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Article
Publication date: 27 May 2014

Ayssar Nahlé, Ibrahim Almaidoor and Ibrahim Abdel-Rahman

This study aims to study electrochemically and by weight-loss experiments the effect of UAE Rhazya Stricta Decne extract on the corrosion…

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Abstract

Purpose

This study aims to study electrochemically and by weight-loss experiments the effect of UAE Rhazya Stricta Decne extract on the corrosion inhibition of mild steel in 1.0 M HCl solution, which will serve researchers in the field of corrosion.

Design/methodology/approach

Weight loss measurements were carried out on mild steel specimens in 1.0 M HCl and in 1.0 M HCl containing various concentrations (ranging from 2.0 to 0.002 g/L.) of the UAE Rhazya Stricta Decne extract at temperatures ranging from 303 to 343 K.

Findings

The aqueous Rhazya Stricta Decne leaves extract was found to be a highly efficient inhibitor for mild steel in 1.0 M HCl solution, reaching about 90 per cent at 2.0 g/L and 303 K, a concentration considered to be very moderate. Even with one-tenth of that concentration, 0.2 g/L, an inhibition of about 82 per cent was obtained at 303 K. The rate of corrosion of the mild steel in 1.0 M HCl is a function of the concentration of the Rhazya Stricta Decne extract. This rate increases as the concentration of the Rhazya Stricta Decne extract is increased. The percentage of inhibition in the presence of this inhibitor was decreased with temperature which indicates that physical adsorption was the predominant inhibition mechanism because the quantity of adsorbed inhibitor decreases with increasing temperature.

Practical implications

This inhibitor could have application in industries, where HCl solutions at elevated temperatures are used to remove scale and salts from steel surfaces, such as acid cleaning of tankage and pipeline, and may render dismantling unnecessary.

Originality/value

This paper is intended to be added to the family of green corrosion inhibitors which are highly efficient and can be used in the area of corrosion prevention and control.

Details

Anti-Corrosion Methods and Materials, vol. 61 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 March 2017

Santiago Flores Merino, Juan José Caprari, Luis Vasquez Torres, Luis Figueroa Ramos and Antonella Hadzich Girola

The purpose of this paper is to study the ability of commercial tara powder to convert rust into iron tannate and evaluate their use as raw material for the formulation of water…

Abstract

Purpose

The purpose of this paper is to study the ability of commercial tara powder to convert rust into iron tannate and evaluate their use as raw material for the formulation of water based rust converter.

Design/methodology/approach

Water-borne acrylic primers were formulated with tara powder and aqueous tara extract and applied on steel rusted by three different methods. The conversion of rusted steel by tara tannins was studied by X-ray diffraction spectroscopy, infrared spectroscopy and scanning electron microscopy. The acrylic primers, containing hydrolysable tannins, were coated with alkyd finish and were evaluated in comparison to commercial systems in accelerated corrosion tests. The corrosion inhibition effects of tara powder on mild steel in 0.1M NaCl were studied by DC electrochemical techniques.

Findings

Tara tannin converts rust to ferric tannate and increases the magnetite content of rusted steel. The water-based acrylic primer formulated with aqueous extract of tara, alkyd-coated finish, showed performance equivalent to pure alkyd system.

Research limitations/implications

The chlorides content in the commercial tara powder can be screened the beneficial effect of hydrolysable tannins to convert rust. Furthermore, the water-based rust converter formulated with acrylic resin may be sensitive to salt contamination of rust.

Originality/value

Hydrolysable tannins from commercial tara powder have not been studied yet in its application to the development of rust converters. A water-based primer formulated with commercial tara powder developed for the effective treatment of rusted surfaces can be of interest as an environmentally friendly to current commercial approaches.

Details

Anti-Corrosion Methods and Materials, vol. 64 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

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