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The purpose of this paper is modeling the effect of negative capacitance in the capacitance-voltage characteristic of the intergranular potential barrier of varistor structure.

The modeling of the capacitance-voltage characteristic of the intergranular barrier in metal oxide varistor ceramics is based on the development of the algorithm. It includes all the known mechanisms of electrotransfer in a wide range of voltages and currents, and also takes into account the voltage drop on the intergranular interlayer of intergranular potential barrier.

The models and algorithms for calculating the capacitance-voltage characteristics of a single intergranular potential barrier with the use of the most established understanding used at the interpretation of the nonlinear conductivity intergranular barrier are developed. The results of the capacitance-voltage characteristics modeling correspond to the existing understanding of the electrical properties on the ac current varistor ceramics are based on zinc oxide. The model allows to predict the behavior of varistors on the alternating current (voltage).

It is established that the recharge of the surface localized states occurs when a voltage is applied to the varistor structure, it can lead to a relaxation decrease in the width of the potential barrier overcome by tunneling electrons in the field emission from the conduction band of the one crystallite in the conduction band of the other crystallite and thus to the current backlog of applied voltage on the phase (i.e. the expression of the negative capacitance effect).

The purpose of this paper is to develop a generalized model of the nonlinear conductivity of varistor ceramic suitable for solving problems of prediction and control of ceramic nonlinearity, stability of varistor properties.

The modeling of current-voltage characteristic of the intergranular barrier in metal oxide varistor ceramics is based on the development of the algorithm. It includes all the known mechanisms of electrotransfer in a wide range of voltages and currents of the current-voltage characteristics, and also takes into account the deviation of the barrier form the Schottky barrier.

The models of double Schottky barrier and double barrier of arbitrary form, as well as the algorithms for calculating the current-voltage characteristics of a single intergranular potential barrier and a separate “microvaristor” with the use of the most well-established understanding of the main mechanisms of electrical are developed. The results of current-voltage characteristics modeling correspond to the existing understanding of the nonlinear electrical conductivity varistor ceramics are based on zinc oxide. The model of double barrier of arbitrary form takes into account the deviation of the barrier form the Schottky barrier which is important in predicting the deformation of the current-voltage characteristics of the varistor products in the process of degradation.

The relation between the form of the current-voltage characteristic and the distribution profile of the donor concentration in the surface regions of the semiconductor crystallites constituting the intergranular potential barrier is established. The accumulation of donors in the space charge region leads to the increase in the current on the prebreakdown region of the current-voltage characteristic and the reduction of voltage corresponding to the breakdown region beginning of the current-voltage characteristic. The significant role of the interlayer in the formation of current-voltage characteristic of the intergranular potential barrier is shown.

The purpose of this paper is to explore and develop specific models of the kinetics of isothermal depolarization currents (IDC) and the corresponding methods for the diagnostics of the physical parameters of localized electronic states (LES) in heterogeneous materials and corresponding polycrystalline semiconductor materials and heterogeneous insulators with a conductive phase.

Analysis of the kinetics of isothermal depolarization on the basis of the models allowed the authors to establish a sufficient level of their information content. This also allowed the possibility of applying for research and testing of heterogeneous structures of electronic technique.

Optimal conditions (full charge of LES on one side of the object and full discharge on the other side) and the correction factors, allowed the researchers to find concentration of these states using the developed models.

This paper uses a particular method to determine and test the parameters of LES, including operations of determining the time constant of IDC signal from its frequency spectrum, finding the ionization energy and the capture coefficient of electrons from the temperature dependence of this time constant, determining the concentration based on the integration of the time dependence of current density of IDC in the time interval that boundaries are determined from the limited range of frequencies of the signal IDC spectrum has been proposed, validated and verified by numerical experiments.

Stainless-clad bimetallic steels (SCBS) are widely investigated in some extremely environmental applications areas, such as polar sailing area and tropical oil and gas platforms areas, because of their excellent anticorrosion performance and relatively lower production costs. However, the properties of SCBS, including the mechanical strength, weldability and the anticorrosion behavior, have a direct relation with the manufacturing process and can affect their practical applications. This paper aims to review the application and the properties requirements of SCBS in marine environments to promote the application of this new material in more fields.

In this paper, the manufacturing process, welding and corrosion-resistant properties of SCBS were introduced systematically by reviewing the related literatures, and some results of the authors’ research group were also introduced briefly.

