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1 – 10 of 23
Article
Publication date: 3 May 2022

Fatemeh Ashouri Mirsadeghi, Enayatollah Moradi Rufchahi and Saeid Zarrabi

The purpose of this study, 3-aminopyridine, 8-aminoquinoline and some new synthesized 2-aminobenzothiazoles were diazotized with nitrosyl sulfuric acid and subsequently coupled…

Abstract

Purpose

The purpose of this study, 3-aminopyridine, 8-aminoquinoline and some new synthesized 2-aminobenzothiazoles were diazotized with nitrosyl sulfuric acid and subsequently coupled with 5-chloro-8-hydroxy quinoline to synthesize the corresponding heteroarylazo dyes 6–13.

Design/methodology/approach

The structures of dyes were characterized by mass, Fourier transform infra red, 1H proton nuclear magnetic resonance and ultra violet-visible spectroscopic techniques. Absorption spectra of the dyes were measured in acetic acid, ethanol, chloroform, acetonitrile, dimethyl formamide and dimethyl sulfoxide and correlated with the nature of the solvents and substituents. The effects of varying pH on the absorption wavelengths of the azo dyes were also studied. In addition, the acidity constants (pKa) of the dyes were determined using the spectrophotometric method in an ethanol-water mixture (80:20, v/v) at 20–23°C. Besides, density functional theory (DFT) calculations were carried out to compare the energies of proposed azo and hydrazone tautomers of the dyes.

Findings

The results showed that the withdrawing chloro groups on the diazo moiety have significant influence (red shift) on the electron absorption spectra of these dyes. In addition, introducing electron withdrawing chloro groups into the benzothiazoles moiety increased the acidic character of dyes.

Originality/value

The synthesized 7-hetroarylazo-5-chloro-8-hydroxy quinoline dyes are new members in the 8-hydroxyquinoline azo dyes family, where very few details regarding the synthesis of such dyes are reported before in the literature. They are unique in terms of synthesis, spectral properties and DFT calculations.

Details

Pigment & Resin Technology, vol. 52 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 8 November 2021

Siti Aisyah Ishak, Mohamad Fared Murshed, Nuridah Sabtu and Hamizah Mokhtar

In this study, new hybrid polymers composed of Zinc chloride (ZnCl2), acrylamide and chitosan were prepared at different ratios and temperatures. The effects of pH and polymer…

Abstract

Purpose

In this study, new hybrid polymers composed of Zinc chloride (ZnCl2), acrylamide and chitosan were prepared at different ratios and temperatures. The effects of pH and polymer dosage were examined for different polymers to observe their efficiency in the removal of turbid water. The polymers’ zeta potential, morphology, elemental composition and functional groups were also identified and studied.

Design/methodology/approach

The free-radical polymerisation process was executed in the presence of N, N’-Methylene bis-acrylamide and potassium persulphate in one molar acrylamide solution. ZnCl2 and chitosan (CO) were later introduced into the suspension under nitrogen gas flow. Ratio and temperature were varied during polymerisation. The hybrid polymer produced, termed Polyacrylamide + chitosan oligosaccharide + zinc chloride (PAMCOZ), was analysed using Fourier transform infra-red spectroscopy attenuated total reflectance and scanning electron microscope with energy dispersive X-ray. The hybrid PAMCOZ was experimented with in high turbid kaolin suspension using jar testing analysis to see its ability as a coagulant.

Findings

The coagulation process using PAMCOZ with a ratio of 11 (3:2) at 70°C surrounding temperature showed a 100% reduction at pH 4 with 50 mg/L of the polymer. The functional groups present in ratio 11 polymer were hydroxyl, carbonyl, amide and methyl groups. In addition, several elements were spotted on the surface of PAMCOZ, such as zinc (Zn), carbon (C), chlorine (Cl), nitrogen (N) and oxygen (O). The effect of pH also demonstrated that PAMCOZ was unfavourable in an alkaline turbid water environment.

Research limitations/implications

Due to the research methodology approach, the research results may lack actual wastewater application. Therefore, researchers are encouraged to test the hybrid coagulant on raw wastewater, such as pulp and paper mill effluent with a high turbidity value similar to this study.

Originality/value

The polymerisation between zinc chloride, acrylamide and chitosan has not yet been applied. The different ratios and effects of temperature were analysed on PAMCOZ to see the turbidity removal. PAMCOZ showed better turbidity removal in acidic conditions.

