Search results

1 – 10 of 177
Article
Publication date: 3 August 2022

Nargess Yousefi-Limaee, Behzad Shirkavand Hadavand and Zahra Rahmani

Methylene blue (MB) is classified as a cationic dye which is widely used as chemical indicator, coloring agent and biological stain. The discharge of this dye to the water streams…

Abstract

Purpose

Methylene blue (MB) is classified as a cationic dye which is widely used as chemical indicator, coloring agent and biological stain. The discharge of this dye to the water streams is harmful to the human beings. For this reason, this study investigated the removal of MB from aqueous solution by hydrogel nanocomposite.

Design/methodology/approach

In experimental part, at first, ultraviolet (UV)-curable hydrogel/chitosan nanocomposite, which improves its elasticity by urethane acrylate, was synthesized and characterized by FTIR and SEM analysis. Afterward, the synthesized hydrogel nanocomposite was applied for the removal of MB and the influence of operational condition including nanocomposite loading, dye concentration, contact time and pH of solution was specified. Moreover, isotherm studies as well as kinetics survey were performed.

Findings

Langmuir, Freundlich, Brunauer, Emmett and Teller and Tempkin adsorption isotherms were assessed for the analysis of experimental data indicating the Freundlich isotherm was the best fitted one. The adsorption kinetics data was examined indicating the adsorption kinetics appropriate to pseudo-second-order kinetics model.

Originality/value

The predominant water absorption property of the UV-curable hydrogel/chitosan nanocomposite to 8.5 steps and outstanding adsorption capacity for the elimination of MB on hydrogel nanocomposite subscribed that the synthesized hydrogel could be a favorable adsorbent for simultaneous absorption of water and removal of cationic dyes.

Details

Pigment & Resin Technology, vol. 52 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Open Access
Book part
Publication date: 4 May 2018

Intan Lestari

Purpose – The purpose of this paper to immobilization provides biosorbent particle with density and mechanichal strength, immobilization can save the cost of separating from…

Abstract

Purpose – The purpose of this paper to immobilization provides biosorbent particle with density and mechanichal strength, immobilization can save the cost of separating from biomass, can be regeneration and to increase adsorption capacity for metal ions.

Design/Methodology/Approach – The parameters affecting the adsorption, such as initial metal ion concentration, pH, contact time, and temperature, were studied. The analysis of biosorbent functional group was carried out by Fourier Transform Infrared Spectroscopy, SEM-EDX, for elemental analysis.

Findings – Optimum pH condition for biosorption Cd(II) was pH 5, contact time was 45 min, and initial concentration was 250 mg/L. Biosorbent analysis was characterized using SEM-EDX and FTIR analysis. Kinetics adsorption was studied and analyzed in terms of the pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetics models. The result showed that the biosorption for Cd(II) ion followed the pseudo-second-order kinetic model. Biosorption data of Cd(II) ion at 300°K, 308°K, and 318°K was analyzed with Temkin, Langmuir, and Freundlich isotherms. Biosorption of Cd(II) by durian seed immobilization in alginate according to the Langmuir isotherm equation provided a coefficient correlation of r2 = 0.939 and maximum capacity biosorption of 25.05 mg/g.

Details

Proceedings of MICoMS 2017
Type: Book
ISBN:

Keywords

Article
Publication date: 11 July 2023

Nagla Elshemy, Hamada Mashaly and Shimaa Elhadad

This study aims to observe the coloring efficacy of graphite (G) and nano bentonite clay (BCNPs) on the adsorption of Basic Blue 5 dye from residual dye bath solution.

Abstract

Purpose

This study aims to observe the coloring efficacy of graphite (G) and nano bentonite clay (BCNPs) on the adsorption of Basic Blue 5 dye from residual dye bath solution.

Design/methodology/approach

Some factors that affected the adsorption processes were examined and found to have significant impacts on the adsorption capacity such as the initial concentration of G and/or BCNPs (Co: 40–2,320 mg/L), adsorbent bath pH (4–9), shaking time (30–150 min.) and initial dye concentration (40–200 mg/L). The adsorption mechanism of dye by using G and/or BCNPs was studied using two different models (first-pseudo order and second-pseudo order diffusion models). The equilibrium adsorption data for the dye understudy was analyzed by using four different models (Langmuir, Freundlich, Temkin modle and Dubinin–Radushkevich) models.

