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The purpose of this paper is fourfold: to experimentally determine the standby thermal energy losses in various hot water cylinders in both scenarios, without isotherm blanket installation and with isotherm blanket installation; to analytically evaluate the performance of either the geyser, split- or integrated-type ASHP water heaters based on the number of heating up cycles and total electrical energy consumptions over a 24-h period without isotherm blankets and with isotherm blankets installed; to demonstrate the impact of the electrical energy factors of the split- and integrated-type ASHP water heaters under both the scenarios (without and with the isotherm blankets installed); and to use statistical tests (one way ANOVA and multiple comparison procedure tests) to verify whether any significant difference in the standby thermal energy losses occurred for each of the heating devices under both the scenarios.

The methodology was divided into monitoring of the performance of the electrical energy consumptions and ambient conditions of the hot water heating technologies without isotherm blanket installation and with isotherm blanket installation.

The results reveal that the average standby thermal energy loss of the geyser without the installation of an isotherm blanket was 2.5 kWh. And this standby loss can be reduced to over 18.5 per cent by just installing a 40-mm thick isotherm blanket on the tank. The statistical tests show a significant mean difference in the group electrical energy consumed to compensate for the standby losses under both scenarios. In contrast, the average standby thermal energy losses for the split- and integrated-type ASHP water heaters were 1.33 kWh and 0.92 kWh, respectively. There was a reduction of 15.5 per cent and 3.5 per cent in the electrical energy consumed in compensating for standby losses for both the split and integrated types, respectively, but there was no significant mean difference in the standby losses under both scenarios for the two systems. Again, without any loss of generality, the electrical energy factor of both the ASHP water heaters decreased upon installation of the isotherm blanks.

The experiments were conducted only for a 150-L geyser and 150-L split- and integrated-type ASHP water heaters. The category of the different types of ASHP water heaters was limited to one because of the cost implication.

The experiments were not conducted with various hot water storage tanks installed in different positions (roof, inside or outside of a building wall, etc.) so that actual real-life observations could be obtained. The challenges of easy disassembling and deployment of systems and DAS to different positions were also a real concern.

The findings can help homeowners and ESCO in deciding whether to install isotherm blankets on storage tanks of ASHP water heaters on the basis of the impact of standby losses and its potential viability.

The experimental design and methodology are the first of its kind to be conducted in South Africa. The results and interpretation were obtained from original data collected from a set of experiments conducted. The findings also show that the installation of isotherm blanket on an electric geyser can result in a significant mean reduction in the standby losses. In contrast, an installation of the isotherm blankets on the storage tanks of ASHP water heaters can reduce the standby losses, but there exists no significant mean difference.

This study aims to investigate the numerical analysis of mixed convection within the horizontal annulus in the presence of water-based fluid with nanoparticles of aluminum oxide, copper, silver and titanium oxide. Numerical solution is performed using a finite-volume method based on the SIMPLE algorithm, and the discretization of the equations is generally of the second order. Inner and outer cylinders have a constant temperature, and the inner cylinder temperature is higher than the outer one. The two cylinders can be rotated in both directions at a constant angular velocity. The effect of parameters such as Rayleigh, Richardson, Reynolds and the volume fraction of nanoparticles on heat transfer and flow pattern are investigated. The results show that the heat transfer rate increases with the increase of the Rayleigh number, as well as by increasing the volume fraction of the nanoparticles, the heat transfer rate increases, and this increase is about 8.25 per cent for 5 per cent volumetric fraction. Rotation of the cylinders reduces the overall heat transfer. Different directions of rotation have a great influence on the flow pattern and isotherms, and ultimately on heat transfer. The addition of nanoparticles does not have much effect on the flow pattern and isotherms, but it is quantitatively effective. The extracted results are in good agreement with previous works.

Studying mixed convection heat transfer in the horizontal annulus in the presence of a water-based fluid with aluminum oxide, copper, silver and titanium oxide nanoparticles is carried out quantitatively using a finite-volume method based on the SIMPLE algorithm.

Increasing the Rayleigh number increases the Nusselt number. Increasing the Richardson number increases heat transfer. Adding nanoparticles does not have much effect on the flow pattern but is effective quantitatively on heat transfer parameters. The addition of nanoparticles sometimes increases the heat transfer rate by about 8.25 per cent. In constant Rayleigh numbers, increasing the Reynolds number reduces heat transfer. The Rayleigh and Reynolds numbers greatly affect the isotherms and streamlines. In addition to the thermal conductivity of nanoparticles, the thermo-physical properties of nanoparticles has great effect in the formation of isotherms and streamlines and ultimately heat transfer.

Studying the effect of different direction of rotation on the isotherms and streamlines, as well as the comparison of different nanoparticles on mixed convection heat transfer in annulus.