Details

World Journal of Engineering, vol. 20 no. 2
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 8 September 2022

Asieh Yahyazadeh, Enayatollah Moradi Rufchahi, Hessamoddin Yousefi and Seyyedeh Maryam Golzar Poursadeghi

This paper aims to synthesize 6-ethyl-4-hydroxyquinolin-2(1H)-one as a new enol-type coupling component in the preparation of some 3-arylazo-4-hydroxyquinolin-2(1H)-one dyes and…

Abstract

Purpose

This paper aims to synthesize 6-ethyl-4-hydroxyquinolin-2(1H)-one as a new enol-type coupling component in the preparation of some 3-arylazo-4-hydroxyquinolin-2(1H)-one dyes and evaluate the solvent effects on their absorption in ultraviolet-visible spectra.

Design/methodology/approach

6-Ethyl-4-hydroxyquinolin-2(1H)-one was synthesized by thermal cyclocondensation reaction of N, N′-bis(4-ethylphenyl) malonamide at 130–140°C in polyphosphoric acid. This compound was then applied in the azo-coupling reaction with some aniline-based diazonium salts, so as to prepare seven new mono-heterocyclic azo dyes. The structures of the compounds were confirmed using mass spectroscopic technique. Fourier transform infra red (FT-IR) and 1H proton nuclear magnetic resonance (1H NMR) and carbon-13 nuclear magnetic resonance (13 C NMR) studies on the structure of the azo compounds revealed that they exist as two E- and Z-isomers of hydrazone tautomer both in solid and solution state. The effects of acid and base on the visible absorption spectra of the dyes were also evaluated and discussed.

Findings

Ultra violet-visible UV-vis absorption spectra of the dyes didn’t show significant variation by changing of solvents because of intramolecular H-bonding between proposed hydrazone forms and 2- and 4-keto functions in their structures. The spectra of the dyes were not sensitive to the addition of acid but were very sensitive to base.

Originality/value

The synthesized 3-arylazo-4-hydroxyquinolin-2(1H)-one dyes are new members in the 4-hydroxyquinolin-2(1H)-one azo dyes family, where very few details regarding the synthesis of such dyes are reported before in the literature. They are unique in terms of synthesis and spectral properties.

Details

Pigment & Resin Technology, vol. 53 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 31 March 2023

Robert Bogue

This paper aims to illustrate the growing role of drones in applications involving physical tasks.

Abstract

Purpose

This paper aims to illustrate the growing role of drones in applications involving physical tasks.

Design/methodology/approach

Following a short introduction, this first provides a brief introduction to drone technology. It then describes and discusses products and applications involving physical tasks in agricultural and forestry, maritime rescue, firefighting and product delivery. Finally, brief conclusions are drawn.

Findings

Excluding military applications, drones were initially used primarily for image acquisition. Numerous different designs have since been developed with greatly varying wing configurations, payloads, flight duration, power sources and other features which are increasingly being used to conduct physical tasks. In the applications considered here drones are applying agrochemicals and dispersing crop and tree seeds; saving lives by deploying lifeboats and buoyancy aids; extinguishing fires in high-rise buildings and forests; and delivering groceries, food, mail, medicines and humanitarian aid, often in and to remote locations.

Originality/value

This study provides a detailed insight into selection of applications in which drones conduct physical tasks.

Details

Industrial Robot: the international journal of robotics research and application, vol. 50 no. 4
Type: Research Article
ISSN: 0143-991X

Keywords

Article
Publication date: 7 June 2022

O.A. Elhefnawy and A.A. Elabd

The purpose of this study is to prepare Polystyrene grafted with Zeolite Y (Zeosty) for Uranyl ion [U(VI)] adsorption from aqueous solution. The adsorption mechanism has been…

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Abstract

Purpose

The purpose of this study is to prepare Polystyrene grafted with Zeolite Y (Zeosty) for Uranyl ion [U(VI)] adsorption from aqueous solution. The adsorption mechanism has been explained by studying kinetic, isothermal and thermodynamic models.

Design/methodology/approach

Polystyrene was grafted with Zeosty by a simple hydrothermal technique. Zeosty was characterized by different techniques such as X-ray diffraction, scanning electron microscope, energy dispersive X-ray and Infrared spectroscopy to confirm its structure and its molecular composition. Zeosty was used for U(VI) adsorption from an aqueous solution in a series of batch experiments. The effects of pH, contact time, initial U(VI) concentration and temperature on the adsorption process were investigated.

Findings

The results showed that the adsorption of U(VI) on the prepared reached equilibrium at pH 6 with a removal efficiency of 98.9%. Adsorption kinetics and isotherms models are studied on the experimental data to estimate the mechanism of the adsorption reaction was chemisorption and homogenous reaction. The activity of Zeosty increased at high temperatures, resulting in the adsorption capacity increase. Thermodynamic parameters ΔGo, ΔHo and ΔSo indicate that the adsorption processes are spontaneous and endothermic. Zeosty has an effective surface and could be considered a valuable adsorbent for U(VI) removal from aqueous waste. A comparison study proves that the new adsorbent has high effective behavior in the adsorption process, and it is considered a new reliable adsorbent for U(VI) removal from wastewater.

