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1 – 10 of 27Nagla Elshemy, Hamada Mashaly and Shimaa Elhadad
This study aims to observe the coloring efficacy of graphite (G) and nano bentonite clay (BCNPs) on the adsorption of Basic Blue 5 dye from residual dye bath solution.
Abstract
Purpose
This study aims to observe the coloring efficacy of graphite (G) and nano bentonite clay (BCNPs) on the adsorption of Basic Blue 5 dye from residual dye bath solution.
Design/methodology/approach
Some factors that affected the adsorption processes were examined and found to have significant impacts on the adsorption capacity such as the initial concentration of G and/or BCNPs (Co: 40–2,320 mg/L), adsorbent bath pH (4–9), shaking time (30–150 min.) and initial dye concentration (40–200 mg/L). The adsorption mechanism of dye by using G and/or BCNPs was studied using two different models (first-pseudo order and second-pseudo order diffusion models). The equilibrium adsorption data for the dye understudy was analyzed by using four different models (Langmuir, Freundlich, Temkin modle and Dubinin–Radushkevich) models.
Findings
It has been found that the adsorption kinetics follow rather a pseudo-first-order kinetic model with a determination coefficient (R2) of 0.99117 for G and 0.98665 for BCNPs. The results indicate that the Freundlich model provides the best correlation for G with capacities q_max = 2.33116535 mg/g and R2 = 0.99588, while the Langmuir model provides the best correlation for BCNPs with R2 = 0.99074. The adsorbent elaborated from BCNPs was found to be efficient and suitable for removing basic dyes rather than G from aqueous solutions due to its availability, good adsorption capability, as well as low-cost preparation.
Research limitations/implications
There is no research limitation for this work. Basic Blue 5 dye graphite (G) and nano bentonite clay (BCNPs) were used.
Practical implications
This work has practical applications for the textile industry. It is concluded that using graphite and nano bentonite clay can be a possible alternative to adsorb residual dye from dye bath solution and can make the process greener.
Social implications
Socially, it has a good impact on the ecosystem and global community because the residual dye does not contain any carcinogenic materials.
Originality/value
The work is original and contains value-added products for the textile industry and other confederate fields.
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Nancy Sobh, Nagla Elshemy, Sahar Nassar and Mona Ali
Due to herbs and plants’ therapeutic properties and simplicity of availability in nature, humans have used them to treat a variety of maladies and diseases since ancient times…
Abstract
Purpose
Due to herbs and plants’ therapeutic properties and simplicity of availability in nature, humans have used them to treat a variety of maladies and diseases since ancient times. Later, as technology advanced, these plants and herbs gained significant relevance in some industries due to their suitable chemical composition, abundant availability and ease of access. Aegle marmelos is a species of plant that may be found in nature. Yet, little or very little literature was located on the coloration behavior of this plant’s leaves. This study aims to focus on the effect of different parameters on the extraction of colorant from Aegle marmelos leaves.
Design/methodology/approach
Some factors that affected on the extraction processes were examined and found to have significant impacts on the textile dyeing such as the initial dye concentration, extracted temperature, extracted bath pH and extracted time were all changed to see how they affected color extraction. The authors report a direct comparison between three heating methods, namely, microwave irradiation (MWI), ultrasonic waves (USW) and conventional heating (CH). The two kinetic models have been designed (pseudo-first and pseudo-second orders) in the context of these experiments to investigate the mechanism of the dyeing processes for fabrics under study. Also, the experimental data were analyzed according to the Langmuir and Freundlich isotherms.
Findings
From the result, it was discovered these characteristics were found to have a substantial effect on extraction efficiency. Temperature 90°C and 80°C when using CH and USW, respectively, while at 90% watt when using MWI, period 120 min when using CH as well as USW waves, while 40 min when using MWI, and pH 4, 5 and 10 for polyamide, wool and cotton, respectively, were the optimal extraction conditions. Also, the authors can say that wool gives a higher absorption than the other fabric. Additionally, MWI provided the best color strength (K/S) value, and homogeneity, at low temperatures reducing the energy and time consumed. The coloring follows the order: MWI > USW > CH. The adsorption isotherm of wool could be well fitted by Freundlich isotherm when applying CH and USW as a heating source, while it is well fitted by the Langmuir equation in the case of MWI. In the study, it was observed that the pseudo-first-order kinetic model fits better the experimental results of CH with a constant rate K1 = −0.000171417 mg/g.min, while the pseudo-second-order kinetic model fits better the experimental results of absorption of both MWI (K2 = 38.14022572 mg/g.min) and USW (K2 = 12.45343554 mg/g.min).