In order to understand interactions a_w vs equilibrium moisture content (EMC) in fortified coconut powder, moisture sorption isotherms were constructed under different storage conditions in order to predict the changes in their physical, chemical and microbiological properties that occur during storage and processing, which are unique to each food.

For which the moisture sorption isotherms were determined at three different temperatures (15, 25 and 35 °C), in a range of water activity from 0.1 to 0.90. Nine models, namely, the GAB, BET, Oswin, Smith, Halsey, Henderson, Chung and Pfost, Peleg and Caurie equations, were fitted to the sorption data. Various statistical tests were adopted as criteria to evaluate the fit performance of the models.

Of the models tested, the Peleg model gave the best fit to experimental data (R² = 0.997; R_MSE = 0.276), across the full range of water activities and at different temperatures. Humidity of the monolayer (m_o) was found between 2.54 and 2.34%, a fundamental parameter to define the storage and control conditions, given that it is considered the value at which the product is more stable. The net sorption isosteric heat (Q_st) increased to maximum and then diminished with increased moisture content (X_w); maximum values were obtained in the X_w interval between 0.48 and 2.87% (db), being between 35.72 and 99.26 kJ/mol, where the maximum value indicates coverage of the strongest bond sites and higher adsorbate-adsorbent interaction.

These results provide reliable experimental data on water absorption isotherms of the CP + FAC important to determine optimal processing, storing and packaging conditions.

In this study, the removal of a series of acid dyes by hybrid polymer adsorbent was investigated. Textile industry wastewater is mainly consisted of suspended solid particles and organic compounds with complex and nondecomposable structures. Treatment of such wastewaters has received much attention by researchers because of high water consumption and the presence of various chemical compounds, especially dyes. The use of polymers has recently attracted much attention for the treatment of textile wastewaters. According to the literature, hybrid polymers are highly capable of adsorbing dyes. In this research work, polyacrylamide/iron sulfate (PAM-FeSO₄) hybrid polymer was successfully synthesized through solution polymerization of acrylamide with ammonium persulfate and sodium thiosulfate and gradual addition of iron sulfate. The hybrid polymeric adsorbent was then used for removing acidic dyes with different chemical structures.

The effects of various experimental conditions and parameters, such as initial concentrations of dye and adsorbent, on the adsorption capacity of the adsorbent were investigated. The dye concentration was measured by an UV–vis spectrophotometer. The adsorption equilibrium was studied by plotting adsorption isotherms. The experimental data was fitted to Langmuir and Freundlich isotherms.

The adsorption experiments indicated that the PAM-FeSO₄ hybrid polymer has a high adsorption capacity (117.64 mg g⁻¹ for the Orange ІІ and 80.64 mg g⁻¹ for the Sunset Yellow [SY]) when 80 mg of adsorbent was immersed in the dye solution (1 g L⁻¹) with a pH of 11 at 25°C. The analysis of the equilibrium isotherms using the Langmuir and Freundlich isotherms indicated that the Langmuir model fit well to the experimental data.

To the best of the authors’ knowledge, this study is original. The removal of acid dyes such as Sunset Yellow and Methyl Orange using PAM-FeSO₄ hybrid polymer as flocculant was done for the first time.

Methylene blue (MB) is classified as a cationic dye which is widely used as chemical indicator, coloring agent and biological stain. The discharge of this dye to the water streams is harmful to the human beings. For this reason, this study investigated the removal of MB from aqueous solution by hydrogel nanocomposite.

In experimental part, at first, ultraviolet (UV)-curable hydrogel/chitosan nanocomposite, which improves its elasticity by urethane acrylate, was synthesized and characterized by FTIR and SEM analysis. Afterward, the synthesized hydrogel nanocomposite was applied for the removal of MB and the influence of operational condition including nanocomposite loading, dye concentration, contact time and pH of solution was specified. Moreover, isotherm studies as well as kinetics survey were performed.

Langmuir, Freundlich, Brunauer, Emmett and Teller and Tempkin adsorption isotherms were assessed for the analysis of experimental data indicating the Freundlich isotherm was the best fitted one. The adsorption kinetics data was examined indicating the adsorption kinetics appropriate to pseudo-second-order kinetics model.

The predominant water absorption property of the UV-curable hydrogel/chitosan nanocomposite to 8.5 steps and outstanding adsorption capacity for the elimination of MB on hydrogel nanocomposite subscribed that the synthesized hydrogel could be a favorable adsorbent for simultaneous absorption of water and removal of cationic dyes.

The purpose of this paper is to investigate the performance of natural Jordanian zeolite tuff to remove ammonia from aqueous solutions using a laboratory batch method and fixed-bed column apparatus. Equilibrium data were fitted to Langmuir and Freundlich models.

