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Measures the intrinsic viscosities, in acetone and tetrahydrofurane (THF) at different temperatures, of a terpolymer of methyl methacrylate, ethyl acrylate and methacrylic acid, prepared by semicontinuous emulsion polymerization (latex). Analyses data with the aid of the equations of Huggins, Kraemer, Martin, Schulz‐Blaschke and an equation recently suggested by Rao. Considers relationships between different parameters. By comparing uncleaned samples with samples purified by single precipitation or by dissolution and precipitation from THF, observes the effects of low‐molecular weight and water‐soluble on the intrinsic viscosities. Discusses solvent powers and effects of degree of purification and temperature on viscosity. Discusses polymer‐solvents interactions in terms of the acceptor/donor properties of the solvents. Concludes that purification of functionalized latices can lead to modifications of the original systems, through the elimination of different polymer chains.

This study aims to introduce a new theoretical approach to blend spherical and non‐spherical particles in a coating to improve its viscosity characteristics.

Theoretical analysis has been used to modify an existing model developed by this author to apply to a broad range of particle configurations.

Non‐spherical particles like fibres or discs in a suspension or coating have been found to have three different viscosity response regions. Consequently, the viscosity of suspensions or coatings with these types of particles appears to have two apparent maximums as a function of concentration. Improved viscosity control of coatings have been found to be directly achievable by blending particles with different shapes based on the concentration relative to this first maximum. This optimisation process has been found to be better understood using a new variable which has been described as the “sphericity”, s. The “sphericity”, s, as described in this study has been defined as the relative ratio of the surface to volume fraction for a non‐spherical particle to that of a sphere of equivalent volume.

Experimental data involving monodisperse particles of different configurations is often extremely difficult to obtain. However, the theoretical general concepts can still be applicable.

The model presented in this paper provides practical guidelines to blending pigments with different particle shapes to control the viscosity of coatings and suspensions.

The model presented in this paper provides the first apparent guidelines to control the blending of pigments in coatings and composites with different particle shapes using the “sphericity” of the pigment particle.

The purpose of this study is to determine the physicochemical and rheological parameters of Albizia lebbeck gum.

Physicochemical analysis was carried out using recommended methods. Gas chromatography mass spectrophotometer and Fourier transformed infra red (FTIR) analyses were carried out using their respective spectrophotometer. Scanning electron microscopy was carried out using scanning electron microscope, while rheological measurements were carried out using Ubbelohde capillary viscometer, digital Brookfield DV 1 viscometer and a rheometer.

Albizia zygia gum is an ionic gum with unique physical and chemical properties. Scanning electron micrograph revealed that the internal structure of the gum is porous with irregular molecular arrangement. Thermodynamic parameters of viscous flow indicated the existence of few inter- and intra-molecular interactions, and the attainment of transition state was linked to bond breaking. Coil overlap transition studies revealed the existence of dilute and concentrated regimes. The viscosity of the gum was also found to decrease with decrease in the charge of cation (such that Al3+ > Ca2+ > K+) and with increase in ionic strength.

The paper provided information on physicochemical and rheological characteristics/behaviour of Albizia zygia gum, of Nigerian origin. From this information, possible application of this gum in the food and pharmaceutical industries can be deduced.

The paper is original since information concerning Albizia zygia gum of Nigerian origin are not well documented as established in the work. It also adds values on the use of Albizia zygia gum, either on its own or in combination with other gums for industrial purpose.

The importance of maximizing the particle packing fraction in a suspension by maximizing average particle size ratio of D₅/D₁ has been adequately shown to be important as previously reported in the literature. This study aims to extend that analysis to include the best formulation approach to maximize the packing fraction with a minimum number of monodisperse particle sizes.

An existing model previously developed by this author was modified theoretically to optimize the ratio used between consecutive monodisperse particle sizes. This process was found to apply to a broad range of particle configurations and applications. In addition, five different approaches for maximizing average particle size ratio D̅₅/D̅₁ were addressed for blending several different particle size distributions. Maximizing average particle size ratio D̅₅/D̅₁ has been found to result in an optimization of the packing fraction. Several new concepts were also introduced in the process of maximizing the packing fraction for these different approaches.

