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1 – 10 of 123Amirul Syafiq, Nasrudin Abd. Rahim, Vengadaesvaran Balakrishnan and A.K. Pandey
This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium…
Abstract
Purpose
This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium carbonate (nano-CaCO3) and titanium dioxide (TiO2).
Design/methodology/approach
The synthesis method of PDMS/nano-CaCO3-TiO2 is based on sol-gel process. The crosslinking between PDMS and nanoparticles is driven by the covalent bond at temperature of 50°C. The 3-Aminopropyltriethoxysilane is used as binder for nanoparticles attachment in polymer matrix. Two fabrication methods are used, which are dip- and spray-coating methods.
Findings
The prepared coated glass fulfilled the requirement of standard self-cleaning and fog-resistance performance. For the self-cleaning test BS EN 1096-5:2016, the coated glasses exhibited the dust haze value around 20%–25% at tilt angle of 10°. For the antifog test, the coated glasses showed the fog haze value were below 2% and the gloss value were above 85%. The obtained results completely achieved the standard antifog value ASTM F659-06 protocol.
Research limitations/implications
Findings will provide an infrastructure support for the building glass to enhance building’s energy efficiency, cleaning performance and friendly environment.
Practical implications
This study proposed the simple synthesis method using hydrophobic polymer and nano-CaCO3 and nano-TiO2, which can achieve optimum self-cleaning property at low tilt angle and fog-resistance performance for building glass.
Social implications
The research findings have high potential for building company, cleaning building company and government sector. The proposed project capable to reduces the energy consumption about 20% per annum due to labor cost, time-consuming and safety during manual cleaning.
Originality/value
The novel method to develop self-cleaning coating with fog-resistance using simple synthesis process and fabrication method for building glass application.
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Keywords
A. Syafiq, A.K. Pandey, Vengadaesvaran Balakrishnan and Nasrudin Abd Rahim
The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO2) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass…
Abstract
Purpose
The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO2) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass substrate.
Design/methodology/approach
Two methods have been used to enhance the hydrophobicity on glass substrates, namely, surface modification by using low surface energy isooctyltrimethoxysilane (ITMS) solution and construction of rough surface morphology using Degussa P-25 TiO2 nanoparticles with simple bottom-up approach. The prepared sol was applied onto glass substrate using dip-coating technique and stoved in the vacuum furnace 350°C.
Findings
The ITMS coating with nano TiO2 pigment has modified the glass substrate surface by achieving the water contact angle as high as 169° ± 2° and low sliding angle of 0° with simple and low-cost operation. The solid and air phase interface has created excellent anti-dirt and self-cleaning properties against dilute ketchup solution, mud and silicon powder.
Research limitations/implications
Findings will be useful in the development of self-cleaning and anti-dirt coating for photovoltaic panels.
Practical implications
Sol method provides the suitable medium for the combination of organic–inorganic network to achieve high superhydrophobicity and optimum self-cleaning ability.
Originality/value
Application of blended organic–inorganic sol as self-cleaning and anti-dirt coating film.
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Bassem Assfour, Bassam Abdallah, Hour Krajian, Mahmoud Kakhia, Karam Masloub and Walaa Zetoune
The purpose of this study is to investigate the structural, surface roughness and corrosion properties of the zirconium oxide thin films deposited onto SS304 substrates using the…
Abstract
Purpose
The purpose of this study is to investigate the structural, surface roughness and corrosion properties of the zirconium oxide thin films deposited onto SS304 substrates using the direct current (DC) magnetron sputtering technique.
Design/methodology/approach
DC sputtering at different powers – 80, 100 and 120 W – was used to deposit ZrO2 thin films onto different substrates (Si/SS304) without annealing of the substrate. Atomic force microscope (AFM), energy-dispersive X-ray spectroscopy (EDS), Tafel extrapolation and contact angle techniques were applied to investigate the surface roughness, chemical compositions, corrosion behavior and hydrophobicity of these films.
Findings
Results showed that the thickness of the deposited film increased with power increase, while the corrosion current decreased with power increase. AFM images indicated that the surface roughness decreased with an increase in DC power. EDS analysis showed that the thin film has a stoichiometric ZrO2 (Zr:O 1:2) composition with basic uniformity. Water contact angle measurements indicated that the hydrophobicity of the synthesized films decreased with an increase in surface roughness.
Originality/value
DC magnetron sputtering technique is infrequently used to deposition thin films. The obtained thin films showed good hydrophobic and anticorrosion properties. Finally, results are compared with other deposition techniques.
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Dexin Chen, Hongyuan He, Zhixin Kang and Wei Li
This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.
Abstract
Purpose
This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.
Design/methodology/approach
One-step electrodeposition is a versatile and simple technology to prepare superhydrophobic coatings on metal surfaces.
Findings
Preparing superhydrophobic coatings by one-step electrodeposition is an efficient method to protect metal surfaces.
Originality/value
Even though there are several technologies, one-step electrodeposition still plays a significant role in producing superhydrophobic coatings.