Findings

It has been found that the adsorption kinetics follow rather a pseudo-first-order kinetic model with a determination coefficient (R2) of 0.99117 for G and 0.98665 for BCNPs. The results indicate that the Freundlich model provides the best correlation for G with capacities q_max = 2.33116535 mg/g and R2 = 0.99588, while the Langmuir model provides the best correlation for BCNPs with R2 = 0.99074. The adsorbent elaborated from BCNPs was found to be efficient and suitable for removing basic dyes rather than G from aqueous solutions due to its availability, good adsorption capability, as well as low-cost preparation.

Research limitations/implications

There is no research limitation for this work. Basic Blue 5 dye graphite (G) and nano bentonite clay (BCNPs) were used.

Practical implications

This work has practical applications for the textile industry. It is concluded that using graphite and nano bentonite clay can be a possible alternative to adsorb residual dye from dye bath solution and can make the process greener.

Social implications

Socially, it has a good impact on the ecosystem and global community because the residual dye does not contain any carcinogenic materials.

Originality/value

The work is original and contains value-added products for the textile industry and other confederate fields.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 January 2016

Baskar Gurunathan, Dhanusree Viswanathan, Shravanthi Rajasekar and Garrick Bikku George

The purpose of this paper is to focus on the removal of Congo red dye from aqueous solution using magnetically separable novel adsorbent prepared by coating activated charcoal on…

Abstract

Purpose

The purpose of this paper is to focus on the removal of Congo red dye from aqueous solution using magnetically separable novel adsorbent prepared by coating activated charcoal on magnetic nanoparticles.

Design/methodology/approach

The synthesized magnetic nanocomposite of activated charcoal was characterized using Fourier transform infra-red (FTIR), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) analysis. The removal of Congo red from aqueous solution using magnetic nanocomposite of activated charcoal was optimized. The equilibrium and kinetics modeling of adsorption of Congo red was analyzed.

Findings

The presence of activated charcoal on magnetic nanocomposite was confirmed by FTIR analysis. The average size of the nanocomposite was found to be 12.77 nm using SEM characterization. The elemental composition by EDS analysis confirmed the increase in concentration of carbon due the adsorption of Congo red dye. The optimum conditions for batch adsorption was found to be 1 g/L of adsorbent, dye concentration 50 mg/L, pH 3 and temperature 70°C. The adsorption of Congo red dye on magnetic nanocomposite of activated charcoal was found to follow Temkin adsorption isotherm.

Originality/value

The experimental data were found to fit well with the pseudo second-order kinetics and the rate of adsorption was found to be controlled by intra-particle diffusion.

Details

Management of Environmental Quality: An International Journal, vol. 27 no. 1
Type: Research Article
ISSN: 1477-7835

Keywords

Article
Publication date: 3 December 2021

Tanmay Ilame and Arpita Ghosh

Water is a vital natural resource without which life on earth would be impossible. Properties of synthetic dyes like high stability and noxious nature make it difficult to remove…

Abstract

Purpose

Water is a vital natural resource without which life on earth would be impossible. Properties of synthetic dyes like high stability and noxious nature make it difficult to remove them from the effluent. This review focuses on the removal of synthetic dyes using nanoparticles (NPs) based on the adsorption principle.

Design/methodology/approach

Adsorption technique is widely used to remove synthetic dyes from their aqueous solution for decades. Synthetic dye removal using NPs is promising, less energy-intensive and has become popular in recent years. NPs are in high demand for treating wastewater using the adsorption principle due to their tiny size and vast surface area. To maximise environmental sustainability, the utilisation of green-produced NPs as efficient catalysts for dye removal has sparked attention amongst scientists.

Findings

This review has prioritised research and development of optimal dye removal systems that can be used to efficiently remove a large quantity of dye in a short period while safeguarding the environment and producing fewer harmful by-products. The removal efficiency of synthetic dye using different NPs in wastewater treatment varies mostly between 75% to almost 100%. This review will aid in the scaling up of the wastewater treatment process.

Research limitations/implications

There is a lack of research emphasis on the safe disposal of NPs once the reuse efficiency significantly drops. The relevance of cost analysis is equally critical, yet only a few papers discuss cost-related information.

