of this paper to immobilization provides biosorbent particle with density and mechanichal strength, immobilization can save the cost of separating from biomass, can be regeneration and to increase adsorption capacity for metal ions.

Design/Methodology/Approach – The parameters affecting the adsorption, such as initial metal ion concentration, pH, contact time, and temperature, were studied. The analysis of biosorbent functional group was carried out by Fourier Transform Infrared Spectroscopy, SEM-EDX, for elemental analysis.

Findings – Optimum pH condition for biosorption Cd(II) was pH 5, contact time was 45 min, and initial concentration was 250 mg/L. Biosorbent analysis was characterized using SEM-EDX and FTIR analysis. Kinetics adsorption was studied and analyzed in terms of the pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetics models. The result showed that the biosorption for Cd(II) ion followed the pseudo-second-order kinetic model. Biosorption data of Cd(II) ion at 300°K, 308°K, and 318°K was analyzed with Temkin, Langmuir, and Freundlich isotherms. Biosorption of Cd(II) by durian seed immobilization in alginate according to the Langmuir isotherm equation provided a coefficient correlation of r² = 0.939 and maximum capacity biosorption of 25.05 mg/g.

Adsorption parameters (e.g. Langmuir constant, mass transfer coefficient and Thomas rate constant) are involved in the design of aqueous-media adsorption treatment units. However, the classic approach to estimating such parameters is perceived to be imprecise. Herein, the essential features and performances of the ant colony, bee colony and elephant herd optimisation approaches are introduced to the experimental chemist and chemical engineer engaged in adsorption research for aqueous systems. Key research and development directions, believed to harness these algorithms for real-scale water treatment (which falls within the wide-ranging coverage of the Sustainable Development Goal 6 (SDG 6) ‘Clean Water and Sanitation for All’), are also proposed. The ant colony, bee colony and elephant herd optimisations have higher precision and accuracy, and are particularly efficient in finding the global optimum solution. It is hoped that the discussions can stimulate both the experimental chemist and chemical engineer to delineate the progress achieved so far and collaborate further to devise strategies for integrating these intelligent optimisations in the design and operation of real multicomponent multi-complexity adsorption systems for water purification.

Heavy metals play a crucial role in the economic development of any nation. Industries utilizing heavy metals, consequently, emanate a large volume of metal-containing liquid effluents. Since metals are non-renewable and finite resources, their judicious and sustainable use is the key. Hazardous metal-laden water poses threat to human health and ecology. Apart from metals, these industrial effluents also consist of toxic chemicals. Conventional physical–chemical techniques are not efficient enough as it consumes energy and are, therefore, not cost effective.

It is known that biomaterials namely microorganisms, plants, and agricultural biomass have the competence to bind metals, in some cases, selectively, from aqueous medium. This phenomenon is termed as “metal biosorption.” Biosorption has immense potential of becoming an effective alternative over conventional methods. The authors in the present chapter have used secondary data from their previous research work and attempted to develop few strategic models through their feasibility studies for metal sustainability.

This study has covered many types of solar-powered air-conditioning systems that may be used as an alternative to traditional electrically powered air-conditioning systems in order to reduce energy usage. Solar adsorption air cooling is a great alternative to traditional vapor compression air-conditioning. Solar adsorption has several advantages over traditional vapor-compression systems, including being a green cooling technology which uses solar energy to drive the cycle, using pure water as an eco-friendly HFC-free refrigerant, and being mechanically simple with only the magnetic valves as moving parts. Several advancements and breakthroughs have been developed in the area of solar adsorption air-conditioners during the previous decade. However, further study is required before this technology can be put into practise. As a result, this book chapter highlights current research that adds to the understanding of solar adsorption air-conditioning technologies, with a focus on practical research. These systems have the potential to become the next iteration of air-conditioning systems, with the benefit of lowering energy usage while using plentiful solar energy supplies to supply the cooling demand.

Cities have been exposed to a variety of natural disasters such as flooding, extreme temperatures, storms, earthquakes, and other natural shocks, and have had to respond and adapt to such pressures over time. In the context of global climate change, natural disasters have increased across the globe. Apart from climate change, many urban environments in Latin America are experiencing significant transformations in land use patterns, socio-demographic change, changing labor markets, and economic growth, resulting from recent decades of globalization. Such transformations have resulted in the internal fragmentation of cities. In this context, the purpose of the present chapter is to demonstrate the importance in both theoretical and methodological terms, of integrating the concept of socio-environmental fragmentation into urban vulnerability research in order to make progress toward higher degrees of local sustainability in those areas of the city that suffer natural disasters and fragmentation.

A mixed methods approach is used in order to combine different technical issues from urban and climate change studies.

The findings are related to the importance of an integrated approach, regarding the complexity of urban life, and the relationship between the urban, the social, and the environmental phenomenon.

This chapter relates to the revisit of the current state of preparedness and to determine whether further adaptations are required. The authors understood that these kinds of mixed approaches are necessary in order to understand the new complexity of urban processes.

Purpose – In this study, the possibility of the application of rice husks for adsorbing Mn(II) ion in the water phase has been studied.

Design/Methodology/Approach – Experimental studies have been initiated by preparing activated carbon from rice husks. The activation of rice husks was done using both physical and chemical treatment methods through heating at 110 °C and washing with citric acid activator at 0.2 M, 0.4 M, and 0.6 M. The adsorption tests were conducted as two part tests: preliminary and primary. The preliminary test was conducted to choose the best condition of four independent variables, i.e., contact time (0–120 minutes), activator concentrations (0.2, 0.4, and 0.6 M), initial Mn(II) concentrations (10, 20, 50, 100, 200, and 400 mg/L), and adsorption temperatures (30, 47, and 67 °C).

Findings – By identifying the substituted groups using Fourier Transform Infrared Spectroscopy after activation with citric acid, it was found that the highest transmittance percentage was present in activated carbon with 0.2 M of citric acid. The best adsorption capacity and efficiency was 13.87 mg/g and 79.60%, respectively, which were obtained at 200 mg/L initial concentration with a 0.2 M citric acid concentration for 120 min contact time at 47 °C. These results lead to a conclusion that rice husks after activation with citric acid can be applied as an adsorbent for Mn(II) adsorption in the water phase.

Research Limitations/Implications – The activated carbon produced was only applicable for the adsorption of Mn(II) ions from the water phase, but not applicable for the adsorption of other heavy metals ions.

Practical Implications – Rice husks were potentially prepared as an adsorbent for Mn(II) ion adsorption in the water phase that was low cost, environmental friendly, and easy to prepare.

Originality/Value – Activated carbon prepared from biomass was mostly carried out using acids at high concentrations while the study was conducted using weak acids (citric acid) at low concentrations.

The model-based enquiry depends on the form in which models are formulated and represented. When economists select a model as an efficient reasoning tool, they may first consider the type of model whose inherited epistemic virtue and reasoning rules best fits their needs. This chapter studies the dependence between the different forms of models and scientific knowledge by considering a particular form of model, that is, the diagram. This chapter draws from the history of location theory, which provides us with an example of how economists reasoned with diagrams, how their particular geometric shapes became an idealized landscape, and how they reasoned into them to account for actual spatial patterns of economic activity providing the opportunity for policy advice. Three different diagrams are examined: Johann Heinrich von Thünen’s concentric rings of agricultural land use, Alfred Weber’s triangles of industrial locations, and Walter Christaller’s hexagons of market area.