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The purpose of the study is regarding the development of eco-oriented technologies for obtaining the building gypsum materials with the involvement of industrial by-products or waste.

The scanning electron microscopy, X-ray microanalysis and IR spectral analysis were used to study the structure of gypsum matrix. The method of comparison of modified and unmodified gypsum matrix was used. Physical modeling of gypsum matrix crystallization is used to study changes in the morphology of hydration products.

The experimental results show that the addition of technical soot into a gypsum binder leads to a change in the morphology of crystalline hydrates of calcium sulfate dihydrate. Results of the scanning electron microscopy, X-ray microanalysis and IR spectral analysis confirm the change of physical and mechanical characteristics of the gypsum binder due to the structural modification of the gypsum matrix with ultrafine carbon soot. The achieved degree of the structural modification of the gypsum matrix is compatible with the results obtained when the gypsum binder was modified with dispersions of carbon nanotubes.

The morphology of the crystalline hydrates of the gypsum matrix with the addition of 0.04%, 0.06% and 1% of the carbon soot is characterized by the transition of the classical needle-like structure of gypsum dihydrate to the lamellar structure of increased density. One can observe the formation of intergrowths around ultrafine carbon soot particles. The studied carbon additive can improve strength characteristics of the gypsum matrix.

The purpose of this study is to utilize two types of gypsum mold wastes from two different factories as novel and economical reinforcing fillers for composites that may be useful for building materials and floors. Two types of gypsum mold wastes from two different factories as raw materials were incorporated into linear low density polyethylene (LLDPE) aiming to get rid of that waste in one hand and obtaining useful economical composites suitable for building materials and floors.

Composites were prepared from two types of gypsum mold wastes substituted with different ratios from raw gypsum and LLDPE throughout the melt blending technique. The physico-mechanical and electrical investigations in addition to the morphology of the composites were included.

The mechanical results illustrate that substituting commercial gypsum with gypsum mold waste positively affects tensile strength, flexural strength and hardness shore D for the LLDPE composites. The tensile strength increased from 5 MPa for LLDPE filled with commercial gypsum as blank samples to 11.2 and 13.2 MPa for LLDPE filled with D and S waste. Also, electrical properties which include both permittivity ɛ′ and dielectric loss ɛ″ increased with increasing the waste content in the LLDPE matrix. In addition to the electrical conductivity values, σ lies in the order of insulation materials. Consequently, it is possible to produce materials with a gypsum matrix by adding industrial waste, improving the behavior of the traditional gypsum and enabling those composites to be applied in various construction applications as eco-friendly tiles.

This study aims to prepare eco-friendly composites based on LLDPE and waste gypsum mold to preserve resources for the coming generations, other than lowering the environmental footprint and saving the costs of getting rid of it.

Animal liquid manure contains large amounts of phosphorus (P), which is susceptible to runoff losses when manure is surface-applied on farms as a soil amendment. Even very small quantities of P can have a large impact on waterways and lead to eutrophication. Previous studies have shown that flue gas desulfurization (FGD) gypsum, a coal combustion by-product, can reduce P losses from runoff in soils. Therefore, the authors hypothesize that FGD gypsum could reduce nutrients in liquid manure prior to field applications. The purpose of this paper is to evaluate the effect of FGD gypsum to reduce P and suspended solids (SS) concentrations in liquid manure, also determining its proper rate(s) and minimum time of reaction.

The experimental design was completely randomized with three replicates. Each plot was constituted by a polyvinyl chloride (PVC) column (1 m height and 0.15 m diameter). Dairy liquid manure and FGD gypsum rates (0, 0.62, 1.25 and 2.5 mgl⁻¹) were added to the PVC columns and manually shaken for two minutes. Sampling was performed at 0.35, 0.65 and 0.95 m depths after 0 (immediately after shaking), 4, 8, 16 and 24 hours. Amount of phosphorus was determined by a colorimetric method and solids concentration by mass difference.

FGD gypsum reduced P concentrations in the liquid manure after four hours of reaction. The most effective rate was 0.62 mgl⁻¹at a 0.35 m depth. FGD gypsum increased SS concentrations in depth in all treatments.

There are growing concerns regarding the fate of nutrients, especially phosphorus, from land application of animal waste. The results indicated that treating liquid manure in the settling tanks with FGD gypsum before field application can be particularly useful on farms where surface-manure is applied, reducing potential losses of P following manure applications, and consequently the eutrophication risk to waterways.

