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Owing to the toxicity, biodegradability, and cost of most corrosion inhibitors, research attention is now focused on the development of environmentally benign, biodegradable, cheap, and efficient options. In consideration of these facts, chrysin, a phytocompound of Populus tomentosa (Chinese white poplar) has been isolated and investigated for its anticorrosion abilities on carbon steel in a mixed acid and chloride system. This highlights the main purpose of the study.

Chrysin was isolated from Populus tomentosa using column chromatography and characterized using Fourier Transform Infrared Spectroscopy and Nuclear Magnetic Resonance Spectroscopy. The investigations are outlined based on theory (Fukui indices, condensed density functional theory and molecular dynamic simulation) and experiments (electrochemical, gravimetry and surface morphology examinations).

Theoretical evaluations permitted the description of the adsorption characteristics, and molecular interactions and orientations of chrysin on Fe substrate. The interaction energy for protonated and neutral chrysin on Fe (110) were −149.10 kcal/mol and −143.28 kcal/mol, respectively. Moreover, experimental investigations showed that chrysin is a potent mixed-type corrosion inhibitor for steel, whose effectiveness depends on its surrounding temperature and concentration. The optimum inhibition efficiency of 78.7% after 24 h for 1 g/L chrysin at 298 K indicates that the performance of chrysin, as a pure compound, compares favorably with other phytocompounds and plant extracts investigated under similar conditions. However, the inhibition efficiency decreased to 62.5% and 51.8% at 318 K after 48 h and 72 h, respectively.

The novelty of this study relies on the usage of a pure compound in corrosion suppression investigation, thus eliminating the unknown influences obtainable by the presence of multi-phytocompounds in plant extracts, thereby advancing the commercialization of bio-based corrosion inhibitors.

The purpose of this paper is to study the adsorption properties of a proven traditional medicine of West Africa origin, Alstonia boonei with an attempt to evaluate its application in the corrosion protection of mild steel in 5 M H₂SO₄ and 5 M HCl.

Phytochemical screening and Fourier transform infrared spectroscopy analysis were used to characterize the methanolic extract of the plant. Gravimetry, gasometry and electrochemical techniques were used in the corrosion inhibition studies of the extract and computational studies were used to describe the electronic and adsorption properties of eugenol, the most abundant phytochemical in Alstonia boonei.

The extract acted as a mixed-type inhibitor in both acidic solutions, with improved inhibition efficiency achieved with increasing concentration. While the efficiency increased with temperature for the HCl system, it decreased for the H₂SO₄ system. The mechanism of adsorption proposed for Alstonia boonei was chemisorption in the HCl system and physisorption in the H₂SO₄ system, and the adsorptions obeyed Langmuir isotherm at low temperatures. Computational parameters showed that eugenol, being a representative of Alstonia boonei, possesses excellent adsorption properties and has the potential to compete with other established plant-based corrosion inhibitors.

As opposed to pure compounds with distinctive corrosion effects, plant extracts are generally composed of a myriad of phytoconstituents that competitively promote or inhibit the corrosion process and their net effect is evident as inhibition efficiencies. This is, therefore, the main research limitation associated with the corrosion inhibition study of Alstonia boonei.

Being very rich in antioxidant properties by its proven curative and preventive effects for diseases, the interest was stimulated towards the attractive results that abound from its corrosion protection of metals via its anti-oxidation route.

The monitoring of respirable particulate matter (PM₁₀) and of total carbon percentage (mass basis) in the atmosphere of São Carlos (SP) was performed in the period between September 1997 and January 2000. São Carlos, located in the central region of the state of São Paulo, has a population of close to 180,000 inhabitants and about 500 industrial establishments of medium to small size, mainly dealing with metallurgy, textiles, food and ceramics. The equipment used for air monitoring was a high volume sampler (GVS‐GRASEBY/GMW) equipped with a one‐stage inertial separator for a 10μm particle cut diameter. The PM₁₀ concentration was determined by gravimetry and the total carbon concentration by the Ströheim method. The results show a well defined seasonal dependence of both the PM₁₀ and of the total carbon concentration. Higher concentrations of PM₁₀ and carbon were observed in autumn and winter, which also coincided with low relative humidity and precipitation. The measured trends were compared with the PM₁₀ data from the city of São Paulo in the same period and showed similar seasonal dependence. However, in relative terms, the PM₁₀ concentration in São Carlos showed stronger seasonal dependence than in São Paulo.

