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1 – 10 of 176Xiansheng Zhang, Xianjing Du, Lili Wang and Meiwu Shi
The purpose of this paper is to investigate the effect of char on the flame retardancy of fabrics by a cone calorimeter, which is an important factor to compare the flame…
Abstract
Purpose
The purpose of this paper is to investigate the effect of char on the flame retardancy of fabrics by a cone calorimeter, which is an important factor to compare the flame retardancy of different fabrics.
Design/methodology/approach
Cone calorimeter measurements were carried out in a Fire Testing Technology (UK) apparatus at the heat fluxes of 50 and 75 kW/m2. Fabrics with one and three layers were employed, with the name of cotton1, cotton3, FR cotton1, FR cotton3, PMIA1 and PMIA3. The dimension of the fabric was 100×100 mm2. A cross-steel grid was used to prevent the fabrics from curling during burning. The distance between the bottom of the cone heater and the top of the sample was 25 mm.
Findings
This work was generously supported by National Key R&D Program of China (Project No. 2017YFB0309000), Natural Science Foundation of Shandong Province of China (Project No. ZR2019BEM026), Natural Science Foundation of China (Project No. 51803101) and China postdoctoral science foundation funded project (Project No. 2018M632619).
Originality/value
The present research provides insight into the effect of the char formation on the flame retardancy of the fabrics, and a method to comprehensively investigate the char influence in the flame retardancy of the fabrics by a cone calorimeter is proposed.
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Aysun Aksit, Nurhan Onar, Bengi Kutlu, Evren Sergin and Ismail Yakin
The purpose of this paper is to develop the flame retardancy properties of cotton fabrics with treatment of phosphorus and nitrogen containing silane-based nanosol by sol-gel…
Abstract
Purpose
The purpose of this paper is to develop the flame retardancy properties of cotton fabrics with treatment of phosphorus and nitrogen containing silane-based nanosol by sol-gel process.
Design/methodology/approach
Nanosols containing tetraethoxysilane or (3-aminopropyl) triethoxysilane as precursors, (3-glycidyloxypropyl) trimethoxysilane as cross-linking agent and guanidine phosphate monobasic as flame retarding agent were impregnated on cotton fabrics. Flame retardancy properties of the fabric samples were determined by limited flame spread test and limited oxygen index (LOI) test. In addition, microstructural and surface morphological properties of the fabric samples were characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope.
Findings
Depending on the limited flame spread test, the authors show that the coated fabric samples gain flame retardancy properties and the LOI value of the samples increased as to 45.7 per cent by the synergistic effect of phosphorus-nitrogen-silicon.
Originality/value
There have some studies in flame retardancy behaviour of textiles. In this study, flame retardant cotton fabric with very low weight in grams was improved by sol-gel process. Moreover, ecological process was provided thanks to using halogen-free flame retardant.
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Yuan Li, Yanzhi Xia, Min Li, Jinchi Liu, Miao Yu and Yutian Li
In this paper the aim is that Aramid/alginate blended nonwoven fabrics were prepared, and the flame retardancy of the blended nonwoven fabrics was studied by thermogravimetric…
Abstract
Purpose
In this paper the aim is that Aramid/alginate blended nonwoven fabrics were prepared, and the flame retardancy of the blended nonwoven fabrics was studied by thermogravimetric analysis, vertical flame test, limiting oxygen index (LOI) and cone calorimeter test.
Design/methodology/approach
The advantages of different fibers can be combined by blending, and the defects may be remedied. The study investigates whether incorporating alginate fibers into aramid fibers can enhance the flame retardancy and reduce the smoke production of prepared aramid/alginate blended nonwoven fabrics.
Findings
Thermogravimetric analysis indicated that alginate fibers could effectively inhibit the combustion performance of aramid fibers at a higher temperature zone, leaving more residual chars for heat isolation. And vertical flame test, LOI and cone calorimeter test testified that the incorporation of alginate fibers improved the flame retardancy and fire behaviors. When the ratio of alginate fibers for aramid/alginate blended nonwoven fabrics reached 80%, the incorporation of alginate fibers could notably decreased peak-heat release rate (54%), total heat release (THR) (29%), peak-smoke production rate (93%) and total smoke production (86%). What is more, the lower smoke production rate and lower THR of the blends vastly reduced the risk of secondary injury in fires.