The critical part of the analysis to maximize the packing fraction with a minimum number of particles was the theoretical optimization of the ratio used between consecutive monodisperse particle sizes. This analysis was also found to be effectively independent of the maximum starting particle size. This study also clarified the recent incorrect claim in the literature that Furnas in 1931 was the first to generate the maximum theoretical packing fraction possible for n different particles that was actually originally developed in conjunction with the Sudduth generalized viscosity equation. In addition, the Furnas generated equation was also shown to give significantly different results from the Sudduth generated equation.

Experimental data involving monodisperse particles of different blends with a minimum number of particle sizes that are truly monodisperse are often extremely difficult to obtain. However, the theoretical general concepts can still be applicable.

The expanded model presented in this article provides practical guidelines for blending pigments using a minimum number of monodisperse particle sizes that can yield much higher ratios of the particle size averages D̅₅/D̅₁ and thus potentially achieve significantly improved properties such as viscosity.

The model presented in this article provides the first apparent guidelines to control the blending of pigments in coatings by the optimization of the ratio used between consecutive monodisperse particle sizes. This analysis was also found to be effectively independent of the maximum starting particle size.

The purpose of this paper is to evaluate the efficiency of acrylated guar gum (AGG) as an additive in alkyd resin for improved mechanical properties and to optimize the results of such an addition.

For studying the effect of AGG on coating properties, guar gum was modified to various degrees of esterification and various compositions of alkyd systems were made by incorporating different concentrations of AGG. The mechanical and solvent absorption of the unmodified and modified alkyd systems were characterized.

The incorporation of AGG into alkyd coating showed significant improvement of mechanical properties over the unmodified one. The modification caused an additional crosslink site through its unsaturation which led to increased crosslink density without phase separation of additive from the alkyd system which was confirmed by SEM scans.

The reactive additive, AGG used in the present study was synthesised using acryloyl chloride. Besides, it could also be synthesised from methacryloyl chloride and the effect of methyl substitution on water and solvent absorption could be studied.

The method developed provided a simple and practical solution to improving the mechanical properties of alkyd coatings.

The method for enhancing mechanical properties of cured alkyd system was novel and could find numerous applications in surface coatings.

ESPE, the market leader, is a medium-sized German manufacturer of precision dental impression materials competing in a shrinking market. To grow the business, ESPE invests substantial resources in innovative impression materials and associated distribution mechanisms. Squeezed by the shrinking market, the competition is increasingly using the proprietary channels (dispensing mechanisms) and brand equity (trademark) of ESPE to maintain their market share. There is a potential infringement. Explores how ESPE is organized to execute on the options imbedded in its IP rights.

To provide students with an understanding of how to use brands and trademarks in conjunction with trade secrets, patents, and other forms of IP in mature markets to build and maintain innovation-based competitive advantage.

To synthesise and characterise homo and copolymer of 4‐nonylphenyl methacrylate (NPMA) and styrene and to determine monomer reactivity ratios by the application of conventional linearisation methods such as Finemann‐Ross (F‐R) and Kelen‐Tudos (K‐T) methods.

New methacrylic monomer, NPMA with a pendant nonylphenyl group was copolymerised with styrene. All monomer and polymers (homo and copolymer) are characterised and subsequently the monomer reactivity ratio was determined.

The monomer reactivity ratios were determined by application of conventional linearisation methods such as F‐R (r₁=0.41±0.05; r₂=3.47±0.31), K‐T (r₁=0.43±0.19; r₂=3.54±0.09) methods. The thermogravimetric analysis (TGA) of the polymer in nitrogen reveals that it posses very good thermal stability in comparison to alkyl acrylates due to presence of pendant nonylphnyl group.

New methacrylic monomer, NPMA was synthesised by reacting nonylphenol dissolved in methyl ethyl ketone (MEK) with methacryloyl chloride in the presence of triethylamine as a base. Copolymers of NPMA with styrene were synthesised in MEK using benzoyl peroxide (BPO) as initiator under nitrogen atmosphere at different feed composition.