This paper aims to investigate the tribological properties of polytetrafluoroethylene (PTFE) composites modified by nano-serpentine and nano-lanthanum oxide in a seawater environment.

In this paper, seven PTFE composites were prepared by unified design method and vacuum thermoforming method, and their hardness, water absorption and tribological properties were measured under seawater environment. The modification effects and thermal stability of the materials were analyzed by Fourier transform infrared spectroscopy, thermal gravimetry and differential scanning calorimetry. This paper analyzed the wear mechanism of PTFE composites by scanning electron microscopy and energy spectroscopy.

The results showed that the hardness of the PTFE composites were all improved, but the water absorption was increased with the increase of additives. The modification of nano-serpentine was successful and the thermal stability of PTFE composites was better. The lowest coefficient and minimum wear rate are 0.0267 and 8.67 × 10⁻⁵ · mm³ · (N · m)⁻¹ respectively, which is 34.9% and 76% less than the pure PTFE.

The analysis showed that the wear mechanism of PTFE composites was abrasive wear and a small amount of adhesive wear, and when the additive content was appropriate, it easily formed a transfer film on the surface mating parts.

Okara, which is the residue of hydrosoluble extract from soybean obtained after soymilk and tofu production, has high nutritional value and can be used for ingredient in specific food products. This study aims to evaluate the production and properties (physicochemical, microscopical and functional ones) of okara flour (OF) obtained from okara as a by-product of soymilk and tofu production.

Wet okara resulted from the soymilk process underwent convective drying up to reach mass stability (60°C for 12 h). OF properties were analyzed by official methods by AOAC, i.e. mineral composition was evaluated by atomic absorption equipment; color; water absorption index (WAI); milk absorption index (MAI); oil absorption capacity (OAC); and foam capacity (FC) required mixtures with water, milk and oil, separation and gravimetry, respectively; and microstructure was determined by a scanning electron microscope.

Results showed the potential OF has as a source of protein (24.74 g/100 g) and dietary fiber (58.27 g/100 g). Regarding its color after the drying process, OF was markedly yellow (b* parameter 20.16). Its WAI was 3.62 g/g, MAI was 4.33 g/g, OAC was 3.68 g/g and FC was 1.32 per cent. The microscopic analysis of OF showed that both loose and agglomerated particles had irregular structures and indefinite forms.

Production of flour from wet okara can be an alternative use of this by-product. This study showed important characteristics of OF and its possible application to the food industry. Thus, OF was shown as a potential ingredient with high nutritional value.

This paper aims to report the first iteration on the Light Detection and Ranging (LIDAR) Engineering Model altimeter named HELENA. HELENA is a Time of Flight (TOF) altimeter that provides time-tagged distances and velocity measurements. The LIDAR can be used for support near asteroid navigation and provides scientific information. The HELENA design comprises two types of technologies: a microchip laser and low noise sensor. The synergies between these two technologies enable developing a compact instrument for range measurements of up to 14 km. Thermal-mechanical and radiometric simulations of the HELENA telescope are reported in this paper. The design is subjected to vibrational, static and thermal conditions, and it was possible to conclude by the results that the telescope is compliant with the random vibration levels, the static load and the operating temperatures.

The Asteroid Impact & Deflection Assessment (AIDA) is a collaboration between the NASA DART mission and ESA Hera mission. The aim scope is to study the asteroid deflection through a kinetic collision. DART spacecraft will collide with Didymos-B, while ground stations monitor the orbit change. HERA spacecraft will study the post-impact scenario. The HERA spacecraft is composed by a main spacecraft and two small CubeSats. HERA will monitor the asteroid through cameras, radar, satellite-to-satellite doppler tracking, LIDAR, seismometry and gravimetry.