Research limitations/implications
There is no research limitation for this work. Dye was extracted from Aegle marmelos leaves by applying three different heating sources (MWI, ultrasonic waves [USWW] and CH).
Practical implications
This work has practical applications for the textile industry. It is concluded that using Aegle marmelose leaves can be a possible alternative to extract dye from natural resource by applying new technology to save energy and time and can make the process greener.
Social implications
Socially, it has a good impact on the ecosystem and global community because the extracted dye does not contain any carcinogenic materials.
Originality/value
The work is original and contains value-added products for the textile industry and other confederate fields.
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Zeliha Betül Kol and Dilek Duranoğlu
This study aims to model and investigate Basic Yellow 28 (BY28) adsorption onto activated carbon in batch and continuous process.
Abstract
Purpose
This study aims to model and investigate Basic Yellow 28 (BY28) adsorption onto activated carbon in batch and continuous process.
Design/methodology/approach
Batch adsorption experiments were carried out at 25 °C with 50 mg/L BY28 solution at pH 6 with different amounts of activated carbon. Freundlich and Langmuir adsorption isotherm models were used to model batch data. Pseudo-first-order and pseudo-second-order kinetic models were applied with linear regression. The changes of the breakthrough curve with the column height, flow rate, column diameter and adsorbent amount were examined in fixed bed column at room temperature. BY28 adsorption data were modelled by using different adsorption column models (Adams & Bohart, Thomas, Yoon & Nelson, Clark and modified dose–response) with non-linear regression.
Findings
Freundlich model and pseudo-second-order kinetic model expressed the experimental data with high compatibility. Modified dose-response model corresponded to the fixed bed column data very well.
Originality/value
Adsorption of Basic Yellow 28 on activated carbon in a fixed bed column was studied for the first time. Continuous adsorption process was modelled with theoretical adsorption models using non-linear regression.
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Khaled Mostafa, Heba Ameen, Amal El-Ebeisy and Azza El-Sanabary
Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a…
Abstract
Purpose
Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate for copper ions removal from wastewater effluent after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.
Design/methodology/approach
The calorimetric sensor batch technique was used to determine the resin's adsorption capacity, while atomic adsorption spectrometry was used to determine the residual copper ions concentration in the filtrate before and after adsorption. This was done to convert the copolymer's abundant nitrile groups into amidoxime groups, and the resulting poly (amidoxime) resin was used as a copper ion adsorbent. To validate the existence of amidoxime groups, the resin was qualitatively characterized using a rapid vanadium ion test and instrumentally using Fourier transform infrared spectroscopy spectra and scanning electron microscopy morphological analysis.
Findings
At pH 7, 400 ppm copper ions concentration and 0.25 g adsorbent at room temperature, the overall adsorption potential of poly (amidoxime) resin was found to be 115.2 mg/g. The process's adsorption, kinetics and isothermal analysis were examined using various variables such as pH, contact time, copper ion concentration and adsorbent dose. To pretend the adsorption kinetics, various kinetics models, including pseudo-first-order and pseudo-second-order, were applied to the experimental results. The kinetic analysis indicated that the pseudo-second-order rate equation promoted the development of the chemisorption phase better than the pseudo-first-order rate equation. In the case of isothermal investigations, a study of observed correlation coefficient (R2) values indicated that the Langmuir model outperformed the Freundlich model in terms of matching experimental data.
Originality/value
To the best of the author's information, there is no comprehensive study for copper ions removal from waste water effluent using the recently tailored and fully characterized poly (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.
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Mounir Kouhila, Younes Bahammou, Hamza Lamsyehe, Zakaria Tagnamas, Haytem Moussaoui, Ali Idlimam and Abdelkader Lamharrar
The paper aims to evaluate drying performance of earth mortar by solar drying for more durability, minimize pathologies in traditional construction and determine the influence of…
Abstract
Purpose
The paper aims to evaluate drying performance of earth mortar by solar drying for more durability, minimize pathologies in traditional construction and determine the influence of temperature and humidity on the microstructure of earth mortar using static gravimetric method.
Design/methodology/approach
A convective solar dryer was used for the pretreatment of building and solid materials for construction.
Findings
The humidity influences the mortar sorption – surface water sorption of earth mortar increased with increasing temperature.
Originality/value
The study used a novel method for pretreatment building materials by using solar dryer.