Originality/value

This study is complementary to the previous study using the same technique to prove that the effective fine particle adsorbents need solid support to enhance their absorption capacities.

Details

Pigment & Resin Technology, vol. 52 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Open Access
Article
Publication date: 4 May 2021

Michael Y.L. Chew

This paper highlights a crucial public safety issue due to falling objects from tall residential buildings in Singapore. A systematic façade inspection regime and a system of…

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Abstract

Purpose

This paper highlights a crucial public safety issue due to falling objects from tall residential buildings in Singapore. A systematic façade inspection regime and a system of evaluation of severity for the detection and assessment of potential falling objects from tall buildings are presented.

Design/methodology/approach

The research uses qualitative case study approach with 450 tall residential buildings sampled for the study. The common materials, elements, components with high risk of falling objects, the nature and type of the falling, the critical factors affecting the falling, the respective level of severity, and the effectiveness of various diagnostic techniques and protocols, are summarised.

Findings

Façade for tall residential buildings in Singapore comprises mainly cementitious materials cast in situ or precast, with fixtures and architectural features, all of which have potential of falling. The common anomalies arising from each material and fixture/features are identified, the causes evaluated and their implications to future design, construction and maintenance analysed.

Originality/value

This study provides original and significant information to a crucial public safety issue, setting design and construction criteria that will serve as a benchmark for new and existing facades, applicable to all cities dominated by tall buildings. The paper presents original figures, checklists and guides as a basis for readers' consideration to use according to their respective unique conditions.

Details

International Journal of Building Pathology and Adaptation, vol. 41 no. 6
Type: Research Article
ISSN: 2398-4708

Keywords

Article
Publication date: 16 February 2024

Sergejs Pavlovs, Andris Jakovičs and Alexander Chudnovsky

The purpose of this paper is the study of the electro-vortex flow (EVF) as well as heating and melting processes for mini industrial direct current electric arc furnace (DC EAF).

Abstract

Purpose

The purpose of this paper is the study of the electro-vortex flow (EVF) as well as heating and melting processes for mini industrial direct current electric arc furnace (DC EAF).

Design/methodology/approach

A mini DC EAF was designed, manufactured and installed to study the industrial processes of heating and melting a small amount of melt, being 4.6 kg of steel in the case under study. Numerical modelling of metal melting was performed using the enthalpy and porosity approach at equal values and non-equal values of the solidus and liquidus temperatures of the metal. The EVF of the liquid phase of metal was computed using the large eddy simulation model of turbulence. Melt temperature measurements were made using an infrared camera and a probe with a thermocouple sensor. The melt speed was estimated by observing the movement of particles at the top surface of melt.

Findings

The thermal flux for metal heating and melting, which is supplied through an arc spot at the top surface of metal, is estimated using the thermal balance of the furnace at melting point. The melting time was estimated using numerical modelling of heating and melting of metal. The process started at room temperature and finished once whole volume of metal was molten. The evolution of the solid/melt phase boundary as well as evolution of EVF patterns of the melt was studied.

Originality/value

Numerical studies of heating and melting processes in metal were performed in the case of intensive liquid phase turbulent circulation due to the Lorentz force in the melt, which results from the interaction of electrical current with a self-magnetic field.

Details

COMPEL - The international journal for computation and mathematics in electrical and electronic engineering , vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0332-1649

Keywords

Article
Publication date: 12 December 2023

Robert Bogue

The purpose of this paper is to provide a detailed insight into the global military robot industry with an emphasis on products and their applications.

Abstract

Purpose

The purpose of this paper is to provide a detailed insight into the global military robot industry with an emphasis on products and their applications.

Design/methodology/approach

Following an introduction which includes a brief historical account, this provides an industry overview, including various market dimensions and a discussion of the geopolitical and technological factors driving market development. The three following sections provide details of land, airborne and marine robots, their capabilities and deployments in recent conflicts. Finally, brief conclusions are drawn.

Findings

Military robots which operate on land, in the air and at sea constitute a multi-billion dollar industry which is growing rapidly. It is being driven by geopolitical tensions, notably the military-technology arms race between China and the USA and the conflict in Ukraine, together with technological progress, particularly in AI. Many robots possess multi-functional capabilities, and the leading application is presently intelligence, surveillance and reconnaissance. An increasing number of heavily armed robots are being developed, and AI has the potential to impart these with the capacity to deliver lethal force without human intervention. Although heavily criticised in some quarters, this capability has probably already been deployed on the battlefield. With ever-growing military budgets, escalating political tensions and technological innovations, robots will play an increasingly significant role in future conflicts.