Originality/value

Comprehensive and planned research in this area can aid in the development of long-term wastewater treatment technology to meet the growing need for safe and reliable water emphasising reuse and desorption efficiency of the NPs.

Details

Management of Environmental Quality: An International Journal, vol. 33 no. 2
Type: Research Article
ISSN: 1477-7835

Keywords

Article
Publication date: 7 March 2023

Khaled Mostafa, Heba Ameen, Amal El-Ebeisy and Azza El-Sanabary

Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a…

42

Abstract

Purpose

Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate for copper ions removal from wastewater effluent after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.

Design/methodology/approach

The calorimetric sensor batch technique was used to determine the resin's adsorption capacity, while atomic adsorption spectrometry was used to determine the residual copper ions concentration in the filtrate before and after adsorption. This was done to convert the copolymer's abundant nitrile groups into amidoxime groups, and the resulting poly (amidoxime) resin was used as a copper ion adsorbent. To validate the existence of amidoxime groups, the resin was qualitatively characterized using a rapid vanadium ion test and instrumentally using Fourier transform infrared spectroscopy spectra and scanning electron microscopy morphological analysis.

Findings

At pH 7, 400 ppm copper ions concentration and 0.25 g adsorbent at room temperature, the overall adsorption potential of poly (amidoxime) resin was found to be 115.2 mg/g. The process's adsorption, kinetics and isothermal analysis were examined using various variables such as pH, contact time, copper ion concentration and adsorbent dose. To pretend the adsorption kinetics, various kinetics models, including pseudo-first-order and pseudo-second-order, were applied to the experimental results. The kinetic analysis indicated that the pseudo-second-order rate equation promoted the development of the chemisorption phase better than the pseudo-first-order rate equation. In the case of isothermal investigations, a study of observed correlation coefficient (R2) values indicated that the Langmuir model outperformed the Freundlich model in terms of matching experimental data.

Originality/value

To the best of the author's information, there is no comprehensive study for copper ions removal from waste water effluent using the recently tailored and fully characterized poly (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 15 June 2022

Mounir Kouhila, Younes Bahammou, Hamza Lamsyehe, Zakaria Tagnamas, Haytem Moussaoui, Ali Idlimam and Abdelkader Lamharrar

The paper aims to evaluate drying performance of earth mortar by solar drying for more durability, minimize pathologies in traditional construction and determine the influence of…

Abstract

Purpose

The paper aims to evaluate drying performance of earth mortar by solar drying for more durability, minimize pathologies in traditional construction and determine the influence of temperature and humidity on the microstructure of earth mortar using static gravimetric method.

Design/methodology/approach

A convective solar dryer was used for the pretreatment of building and solid materials for construction.

Findings

The humidity influences the mortar sorption – surface water sorption of earth mortar increased with increasing temperature.

Originality/value

The study used a novel method for pretreatment building materials by using solar dryer.

Details

International Journal of Building Pathology and Adaptation, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2398-4708

Keywords

Article
Publication date: 10 December 2020

Xiaoping Zhang, Yanhui Li, Meixiu Li, Qiuju Du, Hong Li, Yuqi Wang, Dechang Wang, Cuiping Wang, Kunyan Sui, Hongliang Li, Yanzhi Xia and Yuanhai Yu

In order to discover a new adsorbent that can be used to purify dye wastewater in the textile and apparel industry, a novel type of graphene oxide/gluten composite material using…

Abstract

Purpose

In order to discover a new adsorbent that can be used to purify dye wastewater in the textile and apparel industry, a novel type of graphene oxide/gluten composite material using an improved acid bath coagulation method was synthesized, which can remove methylene blue in an aqueous environment.

Design/methodology/approach

After experimentally compounding different ratios of graphene oxide and gluten, the graphene oxide/gluten composite material with 20% graphene oxide content and superlative adsorption effect was chosen. The synthesized material was characterized by different techniques such as FT-IR and SEM, indicating the microstructure of the material and the success of the composite. Various factors were considered, namely, the influence of temperature, dosage, pH and contact time. The isotherms, kinetics and thermodynamic parameters were successively discussed.