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The purpose of this study is to prepare a new adsorbent activated carbon immobilized on polystyrene (ACPS) for uranium (VI) and thorium (IV) removal from an aqueous solution…
Abstract
Purpose
The purpose of this study is to prepare a new adsorbent activated carbon immobilized on polystyrene (ACPS) for uranium (VI) and thorium (IV) removal from an aqueous solution. Activated carbon (AC) was derived from biochar material by chemical activation to increase the active sites on its surface and enhance the adsorption capacity. Activated carbon (AC) was immobilized on polystyrene (PS) to improve the physical properties and facilitate separation from the working solution. A feasibility study for the adsorption of uranium (VI) and thorium (IV) on the new adsorbent (ACPS) has been achieved. Adsorption kinetics, isotherms, and thermodynamics models of the adsorption process were used to describe the reaction mechanism.
Design/methodology/approach
Activated carbon was synthesized from biochar charcoal by 2 M H2SO4. Activated carbon was immobilized on the pretreatment polystyrene by hydrothermal process forming new adsorbent (ACPS). Characterization studies were carried out by scanning electron microscope, energy-dispersive X-ray spectrometer, infrared spectroscopy and X-ray diffraction techniques. Different factors affect the adsorption process as pH, contact time, solid/liquid ratio, initial concentration and temperature. The adsorption mechanism was explained according to kinetic, isothermal and thermodynamic studies. Also, the regeneration of spent ACPS was studied.
Findings
The experimental results showed that pH and equilibrium time of the best adsorption were 6.0 and 60 min for U(VI), 4.0 and 90 min for Th(IV), (pHPZC = 3.4). The experimental results fit well with pseudo-second order, Freundlich and Dubinin–Radushkevich models proving the chemisorption and heterogenous adsorption reaction. Adsorption thermodynamics demonstrated that the adsorption process is exothermic and has random nature of the solid/liquid interface. In addition, the regeneration of spent ACPS research showed that the adsorbent has good chemical stability. According to the comparative study, ACPS shows higher adsorption capacities of U(VI) and Th(IV) than other previous bio-adsorbents.
Originality/value
This study was conducted to improve the chemical and physical properties of bio-charcoal purchased from the local market to activated carbon by hydrothermal method. Activated carbon was immobilized on polystyrene forming new adsorbent ACPS for eliminating U(VI) and Th(IV) from aqueous solutions.
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Kalidas Das and Pinaki Ranjan Duari
Several graphs, streamlines, isotherms and 3D plots are illustrated to enlighten the noteworthy fallouts of the investigation. Embedding flow factors for velocity, induced…
Abstract
Purpose
Several graphs, streamlines, isotherms and 3D plots are illustrated to enlighten the noteworthy fallouts of the investigation. Embedding flow factors for velocity, induced magnetic field and temperature have been determined using parametric analysis.
Design/methodology/approach
Ternary hybrid nanofluids has outstanding hydrothermal performance compared to classical mono nanofluids and hybrid nanofluids owing to the presence of triple tiny metallic particles. Ternary hybrid nanofluids are considered as most promising candidates in solar energy, heat exchangers, electronics cooling, automotive cooling, nuclear reactors, automobile, aerospace, biomedical devices, food processing etc. In this work, a ternary hybrid nanofluid flow that contains metallic nanoparticles over a wedge under the prevalence of solar radiating heat, induced magnetic field and the shape factor of nanoparticles is considered. A ternary hybrid nanofluid is synthesized by dispersing iron oxide (Fe3O4), silver (Ag) and magnesium oxide (MgO) nanoparticles in a water (H2O) base fluid. By employing similarity transformations, we can convert the governing equations into ordinary differential equations and then solve numerically by using the Runge–Kutta–Fehlberg approach.
Findings
There is no fund for the research work.
Social implications
This kind of study may be used to improve the performance of solar collectors, solar energy and solar cells.
Originality/value
This investigation unfolds the hydrothermal changes of radiative water-based Fe3O4-Ag-MgO-H2O ternary hybrid nanofluidic transport past a static and moving wedge in the presence of solar radiating heating and induced magnetic fields. The shape factor of nanoparticles has been considered in this study.
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Hung Ngoc Phan, Huong Mai Bui and Nguyen Khanh Vu
Bacterial cellulose (BC) is an ideal alternative filtering material. However, current functionalization approaches for BC have not been fully discovered industrially as well as…
Abstract
Purpose
Bacterial cellulose (BC) is an ideal alternative filtering material. However, current functionalization approaches for BC have not been fully discovered industrially as well as academically applying textile processing. This study aims to create a sustainable fabric-like membrane made of BC/activated carbon (AC) for applications in filtration using textile padding method, to protect people from respiratory pandemics.