Originality/value
This study proposes to inhibit the flue gas release of aramid fiber and enhance the flame retardant by mixing with alginate fiber, and proposes that alginate fiber can be used as a biological smoke inhibitor, as well as a flame retardant for aramid fiber.
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Hongkun Zhang, Xianyun Gong, Zan Li and Yang Wang
The epoxy resins need to be added with flame retardant to ensure safety in practical applications. There were a lot of highly toxic substances in the flame retardant used in the…
Abstract
Purpose
The epoxy resins need to be added with flame retardant to ensure safety in practical applications. There were a lot of highly toxic substances in the flame retardant used in the past, which caused greater harm to human body and the environment. Therefore, this study aims to propose a research on the synthesis of new phosphorous-containing flame retardant and the properties of flame retardant epoxy resins.
Design/methodology/approach
The flame retardant intermediate DOPO was synthesized using o-phenylphenol as the substrate. The intermediate was mixed with D4Vi under certain conditions to synthesize a new phosphorous-containing flame retardant. The flame retardant was added to the epoxy resins to prepare the flame retardant epoxy resins.
Findings
The experimental results show that the synthetic new phosphorous-containing flame retardant is far less harmful than the flame retardant used in the past and has extremely low toxicity, which is suitable for use in practical projects.
Originality/value
The new phosphorus-containing flame retardant synthesized by forms a more uniform and dense carbon layer in the combustion process, which well protects the underlying materials, thus improving the flame retardancy of epoxy resin materials. The harm of the new phosphorus-containing flame retardant is far less than that of ordinary flame retardant. The flame retardant used in the past has very low toxicity and is suitable for practical engineering.
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Bing Liang, Jiao Lv, Gang Wang and Tsubaki Noritatsu
The purpose of this paper is to prepare a novel halogen-free intumescent flame retardant (IFR) BHPPODC (benzene hydroquinone phosphorous oxy dichloride cyanuric chloride) for…
Abstract
Purpose
The purpose of this paper is to prepare a novel halogen-free intumescent flame retardant (IFR) BHPPODC (benzene hydroquinone phosphorous oxy dichloride cyanuric chloride) for application to epoxy resin (EP) and study their mechanical and flame-retardant performance.
Design/methodology/approach
The IFR was synthesised by phenylphosphonic dichloride, hydroquinone and cyanuric chloride via solvent reaction, and the structure was fully characterised by proton nuclear magnetic resonance (1H-NMR), mass spectrometry (MS) and Fourier transform infrared (FT-IR) spectroscopy. The thermal stability, mechanical and flame properties and morphology of the char layer of the flame-retardant EP was investigated by using thermogravimetric analysis (TGA), tensile and Charpy impact tests, limiting oxygen index (LOI) and vertical burning test (UL-94) and scanning electron microscopy (SEM).
Findings
Results of the LOI indicated that the halogen-free flame retardant as an additive exhibits very good flame-retardant effects. The results showed that the addition of IFR improved the flame resistance properties of epoxies resin composites, and the residual char ratio at 800°C significantly increased.
Research limitations/implications
The IFR can be prepared successfully and can improve the flame-retardant performance.
Practical implications
This contribution can provide a high flame retardant performance and has minimal impact on the mechanical performance of the BHPPODC/EP composition.
Originality/value
This study showed that flame-retardant BHPPODC has an effective flame effect under optimal conditions. When the 12 Wt.% IFR was added to the EP, the LOI was 29.1 and the UL-94 rank can reach V-0 rank, the tensile strength was 83.86 MPa and the impact strength was 8.82 kJ/m2.
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Suzhu Yu, Aloysius Tan, Wei Ming Tan, Xinying Deng, Cher Lin Tan and Jun Wei
This paper aims to develop flame-retardant (FR) polyamide 12 (PA12) nanocomposite from regenerated powder via selective laser sintering (SLS), an additive manufacturing technique.
