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Article
Publication date: 17 February 2023

Khaled Mostafa, Mohamed Ramadan and Azza El-Sanabary

The purpose of this study is to investigate the authors' previously prepared and fully characterized poly (methacrylamide)-chitosan nanoparticles (CNPs) graft copolymer having…

Abstract

Purpose

The purpose of this study is to investigate the authors' previously prepared and fully characterized poly (methacrylamide)-chitosan nanoparticles (CNPs) graft copolymer having 50.2% graft yield with respect to flocculation efficiency for ferric laurate aqueous dispersions. This was done to compare the ability of the latter cheap, biodegradable and ecofriendly hybrid natural-synthetic polymeric substrate as a flocculant in comparison with higher cost, nonbiodegradable and harmful polyacrylamide as a well-known synthetic flocculant counterpart.

Design/methodology/approach

The graft copolymerization process was carried out at 450°Cfor 120 min using (1.0 g) CNPs, methacrylamide (1.5 g), 100 mmol/l potassium chromate and 80 mmol/l mandelic acid. Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis and specific viscosity were used to characterize and analyze the resultant copolymer. The flocculation efficiency was conferred in terms of transmittance % and weight removal %. The main factors influencing the flocculation process, such as flocculent dose, flocculation medium pH, stirring speed, flocculation temperature and grafting extent, were comprehensively discussed.

Findings

The flocculation efficiency of the prepared copolymers revealed the following findings: increased by increasing the flocculant dose, pH, temperature and stirring speed to a maximum values denoted at 30 ppm, 6.0, 30°C and 50 r/min, respectively, then decreased thereafter; increased by increasing the extent of grafting within the range studied; showed a comparable flocculation efficiency in comparison with polyacrylamide as a synthetic polymeric flocculent; and, finally, a preliminary bridging mechanism representing the attraction between the anionic suspended particles ferric laurate and cationic poly (MAam)-CNPs graft copolymer has been projected.

Originality/value

The advancement addressed here is undertaken with using the authors’ poly (MAam)-CNPs graft copolymers having different extent of grafting (a point which is not cited in the literature especially for the authors’ prepared copolymer) as a hybrid natural-synthetic polymeric substrate as a flocculant for ferric laurate aqueous dispersions in comparison with the high cost and nondegradable polyacrylamide synthetic flocculant.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 29 July 2022

Khaled Mostafa, Mohamed Ramadan and Azza El-Sanabary

This study aims to address a comprehensive and integrated investigations pertaining to the preparation of AgNPs with well-defined nano-sized scale using the aforementioned poly…

Abstract

Purpose

This study aims to address a comprehensive and integrated investigations pertaining to the preparation of AgNPs with well-defined nano-sized scale using the aforementioned poly (meth acrylic acid [MAA])–chitosan graft copolymer, which is cheap, nontoxic, biodegradable and biocompatible agent as a substitute for the traditionally used toxic reducing agents.

Design/methodology/approach

AgNPs are prepared under a range of conditions, containing silver nitrate and poly (MAA)–chitosan graft copolymer concentrations, time, temperature and pH of the preparation medium. To classify AgNPs obtained under the various conditions, ultraviolet–visible spectroscopy spectra and transmission electron microscopy images are used for characterization of AgNPs instrumentally in addition to the visual color change throughout the work. The work was further extended to study the application of the so prepared AgNPs on cotton fabric to see their suitability as antibacterial agent as well as their durability after certain washing cycles.

Findings

According to the current investigation, the optimal conditions for AgNPs formation of nearly 3–15 nm in size are 5 g/l, poly (MAA)–chitosan graft copolymer and 300 ppm AgNO3 in addition to carrying out the reaction at 60°C for 30 min at pH 12. Besides, the application of the so prepared AgNPs on cotton fabric displayed a substantial reduction in antibacterial efficiency against gram-positive and gram-negative bacteria estimated even after 10 washing cycles in comparison with untreated one.

Originality/value

To the best of the authors’ information, no comprehensive study of the synthesis of AgNPs using poly (MAA)–chitosan graft copolymer with a graft yield of 48% has been identified in the literature.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 16 August 2022

Zhao Yuhang, Zhicai Yu, Hualing He and Huizhen Ke

This study aims to fabricate a multifunctional electromagnetic interference (EMI) shielding composite fabric with simultaneous high-efficiency photothermal conversion and Joule…

Abstract

Purpose

This study aims to fabricate a multifunctional electromagnetic interference (EMI) shielding composite fabric with simultaneous high-efficiency photothermal conversion and Joule heating performances.

Design/methodology/approach

A multifunctional polypyrrole (PPy) hydrogel/multiwalled carbon nanotube (MWCNT)/cotton EMI shielding composite fabric (hereafter denoted as PHMC) was prepared by loading MWCNT onto tannin-treated cotton fabric, followed by in situ crosslinking-polymerization to synthesize three-dimensional (3D) conductive networked PPy hydrogel on the surface of MWCNT-coated cotton fabric.