Design/methodology/approach
Fabric-like BC is first mechanically dehydrated then AC is loaded via a textile padding step. The finishing efficacy, properties of fabric-like BC/AC and NaOH pretreatment are analyzed and characterized by scanning electron microscope (SEM), field emission scanning electron microscope (FE SEM), X-ray diffraction (XRD), CIELab color space, color strength (K/S), nitrogen adsorption-desorption isotherm including Brunauer–Emmett–Teller (BET) specific surface area and Barrett–Joyner–Halenda (BJH) pore size and volume.
Findings
This research results in a fabric-like BC/AC with pore diameters of 3.407 ± 0.310 nm, specific surface area of 115.28 m2/g and an efficient scalable padding process, which uses 8 times less amount of chemical and nearly 30 times shorter treating duration than conventional methods.
Practical implications
Our globe is now consuming an alarming amount of non-degradable disposable masks resulting in massive trash buildup as a future environmental problem. Besides, current disposable masks requiring a significant upfront technological investment have posed challenges in human protection from respiratory diseases, especially for countries with limited conditions. By combining a sustainable material (BC) with popular padding method of textile industry, the fabric-like BC/AC will offer sustainable and practical values for both humankind and nature.
Originality/value
This research has offered an effective padding process to functionalize BC, and a unique fabric-like BC/AC membrane for filtration applications.
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Ali A. Ali, Malek Alshukur, Ashraf M. Ashmawy, Ammar M. Mahmoud, Ahmed Saleh, Hesham S. Nassar and Bo Yao
This study aims to show the dyeing behaviour of polyester fabrics using four novel heterocyclic disperse dyes.
Abstract
Purpose
This study aims to show the dyeing behaviour of polyester fabrics using four novel heterocyclic disperse dyes.
Design/methodology/approach
The four dyes were synthesized based on 5, 5'-(1, 4-phenylene) bis (1, 3, 4-thiadiazol-2-amine) as a diazonium compound. The UV/Vis absorption spectroscopic data of these disperse dyes while dyeing polyester fabrics were investigated. Following this, the dyeing properties of these dyes on polyester fabrics were investigated under acid condition.
Findings
The results showed that increasing the dyeing temperature from 80°C to 100°C led to an increase in dye uptake for all dyes, but further increases of the temperature to 130°C led to higher dye uptake for dye 3 as the dye exhaustion increased by about 50% from 55.9% to 91.4%.
Originality/value
This study is important as it introduces new dyes for the dyeing of polyethylene terephthalate (PET) fibres with colours that range from yellowish orange to bluish yellow and scarlet red and all with excellent brightness, levelness and depth of shade.
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Chigoziri N. Njoku, Temple Uzoma Maduoma, Wilfred Emori, Rita Emmanuel Odey, Beshel M. Unimke, Emmanuel Yakubu, Cyril C. Anorondu, Daniel I. Udunwa, Onyinyechi C. Njoku and Kechinyere B. Oyoh
Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to…
Abstract
Purpose
Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to protect metals from deterioration in corrosive environments. Moreover, the toxic nature, non-biodegradability and price of most conventional corrosion inhibitors have encouraged the application of greener and more sustainable options, with natural and synthetic drugs being major actors. Hence, this paper aims to stress the capability of natural and synthetic drugs as manageable and sustainable, environmentally friendly solutions to the problem of metal corrosion.
Design/methodology/approach
In this review, the recent developments in the use of natural and synthetic drugs as corrosion inhibitors are explored in detail to highlight the key advancements and drawbacks towards the advantageous utilization of drugs as corrosion inhibitors.
Findings
Corrosion is a critical issue in numerous modern applications, and conventional strategies of corrosion inhibition include the use of toxic and environmentally harmful chemicals. As greener alternatives, natural compounds like plant extracts, essential oils and biopolymers, as well as synthetic drugs, are highlighted in this review. In addition, the advantages and disadvantages of these compounds, as well as their effectiveness in preventing corrosion, are discussed in the review.
Originality/value
This survey stresses on the most recent abilities of natural and synthetic drugs as viable and sustainable, environmentally friendly solutions to the problem of metal corrosion, thus expanding the general knowledge of green corrosion inhibitors.
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