Search results

In this study, the oxidative degradation performance of indigo wastewater based on electrochemical systems was explored. The decolourization degrees, removal rate of chemical oxygen demand and biochemical oxygen demand of the indigo wastewater after degradation were evaluated and optimized treatment conditions being obtained.

The single factor method was first used to select the electrolyte system and electrode materials. Then the response surface analysis based on Box–Behnken Design was chosen to determine the influence of four independent variables such as FeCl₃ concentration, NaCl concentration, decolourization time and voltage on the degradation efficiency.

On the basis of single factor experiment, the electrode material of stainless steel was selected in the double cell, and the indigo wastewater was electrolyzed with FeCl₃ and NaCl electrolytes. The process conditions of electrochemical degradation of indigo wastewater were optimized by response surface analysis: the concentration of FeCl₃ and NaCl was of 16 and 9 g/L, respectively, with a decolourization time of 50 min, voltage of 10 V and decolourization percentage of 98.94. The maximum removal rate of chemical oxygen demand reached 75.46 per cent. The highest ratio of B/C was 3.77, which was considered to be more biodegradable.

Dyeing wastewater is bringing out more and more pollution problems to the environment. However, there are some shortcomings in traditional technologies such as adsorption and filtration. As a kind of efficient and clean water treatment technology, electrochemical oxidation has been applied to the treatments of various types of wastewater. The decolourization and degradation of indigo wastewater is taken as an example to provide reference for the treatment of wastewater in actual plants.

The developed method provided a simple and practical solution for efficiently degrading indigo wastewater.

The method for the electrochemical oxidation technology was novel and could find numerous applications in the degradation of printing and dyeing wastewater.

Tailings generated by sulphide ore processing at Chaabet El Hamra mine contain a variety of sulphide minerals such as pyrite, marcasite, sphalerite, galena and chalcopyrite with carbonated and siliceous gangue. It is well known that the presence of pyrite can cause environmental threats, in particular the acid mine drainage risk (AMD), if there is not enough neutralizing potential. Waste chemical analyses show that the content of total sulphur (S) is more than 9 per cent, which could be possible to separate the pyrite from other heavy minerals based on interfacial property of these minerals, because the pyrite contain the sulphur-rich fraction.

In this study, the possibility of waste reprocessing using froth flotation of sulphuric bulk and depression-heavy minerals. It is environmental desulphurization that removes much of the high S fraction.

The results obtained in terms of S recovery and residual S content are interesting after merely 12 min of flotation by addition of potassium amyl xanthate collector (140 g/t), pine oil frother (10 g/t) and activation with copper sulphate (CuSO4+; 60 g/t) and at optimum pH of 5.

It can be shown from waste treatment by flotation of pyrite depression sphalerite collects significant desulphurization in sulphur content is 19 per cent against 8 per cent in the initial release.

The purpose of this study to investigate acetaminophen (ACT) degradation efficiencies by using ozone/persulfate oxidation process in a batch reactor. In addition, the effects of various parameters on the ACT removal efficiency toward pathway inference of ACT degradation were investigated.

The experiments were in the 2 L glass vessels. Ozone gas with flow rate at 70 L.h⁻¹ was produced by ozone generator. After the adjustment of the pH, various dosages of persulfate (1, 3, 5, 7 and 9 mmol.L⁻¹) were then added to the 500 mL ACT-containing solution with 150 mg.L⁻¹ of concentration. Afterward, ozone gas was diffused in glass vessels. The solution after reaction flowed into the storage tank for the detection. The investigated parameters included pH and the amount of ozone and persulfate addition. For comparison of the ACT degradation efficiency, ozone/persulfate, ozone and persulfate oxidation in reactor was carried out. The ACT concentration using a HPLC system equipped with 2998 PDA detector was determined at an absorbance of 242 nm.

ACT degradation percentage by using ozone or persulfate in the process were at 63.7% and 22.3%, respectively, whereas O₃/persulfate oxidation process achieved degradation percentage at 91.4% in 30 min. Degradation efficiency of ACT was affected by different parameter like pH and addition of ozone or persulfate, and highest degradation obtained when pH and concentrations of persulfate and ozone was 10 and 3 mmol.L⁻¹ and 60 mg.L⁻¹, respectively. O₃, OH^• and SO⁴⁻ were evidenced to be the radicals for degradation of ACT through direct and indirect oxidation. Gas chromatography–mass spectrometer analysis showed intermediates including N-(3,4-dihydroxyphenyl) formamide, hydroquinone, benzoic acid, 4-methylbenzene-1,2-diol, 4-aminophenol.