Describes the novel utilization of waste newsprint paper as inexpensive agro‐fibers for production of lightweight building panels. Thermal gravimetric analysis of treated news paper fibers was studied as a method for testing fire retardancy of agro‐fibers in light building panels. The activation energy of degradation stages was evaluated by applying the Coats and Redfern method of analysis. Results showed that the treatment of newsprint waste with 6 per cent sodium silicate also improved fire retardancy in addition to improving the compressive strength of the produced panels, with the reduction in the bulk density to ∼28.6 per cent compared with gypsum panel. Such treatment gives the produced panels a relatively low water absorption property compared with those produced by other treatments.

The purpose of this study is to investigate the performance of fire protective materials in protecting steel section. A new indexing system is introduced, named as fire endurance index (FEI), which can be used to evaluate the performance of fire protective materials.

In this study, experiments were carried out using W4 × 13 steel section. Eight samples were prepared; one was a bare steel section without any coating material, and seven were prepared using four types of materials such as vermiculite-gypsum plaster, gypsum plaster, concrete cover and glass wool-concrete cover for fireproofing of the sections. An enclosed electric coiled furnace was used for heating the samples for a certain period. The duration of protection was determined, and the FEI of the materials was calculated. The higher the index value is, the better the performance.

The results demonstrate that the glass-wool-concrete cover offered the best performance at high temperature among the four types of materials. In the experiment with glass-wool-concrete cover, the furnace temperature reached 750°C, whereas the steel temperature reached only 100°C. The FEI of the coatings were calculated. Among the eight samples, glass wool-concrete cover also achieved the highest index value.

The experimental work was performed using a limited number of specimens. Furthermore, the robustness of the indexing system needs to be evaluated with other materials and a wide range of heating rate and temperature. This study sets the foundation for future work.

The findings of this research may contribute to a better understanding of the performance of the materials used as fire protective coatings. This might be helpful for the researchers and practitioners in their design and implementation of legislation of fire safety codes.

Understanding the performance of the fire protective coatings will help in evaluating the fire resistance capabilities of the materials to use for the structural steel members, which may protect collapses and disasters of buildings.

This paper deals with the performance of four types of materials, that can be used as fire protective coatings for structural steel members. Furthermore, the FEI explicitly indicated their performance with numerical values. In this study, the heating of the specimens was performed using a non-standard fire curve based on the concept that naturally occurring incidents of fire do not follow the standard fire curves.

The purpose of this study is to quantify the vertical shrinkage rates and the mechanical strength of three-dimensional (3D) printed parts for a variety of wood-based materials for liquid deposition modeling.

The overall hypothesis was that a well-chosen combination of binders, fibers and fillers could reduce shrinkage in the Z dimension and increase compressive and flexural strength (DIN 52185, 52186). To test this assumption, eight sub-hypotheses were formulated. Mixtures of the ingredients were chosen in different ratios to measure the performance of prints. For time efficiency, an iterative heuristic approach was used – not testing all variations of all variables in even increments, but cutting off lines of testing when mixtures were clearly performing poorly.

The results showed that some mixtures had high dimensional accuracy and strength, while others had neither, and others had one but not the other. Shrinkage of 3D printed objects was mainly caused by water release during drying. An increase of the wood as well as the cement, sand, salt and gypsum content led to reduced vertical shrinkage, which varied between 0 and 23%. Compressive and flexural strength showed mixed trends. An increase in wood and salt content worsened both strength properties. The addition of fibers improved flexural, and the addition of cement improved compression strength. The highest strength values of 14 MPa for compressive and 8 MPa for flexural strength were obtained in the test series with gypsum.

This paper is an important milestone in the development of environmentally friendly materials for additive manufacturing. The potential of many ingredients to improve physical properties could be demonstrated.

Evaluating mechanical properties of simply made samples by 3D printing technology at nanoscale provides a clear path to better understand larger-scale responses of complex natural rocks. Therefore, to realize the similarity between synthetically manufactured materials and natural geomaterials, this study focused on nanoscale mechanical characterization of a 3D printed object with only two constituent components (gypsum powder and infiltrant).

The study method includes nanoindentation technique combined with numerical simulation via discrete element method (DEM).

Four typical load-displacement curves were identified from nanoindentation of total test points indicating a typical elastic-plastic behavior of the 3D printed gypsum rock sample. Mechanical parameters such as Young’s modulus and hardness were calculated by energy-based methods and a positive correlation was observed. The infiltrant was found to considerably be responsible for the majority of the sample nano-mechanical behavior rather than the gypsum particles, thus expected to control macroscale properties. This was decided from deconvolution and clustering of elastic modulus data. Particle flow modeling in DEM was used to simulate the nanoindentation process in a porous media yielding rock-alike mechanical behavior.