Different preparation methods, such as rolling composite, casting rolling composite, explosive composite, laser cladding and plasma arc cladding, as well as the process parameters, including the vacuum degree, rolling temperature, rolling reduction ratio, volume ratios of liquid to solid, explosive ratio and the heat treatment, influenced a lot on the properties of the SCBS through changing the interface microstructures. Otherwise, the variations in rolling temperature, pass, reduction and the grain size of clad steel also brought the dissimilarities of the mechanical properties, microhardness, bonding strength and toughness. Another two new processes, clad teeming method and interlayer explosive welding, deserve more attention because of their excellent microstructure control ability. The superior corrosion resistance of SCBS can alleviate the corrosion problem in the marine environment and prolong the service life of the equipment, but the phenomenon of galvanic corrosion should be noted as much as possible. The high dilution rate, welding process specifications and heat treatment can weaken the intergranular corrosion resistance in the weld area.

This paper summarizes the application of SCBS in marine environments and provides an overview and reference for the research of stainless-clad bimetallic steel.

To study the metallurgical characteristics obtained from the process of diffusion bonding of 316L stainless steel (SS) using a commercial Ni‐based amorphous alloy interlayer and its effect on the corrosion resistance of the self‐joined SS‐amorphous alloy‐SS junction zone.

Squared samples of austenitic SS were joined using a brazing metallic foil BMF‐15^® in a sandwich‐like arrangement. The samples were then placed into a resistance furnace with a controlled N₂ atmosphere. The joining process was carried out at 1105 and 1170°C holding the samples in the furnace for periods of 5, 10, 15, 20 and 40 min. The junction zone was evaluated by scanning electron microscopy (SEM) in order to determine the metallurgical structure induced during the process. The corrosion resistance of the SS/BMF‐15^®/SS joints were evaluated using DC electrochemical methods on joined samples immersed in a 3.5 wt% NaCl solution.

The samples of 316L SS showed self‐diffusion bonding at both temperatures which are quality depended upon the holding times. A concentration of second phases was observed by SEM at the BMF‐15^®. The joints developed crevice corrosion at open circuit potential due to a galvanic couple formed between the SS and the amorphous alloy, and presented preferential dissolution of the Ni‐amorphous alloy under anodic polarization in 3.5 per cent NaCl solution at room temperature.

This work presents a systematic study of the self‐diffusion bonding process of SS pieces jointed with an amorphous alloy interlayer and the metallurgical effects on its corrosion resistance of in a 3.5 wt% NaCl solution.

This paper gives a bibliographical review of the finite element methods (FEMs) applied to the analysis of ceramics and glass materials. The bibliography at the end of the paper contains references to papers, conference proceedings and theses/dissertations on the subject that were published between 1977‐1998. The following topics are included: ceramics – material and mechanical properties in general, ceramic coatings and joining problems, ceramic composites, ferrites, piezoceramics, ceramic tools and machining, material processing simulations, fracture mechanics and damage, applications of ceramic/composites in engineering; glass – material and mechanical properties in general, glass fiber composites, material processing simulations, fracture mechanics and damage, and applications of glasses in engineering.

Wire and arc additive manufacturing (WAAM) technology-based cold metal transfer (CMT) to produce large aluminum alloy parts has become more and more popular. In WAAM, wire is the only raw material. The purpose of this paper is to study the effect of wire composition on the microstructure and properties of the ZAlCu5MnCdVA alloy deposited by WAAM.

Two thin-walled ZAlCu5MnCdVA alloys with different wire compositions were prepared by WAAM. The copper contents were 4.7% (Al-4.7Cu) and 5.0% (Al-5.0Cu), respectively. The microstructure, element distribution and evolution of precipitated phases of the two samples were characterized and analyzed by optical microscopy, scanning electron microscopy and transmission electron microscopy. Hardness and tensile properties of samples were tested, and strengthening mechanism was analyzed in detail.

The results show that grain sizes of Al-4.7Cu and Al-5.0Cu are less than 40 μm. The average mass fraction of Cu in Al matrix and the number of nanometer scale θ'' and θ' phases are the main factors affecting the tensile properties of Al-Cu alloy. Tensile properties of two materials show different characteristics at room temperature and high temperature. Al-5.0Cu is better at room temperature and Al-4.7Cu is better at high temperature. The yield strength (YS), ultimate tensile strength (UTS) and elongation in the x direction of Al-5.0Cu at room temperature are 451 ± 10.2 MPa, 486 ± 10.2 MPa and 9 ± 0.5%, respectively. The YS, UTS and elongation in the x direction of Al-4.7Cu at high temperature are 290 ± 4.5 MPa, 356 ± 7.0 MPa and 13% ± 0.2%, respectively.

Experiments show that the increase of Cu element can improve the properties at room temperature of the ZAlCu5MnCdVA alloy by WAAM, but its properties at high temperature decrease.

The purpose of this paper is to quickly manufacture full Cu₃Sn-microporous copper composite joints for high-temperature power electronics applications and study the microstructure evolution and the shear strength of Cu₃Sn at different bonding times.

