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1 – 10 of 35Weiwei Lv, Zhijie Huangfu, Kangkang Wang, Wei Zhang and Jiming Yao
Indirect electrochemical oxidation and electro-flocculation were combined to degrade indigo wastewater.
Abstract
Purpose
Indirect electrochemical oxidation and electro-flocculation were combined to degrade indigo wastewater.
Design/methodology/approach
The degradation efficiency of indigo wastewater in single-cell and double-cell were investigated. Based on the previous single factor experiments, the oxidative degradation conditions of indigo wastewater in single cell were optimized by response surface methodology (RSM). The decolorization rate, chemical oxygen demand (COD) removal rate, the contents of flocculation precipitation and indigo were measured and analyzed.
Findings
The degradation efficiency in single cell was higher than in double cell. The electrolysis conditions were optimized by RSM and the decolorization rate was 99.01% with COD removal rate of 60.34% and conductivity of 89.75 mS/cm. The amount of flocculated precipitation decreased by 53.33% and the indigo increased by 86.34%. The content of Na and S decreased by 12.13 and 6.49%, respectively. The ratio of Fe3+ to Fe2+ in the solution was 4.62:1, indicating that most of the iron dropped on the electrode sheet was converted to Fe3+.
Research limitations/implications
The one-step electrochemical oxidation and flocculation method with the advantages of simple operation and environmental protection, provided a reference for the actual treatment of dyeing wastewater.
Practical implications
Combining the electrochemical flocculation and oxidation provided an efficient and practical solution for degradation of indigo wastewater.
Originality/value
Combining the advantages of electrochemical oxidation and electroflocculation, the application of electrochemistry in printing and dyeing wastewater treatment technology has been expanded.
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Wei Zhang, Weiwei Lv, Xiaoyan Li and Jiming Yao
In this study, the oxidative degradation performance of indigo wastewater based on electrochemical systems was explored. The decolourization degrees, removal rate of chemical…
Abstract
Purpose
In this study, the oxidative degradation performance of indigo wastewater based on electrochemical systems was explored. The decolourization degrees, removal rate of chemical oxygen demand and biochemical oxygen demand of the indigo wastewater after degradation were evaluated and optimized treatment conditions being obtained.
Design/methodology/approach
The single factor method was first used to select the electrolyte system and electrode materials. Then the response surface analysis based on Box–Behnken Design was chosen to determine the influence of four independent variables such as FeCl3 concentration, NaCl concentration, decolourization time and voltage on the degradation efficiency.
Findings
On the basis of single factor experiment, the electrode material of stainless steel was selected in the double cell, and the indigo wastewater was electrolyzed with FeCl3 and NaCl electrolytes. The process conditions of electrochemical degradation of indigo wastewater were optimized by response surface analysis: the concentration of FeCl3 and NaCl was of 16 and 9 g/L, respectively, with a decolourization time of 50 min, voltage of 10 V and decolourization percentage of 98.94. The maximum removal rate of chemical oxygen demand reached 75.46 per cent. The highest ratio of B/C was 3.77, which was considered to be more biodegradable.
Research limitations/implications
Dyeing wastewater is bringing out more and more pollution problems to the environment. However, there are some shortcomings in traditional technologies such as adsorption and filtration. As a kind of efficient and clean water treatment technology, electrochemical oxidation has been applied to the treatments of various types of wastewater. The decolourization and degradation of indigo wastewater is taken as an example to provide reference for the treatment of wastewater in actual plants.
Practical implications
The developed method provided a simple and practical solution for efficiently degrading indigo wastewater.
Originality/value
The method for the electrochemical oxidation technology was novel and could find numerous applications in the degradation of printing and dyeing wastewater.
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Zhijie Huangfu, Wei Zhang, Shang Hao, Mengdi Zhang and Jiming Yao
This study aims to evaluate the efficiency of metal electrode and electrolytes on the electroflocculation of indigo wastewater, produced by printing and dyeing factory, and to…
Abstract
Purpose
This study aims to evaluate the efficiency of metal electrode and electrolytes on the electroflocculation of indigo wastewater, produced by printing and dyeing factory, and to optimize the treatment system.
Design/methodology/approach
For effective purging, various types of metal electrodes (graphite, pure aluminum and stainless steel) and supporting electrolytes (sodium chloride and sodium sulfate) were selected for electroflocculation experiments. The decolorization rate and chemical oxygen demand (COD) removal rate were characterized.
