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Purpose – The purpose of this paper to immobilization provides biosorbent particle with density and mechanichal strength, immobilization can save the cost of separating from biomass, can be regeneration and to increase adsorption capacity for metal ions.

Design/Methodology/Approach – The parameters affecting the adsorption, such as initial metal ion concentration, pH, contact time, and temperature, were studied. The analysis of biosorbent functional group was carried out by Fourier Transform Infrared Spectroscopy, SEM-EDX, for elemental analysis.

Findings – Optimum pH condition for biosorption Cd(II) was pH 5, contact time was 45 min, and initial concentration was 250 mg/L. Biosorbent analysis was characterized using SEM-EDX and FTIR analysis. Kinetics adsorption was studied and analyzed in terms of the pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetics models. The result showed that the biosorption for Cd(II) ion followed the pseudo-second-order kinetic model. Biosorption data of Cd(II) ion at 300°K, 308°K, and 318°K was analyzed with Temkin, Langmuir, and Freundlich isotherms. Biosorption of Cd(II) by durian seed immobilization in alginate according to the Langmuir isotherm equation provided a coefficient correlation of r² = 0.939 and maximum capacity biosorption of 25.05 mg/g.

The purpose of this paper is to focus on the removal of hexavalent chromium [Cr(VI)] from wastewater by using activated carbon-supported Fe catalysts derived from walnut shell prepared using a wetness impregnation process. The different conditions of preparation such as impregnation rate and calcination conditions (temperature and time) were optimized to determine their effects on the catalyst’s characteristics.

The catalyst samples were characterized using thermogravimetric analysis, scanning electron microscopy and Fourier transform infrared spectroscopy. The adsorption of Cr(VI) by using using activated carbon supported Fe catalysts derived from walnut shell as an adsorbent and catalyst was investigated under different adsorption conditions. The parameters studied were contact time, adsorbent dose, solution pH and initial concentrations.

Results showed that higher adsorption capacity and rapid kinetics were obtained when the activated walnut shell was impregnated with Fe at 5 per cent and calcined under N₂ flow at 400°C for 2 h. The adsorption isotherms data were analyzed with Langmuir and Freundlich models. The better fit is obtained with the Langmuir model with a maximum adsorption capacity of 29.67 mg/g for Cr(VI) on Fe5-AWS at pH 2.0.

A comparison of two kinetic models shows that the adsorption isotherms system is better described by the pseudo-first-order kinetic model.

One of the major challenges in the design of thermal equipment is to minimize the entropy production and enhance the thermal dissipation rate for improving energy efficiency of the devices. In several industrial applications, the structure of thermal device is cylindrical shape. In this regard, this paper aims to explore the impact of isothermal cylindrical solid block on nanofluid (Ag – H₂O) convective flow and entropy generation in a cylindrical annular chamber subjected to different thermal conditions. Furthermore, the present study also addresses the structural impact of cylindrical solid block placed at the center of annular domain.

The alternating direction implicit and successive over relaxation techniques are used in the current investigation to solve the coupled partial differential equations. Furthermore, estimation of average Nusselt number and total entropy generation involves integration and is achieved by Simpson and Trapezoidal’s rules, respectively. Mesh independence checks have been carried out to ensure the accuracy of numerical results.

Computations have been performed to analyze the simultaneous multiple influences, such as different thermal conditions, size and aspect ratio of the hot obstacle, Rayleigh number and nanoparticle shape on buoyancy-driven nanoliquid movement, heat dissipation, irreversibility distribution, cup-mixing temperature and performance evaluation criteria in an annular chamber. The computational results reveal that the nanoparticle shape and obstacle size produce conducive situation for increasing system’s thermal efficiency. Furthermore, utilization of nonspherical shaped nanoparticles enhances the heat transfer rate with minimum entropy generation in the enclosure. Also, greater performance evaluation criteria has been noticed for larger obstacle for both uniform and nonuniform heating.

The current numerical investigation can be extended to further explore the thermal performance with different positions of solid obstacle, inclination angles, by applying Lorentz force, internal heat generation and so on numerically or experimentally.