The results show a matching load-displacement response between experimental and simulation results, which verified the credibility of simulation modeling for mechanical behavior of 3D printed gypsum rock at nanoscale. Finally, differential effective medium theory was used to upscale the nanoindentation results to the macroscale mechanical properties, which provided an insight into the geomechanical modeling at multiscale.

This study aims to investigate the effect of high temperature (600°C) on the compressive strength of concrete covered with a mixture of polypropylene fiber and gypsum plaster (PFGP).

To study the compressive strength of concrete specimens exposed to temperature, 16 cubic specimens (size: 150 mm × 150 mm × 150 mm) were made. After 28 days of processing and gaining the required strength of specimens, first, polypropylene fiber was mixed with gypsum plaster (CaSO4.2H2O) and then the concrete specimens were covered with this mixture. To cover the concrete specimens with the PFGP, the used PFGP thickness was 15 mm or 25 mm. The polypropylene rates mixed with the gypsum plaster were 1, 3 and 5 per cent. A total of 14 specimens, 12 of which were covered with PFGP, were exposed to high temperature in two target times of 90 and 180 min.

The results show that the PFGP as covering materials can improve the compressive strength lost because of the heating of the concrete specimens. The results also show that the presence of polypropylene fiber in gypsum plaster has the effect on the compressive strength lost because of the heating of the PFGP-covered concrete. The cover of PFGP having 3 per cent polypropylene fiber had the best effect on remained strength of the specimens.

The cover of PFGP having 3 per cent polypropylene fiber has the best effect on remained strength of the PFGP covered specimens exposed to temperature.

This research was aimed at investigating the fire performance of LSF wall systems by using 3-D heat transfer FE models of existing LSF wall system configurations.

This research was focused on investigating the fire performance of LSF wall systems by using 3-D heat transfer finite element models of existing LSF wall system configurations. The analysis results were validated by using the available fire test results of five different LSF wall configurations.

The validated finite element models were used to conduct a parametric study on a range of non-load bearing and load bearing LSF wall configurations to predict their fire resistance levels (FRLs) for varying load ratios.

Fire performance of LSF wall systems with different configurations can be understood by performing full-scale fire tests. However, these full-scale fire tests are time consuming, labour intensive and expensive. On the other hand, finite element analysis (FEA) provides a simple method of investigating the fire performance of LSF wall systems to understand their thermal-mechanical behaviour. Recent numerical research studies have focused on investigating the fire performances of LSF wall systems by using finite element (FE) models. Most of these FE models were developed based on 2-D FE platform capable of performing either heat transfer or structural analysis separately. Therefore, this paper presents the details of a 3-D FEA methodology to develop the capabilities to perform fully-coupled thermal-mechanical analyses of LSF walls exposed to fire in future.

Most of the industrial buildings which are designed to moderate loads are constructed using light gauge cold-formed steel (CFS) sections. Residual mechanical properties of CFS sections exposed to elevated temperature need to be investigated as it is necessary to predict the deterioration of elements to avoid failure of the structure or its elements. Also, it would be helpful to decide whether the structural elements need to be replaced or reused. The use of fire-resistant coatings in steel structures significantly reduces the cost of repairing structural elements and also the probability of collapse. This study investigates the effect of fire-resistant coating on post-fire residual mechanical properties of E350 steel grade.

In this study, an attempt has been made to evaluate the residual mechanical properties of E350 steel. A tensile coupon test was performed for the extracted specimens from the exposed CFS section to determine the mechanical properties. Four different fire-resistant coatings were selected and the sections were coated and heated as per ISO 834 fire temperature curve in the transient state for time durations of 30 minutes (821°C), 60 minutes (925°C), 90 minutes (986°C), and 120 minutes (1,029°C). After the exposure, all the coupon specimens were cooled by either ambient conditions (natural air) or water spraying before conducting the tension test on these specimens.

At 30 min exposure, the reduction in yield and ultimate strength of heated specimens was about 20 and 25% for air and water-cooled specimens compared with reference specimens. Specimens coated with vermiculite and perlite exhibited higher residual mechanical property up to 60 minutes than other coated specimens for both cooling conditions. Generally, water-cooled specimens had shown higher strength loss than air-cooled specimens. Specimens coated with vermiculite and perlite showed an excellent performance than other specimens coated with zinc and gypsum for all heating durations.

As CFS structures are widely used in construction practices, it is crucial to study the mechanical properties of CFS under post-fire conditions. This investigation provides detailed information about the physical and mechanical characteristics of E350 steel coated with different types of fire protection materials after exposure to elevated temperatures. An attempt has been made to improve the residual properties of CFS using the appropriate coatings. The outcome of the present study may enable the practicing engineers to select the appropriate coating for protecting and enhancing the service life of CFS structures under extreme fire conditions.