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This paper aims to investigate the effect of delayed water curing on the mechanical and microstructural properties of fly ash-based geopolymer paste-blended with Ground Granulated Blast Furnace Slag (GGBS) with different rest periods.

The blended geopolymer paste was composed of GGBS (15 per cent of the total weight) and the base material, Fly Ash (FA). The blended mix was activated by activator solution (Sodium hydroxide and Sodium silicate) containing 6 per cent Na₂O of total base material. The effect of delayed water curing has been studied by gradually increasing the aging period (Rest Period) from 2 hours to 24 hours in the formation of activated outcome along with Calcium Silicate Hydrate (CSH). To analyze the mechanical and microstructural properties of the resultant blended geopolymer paste, compressive strength test, FESEM and XRD have been carried out. Moreover, a long-term durability test subjected to sulphate exposure has been performed to evaluate the durability of the designed sustainable geopolymer paste.

The present paper shows that the delayed water curing incorporates secondary heat input enhancing the partial polymer formation along with CSH. Slag-blended AAFA-based geopolymer paste is seen to exhibit quick setting property. Also, AAFA-based geopolymer paste samples subjected to longer rest period show early strength gain at a high rate under water curing as compared to those subjected to the shorter rest period.

To the best of authors’ knowledge, the effect of delayed water curing on the mechanical and microstructural properties of slag-blended AAFA-based geopolymer paste has not been studied before.

The main objective of the study is to present a systematic process that can assess, compare and benchmark different geographical levels environmental impacts of using sustainable materials at construction stage.

Current study presents a methodological framework to evaluate environmental impacts at the construction stage of using sustainable materials through a cradle-to-gate process based quantitative LCA study. Scenario analyses and an optimisation analysis using Monte-Carlo simulation are conducted to investigate the influence of external factors on environmental impacts at different geographical regions.

Materials account for 98% of greenhouse gas (GHG) emissions. Carbon monoxide (CO) and non-methane volatile organic compounds (NMVOC) record significant non-GHG emissions. Particulate matter (PM₁₀) emissions are significant from transportation and equipment. High significance of global warming potential (GWP) (38.98%) and photochemical oxidation formation potential (POFP) (34.49%) at global level and eutrophication potential (EP) (52.83%) and human toxicity potential (HTP) (25.30%) impacts at local level were observed. Shortest transportation distance reduces 14.91% PM₁₀ and 4.69% nitrous oxide (NO_x) emissions. Inventory variations have major influence on POFP impact at global level. Local level impacts are not significantly affected by inventory variations. Optimisation analysis indicated, high fly ash in concrete increase local level carbon emissions, if OPC concrete transportation distance is less than 23.7 km.

Use of case-specific information for validation may lack generalisation. However, methodology can be used for future sustainable decision making over using sustainable materials in construction.

The study estimate environmental impacts at different geographical levels when sustainable materials are used for construction.

Concrete, the second most used material in the world, surpassed only by water, relies on a vast amount of cement. The process of cement production emits substantial amounts of carbon dioxide (CO₂). Consequently, it is crucial to search for cement alternatives. Geopolymer concrete (GC) uses industrial by-product material instead of traditional cement, which not only reduces CO₂ emissions but also enhances concrete durability. On the other hand, the disposal of concrete waste in the landfills represents a significant environmental challenge, emphasising the urgent need for sustainable solutions. This study aimed to investigate waste concrete's best form and rate as the alternative aggregates in self-compacting and ambient-cured GC to preserve natural resources, reduce construction and demolition waste and decrease pertinent CO₂ emissions. The binding material employed in this research encompasses fly ash, slag, micro fly ash and anhydrous sodium metasilicate as an alkali activator. It also introduces the best treatment method to improve the recycled concrete aggregate (RCA) quality.

A total of25%, 50% and 100% of coarse aggregates are replaced with RCAs to cast self-compacting geopolymer concrete (SCGC) and assess the impact of RCA on the fresh, hardened and water absorption properties of the ambient-cured GC. Geopolymer slurry was used for coating RCAs and the authors examined the effect of one-day and seven-day cured coated RCA. The mechanical properties (compressive strength, splitting tensile strength and modulus of elasticity), rheological properties (slump flow, T500 and J-ring) and total water absorption of RCA-based SCGC were studied. The microstructural and chemical compositions of the concrete mixes were studied by the methods of energy dispersive X-Ray and scanning electron microscopy.