This study provided a simple and effective way for degradation of activated ACT as emerging contaminants from aqueous solution. This way was conducted to protect environment from one of the most important and abundant pharmaceutical and personal care product in aquatic environments.

There are two main innovations. One is that the novel process is performed successfully for pharmaceutical degradation. The other is that the optimized conditions are obtained. In addition, the effects of various parameters on the ACT removal efficiency toward pathway inference of ACT degradation were investigated.

Indirect electrochemical oxidation and electro-flocculation were combined to degrade indigo wastewater.

The degradation efficiency of indigo wastewater in single-cell and double-cell were investigated. Based on the previous single factor experiments, the oxidative degradation conditions of indigo wastewater in single cell were optimized by response surface methodology (RSM). The decolorization rate, chemical oxygen demand (COD) removal rate, the contents of flocculation precipitation and indigo were measured and analyzed.

The degradation efficiency in single cell was higher than in double cell. The electrolysis conditions were optimized by RSM and the decolorization rate was 99.01% with COD removal rate of 60.34% and conductivity of 89.75 mS/cm. The amount of flocculated precipitation decreased by 53.33% and the indigo increased by 86.34%. The content of Na and S decreased by 12.13 and 6.49%, respectively. The ratio of Fe3+ to Fe2+ in the solution was 4.62:1, indicating that most of the iron dropped on the electrode sheet was converted to Fe3+.

The one-step electrochemical oxidation and flocculation method with the advantages of simple operation and environmental protection, provided a reference for the actual treatment of dyeing wastewater.

Combining the electrochemical flocculation and oxidation provided an efficient and practical solution for degradation of indigo wastewater.

Combining the advantages of electrochemical oxidation and electroflocculation, the application of electrochemistry in printing and dyeing wastewater treatment technology has been expanded.

Ethylenediaminetetraacetic acid and other organic chelates are widely employed in electroless plating processes used by the printed circuit board and metal finishing industries. These chelating agents can pose problems with downstream waste water treatment, and metals and water recycling processes, due to their ability to complex heavy metal ions and their low biodegradabilities. Conventional treatment methods, such as carbon adsorption, air stripping and reverse osmosis can create secondary waste problems and are normally applied as “end of pipe” treatments. The development of new technology to address these problems would be welcomed. The ROCWAT project, funded by the EC under the “CRAFT” programme, detailed in this paper was undertaken to develop and deliver innovative techniques for the in situ destruction of chelates and other organics found in manufacturing process chemistries and effluent streams.

“As in other fields of lubrication and processing, the incorporation of various chemical additive materials to straight mineral oils can reinforce intrinsic desirable properties or impart new properties necessary to the high performance expected of today's metalworking lubricants and coolants”.

The textile industry is evolving toward nanotechnology, which provides materials with self-cleaning properties. This paper aims to provide a thorough explanation of the green synthesis and mechanism of ZnO nanoparticles, with prospective applications of zinc oxide nanoparticles (ZnO NPs) in self-cleaning textiles.

This review introduces a green mechanism for the synthesis of ZnO NPs using plant extracts, their self-cleaning properties and the mechanisms of physical, chemical and biological self-cleaning actions for textile applications.

ZnO NPs are among the several nanoparticles that are beneficial for self-cleaning textiles because of their exceptional physical and chemical properties, although review publications addressing the use of ZnO NPs in textiles for self-cleaning are uncommon. These results indicate that the plant-synthesized ZnO NPs display excellent biological, physical and chemical self-cleaning properties, the mechanism of which involves photocatalysis, surface roughness and interactions between ZnO NPs and bacterial surfaces.

Nanoformulations of plant-synthesized ZnO have been reviewed to achieve promising self-cleaning textile properties and have not been reviewed earlier.