The method developed is a simple and easy method of copolymerisation of styrene with methacrylate to obtain copolymer of better properties.

The method developed is a novel method for enhancing the thermal, as well as surface adhesion, properties which has several applications in surface coatings and adhesives.

The purpose of this paper is to synthesise, characterise and study polymerisation kinetics of novel 4‐nonylphenylmethacrylate (NPMA) polymer.

New methacrylic monomer, 4‐NPMA with a pendant nonylphenyl group was synthesised and characterised using various characterisation techniques. The free radical polymerisation kinetics study was done with the help of differential scanning calorimetry data.

The average heat of polymerisation (ΔHp) was found to be 685.43 J/g. Activation energy (E_a) of 95.86 kJ mol⁻¹ and frequency factor of (A) 3.4 × 10⁴ min⁻¹ was obtained using Kissinger method. The thermogravimetric analysis of the polymer in nitrogen reveals that it possesses very good thermal stability in comparison to alkyl methacrylates due to presence of pendant nonylphenyl group.

New methacrylic monomer, 4‐NPMA was synthesised by reacting nonylphenol dissolved in methyl ethyl ketone (MEK) with methacryloyl chloride in the presence of triethylamine as a base. Polymerisation of 4‐NPMA was carried out in MEK using benzoyl peroxide (BPO) as initiator under nitrogen atmosphere. The kinetics study of NPMA monomer with 1.1 wt% BPO was reported for evaluation of kinetic parameters by employing the Kissinger equation.

This is a simple and easy method of modification of methacrylate ester with phenyl groups to obtain a polymer of enhanced properties.

This is a novel method for enhancing the thermal as well as surface adhesion properties of methacrylate polymers which finds several applications in surface coatings and adhesives.

It is heartening to observe the large amount of basic research carried out around the world which has a bearing on the problems of the coatings industry. Some of the recent aspects of this work will be described here. At the same time the point can also be made that it is not well‐organized basic research. There are not, for example, basic co‐operative programmes between universities and industry whose objective is to solve some of the key problems with which the coatings industry is confronted. This is not to say that work of this sort does not go on. It is to say that this work does not go on in a way which can bring a number of forces together in the most efficient fashion.

The purpose of this paper was to show that the generalised viscosity model can correctly characterise suspension data over both a wide range of concentration as well as a wide range of temperature. A second objective of this study was to show theoretically and experimentally how the interaction coefficient from the generalised viscosity model also appears to have some thermodynamic properties.

In this study, many well‐known suspension equations were shown mathematically to be subsets of the generalised viscosity equation. The generalised viscosity equation was also found to be able to be reduced mathematically to two well‐known dilute solution equations (Huggins and Kramer's equations) as well. The relationship between Huggins and Kramer's constants and the interaction coefficient from the generalised viscosity equation yielded the potential to evaluate the solubility characteristics of the interaction coefficient. The value of the interaction coefficient was then found to be able to be evaluated as a function of temperature to enhance an understanding of the thermodynamic characteristics of the interaction coefficient using the data of Bueche.

In this study, a polymer plasticiser system involving polymethyl methacrylate in the plasticiser diethyl phthalate yielded an interaction coefficient, σ, primarily in the expected plasticiser range from 0< σ<1. It was also found that the generalised viscosity equation fit Bueche's polymer plasticiser data remarkably well over the whole concentration range for temperatures ranging from 30°C to 140°C. This study also appeared to show that the interaction coefficient from the generalised viscosity model can apparently characterise thermal transitions as well as thermodynamic solubility for a polymer solute (i.e. polymethyl methacrylate) when viscosity is evaluated over a wide temperature range. This result was particularly significant since Bueche's data covered 25 decades of viscosity on a log scale.

This is the first paper to successfully explore the thermodynamic characteristics of the interaction coefficient of the generalised viscosity equation. This opens up new avenues for evaluating the solubility and thermodynamic characteristics of various additives in solutions and polymeric formulations.