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Abhishek Kumar and Manpreet Manshahia
The aim of this study is to present an overview of sustainable practices in the development of waterproof breathable fabrics for garments. It aims to provide insights into the…
Abstract
Purpose
The aim of this study is to present an overview of sustainable practices in the development of waterproof breathable fabrics for garments. It aims to provide insights into the current state of academic research in this domain and identify and analyze major sustainable trends in the field.
Design/methodology/approach
This study conducts a thorough examination of research publications sourced from the Scopus database spanning the years 2013–2023 by employing a systematic approach. The research utilizes both descriptive analysis and content analysis to identify trends, notable journals and leading countries in sustainable waterproof breathable fabric development.
Findings
The study reveals a notable increase in studies focusing on sustainable approaches in the development of waterproof breathable fabrics for garments. Descriptive analysis highlights the most prominent journal and leading country in terms of research volume. Content analysis identifies four key trends: minimizing chemical usage, developing easily degradable materials, creating fabrics promoting health and well-being and initiatives to reduce energy consumption.
Research limitations/implications
The main limitation of this research lies in its exclusive reliance on the Scopus database.
Practical implications
The insights derived from this study offer practical guidance for prospective researchers interested in investigating sustainable approaches to developing waterproof breathable fabric for garments. The identified trends provide a foundation for aligning research endeavors with contemporary global perspectives, facilitating the integration of sustainable methodologies into the garment industry.
Originality/value
This systematic literature review contributes original insights by synthesizing current research trends and outlining evolving sustainable practices in the development of waterproof breathable fabrics. The identification of key focus areas adds a novel perspective to existing knowledge.
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Chongjun Wu, Yutian Chen, Xinyi Wei, Junhao Xu and Dongliu Li
This paper is devoted to prepare micro-cone structure with variable cross-section size by Stereo Lithography Appearance (SLA)-based 3D additive manufacturing technology. It is…
Abstract
Purpose
This paper is devoted to prepare micro-cone structure with variable cross-section size by Stereo Lithography Appearance (SLA)-based 3D additive manufacturing technology. It is mainly focused on analyzing the forming mechanism of equipment and factors affecting the forming quality and accuracy, investigating the influence of forming process parameters on the printing quality and optimization of the printing quality. This study is expected to provide a µ-SLA surface preparation technology and process parameters selection with low cost, high precision and short preparation period for microstructure forming.
Design/methodology/approach
The µ-SLA process is optimized based on the variable cross-section micro-cone structure printing. Multi-index analysis method was used to analyze the influence of process parameters. The process parameter influencing order is determined and validated with flawless micro array structure.
Findings
After the optimization analysis of the top diameter size, the bottom diameter size and the overall height, the influence order of the printing process parameters on the quality of the micro-cone forming is: exposure time (B), print layer thickness (A) and number of vibrations (C). The optimal scheme is A1B3C1, that is, the layer thickness of 5 µm, the exposure time of 3000 ms and the vibration of 64x. At this time, the cone structure with the bottom diameter of 50 µm and the cone angle of 5° could obtain a better surface structure.
Originality/value
This study is expected to provide a µ-SLA surface preparation technology and process parameters selection with low cost, high precision and short preparation period for microstructure forming.
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A. Syafiq, A.K. Pandey, Vengadaesvaran Balakrishnan, Syed Shahabuddin and Nasrudin Abd Rahim
This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.
Abstract
Purpose
This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.
Design/methodology/approach
Sol-gel methods have been used to design superhydrophobic glass substrates through surface modification by using low-surface-energy Isooctyl trimethoxysilane (ITMS) and Ethyl trimethoxysilane (ETMS) solution. Hierarchical double-rough scale solid surface was built by Si micro- and nanoparticles to enhance the surface roughness. The prepared sol was applied onto glass substrate using dip-coating method and was dried at control temperature of 400°C inside the tube furnace.
Findings
The glass substrate achieved the water contact angle as high as 154 ± 2° and 150.4 ± 2° for Si/ITMS and Si/ETMS films, respectively. The Si/ITMS and Si/ETMS also were equipped with low sliding angle as low as 3° and 5°, respectively. The Si micro- and nanoparticles in the coating system have created nanopillars between them, which will suspend the water droplets. Both superhydrophobic coatings have showed good stability against high temperature up to 200°C as there are no changes in WCA shown by both coatings. Si/ITMS film sustains its superhydrophobicity after impacting with further temperature up to 400°C and turns hydrophobic state at 450°C.
Research limitations/implications
Findings will be useful to develop superhydrophobic coatings with high thermal stability.
Practical implications
Sol method provides a suitable medium for the combination of organic-inorganic network to achieve high hydrophobicity with optimum surface roughness.
Originality/value
Application of different alkyl chain groups of silane resin blending with micro- and nanoparticles of Si pigments develops superhydrophobic coatings with high thermal stability.
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Dalei Zhang, Xinwei Zhang, Enze Wei, Xiaohui Dou and Zonghao He
This study aims to improve the corrosion resistance of TA2-welded joints by superhydrophobic surface modification using micro-arc oxidation technology and low surface energy…
Abstract
Purpose
This study aims to improve the corrosion resistance of TA2-welded joints by superhydrophobic surface modification using micro-arc oxidation technology and low surface energy substance modification.