It is evident from the test observations that 100% replacement of natural aggregate with coated RCA using geopolymer slurry containing fly ash, slag, micro fly ash and anhydrous sodium metasilicate cured for one day before mixing enhances the concrete's quality and complies with the flowability requirements. Assessment is based on the fresh and hardened properties of the SCGC with various RCA contents and coating periods. The fresh properties of the mix with a seven-day curing time for coated RCA did not meet the requirements for self-compacting concrete, while this mix demonstrated better compressive strength (31.61 MPa) and modulus of elasticity (15.39 GPa) compared to 29.36 MPa and 9.8 GPa, respectively, for the mix with one-day cured coated RCA. However, incorporating one-day-cured coated RCA in SCGC demonstrated better splitting tensile strength (2.32 MPa) and water absorption (15.16%).

A potential limitation of this study on SCGC with coated RCAs is the focus on the short-term behaviour of this concrete. This limited time frame may not meet the long-term requirements for ensuring the sustained durability of the structures throughout their service life.

This paper highlights the treatment technique of coating RCA with geopolymer slurry for casting SCGC.

Fiber-reinforced polymers (FRP) contain critical electrical conductivity for high-intensity radiated fields such as lightning strike susceptibility, electromagnetic energy from radar, airborne radio frequency transmitter. To provide high-intensity radiated field protection (HIRFP) for the electric and electronic aircraft system and defied the EMI effect on it, metal matrix composite was conquered. To provide the dynamic ever-increasing requirement of industries, it is necessary that Al6061 metal matrix composite assisted with AL₂O₃ and fly ash is used to construct the aircraft to provide HIRFP. The thickness of the material can be maintained as low as possible to use it as a coating material for the aircraft surface. X-band for oblique incidence is used to measure electromagnetic and mechanical safeguarding properties of composites.

Day by day, the applications of aerospace are becoming digital and automated. Proper shielding techniques are required to operate digital electronic devices without electromagnetic interference. It leads to a rapid rise in temperature, thermal ablation, delamination, and adverse effects on the electric and electronic aircraft system. Fly ash, a metal matrix material composite AL6061 with different percentages of reinforcement of Al₂O₃, was contemplated and experimented with for mechanical properties like tensile strength, density and hardness.

The obtained results compared with adjusted values and an improvement of 0.19, 0.18, 0.14 g/cm³ for density of MMC-1, MMC-2, MMC-3.31, 11 MPa for tensile strength of MMC-1, MMC-2. 24, 27, 23 BHN for hardness of MMC-1, MMC-2, MMC-3. With regard to the shielding effectiveness the results compared with adjusted values and obtained 11.36, 14.56, 19.47 dB better value than it. According to the above results, fabricated MMC’s provide superior results for a defined application like HIRFP(Surface material of aircraft).

It can be used to protect electronic devices under a high-intensity radiated field, mainly in aircraft design to protect from lightning effect.

For a better approximation of the signal toward the practical case, the oblique incidence was considered with a different combination of Al₂O₃ and fly ash, reinforced to pure AL6061 to get better shielding and mechanical properties.

The purpose of this paper is to study and analyze the effects of fly ash (FA) as a mineral admixture on compressive strength (CS), carbonation resistance and corrosion resistance of reinforced concrete (RC). In addition, the utilization of inexpensive and abundantly available FA as a cement replacement in concrete has several benefits including reduced OPC usage and elimination of the FA disposal problem.

Reinforcement corrosion and carbonation significantly affect the strength and durability of the RC structures. Also, the utilization of FA as green corrosion inhibitors, which are nontoxic and environmentally friendly alternatives. This review discusses the effects of FA on the mechanical characteristics of concrete. Also, this review analyzes the impact of FA as a partial replacement of cement in concrete and its effect on the depth of carbonation in concrete elements and the corrosion rate of embedded steel as well as the chemical composition and microstructure (X-ray diffraction analysis and scanning electron microscopy) of FA concrete were also reviewed.