Findings
The treatment effects of stainless steel and aluminum were similar, but the dissolution loss of aluminum and the production of flocs greatly limit its application. Electrolytes gave obvious effects to these systems. Sodium sulfate was better than sodium chloride, the decolorization rate was increased by 3.31%, the removal rate of COD in the solution was increased by 28.65% and the weight of flocculation precipitation was reduced by 0.214 g.
Research limitations/implications
The electrochemical treatment system was constructed to compare and analyze the influence of experimental parameters and to provide a reference for the actual treatment of indigo wastewater.
Practical implications
Electrochemical flocculation can remove the insoluble indigo solids and it plays a key role in wastewater treatment.
Originality/value
It is novel to optimize the combination of electrode and electrolyte to improve the efficiency of electroflocculation, which can be widely used in the actual wastewater treatment process.
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Wei Zhang, Mengdi Zhang, Zhijie Huangfu, Jiming Yao and Yuan Xie
This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.
Abstract
Purpose
This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.
Design/methodology/approach
The single factor experiment was used to explore the optimum process parameters for electrochemical decolorization of indigo dyeing wastewater by changing the applied voltage, electrolysis time and electrolyte concentration. At the voltage of 9 V, the morphology of flocs with different electrolytic times was observed and the effect of electrolyte concentration on decolorization rate in two electrolyte systems was also investigated. Further analysis of chemical oxygen demand (COD) removal rate, anode weight loss and sediment quantity after electrochemical treatment of indigo dyeing wastewater were carried out.
Findings
Comprehensive considering the decolorization degree and COD removal rate of the wastewater, the aluminum electrode showed the best treatment effect among several common anode materials. With aluminum electrode as an anode, under conditions of applied voltage of 9 V, electrolysis time of 40 min and sodium sulfate concentration of 6 g/L, the decolorization percentage obtained was of 94.59% and the COD removal rate reached at 84.53%.
Research limitations/implications
In the electrochemical treatment of indigo dyeing wastewater, the aluminum electrode was found as an ideal anode material, which provided a reference for the choice of anodes. The electrodes used in this study were homogenous material and the composite material anode needed to be further researched.
Practical implications
It provided an effective and practical anode material choice for electrochemical degradation of indigo dyeing wastewater.
Originality/value
Combined with the influence of applied voltage, electrolysis time and electrolyte concentration and anode materials on decolorization degree and COD removal rate of indigo dyeing wastewater, providing a better electrochemical treatment system for dyehouse effluent.
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Dawu Shu, Shaolei Cao, Yan Zhang, Wanxin Li, Bo Han, Fangfang An and Ruining Liu
This paper aims to find a suitable solution to degrade the C.I. Reactive Red 24 (RR24) dyeing wastewater by using sodium persulphate to recycle water and inorganic salts.
Abstract
Purpose
This paper aims to find a suitable solution to degrade the C.I. Reactive Red 24 (RR24) dyeing wastewater by using sodium persulphate to recycle water and inorganic salts.
Design/methodology/approach
The effects of temperature, the concentration of inorganic salts and Na2CO3 and the initial pH value on the degradation of RR24 were studied. Furthermore, the relationship between free radicals and RR24 degradation effect was investigated. Microscopic routes and mechanisms of dye degradation were further confirmed by testing the degradation karyoplasmic ratio of the product. The feasibility of the one-bath cyclic dyeing in the recycled dyeing wastewater was confirmed through the properties of dye utilization and color parameters.
Findings
The appropriate conditions were 0.3 g/L of sodium persulphate and treatment at 95°C for 30 min, which resulted in a decolorization rate of 98.4% for the dyeing wastewater. Acidic conditions are conducive to rapid degradation of dyes, while ·OH or SO4−· have a destructive effect on dyes under alkaline conditions. In the early stage of degradation, ·OH played a major role in the degradation of dyes. For sustainable cyclic dyeing of RR24, inorganic salts were reused in this dyeing process and dye uptake increased with the times of cycles. After the fixation, some Na2CO3 may be converted to other salts, thereby increasing the dye uptake in subsequent cyclic staining. However, it has little impact on the dye exhaustion rate and color parameters of dyed fabrics.