Abstract
Purpose
This paper aims to develop flame-retardant (FR) polyamide 12 (PA12) nanocomposite from regenerated powder via selective laser sintering (SLS), an additive manufacturing technique.
Design/methodology/approach
First, the morphology, processibility, thermal and mechanical properties of PA12 regenerated powder, consisting of 50 wt% new and 50 wt% recycled powder, as well as corresponding printed specimens, were evaluated to characterize the effects of previous SLS processing. Second, flame-retardant PA12 was developed by incorporating both single and binary halogen-free flame retardants into the regenerated powder.
Findings
It was found that the printed specimens from regenerated powder had much higher tensile and impact properties compared to specimens made from new powder, which is attributed to better particulate fusion and coalescence realized in higher temperature SLS printing. The effect of FRs on thermal, mechanical and flame retardant properties of the PA12 composites/nanocomposites was investigated systematically. It was found that the nanoclay, as a synergist, improved both flame-retardant and mechanical properties of PA12. UL94 standard rating of V-0 was achieved for the printed nanocomposite by incorporating 1 wt% nanoclay into 15 wt% phosphinates FR. Moreover, on average, the tensile and impact strength of the nanocomposite were increased by 26.13% and 17.09%, respectively, in XY, YZ and Z printing orientations as compared to the equivalent flame retardant composite with 20 wt% of the phosphinates FR.
Originality/value
This paper fulfills the need to develop flame retardant parts via SLS technology with waste feedstock. It also addresses the challenge of developing flame retardant materials without obviously compromising the mechanical properties by making use of the synergistic effect of nanoclay and organic phosphinates.
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Pundalik Pandharinath Mali, Nilesh S. Pawar, Narendra S. Sonawane, Vikas Patil and Rahul Patil
The purpose of this work was to develop a new trispiperazido phosphate-based reactive diluent (diphosphate-piperazine hydroxyl acrylate [DPHA]) and used as a flame retardant with…
Abstract
Purpose
The purpose of this work was to develop a new trispiperazido phosphate-based reactive diluent (diphosphate-piperazine hydroxyl acrylate [DPHA]) and used as a flame retardant with an epoxy acrylate (EA) in ultraviolet (UV)-curable wood coating.
Design/methodology/approach
The concentration of reactive diluent was varied from 0% to 20% in the UV-curable formulation with constant photoinitiator concentration. The effect of DPHA concentration on film properties was studied by differential scanning calorimetry and thermogravimetric analysis, gel content, water absorption and limiting oxygen index.
Findings
The results showed that the viscosity of the prepared formulation decreased by increasing reactive diluent (DPHA) concentration which leads to improving the coating efficiency. A high concentration of reactive diluent (DPHA) of the cured films shows good resistance against stain, mechanical and thermal properties, which results in an increased glass transition temperature (Tg) and cross-linking density of the films.
Originality/value
The new trispiperazido phosphate-based reactive diluent was used in wood coating formulation, which resulted in excellent flame-retardant properties with higher cross-linked density with good stain resistance. This material can provide a wide range of application for coating industries to produce a glossy finish.
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The purpose of this paper is to present a latest update on halogen‐free base materials that are lead‐free compatible and have enhanced electrical properties.
Abstract
Purpose
The purpose of this paper is to present a latest update on halogen‐free base materials that are lead‐free compatible and have enhanced electrical properties.
Design/methodology/approach
Numerous halogen‐free flame retardants are screened in laboratory conditions for a wide arrange of properties. Once suitable candidates are found, they are compounded and processed into copper‐clad laminates and a wide variety of properties are tested.
Findings
Several formulations are found that are lead‐free compatible and that has enhanced electrical properties. Surprisingly, some thermal properties are found to be superior to traditionally halogenated laminates.
Research limitations/implications
The research here only presents the halogen‐free properties of a bare, unpopulated printed wiring board with no build up of inner layers and devoid of solder mask. Further work needs to be done on full circuit assemblies to properly evaluate the impact of removing halogens from interconnecting packages.
