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1 – 10 of over 6000Keiji Houjou, Kotoji Ando and Koji Takahashi
Zirconia ceramics exhibit high strength and fracture toughness. The purpose of this paper is to research a possibility of crack healing in zirconia ceramics.
Abstract
Purpose
Zirconia ceramics exhibit high strength and fracture toughness. The purpose of this paper is to research a possibility of crack healing in zirconia ceramics.
Design/methodology/approach
ZrO2/SiC composite ceramics are sintered and subjected to three‐point bending. A surface crack of 100 μm in diameter is formed on each specimen. The cracks are healed and the specimens are tested under bending.
Findings
The paper finds that ZrO2/SiC composite ceramic material had a high crack‐healing ability at a considerably low temperature. For example, a crack of 100 μm in diameter is healed even at 600°C.
Research limitations/implications
The paper provides a low temperature healing and a new mechanism of crack healing.
Originality/value
The paper shows the healing temperature and the minimum time required to heal showed a good proportional relation on the Arrhenius plot at temperatures of 600‐800°C. Moreover, the crack healing is caused by SiO2 cristobalite produced during the healing.
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Keiji Houjou and Koji Takahashi
The purpose of this paper is to study the crack‐healing mechanism of ZrO2/SiC composite ceramics which have a high crack‐healing ability at low temperature.
Abstract
Purpose
The purpose of this paper is to study the crack‐healing mechanism of ZrO2/SiC composite ceramics which have a high crack‐healing ability at low temperature.
Design/methodology/approach
The effects of dispersed SiC and the environment on crack‐healing behaviour were investigated. The fatigue strength of crack‐healed specimens was also investigated.
Findings
The main conclusions are that for crack‐healing of ZrO2 ceramics, it is necessary to have both a SiC composite and an oxidative environment; and when ZrO2/SiC composite ceramics are heat‐treated in air, a phase transformation attributable to the SiC composite results in crack‐healing and improvement of fracture toughness and bending strength.
Originality/value
An appropriate heat treatment for ZrO2/SiC composite caused not only crack‐healing but also the improvement of fracture toughness, and created a multiplier effect on crack‐healing, bending strength and fracture toughness.
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Sociologists have tended to construct theories of identity based on unitary notions of social location which avoid conceptualizing disjunction and contradiction and which…
Abstract
Sociologists have tended to construct theories of identity based on unitary notions of social location which avoid conceptualizing disjunction and contradiction and which therefore fail to capture certain characteristics of the postcolonial condition. This paper engages in a postcolonial re-reading of sociological theories of practice (in particular, Pierre Bourdieu's notion of habitus). It does so through an analysis of the historical development of the field of health and healing in South Africa. From the beginning of the colonial enterprise, biomedicine resisted amalgamation with other forms of healing and insisted on a monotherapeutic ideology and practice whereas indigenous healing accommodated not only biomedicine, but invited pluralism within and across cultural and ethnic differences. As such, a bifurcated and parallel system of healing emerged, whereby Black South Africans practiced pluralism and white South Africans utilized biomedicine in isolation. This disjuncture became acrimonious in the post-apartheid era as the state attempted to forge a united health system and battle the AIDS epidemic. Despite the historical and contemporary bifurcations within the field of health and healing, people living with AIDS continue to subscribe to a hybrid health ideology. There is, therefore, a structural disjuncture between the realities of consumption within the field of health and healing and the logic of the field as it is articulated in the symbolic struggle raging in the field of power. The field of health and healing is characterized, therefore, by a simultaneous bifurcation and hybridity – which is reflected in HIV-infected South Africans’ beliefs and practices. In order to make sense of this puzzling disjuncture and its impact on subjects’ trajectories of action, this paper draws insight from Pierre Bourdieu's theory of habitus and Homi Bhabha's conceptualization of hybridity – transforming each of them through their synthesis and application to the postcolonial context.