Findings

The qmax value of 214.29 mg/g of the material was higher compared to the general sorbent, thus, the graphene oxide/gluten composite material was a suitable sorbent for methylene blue removal. Overall, the graphene oxide/gluten composite material can be considered as an effectual and prospective adsorbent to remove methylene blue in the textile and apparel industrial effluent.

Originality/value

Graphene oxide is a potentially excellent sorbent. However, the high dispersibility of GO is detrimental to adsorption, it disperses rapidly in an aqueous solution making separation and recovery difficult. The high load capacity and recyclability of gluten as a colloid make it a suitable carrier for fixing GO. Studies on the combination of GO and GT into composite adsorption material and for the removal of dyes from dyeing wastewater have not been reported. The composite material research on GO and GT can provide new ideas for the research of these kinds of materials and contribute to its wider and convenient application in wastewater treatment.

Details

International Journal of Clothing Science and Technology, vol. 33 no. 4
Type: Research Article
ISSN: 0955-6222

Keywords

Content available
Article
Publication date: 12 February 2018

Karima Derdour, Chafia Bouchelta, Amina Khorief Naser-Eddine, Mohamed Salah Medjram and Pierre Magri

The purpose of this paper is to focus on the removal of hexavalent chromium [Cr(VI)] from wastewater by using activated carbon-supported Fe catalysts derived from walnut shell…

6643

Abstract

Purpose

The purpose of this paper is to focus on the removal of hexavalent chromium [Cr(VI)] from wastewater by using activated carbon-supported Fe catalysts derived from walnut shell prepared using a wetness impregnation process. The different conditions of preparation such as impregnation rate and calcination conditions (temperature and time) were optimized to determine their effects on the catalyst’s characteristics.

Design/methodology/approach

The catalyst samples were characterized using thermogravimetric analysis, scanning electron microscopy and Fourier transform infrared spectroscopy. The adsorption of Cr(VI) by using using activated carbon supported Fe catalysts derived from walnut shell as an adsorbent and catalyst was investigated under different adsorption conditions. The parameters studied were contact time, adsorbent dose, solution pH and initial concentrations.

Findings

Results showed that higher adsorption capacity and rapid kinetics were obtained when the activated walnut shell was impregnated with Fe at 5 per cent and calcined under N2 flow at 400°C for 2 h. The adsorption isotherms data were analyzed with Langmuir and Freundlich models. The better fit is obtained with the Langmuir model with a maximum adsorption capacity of 29.67 mg/g for Cr(VI) on Fe5-AWS at pH 2.0.

Originality/value

A comparison of two kinetic models shows that the adsorption isotherms system is better described by the pseudo-first-order kinetic model.

Details

World Journal of Engineering, vol. 15 no. 1
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 10 December 2019

Akbar Eslami, Zahra Goodarzvand Chegini, Maryam Khashij, Mohammad Mehralian and Marjan Hashemi

A nanosilica adsorbent was prepared and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and BET.

Abstract

Purpose

A nanosilica adsorbent was prepared and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and BET.

Design/methodology/approach

The optimum conditions for the highest adsorption performance were determined by kinetic modeling. The adsorbent was used for the adsorption of acetaminophen (ACT), and the parameters affecting the adsorption were discussed like pH, initial concentration, contact time and adsorbent dosage. The adsorbent have been characterized by SEM, XRD and BET analysis. The kinetic models including pseudo-first-order and pseudo-second-order with Langmuir and Freundlich isotherm models were applied to investigate the kinetic and isotherms parameters.

Findings

The adsorption of ACT increased to around 95% with the increase of nanosilica concentration to 30 g/L. Moreover, the adsorption process of ACT follows the pseudo-second-order kinetics and the Langmuir isotherm with the maximum adsorption capacity of 609 mg/g.

Practical implications

This study provided a simple and effective way to prepare of nanoadsorbents. This way was conductive to protect environmental and subsequent application for removal of emerging pollutants from aqueous solutions.

Originality/value

The novelty of the study is synthesizing the morphological and structural properties of nanosilica-based adsorbent (specific surface area, pore volume and size, shape and capability) and improving its removal rate through optimizing the synthesis method; and studying the capability of synthesis of nanosilica-based adsorbent for removal of ACT as a main emerging pharmaceutical water contaminant.

Details

Pigment & Resin Technology, vol. 49 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

1 – 10 of 177