Originality/value
The recommended technology not only reduces the quantity of dyeing wastewater but also enables the recycling of inorganic salts and water, which meets the requirements of sustainable development and clean production.
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Quratulain Mohtashim, Salma Farooq and Fareha Asim
The application of indigo dyes in the denim industries has been criticised due to the introduction of non-renewable oxidation products into the environment. Previous studies have…
Abstract
Purpose
The application of indigo dyes in the denim industries has been criticised due to the introduction of non-renewable oxidation products into the environment. Previous studies have investigated that reducing sugars can be used as green alternatives to sodium dithionite in the indigo dyeing of cotton fabric owing to their reduced and stable redox potential in the dye bath. The purpose of this study was to dye denim cotton fabric with indigo dye using various reducing sugars and alkalis. The use of sucrose and potassium hydroxide (KOH) for indigo dyeing has been explored for the first time.
Design/methodology/approach
A mixed factorial design with four variables including alkali, pH, number of dips and type of reducing sugar at different levels was studied to identify a significant correlation between the effect of these variables on the colour strength and fastness properties of the dyeings.
Findings
Investigations were made to examine the significant factors and interactions of the selected responses in the eco-friendly dyeing method. This process has the potential to reduce the load of sulphite and sulphate generated in the dyebath due to the use of a conventional reducing agent, sodium dithionite. The colour strength of the dyeing reduced with fructose was found to be better than other reducing sugars and significantly influenced by the number of dips, pH levels and the interaction between pH and reducing sugars. Using fructose for indigo dyeing with two dips at a pH of 11.5, using KOH as an alkali, results in higher colour strength values. The fastness properties of the indigo-dyed sample with reducing sugars ranging from fair to good or good to excellent. Specifically, colour change receives a rating of grey scale 3–4, staining 4–5, dry rubbing 4 and light fastness 3–4. These assessments hold true across various factors such as the type of reducing sugar, alkali, pH and the number of dips. The optimised parameters leading to improved colour strength and fastness properties are also discussed.
Originality/value
This dyeing technique is novel and a green alternative to dithionite denim dyeing. This process is found to be useful for indigo dyeing of denim fabric leading to reduced and stable redox potential in the dyebath and acceptable colour strength of the dyed fabric.
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Xiaoyan Li, MengQian Wang, Gang Wu and Jiming Yao
The purpose of this study is to improve the performance of sodium borohydride in reducing indigo at room temperature, the divalent copper ion complex was combined with…
Abstract
Purpose
The purpose of this study is to improve the performance of sodium borohydride in reducing indigo at room temperature, the divalent copper ion complex was combined with electrochemical technology for the reduction of indigo by sodium borohydride.
Design/methodology/approach
According to the K/S value of the dyed cloth sample, find a more suitable ligand for the copper ion in the catholyte. Response surface analysis tests were performed to evaluate the effects of sodium borohydride concentration, sodium hydroxide concentration and copper sulfate pentahydrate concentration on the reduction potential of the dye solution and the K/S value of the dyed fabric samples.
Findings
Sodium gluconate was found to be a more suitable ligand for copper ions in catholyte. The effects of NaOH concentration as well as the interaction of NaBH4 and NaOH on the reduction potential of the catholyte and the K/S value of the dyed fabric samples were extremely significant. The optimal concentrations of NaBH4, NaOH and CuSO4•5H2O were 0.5, 2.5 and 0.65 g/L. In the case of the optimized condition, the absolute value of the reduction potential was 968, and the K/S value was 11.92, which is comparable with that of the conventional reduction process with sodium dithionite.
Originality/value
The divalent copper ion complex combined with electrochemical technology was applied in the process of reducing indigo with NaBH4 at room temperature.
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Xiaoyan Li, Zhihui Zhang, Jiming Yao, MengQian Wang and Na Yang
To improve the problems as the heavy burden of sewage treatment and environmental pollution caused by the traditional sodium hydrosulfite reduction dyeing of indigo, this study…
Abstract
Purpose
To improve the problems as the heavy burden of sewage treatment and environmental pollution caused by the traditional sodium hydrosulfite reduction dyeing of indigo, this study aims to carry out the direct electrochemical reduction dyeing for indigo with the eco-friendly Cu(II)/sodium borohydride reduction system under normal temperature and pressure conditions.