Hongsheng Luo, Xingdong Zhou, Yuncheng Xu, Huaquan Wang, Yongtao Yao, Guobin Yi and Zhifeng Hao
This paper aims to exploit shape-memory polymers as self-healable materials. The underlying mechanism involved the thermal transitions as well as the enrichment of the…
Abstract
Purpose
This paper aims to exploit shape-memory polymers as self-healable materials. The underlying mechanism involved the thermal transitions as well as the enrichment of the healing reagents and the closure of the crack surfaces due to shape recovery. The multi-stimuli-triggered shape memory composite was capable of self-healing under not only direct thermal but also electrical stimulations.
Design/methodology/approach
The shape memory epoxy polymer composites comprising the AgNWs and poly (ε-caprolactone) were fabricated by dry transfer process. The morphologies of the composites were investigated by the optical microscope and scanning electron microscopy (SEM). The electrical conduction and the Joule heating effect were measured. Furthermore, the healing efficiency under the different stimuli was calculated, whose dependence on the compositions was also discussed.
Findings
The AgNWs network maintained most of the pathways for the electrons transportation after the dry transfer process, leading to a superior conduction and flexibility. Consequently, the composites could trigger the healing within several minutes, as applied with relatively low voltages. It was found that the composites having more the AgNWs content had better electrically triggered performance, while 50 per cent poly (ε-caprolactone) content endowed the materials with max healing efficiency under thermal or electrical stimuli.
Research limitations/implications
The findings may greatly benefit the application of the intelligent polymers in the fields of the multifunctional flexible electronics.
Originality/value
Most studies have by far emphasized on the direct thermal triggered cases. Herein, a novel, flexible and conductive shape memory-based composite, which was capable of self-healing under the thermal or electrical stimulations, has been proposed.
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Panagiota Polydoropoulou, Christos Vasilios Katsiropoulos, Andreas Loukopoulos and Spiros Pantelakis
Over the last decades, self-healing materials based on polymers are attracting increasing interest due to their potential for detecting and “autonomically” healing damage…
Abstract
Purpose
Over the last decades, self-healing materials based on polymers are attracting increasing interest due to their potential for detecting and “autonomically” healing damage. The use of embedded self-healing microcapsules represents one of the most popular self-healing concepts. Yet, extensive investigations are still needed to convince on the efficiency of the above concept. The paper aims to discuss these issues.
Design/methodology/approach
In the present work, the effect of embedded self-healing microcapsules on the ILSS behavior of carbon fiber reinforced composite materials has been studied. Moreover, the self-healing efficiency has been assessed. The results of the mechanical tests were discussed supported by scanning electron microscope (SEM) as well as by Attenuated Total Reflection–Fourier-transform infrared spectroscopy (ATR–FTIR) analyses.
Findings
The results indicate a general trend of a degraded mechanical behavior of the enhanced materials, as the microcapsules exhibit a non-uniform dispersion and form agglomerations which act as internal defects. A remarkable value of the self-healing efficiency has been found for materials with limited damage, e.g. matrix micro-cracks. However, for significant damage, in terms of large matrix cracks and delaminations as well as fiber breakages, the self-healing efficiency is limited.
Originality/value
The results obtained by SEM analysis as well as by ATR–FTIR spectroscopy constitute a strong indication that the self-healing mechanism has been activated. However, further investigation should be conducted in order to provide definite evidence.
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Mehdi Shahidi Zandi and Majdeh Hasanzadeh
The aim of this work is to investigate the self-healing performance of epoxy coatings containing microcapsules. The microcapsule-based coatings were applied on AA6061 Al…
Abstract
Purpose
The aim of this work is to investigate the self-healing performance of epoxy coatings containing microcapsules. The microcapsule-based coatings were applied on AA6061 Al alloy and immersed in 3.5 per cent NaCl solution.