Thin film development and nanoscale oxidation studies have been of great interest recent years. Nucleation rate theory[1‐3] has been successfully used to describe metal heteroepitaxy [4] and qualitatively explained the initial stage of oxidation behavior[5]. To further quantitative understanding of these nano‐scale processes and the morphology evolution in general gas‐metal reactions and thin film development, a powerful simulation tool is urgently needed. The Thin Film Oxidation (TFOx) model is an atomistic Kinetic Monte Carlo (KMC) model, which has been developed of this purpose. The TFOx model includes all of the relevant microscopic processes in thin film growth. It simulates various steps and phenomenon during thin film development, which includes deposition, decomposition, adatom diffusion, nucleation, adatom desorption, island growth and et.al. TFOx has a large amount of input parameters compared to other KMC models to assure the realistic and accuracy, which also makes itself a versatile tool of studying the thin film development. Some application of TFOx in simulating the Cu (100) oxidation behavior will also be discussed in this paper.

A viscoelastic boundary element method has been developed to model the motion of silicon dioxide and silicon nitride during thermal oxidation of silicon. This technique uses Kelvin's solution reformulated according to the correspondence principle on viscoelasticity. Constant‐velocity loading is chosen to ensure smooth variations in displacement and stress behavior for a wide range of relaxation times.

The purpose of this paper is to present and discuss the external factors of the solar dryer design that influenced the thermal efficiency of the solar dryer that contribute to the better quality of dried food products.

From the reviewed works of literature, the external factors including the drying temperature, airflow rate and relative humidity have significant effects to increase the rate of moisture diffusivity of the freshly harvested products during the drying process. The proper controls of airflow rate (Q), velocity (V), relative humidity (RH%) and drying temperature (°C) can influence the dried product quality. The dehydration ratio is the procedure to measure the quality of the dried food product.

The indirect solar dryer including the mixed-mode, hybrid and integrated was found shorter in drying time and energy-intensive compared to sun drying and direct drying. The recommended drying temperature is from 35.5°C to 70°C with 1–2 m/s velocity and 20%–60% relative humidity. The optimum thermal efficiency can be reached by additional devices, including solar collectors and solar accumulators. It gives a simultaneous effect and elongated the drying temperature 8%–10% higher than ambient temperature with 34%–40% energy saving. The recommended airflow rate for drying is 0.1204 to 0.0894 kg/s. Meanwhile, an airflow rate at 0.035–0.04 kg/m2 is recommended for an optimum drying kinetic performance.

This paper discusses the influence of the external factors of the solar dryer design on the thermal performance of the solar dryer and final dried food products quality. Therefore, the findings cannot serve as a statistical generalization but should instead be viewed as the quantitative validation subjected to fundamentals of the solar dryer design process and qualitative observation of the dried food product quality.

A well-designed of solar dryer with low operating and initial fabrication cost, which is simple to operate is useful for the farmers to preserve surplus harvested crops to an acceptable and marketable foods product. The optimization of the external and internal factors can contribute to solar dryer thermal performance that later provides an organoleptic drying condition that results in good quality of dried product and better drying process. The recommended drying temperature for a drying method is between 35°C up to 70°C. Drying at 65.56°C was effective to kill microorganisms. Meanwhile, drying at 50°C consider as average drying temperature. The recommended airflow rate for drying is 0.1204 to 0.0894 kg/s. Meanwhile, air flowrate at 0.035–0.04 kg/m² is recommended for optimum drying kinetic performance. The recommended value of aspect ratio and mass flow rate is 200 to 300 for an optimum evaporation rate. The good quality of dried products and good performance of solar dryers can be developed by proper control of airflow rate (Q), velocity (V), relative humidity (RH%) and drying temperature (°C).

The proper control of the drying temperature, relative humidity and airflow rate during the drying process will influence the final dried food products in terms of shape, color, aroma, texture, rupture and nutritious value. It is crucial to control the drying parameters because over-drying caused an increment of energy cost and reduces the dry matter. The quick-drying will disturb the chemical process during fermentation to be completed.

This study identifies the potential of the solar drying method for dehydrating agricultural produces for later use with the organoleptic drying process. The organoleptic drying process can reduce mold growth by promising an effective diffusion of moisture from freshly harvested products. The research paper gives useful understandings that well-designed solar drying technology gives a significant effect on dried product quality.