Design/methodology/approach
The electrochemical behavior of Cu(II)/sodium borohydride reduction system was investigated by cyclic voltammetry. And, the dyeing performance of the Cu(II)/sodium borohydride reduction system was developed by optimizing the concentration of copper sulfate in the anode electrolyte, applied voltage and reduction time via single-factor and orthogonal integrated analysis.
Findings
The dyeing performance of the Cu(II)/sodium borohydride reduction system is superior to that of the traditional reduction dyeing with sodium hydrosulfite. In the case of the optimized condition, the soaping fastness and dry/wet rubbing fastness of the dyed fabric in the two reduction dyeing processes were basically comparable, the K/S value of electrocatalytic reduction of indigo by Cu(II)/NaBH4 is 11.81, which is higher than that obtained by traditional sodium hydrosulfite reduction dyeing of indigo.
Originality/value
The innovative electrocatalytic reduction system applied herein uses sodium borohydride as the hydrogen source combined with Cu(II) complex as the catalyst, which can serve as a medium for electron transfer and active the dye molecule to make it easier to be reduced. The electrochemical dyeing strategy presented here provides a new idea to improve the reduction dyeing performance of indigo by sodium borohydride.
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Raphael Kanyire Seidu, Benjamin Eghan, Emmanuel Abankwah Ofori, George Kwame Fobiri, Alex Osei Afriyie and Richard Acquaye
The purpose of this study is to investigate the physical, ultraviolet (UV), colour appearance and colour fastness properties of selected fabrics dyed with natural dyes from Daboya…
Abstract
Purpose
The purpose of this study is to investigate the physical, ultraviolet (UV), colour appearance and colour fastness properties of selected fabrics dyed with natural dyes from Daboya and Ntonso communities of Ghana. The study further highlights the rich cultural heritage of traditional dyeing from these two communities. Craftsmen in West Africa especially Ghana, have sustained the traditional dyeing methods to produce textile products for consumers.
Design/methodology/approach
In this study, two sample fabrics were purchased from craftsmen at Ntonso and Daboya communities in Ghana. These fabrics were analysed at the laboratory under standard test methods for their physical, UV, colour appearance and colour fastness properties.
Findings
Results showed that all the sample fabrics have good UV shielding performance (ratings above 50+). Daboya sample fabrics (dyed with indigo dyes) produced more colour stains than the sample fabrics from Ntonso (dyed with black “kuntunkuni” dyes). The K/Ssum value or colour yield reduced after washing but that alternatively increased the calculated ultraviolet protection factor.
Practical implications
Findings from this study exposed the unique UV performance of dyed traditional fabrics (using natural dyes) from Ntonso and Daboya communities in Ghana. This inspires and enforces the need for craftsmen to improve their production cycle to produce these fabrics in different sizes which provides the necessary UV shielding abilities for consumers in the wake of climate changes.
Originality/value
This study demonstrated that the natural dyeing process at the two communities produced relatively good UV and colour fastness properties of the sample fabrics. These eco-friendly dyeing practices have survived over time to maintain and promote the concept of sustainability within the textile and fashion industry in Ghana.
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The purpose of this paper is to describe a project intended for the implementation of a formal cradle to grave management program for hauled or trucked industrial wastewater in…
Abstract
Purpose
The purpose of this paper is to describe a project intended for the implementation of a formal cradle to grave management program for hauled or trucked industrial wastewater in Jordan.
Design/methodology/approach
Industries that do not have treatment onsite or that treat their industrial wastewater to a level not suitable for disposal into sewers or those that do not have access to sewer system have to haul their industrial wastewater to a treatment or disposal facility. At present most industries haul their industrial wastewater to a solid waste landfill site specially designated to receive industrial wastewater. In the program presented here, a manifest system for these industries have been introduced and implemented in a number of pilot projects.
Findings
A manifest form has been devised and used in a number of pilot demonstrations that enabled the formulation of specific conclusions and recommendations. Before implementing this manifest a program that includes training, awareness, governmental enforcement and commitment, and upgrading of disposal sites and laboratories capabilities has to be implemented.
Originality/value
Management of hauled industrial wastewater is very important in a water poor country like Jordan. The introduction of a manifest system and the identification of the problems associated with its implementation are key issues for sustainable development in Jordan.
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