Design/methodology/approach
Microcapsules with urea–formaldehyde as the shell and linseed oil as the healing agent were prepared by in situ polymerization in an oil-in-water emulsion. For the sake of an optimum self-healing system, some coating samples were prepared by using different microcapsule concentrations: 0, 5, 10 and 20 Wt.%. The scratch-filling efficiency as the theoretical estimate of the self-healing performance was calculated for the coating samples with different microcapsule concentrations. The scratch-sealing efficiency (SSE) as a particularly crucial parameter in the self-healing evaluation of coatings was measured by both electrochemical impedance spectroscopy (EIS) and electrochemical noise (EN) techniques.
Findings
According to EIS and EN results, the coating samples containing 5 and 10 per cent microcapsules provided the insignificant self-healing performance, while the coating sample containing 20 per cent microcapsules exhibited the acceptable self-healing performance to AA6061 alloy in the NaCl solution. The measured SSE values confirmed the good agreement of EN data with electrochemical parameters obtained from the EIS technique.
Originality/value
This work is an attempt to evaluate the self-healing performance of microcapsule-based epoxy coatings applied on AA6061 Al alloy in sea water.
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Jae Yeon Yang, Soyon Paek, Taegoo (Terry) Kim and Tae Hee Lee
The purpose of this study is to explore the effect of tourists’ needs for healing experience (NHE) on behavioral intentions for transformation (BIT) with healing…
Abstract
Purpose
The purpose of this study is to explore the effect of tourists’ needs for healing experience (NHE) on behavioral intentions for transformation (BIT) with healing involvement (HI) as a mediator. Using the two sub-constructs of BIT in the tourism industry (i.e. selection of healing tour products and transformational intention of healing tour behavior), this study evaluates BIT.
Design/methodology/approach
The survey was administered to visitors in healing resorts/centers in Korea; 383 completed surveys were used to investigate the hypothesized relationships of this study using regression analysis.
Findings
The study results confirmed the hypothesized relationships: the positive effects of NHE on BIT and the significant mediating role of HI in the relationships between NHE and BIT.
Practical implications
The relationships among NHE, HI and BIT can improve the understanding and practices of healing experience and the development of healing products in the tourism industry. This study offers a meaningful and extended perspective on customers’ experience and product development by interpreting customers’ desires and needs.
Originality/value
This study explores the under-researched subject of NHE and HI from a transformative economic perspective. The study is among the first to examine the structural relationships among NHE, HI and BIT. The uniqueness of the study is highlighted by the use of two sub-dimensions of the BIT industry (i.e. selection of healing tour products and transformational intention of healing tour behavior) in a tourism context.
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Marialuigia Raimondo, Felice De Nicola, Ruggero Volponi, Wolfgang Binder, Philipp Michael, Salvatore Russo and Liberata Guadagno
The purpose of this paper is to describe the first experiments to manufacture self-healing carbon fiber reinforced panels (CFRPs) for the realization of structural…
Abstract
Purpose
The purpose of this paper is to describe the first experiments to manufacture self-healing carbon fiber reinforced panels (CFRPs) for the realization of structural aeronautic components in order to address their vulnerability to impact damage in the real service conditions.
Design/methodology/approach
The developed self-healing system is based on ring-opening metathesis polymerizations reaction of microencapsulated 5-ethylidene-2-norbornene/dicyclopentadiene cyclic olefins using Hoveyda-Grubbs’ first generation catalyst as initiator. In this work, the self-healing resin is infused into a carbon fiber dry preform using an unconventional bulk film infusion technique that has allowed to minimize the filtration effects via a better compaction and reduced resin flow paths. Infrared spectroscopy provides a useful way to identify metathesis products and therefore catalyst activity in the self-healing panel after damage. The damage resistance of the manufactured CFRPs is evaluated through hail and drop tests.