Findings

Benefiting from the unique interconnected 3D networked conductive structure of PPy hydrogel, the obtained PHMC exhibited a high EMI-shielding effectiveness vale of 48 dB (the absorbing electromagnetic wave accounted for 84%) within a large frequency range (8.2–12.4 GHz). Moreover, the temperature of the laminated fabric reached 54°C within 900 s under 15 V, and it required more than 100 s to return to room temperature (28.7°C). When the light intensity was adjusted to 150 mW/cm2, the PHMC temperature was about 38.2°C after lighting for 900 s, indicating high-efficiency electro-photothermal effect function.

Originality/value

This paper provides a novel strategy for designing a type of multifunctional EMI shielding composite fabric with great promise for wearable smart garments, EMI shielding and personal heating applications.

Details

Pigment & Resin Technology, vol. 53 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 January 2024

Sabiha Sezgin Bozok

This study aims to embed anatase, rutile and brookite TiO2 nanoparticles (NPs) with different crystal phases into cotton fabrics by epoxy silane and to examine the effect of these…

Abstract

Purpose

This study aims to embed anatase, rutile and brookite TiO2 nanoparticles (NPs) with different crystal phases into cotton fabrics by epoxy silane and to examine the effect of these applications on the photocatalytic and mechanical properties of the fabric.

Design/methodology/approach

Different aqueous dispersions which contain anatase, rutile and brookite were prepared at three different concentrations (5%, 10% and 15%). These NPs were embedded in cotton fabrics by using GPTS [(3-glycidyloxypropyl) trimethoxysilane]. Characterization tests were performed by scanning electron microscopy (SEM), Raman and Fourier-transform infrared spectroscopy (FT/IR). Samples were stained with methylene blue (MB) and then exposed to solar light for different periods. Color changes of the samples were examined with a spectrophotometer. Air permeability, abrasion and tear strength tests were applied to all samples.

Findings

According to SEM images, the NPs were successfully attached to the cotton fabrics, and epoxy silane coating surrounded the fiber surfaces. The presence of the coating was also confirmed by Raman spectroscopy and FT/IR. The treatments reduced the stainability of the samples. The most effective applications for ensuring photocatalytic activity in cotton fabrics were suspensions as 10% brookite, 10% anatase and 5% anatase, in descending order. The applied coating slightly reduced the samples’ air permeability, and wear and tear strength.

Originality/value

The importance of this study is to determine the optimal crystal phase and its concentration by using epoxy silane to ensure self-cleaning properties on cotton fabrics. The sample treated with 10% brookite is the most approached its original white color by 99.65% as a result of degradation of MB (after 120 min). On the other hand, using the pure rutile with epoxy silane was not suitable for removing MB from the fabric.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 February 2024

Umesh Mahajan and S.T. Mhaske

This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl…

Abstract

Purpose

This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl methacrylate (HEMA) terminated urethane acrylate oligomer was synthesized and characterized to study its application in stereolithography 3D printing with different ratios of isobornyl acrylate and hexanediol diacrylate.

Design/methodology/approach

Polyester polyol was synthesized from suberic acid and butanediol. Additionally, isophorone diisocyanate, polyester polyol and HEMA were used to create urethane acrylate oligomer. Fourier transform infrared spectroscopy and 1H NMR were used to characterize the polyester polyol and oligomer. Various formulations were created by combining oligomer with reactive diluents in concentrations ranging from 0% to 30% by weight and curing with ultraviolet (UV) radiation. The cured coatings and 3D printed specimens were then evaluated for their properties.

Findings

The findings revealed an improvement in thermal stability, contact angle value, tensile strength and surface properties of the product which indicated its suitability for use as a 3D printing material.

Originality/value

This study discusses how oligomers that have been cured by UV radiation with mono- and difunctional reactive diluents give excellent coating characteristics and demonstrate suitability and stability for 3D printing applications.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 March 2024

Khaled Mostafa and Azza El-Sanabary

The novelty addressed here is undertaken by using tailor-made and fully characterized starch nanoparticles (SNPs) having a particle size ranging from 80 to 100 nm with a larger…

Abstract

Purpose

The novelty addressed here is undertaken by using tailor-made and fully characterized starch nanoparticles (SNPs) having a particle size ranging from 80 to 100 nm with a larger surface area, biodegradability and high reactivity as a starting substrate for cadmium ions and basic dye removal from wastewater effluent. This was done via carboxylation of SNPs with citric acid via esterification reaction using the dry preparation technique, in which a simple, energy-safe and sustainable process concerning a small amount of water, energy and toxic chemicals was used. The obtained adsorbent is designated as cross-linked esterified starch nanoparticles (CESNPs).

Design/methodology/approach

The batch technique was used to determine the CESNPs adsorption capacity, whereas atomic adsorption spectrometry was used to determine the residual cadmium ions concentration in the filtrate before and after adsorption. Different factors affecting adsorption were examined concerning pH, contact time, adsorbent dose and degree of carboxylation. Besides, to validate the esterification reaction and existence of carboxylic groups in the adsorbent, CESNPs were characterized metrologically via analytical tools for carboxyl content estimation and instrumental tools using Fourier-transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM) morphological analysis.