Originality/value
The paper details the material property differences between various halogen‐free materials as compared to halogenated materials. A method to model composite properties is also discussed.
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Abstract
Purpose
The flammability of poly-acrylate (PA) resin is a major disadvantage in applications that require flame resistance. It has been reported that a flame-retardant PA resin could be prepared by covalent incorporate phosphorous containing monomer with vinyl group via free radical polymerization, and the prepared modified PA resin is expected to exhibit better flame resistance than those by an additive approach. However, the phosphorus-containing monomers reported previously are made from expensive or toxic materials, and the production procedure is tedious and under harsh reaction conditions, which are not feasible for industrial application. Therefore, the purpose of this paper is the preparation of flame-retardant PA resin modified by epoxy resin phosphorous acid (EPPA) and the study of its flame retardancy.
Design/methodology/approach
EPPA is first prepared by epoxy resin E-51 and phosphorous acid and then used to prepare phosphorous containing PA resin by free radical polymerization. The flame retardancy of the prepared EPPA-modified PA (EPPA-PA) resin is studied.
Findings
The results show that EPPA can graft onto the PA polymer chain by free radical polymerization, the flame retardancy of the EPPA-PA resin increases as the EPPA content increasing. The flame retardancy of EPPA-PA resin prepared reaches 27.8% and can pass the V-0 rating in the UL-94 test when EPPA content is 30.0%. SEM and EDS results indicate that phosphorous element in the EPPA-PA resin shows a condensed-phase flame retardant effect.
Research limitations/implications
The grafting degree of EPPA cannot be accurately tested.
Practical implications
It is expected that the large-scale production of this epoxy resin phosphoric acid modified PA resin will enable practical industrial applications.
Originality/value
This method for synthesis of epoxy resin phosphoric acid modified PA resin is newfrangled.
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Xinyue Liang, Hui Qiao, Guilong Xu, Yanchong Zhang, Yun Liang and Jian Hu
The flammability of poly-acrylate (PA) resin is a major disadvantage in applications that require flame resistance. Many studies, including the authors’ previous study, have…
Abstract
Purpose
The flammability of poly-acrylate (PA) resin is a major disadvantage in applications that require flame resistance. Many studies, including the authors’ previous study, have proved that covalent-incorporated phosphorous-containing (P-containing) monomer onto the PA resin can exhibit better flame resistance than that by an additive approach. However, other properties such as thermal stability, coating properties are still deteriorated. To further improve the flame-retardancy and other comprehensive properties of the P-containing PA resin, in this study, melamine formaldehyde(MF) resin was used not only as a curing agent to enhance the coating properties of the PA resin, but also as a nitrogen-containing (N-containing) resin to form a P-N synergistic effect and therefore further improve its flame retardancy.
Design/methodology/approach
Epoxy resin phosphorous acid-modified (EPPA-modified) PA (EPPA-PA) resin was first prepared and then using MF resin as curing agent. The flame retardancy of the cured resin was tested by the limiting oxygen index (LOI) and UL 94 methods. The thermal stability of the cured resin was studied by TGA. The coating technology such as adhesion property, pencil hardness and anti-solvent properties were characterized according to methods of International Standards ISO2409-1992, ISO 15184-1998 and ISO-15184-2012, respectively. The micro-char morphology of the char residue was observed by SEM.
Findings
The results showed that by using MF resin as curing agent has provided the PA resin with excellent coating properties and thermal stability, but also gave a P-N synergistic effect which has greatly enhanced the flame retardancy of the cured resin. The cured resin system containing only 1.7 Wt.% P content and 5.3 Wt.% N content can reach a LOI of 26.9 per cent and pass the V-0 rating in the UL-94 test.
Research limitations/implications
This resin system releases formaldehyde due to the MF resin.
Practical implications
It is expected that the large-scale production of this EPPA-PA resin cured by MF resin system will enable practical industrial applications.
Originality/value
This method for the synthesis of a P- and N-containing PA resin system is newfangled.
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