Findings
The self-healing manufactured panels show, after damage, catalyst activity with metathesis product formation, as evidenced by an infrared peak at 966 cm−1. The damage response of CFRPs, detected in accord to the requirements of hail impact for the design of a fuselage in composite material, is very good. The results are very encouraging and can constitute a solid basis for bringing this new technology to the self-healable fiber reinforced resins for aerospace applications.
Originality/value
In this paper, autonomically healing CFRPs with damage resistance and self-healing function are proposed. In the development of self-healing aeronautic materials it is critical that self-healing activity functions in adverse weather conditions and at low working temperatures which can reach values as low as −50°C.
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Nitin Kumar Gupta, Gananath Doulat Thakre and Manoj Kumar
The purpose of this study is to investigate the tribological performance of the developed self-healing Al6061 composite and to optimize the operating conditions for…
Abstract
Purpose
The purpose of this study is to investigate the tribological performance of the developed self-healing Al6061 composite and to optimize the operating conditions for enhanced tribo-performance of the developed material.
Design/methodology/approach
A unique procedure has been adopted to convert the sand casted Al6061 into self-healing material by piercing a low melting point solder material with and without MoS2. Taguchi-based L9 orthogonal array has been used to optimize the number of experiments and analyze the influence of operating parameters such as speed, sliding distance and load on material wear.
Findings
The results reveal that the paper shows the self-healing and self-repair is possible in metal through piercing low melting point alloy. Then, the load has a significant influence over other input parameters in predicting the wear behavior of developed material. Moreover, addition of MoS2 does not affect the tribo-performance of the developed material. The study concludes that the developed self-healing Al6061 has huge potential to be used in mechanical industry.
Research limitations/implications
The concept of self-healing in metals are very challenging task due to very slow diffusion rate of atoms at room temperature. Therefore, researchers are encouraged to explore the other new techniques to create self-healing in metals.
Practical implications
The self-healing materials had shown huge potential to be used in mechanical industry. The current investigation established a structural fabrication and testing procedure to understand the effects of various parameters on wear. The conclusion from the experimentation and optimization helps researchers to developed and create self-healing in metals.
Originality/value
The previous research works were not focused on the study of tribological property of self-healing metal composite. With the best of author’s knowledge, no one has reported tribological study, as well as optimization of parameters such as speed, load and sliding distance on wear in self-healing metals composite.
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– The purpose of this work was to prepare a catalyst-free microcapsules as self-healing agent in an automotive clearcoat to improve the scratch resistance of coatings.
Abstract
Purpose
The purpose of this work was to prepare a catalyst-free microcapsules as self-healing agent in an automotive clearcoat to improve the scratch resistance of coatings.
Design/methodology/approach
In this research, microcapsule with isophorone diisocyanate (IDPI) core and polyurethane shell were prepared and used in self-healing coatings. Microcapsules synthesised were characterised by thermal gravimeter and infrared spectra. The microcapsules were dispersed in an acrylic-melamine clearcoat, and the scratch resistance was evaluated.
Findings
The triplex product and the formed polyurethane bonds were confirmed by thermal gravimeter and infrared spectra. In addition, smooth spherical particles with a diameter of 1.5 to 1.7 micronmeters were observed by a scanning electron microscope. The microcapsules dispersed in an acrylic-melamine clearcoat increased the scratch resistance of coatings. Also, the self-healing feature of those coatings was proved.
Research limitations/implications
The size of microcapsules can affect its dispersion in the clearcoat and consequently affect the properties of the cured films.
Practical implications
The self-healing coatings are interested for many industries such as building and automotive industries. The reported data can be used by the formulators working in the R & D departments.
Social implications
Self-healing systems are considered as one of the smart coatings. Therefore, the developing of its knowledge can help to extend its usage to different applications.
Originality/value
The application of microcapsules in the coating as healing agents is a great challenge, which has been hardly investigated so far. In the current research, the effect of polyurethane-IDPI microcapsules in an automotive clearcoat as a self-healing coating was investigated.
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