This review provides a clear analysis of the available study, providing a thorough overview of the current state of knowledge on this topic. Regarding concrete CS, the findings indicate that the incorporation of FA often leads to a loss in early-age strength. However, as the curing period increased, the strength of fly ash concrete (FAC) increased with or even surpassed that of conventional concrete. Analysis of the accelerated carbonation test revealed that incorporating FA into the concrete mix led to a shallower carbonation depth and slower diffusion of carbon dioxide (CO₂) into the concrete. Furthermore, the half-cell potential test shows that the inclusion of FA increases the durability of RC by slowing the rate of steel-reinforcement corrosion.

This systematic review analyzes a wide range of existing studies on the topic, providing a comprehensive overview of the research conducted so far. This review intends to critically assess the enhancements in mechanical and durability attributes (such as CS, carbonation and corrosion resistance) of FAC and FA-RC. This systematic review has practical implications for the construction and engineering industries. This can support engineers and designers in making informed decisions regarding the use of FA in concrete mixtures, considering both its benefits and potential drawbacks.

The purpose of this paper is to research the hardened properties of non-dispersible concrete in seawater environment, especially in seawater environment.

The main approach is according to the experiment.

The findings of this paper are: first, because of the washing effect of water, the strength of underwater non-dispersible concrete is lower than that of terrestrial concrete. Second, the strength of non-dispersible underwater concrete with silica fume increases remarkably at different ages. Third, underwater non-dispersible concrete does not produce new products when it is formed and cured in seawater.

In this paper, underwater non-dispersible concrete is formed and maintained on land, freshwater and seawater by underwater pouring method. The working performance, mechanical properties and durability of underwater non-dispersible concrete mixtures after hardening are tested.

The purpose of this paper is to develop a conceptual framework of fly ash (FA) handling by using the total interpretive structural modeling (TISM) technique in the Indian context.

The conceptual framework of the FA handling technique has been developed by using the TISM technique, where the FA handling factors have been identified from literature and verified by experts.

The conceptual framework of FA handling technique developed by using TISM contributes to the development of FA handling hierarchy. The framework identifies that there are 12 important factors which play a vital role in FA handling. The conceptual model indicates that particle size distribution derives FA handling technology.

This study identified important factors for FA handling and it has implication for both organizations and policy makers. This study delivers the factors which play an important role in handling FA in a thermal power plant. This study highlights important linkages essential for the expansion of FA handling technologies and policies.

This study is unique in itself as it studies the FA handling factors through the qualitative modeling technique and has made its contribution in FA handling by providing the conceptual framework for managing FA in the thermal power plant.

The purpose of this study is to analyze the slurry erosion failure of Ni-20Cr (Ni-Cr₂O₃), Ni-20Al (Ni-Al₂O₃) and Al-20Ti (Al₂O₃-TiO₂) coatings deposited on SS316L by the high-velocity oxy-fuel process.

Slurry erosion experiments were conducted using a pot type erosion tester at different velocities 1.81, 2.71, 3.61 and 4.59 m/s for the time duration of 90-180 minutes. Fly ash and bottom ash were used as erodent media; the concentration of mass flux was taken as 30-60 wt. per cent. Artificial neural network (ANN) method was used to simulate the slurry erosion for thermally sprayed coatings.

Slurry erosion of coatings increases non-linearly with an increase in experimental durations, mass flux and velocity. Slurry erosion of Ni-20Cr and Ni-20Al layers was found to be maximum at 60° impingement angle, whereas 30° for SS316L and 45° for Al-20Ti coating. Slurry erosion performance of SS316L was improved by 2.56-3.19 times by depositing Ni-20Cr and Ni-20Al layers, whereas it improved 1.15-1.75 times by Al-20Ti coating. The slurry erosion SS316L was found almost 1.35 ± 1.28 times greater than that of the Ni-20Al coating, whereas it was to be 1.12 ± 1.36 times greater than Al-20Ti. Ni-20Al-coated SS316L showed a lower value of slurry erosion than Al-20Ti-coated SS316L.

Stainless Steel SS316L is widely used in hydraulic machinery (such as turbines, pumps, valves, fittings, etc.) of hydraulic and thermal power plants, chemical industry and marine industry. Therefore, the deposition of ductile and brittle coatings is a better option for their durable performance.