Findings

The overall adsorption potential of CESNPs was found to be 136 mg/g when a 0.1 g adsorbent dose having 190.8 meq/100 g sample carboxyl content at pH 5 for 60 min contact time was used. Besides, increasing the degree of carboxylation of the CESNPs expressed as carboxyl content would lead to the higher adsorption capacity of cadmium ions. FTIR spectroscopy analysis elucidates the esterification reaction with the appearance of a new intense peak C=O ester at 1,700 cm−1, whereas SEM observations reveal some atomic/molecules disorder after esterification.

Originality/value

The innovation addressed here is undertaken by studying the consequence of altering the extent of carboxylation reaction expressed as carboxyl contents on the prepared CESNPs via a simple dry technique with a small amount of water, energy and toxic chemicals that were used as a sustainable bio nano polymer for cadmium ions and basic dye removal from wastewater effluent in comparison with other counterparts published in the literature.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 24 January 2024

Dexin Chen, Hongyuan He, Zhixin Kang and Wei Li

This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.

Abstract

Purpose

This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.

Design/methodology/approach

One-step electrodeposition is a versatile and simple technology to prepare superhydrophobic coatings on metal surfaces.

Findings

Preparing superhydrophobic coatings by one-step electrodeposition is an efficient method to protect metal surfaces.

Originality/value

Even though there are several technologies, one-step electrodeposition still plays a significant role in producing superhydrophobic coatings.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 September 2022

Mohammad Mehralian, Ahmadreza Fallahfaragheh and Mohammad Khajeh Mehrizi

This study aims to investigation of the guar gum-manganese dioxide (GG/MnO2) nanocomposite (NC) synthesized using an environment-friendly method and the degradation of reactive…

Abstract

Purpose

This study aims to investigation of the guar gum-manganese dioxide (GG/MnO2) nanocomposite (NC) synthesized using an environment-friendly method and the degradation of reactive yellow (RY 145) dye in the UV system.

Design/methodology/approach

Characterization of the GG/MnO2 NCs were conducted using field emission scanning electron microscopy, X-ray diffraction and Fourier-transform infrared spectroscopy. Experiments were conducted using a 1 L glass reactor coupled with Ultraviolet (UV-C) blue light bulb of wavelength 250 nm and power of 8 W.

Findings

The NC (2.25 g/L) displayed high RY 145 dye degradation (81%) with 10 mg/L of concentration at pH 3. The coefficient of determination (R2 0.99) also depicted that the model fits the experimental data. The analysis of variance (ANOVA) showed that the F-values of 464.75, 276.04 and 5.15 are related to the dose of GG/MnO2 NCs, initial concentration of RY 145 dye and solution pH, respectively.

Practical implications

The GG/MnO2 NCs followed by photo oxidation process (UV-process) could be used to degrade the RY 145 dye from synthetic wastewater.

Originality/value

There are two main innovations. One is that the novel process is performed successfully for RY 145 dye degradation. The other is that the optimized conditions are obtained by Box–Behnken design. Also, the effects of different variables on the RY 145 dye removal efficiency were investigated.

Details

Pigment & Resin Technology, vol. 53 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 January 2024

Silvia Badini, Serena Graziosi, Michele Carboni, Stefano Regondi and Raffaele Pugliese

This study evaluates the potential of using the material extrusion (MEX) process for recycling waste tire rubber (WTR). By investigating the process parameters, mechanical…

Abstract

Purpose

This study evaluates the potential of using the material extrusion (MEX) process for recycling waste tire rubber (WTR). By investigating the process parameters, mechanical behaviour and morphological characterisation of a thermoplastic polyurethane-waste tire rubber composite filament (TPU-WTR), this study aims to establish a framework for end-of-life tire (ELT) recycling using the MEX technology.

Design/methodology/approach

The research assesses the impact of various process parameters on the mechanical properties of the TPU-WTR filament. Hysteresis analysis and Poisson’s ratio estimation are conducted to investigate the material’s behaviour. In addition, the compressive performance of diverse TPU-WTR triply periodic minimal surface lattices is explored to test the filament suitability for printing intricate structures.

Findings

Results demonstrate the potential of the TPU-WTR filament in developing sustainable structures. The MEX process can, therefore, contribute to the recycling of WTR. Mechanical testing has provided insights into the influence of process parameters on the material behaviour, while investigating various lattice structures has challenged the material’s capabilities in printing complex topologies.

Social implications

This research holds significant social implications addressing the growing environmental sustainability and waste management concerns. Developing 3D-printed sustainable structures using recycled materials reduces resource consumption and promotes responsible production practices for a more environmentally conscious society.

Originality/value

This study contributes to the field by showcasing the use of MEX technology for ELT recycling, particularly focusing on the TPU-WTR filament, presenting a novel approach to sustainable consumption and production aligned with the United Nations Sustainable Development Goal 12.

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