In this paper, a novel structure of Cu/composite solder sheet/Cu was designed. The composite solder sheet was made of microporous copper filled with Sn. The composite joint was bonded by thermo-compression bonding under pressure of 0.6 MPa at 300°C. The microstructure evolution and the growth behavior of Cu₃Sn at different bonding times were observed by electron microscope and metallographic microscope. The shear strength of the joint was measured by shear machine.

At initial bonding stage the copper atoms in the substrate and the copper atoms in the microporous copper dissolved into the liquid Sn. Then the scallop-liked Cu₆Sn₅ phases formed at the interface of liquid Sn/microporous copper and liquid Sn/Cu substrates. During the liquid Sn changing to Cu₆Sn₅ phases, Cu₃Sn phases formed and grew at the interface of Cu₆Sn₅/Cu substrates and Cu₆Sn₅/microporous copper. After that the Cu₃Sn phases continued to grow and the Cu₃Sn-microporous copper composite joint with a thickness of 100 µm was successfully obtained. The growth rule of Cu₃Sn was parabolic growth. The shear strength of the composite joints was about 155 MPa.

This paper presents a novel full Cu₃Sn-microporous copper composite joint with high shear strength for high-temperature applications based on transient liquid phase bonding. The microstructure evolution and the growth behavior of Cu₃Sn in the composite joints were studied. The shear strength and the fracture mechanism of the composite joints were studied.

The purpose of this paper is to eliminate Part defects and enrich additive manufacturing of ceramics. Laser powder bed fusion (L-PBF) experiments were carried to investigate the effects of laser parameters and selective oxidation of Titanium (mixed with TiO₂) on the microstructure, surface quality and melting state of Titania. The causes of several L-PBF parts defects were thoroughly analyzed.

Laser power and scanning speed were varied within a specific range (50–125 W and 170–200 mm/s, respectively). Furthermore, varying loads of Ti (1%, 3%, 5% and 15%) were mixed with TiO₂, which was selectively oxidized with laser beam in the presence of oxygen environment.

Part defects such as cracks, pores and uneven grains growth were widely reduced in TiO₂ L-PBF specimens. Increasing the laser power and decreasing the scanning speed shown significant improvements in the surface morphology of TiO₂ ceramics. The amount of Ti material was fully melted and simultaneously changed into TiO₂ by the application of the laser beam. The selective oxidation of Ti material also improved the melting condition, microstructure and surface quality of the specimens.

TiO₂ ceramic specimens were produced through L-PBF process. Increasing the laser power and decreasing the scanning speed is an effective way to sufficiently melt the powders and reduce parts defects. Selective oxidation of Ti by a high power laser beam approach was used to improve the manufacturability of TiO₂ specimens.

Human aging is becoming a common issue these days as it results in orthopaedic-related issues such as joints disorderness, bone-fracture. People with age = 60 years suffer more from these aforesaid issues. It is expected that these issues in human beings will ultimately reach 2.1 billion by 2050 worldwide. Furthermore, the increase in traffic accidents in young people throughout the world has significantly emerged the need for artificial implants. Their implantation can act as a substitute for fractured bones or disordered joints. Therefore, this study aims to focus on electron beam melted titanium (Ti)-based orthopaedic implants along with their recent trends in the field.

The main contents of this work include the basic theme and background of the metal-based additive manufacturing, different implant materials specifically Ti alloys and their classification based on crystallographic transus temperature (including α, metastable β, β and α + β phases), details of electron beam melting (EBM) concerning its process physics, various control variables and performance characteristics of EBMed Ti alloys in orthopaedic and orthodontic implants, applications of EBMed Ti alloys in various load-bearing implants, different challenges associated with the EBMed Ti-based implants along with their possible solutions. Recent trends and shortfalls have also been described at the end.

EBM is getting significant attention in medical implants because of its minor issues as compared to conventional fabrication practices such as Ti casting and possesses a significant research potential to fabricate various medical implants. The elastic modulus and strength of EBMed ß Ti-alloys such as 24Nb-4Zr-8Sn and Ti-33Nb-4Sn are superior compared to conventional Ti for orthopaedic implants. Beta Ti alloys processed by EBM have near bone elastic modulus (approximately 35–50 GPa) along with improved tribo-mechanical performance involving mechanical strength, wear and corrosion resistance, along with biocompatibility for implants.

Advances in EBM have opened the gateway Ti alloys in the biomedical field explicitly ß-alloys because of their unique biocompatibility, bioactivity along with improved tribo-mechanical performance. Less significant work is available on the EBM of Ti alloys in orthopaedic and orthodontic implants. This study is directed solely on the EBM of medical Ti alloys in medical sectors to explore their different aspects for future research opportunities.