Erosion wear of Ni-20Cr, Ni-20Al and Al-20Ti coatings was successfully simulated by using an artificial neural network model by supplying experimental data as a target.

The purpose of this paper is to investigate the effect of the replacement of natural coarse aggregate (NCA) with different percentages of recycled coarse aggregate (RCA) on properties of low calcium fly ash (FA)-based geopolymer concrete (GPC) cured at oven temperature. Further, this paper aims to study the effect of partial replacement of FA by ground granulated blast slag (GGBS) in GPC made with both NCA and RCA cured under ambient temperature curing.

M25 grade of ordinary Portland cement (OPC) concrete was designed according to IS: 10262-2019 with 100% NCA as control concrete. Since no standard guidelines are available in the literature for GPC, the same mix proportion was adopted for the GPC by replacing the OPC with 100% FA and W/C ratio by alkalinity/binder ratio. All FA-based GPC mixes were prepared with 12 M of sodium hydroxide (NaOH) and an alkalinity ratio, i.e. sodium hydroxide to sodium silicate (NaOH:Na₂SiO₃) of 1:1.5, subjected to 90^°C temperature for 48 h of curing. The NCA were replaced with 50% and 100% RCA in both OPC and GPC mixes. Further, FA was partially replaced with 15% GGBS in GPC made with the above percentages of NCA and RCA, and they were given ambient temperature curing with the same molarity of NaOH and alkalinity ratio.

The workability, compressive strength, split tensile strength, flexural strength, water absorption, density, volume of voids and rebound hammer value of all the mixes were studied. Further, the relationship between compressive strength and other mechanical properties of GPC mixes were established and compared with the well-established relationships available for conventional concrete. From the experimental results, it is found that the compressive strength of GPC under ambient curing condition at 28 days with 100% NCA, 50% RCA and 100% RCA were, respectively, 14.8%, 12.85% and 17.76% higher than those of OPC concrete. Further, it is found that 85% FA and 15% GGBS-based GPC with RCA under ambient curing shown superior performance than OPC concrete and FA-based GPC cured under oven curing.

The scope of the present paper is limited to replace the FA by 15% GGBS. Further, only 50% and 100% RCA are used in place of natural aggregate. However, in future study, the replacement of FA by different amounts of GGBS (20%, 25%, 30% and 35%) may be tried to decide the optimum utilisation of GGBS so that the applications of GPC can be widely used in cast in situ applications, i.e. under ambient curing condition. Further, in the present study, the natural aggregate is replaced with only 50% and 100% RCA in GPC. However, further investigations may be carried out by considering different percentages between 50 and 100 with the optimum compositions of FA and GGBS to enhance the use of RCA in GPC applications. The present study is further limited to only the mechanical properties and a few other properties of GPC. For wider use of GPC under ambient curing conditions, the structural performance of GPC needs to be understood. Therefore, the structural performance of GPC subjected to different loadings under ambient curing with RCA to be investigated in future study.

The replacement percentage of natural aggregate by RCA may be further enhanced to 50% in GPC under ambient curing condition without compromising on the mechanical properties of concrete. This may be a good alternative for OPC and natural aggregate to reduce pollution and leads sustainability in the construction.

The purpose of this paper is to highlight the sustainability benefits of using demolition and industrial wastes as a replacement for aggregates and cement in traditional concrete mixes.

Crushed concrete from demolition sites served as a replacement for fine and coarse aggregate in some of the mixes at various ratios. In addition, ground granulated blast furnace slag, metakaolin, silica fume, and fly ash each served as a cement replacement for cement content in the mixes tested in this research at various rates. Compression strength tests, permeability, and thermal expansion tests were performed on various mixes to compare their performance to that of traditional mixes with natural aggregate, and with no cement replacement.

The compressive strength results indicated the suitability of using such demolition wastes as replacements in producing green concrete (GC) without hindering its mechanical characteristics significantly. In addition, the results indicated an enhancement in the mechanical characteristics of GC when replacing cement with pozzolanic industrial wastes and byproducts.

The research assesses the utilization of sustainable GC using recycled waste aggregate and byproducts.