A pioneering numerical investigation on the structural influence of hot solid block on the convective nanofluid flow, energy transport and entropy production in an annular space has been analyzed. The results in the present study are novel, related to various modern industrial applications. These results could be used as a firsthand information for the design engineers to obtain highly efficient thermal systems.

The purpose of this paper is to develop a method suitable for the design of reinforced concrete columns subjected to a standard fire.

The Zone Method – a ’simplified calculation method” included in Eurocode 2 – has been developed by Hertz as a manual calculation scheme for the check of fire resistance of concrete sections. The basic idea is to disregard the thermal strains and to calculate the resistance of a cross-section by reducing the concrete cross-section by a “damaged zone”. It is assumed that all fibers can reach their ultimate, temperature dependent strength. Therefore, it is a plastic concept; the information on the state of strain is lost. The calculation of curvatures and deflections is thus only possible by making further assumptions. Extensions of the zone method toward a general calculation method, suitable for the implementation in commercial design software and using the temperature dependent stress–strain curves of the Advanced Calculation Method, have been developed in Germany. The extension by Cyllok and Achenbach is presented in detail. The necessary assumptions of the Zone Method are reviewed, and an improved proposal for the consideration of the reinforcement in this extended Zone Method is presented.

The principles and assumptions of the Zone Method proposed by Hertz can be validated.

An extension of the Zone Method suitable for the implementation in design software is proposed.

This paper aims to study the impacts of groundwater seepage on artificial freezing process of gravel strata, the temperature field characteristics of the strata, and the strata process, closure time and thickness evolution mechanism of the frozen wall.

In this paper several laboratory model tests were conducted, considering different groundwater seepage rate.

The results show that there is a significant coupling effect between the cold diffusion of artificial freezing pipes and groundwater seepage; when there is no seepage, temperature fields upstream and downstream of the gravel strata are symmetrically distributed, and the thickness of the frozen soil column/frozen wall is consistent during artificial freezing; groundwater seepage causes significant asymmetry in the temperature fields upstream and downstream of the gravel strata, and the greater the seepage rate, the more obvious the asymmetry; the frozen wall closure time increases linearly with the increase in the groundwater seepage rate, and specifically, the time length under seepage rate of 5.00 m d⁻¹ is 3.2 times longer than that under no seepage; due to the erosion from groundwater seepage, the thickness of the upstream frozen wall decreases linearly with the seepage velocity, while that of the downstream frozen wall increases linearly, resulting in a saddle-shaped frozen wall.

The research results are beneficial to the optimum design and risk control of artificial freezing process in gravel strata.

Purpose – In this study, the possibility of the application of rice husks for adsorbing Mn(II) ion in the water phase has been studied.

Design/Methodology/Approach – Experimental studies have been initiated by preparing activated carbon from rice husks. The activation of rice husks was done using both physical and chemical treatment methods through heating at 110 °C and washing with citric acid activator at 0.2 M, 0.4 M, and 0.6 M. The adsorption tests were conducted as two part tests: preliminary and primary. The preliminary test was conducted to choose the best condition of four independent variables, i.e., contact time (0–120 minutes), activator concentrations (0.2, 0.4, and 0.6 M), initial Mn(II) concentrations (10, 20, 50, 100, 200, and 400 mg/L), and adsorption temperatures (30, 47, and 67 °C).

Findings – By identifying the substituted groups using Fourier Transform Infrared Spectroscopy after activation with citric acid, it was found that the highest transmittance percentage was present in activated carbon with 0.2 M of citric acid. The best adsorption capacity and efficiency was 13.87 mg/g and 79.60%, respectively, which were obtained at 200 mg/L initial concentration with a 0.2 M citric acid concentration for 120 min contact time at 47 °C. These results lead to a conclusion that rice husks after activation with citric acid can be applied as an adsorbent for Mn(II) adsorption in the water phase.

Research Limitations/Implications – The activated carbon produced was only applicable for the adsorption of Mn(II) ions from the water phase, but not applicable for the adsorption of other heavy metals ions.

Practical Implications – Rice husks were potentially prepared as an adsorbent for Mn(II) ion adsorption in the water phase that was low cost, environmental friendly, and easy to prepare.

Originality/Value – Activated carbon prepared from biomass was mostly carried out using acids at high concentrations while the study was conducted using weak acids (citric acid) at low concentrations.