Design/methodology/approach
The microstructure and chemical state of the superhydrophobic film layer were analyzed using scanning electron microscopy, energy dispersive X-ray spectroscopy, three-dimensional morphology, X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transform infrared absorption spectroscopy. The influence of the superhydrophobic film layer on the corrosion resistance of TA2-welded joints was investigated using classical electrochemical testing methods.
Findings
The characterization results showed that the super hydrophobic TiO2 ceramic membrane was successfully constructed on the surface of the TA2-welded joint, and the construction of the super hydrophobic film greatly improved the corrosion resistance of the TA2-welded joint.
Originality/value
The superhydrophobic TiO2 ceramic membrane has excellent corrosion resistance. The micro nanostructure in the superhydrophobic film can intercept air to form an air layer to prevent the corrosion medium from contacting the surface, thus, improving the corrosion resistance of the sample.
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The textile sector is moving towards new technologies, where the application of nanotechnology is offering fabrics with multifunctional properties making fabric odourless…
Abstract
Purpose
The textile sector is moving towards new technologies, where the application of nanotechnology is offering fabrics with multifunctional properties making fabric odourless, hydrophobic, durable and self-cleaning. This aim of this research is to investigate self-cleaning ability of denim fabric with the application of zinc oxide nanoparticles (ZnO NPs) synthesized naturally. The primary focus of this investigation is achieving sustainability mark through green synthesis of ZnO NPs.
Design/methodology/approach
In this analysis, ZnO NPs being one of the metal oxides exhibiting self-cleaning, UV-protective and anti-microbial properties were synthesized naturally using Azadirachta Indica leaves. The prepared NPs were characterized by using X-ray diffraction and scanning electron microscopy analyses confirming their size and crystalline structure. Different formulations were investigated with varying concentration of zinc oxide and auxiliaries onto the denim fabric using pad-dry-cure application technique.
Findings
XRD analysis confirmed the successful green synthesis of ZnO NPs. SEM analysis revealed the homogeneous and hexagonal wurtzite NPs deposition on the denim fabric. It was ascertained that with 5% ZnO NPs and 7% Binder concentrations, the formulation resulted in a smooth and even layer on the denim fabric maintaining the appearance and feel at the same time offers appreciable grading (Grade 4) against the stringent stains of Ketchup, Coffee, Grape and Orange Juice with insignificant change in tensile strength.
Originality/value
In this study, self-cleaning attributes of denim fabric with zinc oxide nano formulations of different composition was studied to achieve promising functional properties in a single step not studied earlier.
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Ernest Mbamalu Ezeh, Ezeamaku U Luvia and Onukwuli O D
Gourd fibres (GF) are a natural biodegradable fibre material with excellent mechanical properties and high tensile strength. The use of natural fibres in composite materials has…
Abstract
Purpose
Gourd fibres (GF) are a natural biodegradable fibre material with excellent mechanical properties and high tensile strength. The use of natural fibres in composite materials has gained popularity in recent years due to their various advantages, including renewability, low cost, low density and biodegradability. Gourd fibre is one such natural fibre that has been identified as a potential reinforcement material for composites. However, it has low surface energy and hydrophobic nature, which makes it difficult to bond with matrix materials such as polyester. To overcome this problem, chemically adapted gourd fibre has been proposed as a solution. Chemical treatment is one of the most widely used methods to improve the properties of natural fibres. This research evaluates the feasibility and effectiveness of incorporating chemically adapted gourd fibre into polyester composites for industrial fabrication. The purpose of this study is to examine the application of chemically modified GF in the production of polyester composite engineering materials.
Design/methodology/approach
This work aims to evaluate the effectiveness of chemically adapted gourd fibre in improving the adhesion of gourd fibre with polyester resin in composite fabrication by varying the GF from 5 to 20 wt.%. The study involves the preparation of chemically treated gourd fibre through surface modification using sodium hydroxide (NaOH), permanganate (KMnO4) and acetic acid (CH3COOH) coupling agents. The mechanical properties of the modified fibre and composites were investigated. It was then characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) to determine the changes in surface morphology and functional groups.
Findings
FTIR characterization showed that NaOH treatment caused cellulose depolymerization and caused a significant increase in the hydroxyl and carboxyl groups, showing improved surface functional groups; KMnO4 treatment oxidized the fibre surface and caused the formation of surface oxide groups; and acetic acid treatment induced changes that primarily affected the ester and hydroxyl groups. SEM study showed that NaOH treatment changed the surface morphology of the gourd fibre, introduced voids and reduced hydrophilic tendencies. The tensile strength of the modified gourd fibres increased progressively as the concentration of the modification chemicals increased compared to the untreated fibres.
Originality/value
This work presents the designed composite with density, mechanical properties and microstructure, showing remarkable improvements in the engineering properties. An 181.5% improvement in tensile strength and a 56.63% increase in flexural strength were got over that of the unreinforced polyester. The findings from this work will contribute to the understanding of the potential of chemically adapted gourd fibre as a reinforcement material for composites and provide insights into the development of sustainable composite materials.
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