Column experiments were conducted in packed bed column. The used apparatus consisted of a bench-mounted glass column of 2.5 cm inside diameter and 100 cm height (column volume = 490 cm3). The column was packed with a certain amount of zeolite to give the desired bed height. The feeding solution was supplied from a 30 liter plastic container at the beginning of each experiment and fed to the column down-flow through a glass flow meter having a working range of 10-280ml/min.

Ammonium ion exchange by natural Jordanian zeolite data were fitted by Langmuir and Freundlich isotherms. Continuous sorption of ammonium ions by natural Jordanian zeolite tuff has proven to be effective in decreasing concentrations ranging from 15-50 mg NH₄-N/L down to levels below 1 mg/l. Breakthrough time increased by increasing the bed depth as well as decreasing zeolite particle size, solution flow-rate, initial NH₄+ concentration and pH. Sorption of ammonium by the zeolite under the tested conditions gave the sorption capacity of 28 mg NH₄-N/L at 20°C, and 32 mg NH₄-N/L at 30°C.

This research investigates the performance of natural Jordanian zeolite tuff to remove ammonia from aqueous solutions using a laboratory batch method and fixed-bed column apparatus. The equilibrium data of the sorption of Ammonia were plotted by using the Langmuir and Freundlich isotherms, then the experimental data were compared to the predictions of the above equilibrium isotherm models. It is clear that the NH₄+ ion exchange data fitted better with Langmuir isotherm than with Freundlich model and gave an adequate correlation coefficient value.

The purpose of this paper is to study thermal (natural) convection in nine different containers involving the same area (area= 1 sq. unit) and identical heat input at the bottom wall (isothermal/sinusoidal heating). Containers are categorized into three classes based on geometric configurations [Class 1 (square, tilted square and parallelogram), Class 2 (trapezoidal type 1, trapezoidal type 2 and triangle) and Class 3 (convex, concave and triangle with curved hypotenuse)].

The governing equations are solved by using the Galerkin finite element method for various processing fluids (Pr = 0.025 and 155) and Rayleigh numbers (10³ ≤ Ra ≤ 10⁵) involving nine different containers. Finite element-based heat flow visualization via heatlines has been adopted to study heat distribution at various sections. Average Nusselt number at the bottom wall ( Nub¯) and spatially average temperature (θ^) have also been calculated based on finite element basis functions.

Based on enhanced heating criteria (higher Nub¯ and higher θ^), the containers are preferred as follows, Class 1: square and parallelogram, Class 2: trapezoidal type 1 and trapezoidal type 2 and Class 3: convex (higher θ^) and concave (higher Nub¯).

The comparison of heat flow distributions and isotherms in nine containers gives a clear perspective for choosing appropriate containers at various process parameters (Pr and Ra). The results for current work may be useful to obtain enhancement of the thermal processing rate in various process industries.

Heatlines provide a complete understanding of heat flow path and heat distribution within nine containers. Various cold zones and thermal mixing zones have been highlighted and these zones are found to be altered with various shapes of containers. The importance of containers with curved walls for enhanced thermal processing rate is clearly established.

Purpose – The purpose of this paper to immobilization provides biosorbent particle with density and mechanichal strength, immobilization can save the cost of separating from biomass, can be regeneration and to increase adsorption capacity for metal ions.

Design/Methodology/Approach – The parameters affecting the adsorption, such as initial metal ion concentration, pH, contact time, and temperature, were studied. The analysis of biosorbent functional group was carried out by Fourier Transform Infrared Spectroscopy, SEM-EDX, for elemental analysis.

Findings – Optimum pH condition for biosorption Cd(II) was pH 5, contact time was 45 min, and initial concentration was 250 mg/L. Biosorbent analysis was characterized using SEM-EDX and FTIR analysis. Kinetics adsorption was studied and analyzed in terms of the pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetics models. The result showed that the biosorption for Cd(II) ion followed the pseudo-second-order kinetic model. Biosorption data of Cd(II) ion at 300°K, 308°K, and 318°K was analyzed with Temkin, Langmuir, and Freundlich isotherms. Biosorption of Cd(II) by durian seed immobilization in alginate according to the Langmuir isotherm equation provided a coefficient correlation of r² = 0.939 and maximum capacity biosorption of 25.05 mg/g.

This paper aims to examine the thermal transmission and entropy generation of hybrid nanofluid filled containers with solid body inside. The solid body is seen as being both isothermal and capable of producing heat. A time-dependent non-linear partial differential equation is used to represent the transfer of heat through a solid body. The current study’s objective is to investigate the key properties of nanoparticles, external forces and particular attention paid to the impact of hybrid nanoparticles on entropy formation. This investigation is useful for researchers studying in the area of cavity flows to know features of the flow structures and nature of hybrid nanofluid characteristics. In addition, a detailed entropy generation analysis has been performed to highlight possible regimes with minimal entropy generation rates. Hybrid nanofluid has been proven to have useful qualities, making it an attractive coolant for an electrical device. The findings would help scientists and engineers better understand how to analyse convective heat transmission and how to forecast better heat transfer rates in cutting-edge technological systems used in industries such as heat transportation, power generation, chemical production and passive cooling systems for electronic devices.