The HELENA design comprises two types of technologies: a microchip laser and low noise sensor. The synergies between these two technologies enable developing a compact instrument for range measurements of up to 14 km.

In this paper is reported the first iteration on the LIDAR Engineering Model altimeter named HELENA. HELENA is a TOF altimeter that provides time-tagged distances and velocity measurements. The LIDAR can be used for support near asteroid navigation and provides scientific information. The HELENA design comprises two types of technologies: a microchip laser and low noise sensor. The synergies between these two technologies enable developing a compact instrument for range measurements of up to 14 km.

The purpose of this paper is to compare the performance of X‐ray fluorescence (XRF) instruments with different detector systems (proportional counter, positive intrinsic negative and Si drift detectors) for measuring thin Au and Pd coatings on printed circuit boards and to investigate different ways of background treatment. It also aims to provide and certify suitable reference materials which are similar to samples used in production.

XRF measurements were performed with different instruments and detector types. The quantification of the reference materials is based on XRF, gravimetric analysis and Rutherford backscattering (RBS).

The well‐established X‐ray instrumentation for coating thickness measurement, with proportional counter detectors, are not very suitable for measuring thin ( < approx. 100 nm) coatings of gold and palladium due to the poor energy resolution of the proportional counter‐tubes. Systems with semiconductor detectors achieve results that are more reliable with a significantly higher accuracy. A correct background treatment is especially important for very thin coatings. The composition of the base material has to be taken into account by the software evaluation algorithm for each measurement. A global base subtraction performed prior to the measurement can achieve better repeatability, but can also lead to incorrect absolute values.

If small measuring spots (e.g. 150 μm) have to be realized with semiconductor detector systems, special X‐ray optics (polycapillaries) have to be used to obtain an intensity comparable to that offered by proportional counter devices. This will be the subject of a further publication.

The paper provides an overall review and results for different types of instruments (detectors) and compares different background treatments. Suitable reference materials have been developed for precise and traceable measurements. Their quantification is based on gravimetric analysis and RBS. The standard‐free energy dispersive X‐ray fluorescence (ED‐X‐ray fluorescence analysis (XRFA)) was used for interpolation of the gravimetric data for thin coatings. For the region below 100 nm, measurement uncertainties of less than 1 nm can be achieved.

The purpose of this paper is the production of fire retardant and smoke suppressant rigid polyurethane foam (RPUF) with lower toxicity by using several fire-retardant combinations.

Fire-retardant additives with cooling effect, barrier ash formation effect, gas-phase inhibition effect and smoke suppressant effect combined to produce an optimum outcome on RPUF. The additive amount and burning time correlation were studied to find out the minimum amount of fire-retardant to obtain fire-retardant polyurethane foam.

Zinc borate powder was coated with 1.5 wt % of stearic acid and hydroxy stearic acid. Polyammonium diborates (PABs) were synthesized and used as a fire-retardant and smoke suppressant for rigid PU foam. Fire-retardant rigid polyurethane foams (FR-RPUF) composites formed by using several combinations of zinc borate, aluminum trihydroxide, trischloroisopropyl phosphate (TCPP), PABs, zinc borate coated with stearic acid and hydroxy stearic acid. Produced FR-RPUF were horizontal burning grade, and burning time was in the range of 1–10 s.

There were limitations during the mixing of fire-retardant powders with polyol due to the high viscosity of the mixture.

FR-RPUF foam with lower toxicity can be produced industrially with these fire-retardant combinations.

FR-RPUF could be produced by using non-toxic additives. During a fire, these additives do not evolve toxic gases. The TCPP content of RPUF foam was reduced, and fire-retardant PU with lower toxicity was produced.

Coated zinc borate and the combinations of the fire-retardants were successful in producing non-toxic fire-retardant and smoke suppressant PU foam.

Ink mist consists of airborne droplets of ink ejected from the nip of press distribution systems and other rotating rolls as a result of the ink film splitting process. To help the printing ink industry deal with the problem, the National Association of Printing Ink Manufacturers, through the NAPIM Technical Institute, inaugurated a project on misting at Lehigh University. The objective of this project was to develop a reliable laboratory test to rate the misting tendencies of printing inks.