Originality/value

This provides a detail account of military robots and their role in modern warfare.

Details

Industrial Robot: the international journal of robotics research and application, vol. 51 no. 2
Type: Research Article
ISSN: 0143-991X

Keywords

Article
Publication date: 23 November 2023

Ruizhen Song, Xin Gao, Haonan Nan, Saixing Zeng and Vivian W.Y. Tam

This research aims to propose a model for the complex decision-making involved in the ecological restoration of mega-infrastructure (e.g. railway engineering). This model is based…

Abstract

Purpose

This research aims to propose a model for the complex decision-making involved in the ecological restoration of mega-infrastructure (e.g. railway engineering). This model is based on multi-source heterogeneous data and will enable stakeholders to solve practical problems in decision-making processes and prevent delayed responses to the demand for ecological restoration.

Design/methodology/approach

Based on the principle of complexity degradation, this research collects and brings together multi-source heterogeneous data, including meteorological station data, remote sensing image data, railway engineering ecological risk text data and ecological restoration text data. Further, this research establishes an ecological restoration plan library to form input feature vectors. Random forest is used for classification decisions. The ecological restoration technologies and restoration plant species suitable for different regions are generated.

Findings

This research can effectively assist managers of mega-infrastructure projects in making ecological restoration decisions. The accuracy of the model reaches 0.83. Based on the natural environment and construction disturbances in different regions, this model can determine suitable types of trees, shrubs and herbs for planting, as well as the corresponding ecological restoration technologies needed.

Practical implications

Managers should pay attention to the multiple types of data generated in different stages of megaproject and identify the internal relationships between these multi-source heterogeneous data, which provides a decision-making basis for complex management decisions. The coupling between ecological restoration technologies and restoration plant species is also an important factor in improving the efficiency of ecological compensation.

Originality/value

Unlike previous studies, which have selected a typical section of a railway for specialized analysis, the complex decision-making model for ecological restoration proposed in this research has wider geographical applicability and can better meet the diverse ecological restoration needs of railway projects that span large regions.

Details

Engineering, Construction and Architectural Management, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0969-9988

Keywords

Article
Publication date: 11 July 2023

Nagla Elshemy, Hamada Mashaly and Shimaa Elhadad

This study aims to observe the coloring efficacy of graphite (G) and nano bentonite clay (BCNPs) on the adsorption of Basic Blue 5 dye from residual dye bath solution.

Abstract

Purpose

This study aims to observe the coloring efficacy of graphite (G) and nano bentonite clay (BCNPs) on the adsorption of Basic Blue 5 dye from residual dye bath solution.

Design/methodology/approach

Some factors that affected the adsorption processes were examined and found to have significant impacts on the adsorption capacity such as the initial concentration of G and/or BCNPs (Co: 40–2,320 mg/L), adsorbent bath pH (4–9), shaking time (30–150 min.) and initial dye concentration (40–200 mg/L). The adsorption mechanism of dye by using G and/or BCNPs was studied using two different models (first-pseudo order and second-pseudo order diffusion models). The equilibrium adsorption data for the dye understudy was analyzed by using four different models (Langmuir, Freundlich, Temkin modle and Dubinin–Radushkevich) models.

Findings

It has been found that the adsorption kinetics follow rather a pseudo-first-order kinetic model with a determination coefficient (R2) of 0.99117 for G and 0.98665 for BCNPs. The results indicate that the Freundlich model provides the best correlation for G with capacities q_max = 2.33116535 mg/g and R2 = 0.99588, while the Langmuir model provides the best correlation for BCNPs with R2 = 0.99074. The adsorbent elaborated from BCNPs was found to be efficient and suitable for removing basic dyes rather than G from aqueous solutions due to its availability, good adsorption capability, as well as low-cost preparation.

Research limitations/implications

There is no research limitation for this work. Basic Blue 5 dye graphite (G) and nano bentonite clay (BCNPs) were used.

Practical implications

This work has practical applications for the textile industry. It is concluded that using graphite and nano bentonite clay can be a possible alternative to adsorb residual dye from dye bath solution and can make the process greener.

Social implications

Socially, it has a good impact on the ecosystem and global community because the residual dye does not contain any carcinogenic materials.

Originality/value

The work is original and contains value-added products for the textile industry and other confederate fields.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

1 – 10 of 23