Thermal transmission and entropy generation of hybrid nanofluid are analysed within the enclosure. The domain of interest is a square chamber of size L, including a square solid block. The solid body is considered to be isothermal and generating heat. The flow driven by temperature gradient in the cavity is two-dimensional. The governing equations, formulated in dimensionless primitive variables with corresponding initial and boundary conditions, are worked out by using the finite volume technique with the SIMPLE algorithm on a uniformly staggered mesh. QUICK and central difference schemes were used to handle convective and diffusive elements. In-house code is developed using FORTRAN programming to visualize the isotherms, streamlines, heatlines and entropy contours, which are handled by Tecplot software. The influence of nanoparticles volume fraction, heat generation factor, external magnetic forces and an irreversibility ratio on energy transport and flow patterns is examined.

The results show that the hybrid nanoparticles concentration augments the thermal transmission and the entropy production increases also while the augmentation of temperature difference results in a diminution of entropy production. Finally, magnetic force has the significant impact on heat transfer, isotherms, streamlines and entropy. It has been observed that the external magnetic force plays a good role in thermal regulations.

Hybrid nanofluid is a desirable coolant for an electrical device. Various nanoparticles and their combinations can be analysed. Ferro-copper hybrid nanofluid considered with the help of prevailing literature review. The research would benefit scientists and engineers by improving their comprehension of how to analyses convective heat transmission and forecast more accurate heat transfer rates in various fields.

Due to its helpful characteristics, ferrous-copper hybrid nanofluid is a desirable coolant for an electrical device. The research would benefit scientists and engineers by improving their comprehension of how to analyse convective heat transmission and forecast more accurate heat transfer rates in cutting-edge technological systems used in sectors like thermal transportation, cooling systems for electronic devices, etc.

Entropy generation is used for an evaluation of the system’s performance, which is an indicator of optimal design. Hence, in recent times, it does a good engineering sense to draw attention to irreversibility under magnetic force, and it has an indispensable impact on investigation of electronic devices.

An efficient numerical technique has been developed to solve this problem. The originality of this work is to analyse convective energy transport and entropy generation in a chamber with internal block, which is capable of maintaining heat and producing heat. Effects of irreversibility ratio are scrutinized for the first time. Analysis of convective heat transfer and entropy production in an enclosure with internal isothermal/heat generating blocks gives the way to predict enhanced heat transfer rate and avoid the failure of advanced technical systems in industrial sectors.

This study aims to undertake a comprehensive examination of heat transfer by convection in porous systems with top and bottom walls insulated and differently heated vertical walls under a magnetic field. For a specific nanofluid, the study aims to bring out the effects of different segmental heating arrangements.

An existing in-house code based on the finite volume method has provided the numerical solution of the coupled nondimensional transport equations. Following a validation study, different explorations include the variations of Darcy–Rayleigh number (Ra_m = 10–10⁴), Darcy number (Da = 10^–5–10^–1) segmented arrangements of heaters of identical total length, porosity index (ε = 0.1–1) and aspect ratio of the cavity (AR = 0.25–2) under Hartmann number (Ha = 10–70) and volume fraction of φ = 0.1% for the nanoparticles. In the analysis, there are major roles of the streamlines, isotherms and heatlines on the vertical mid-plane of the cavity and the profiles of the flow velocity and temperature on the central line of the section.

The finding of a monotonic rise in the heat transfer rate with an increase in Ra_m from 10 to 10⁴ has prompted a further comparison of the rate at Ra_m equal to 10⁴ with the total length of the heaters kept constant in all the cases. With respect to uniform heating of one entire wall, the study reveals a significant advantage of 246% rate enhancement from two equal heater segments placed centrally on opposite walls. This rate has emerged higher by 82% and 249%, respectively, with both the segments placed at the top and one at the bottom and one at the top. An increase in the number of centrally arranged heaters on each wall from one to five has yielded 286% rate enhancement. Changes in the ratio of the cavity height-to-length from 1.0 to 0.2 and 2 cause the rate to decrease by 50% and increase by 21%, respectively.

Further research with additional parameters, geometries and configurations will consolidate the understanding. Experimental validation can complement the numerical simulations presented in this study.

This research contributes to the field by integrating segmented heating, magnetic fields and hybrid nanofluid in a porous flow domain, addressing existing research gaps. The findings provide valuable insights for enhancing thermal performance, and controlling heat transfer locally, and have implications for medical treatments, thermal management systems and related fields. The research opens up new possibilities for precise thermal management and offers directions for future investigations.