Search results
1 – 10 of 113Thejas Ramakrishnaiah, Prasanna Gunderi Dhananjaya, Chaturmukha Vakwadi Sainagesh, Sathish Reddy, Swaroop Kumaraswamy and Naveen Chikkahanumajja Surendranatha
This paper aims to study the various developments taking place in the field of gas sensors made from polyaniline (PANI) nanocomposites, which leads to the development of…
Abstract
Purpose
This paper aims to study the various developments taking place in the field of gas sensors made from polyaniline (PANI) nanocomposites, which leads to the development of high-performance electrical and gas sensing materials operating at room temperature.
Design/methodology/approach
PANI/ferrite nanocomposites exhibit good electrical properties with lower dielectric losses. There are numerous reports on PANI and ferrite nanomaterial-based gas sensors which have good sensing response, feasible to operate at room temperature, requires less power and cost-effective.
Findings
This paper provides an overview of electrical and gas sensing properties of PANI/ferrite nanocomposites having improved selectivity, long-term stability and other sensing performance of sensors at room temperature.
Originality/value
The main purpose of this review paper is to focus on PANI/ferrite nanocomposite-based gas sensors operating at room temperature.
Details
Keywords
R. Masrour, M. Ben Ali, H. El Moussaoui, Mohamed Hamedoun, A. Benyoussef and E.K. Hlil
The purpose of this paper is to synthesize the manganese ferrite nanoparticle MnFe2O4 and to investigate the structure, size and to study the electronic and the magnetic…
Abstract
Purpose
The purpose of this paper is to synthesize the manganese ferrite nanoparticle MnFe2O4 and to investigate the structure, size and to study the electronic and the magnetic properties of MnFe2O4 nanoparticles.
Design/methodology/approach
The co-precipitation method is used to synthesize the MnFe2O4. The structure and size were investigated by X-ray diffraction. The superconducting quantum interference device is used to determine the some magnetic ground. From theoretical investigation point of view self-consistent ab initio calculations, based on density functional theory approach using full potential linear augmented plane wave method, were performed to investigate both electronic and magnetic properties of the MnFe2O4. The high temperatures series expansion (HTSE) is used to study the magnetic properties of MnFe2O4.
Findings
The saturation magnetization, the coercivity and the transition temperature varied between 21-43 emu/g, 20-50 Oe and 571-630 K, respectively, have been studied. The gap energy of MnFe2O4 has been deduced. The critical temperature and the critical exponent have been obtained using HTSEs.
Originality/value
In the present work, the authors study the electronic and magnetic properties of MnFe2O4. The results obtained by the experiment and by ab initio calculations were used in HTSE as input to deduce other physical parameters.
Details
Keywords
Ibrahim A. Amar, Sarah S. Kanah, Hibah A. Hijaz, Mabroukah A. Abdulqadir, Shamsi A. Shamsi, Ihssin A. Abdalsamed and Mohammed A. Samba
The purpose of this research is to assess the removal of oil spills from the seawater surface as well as the antibacterial activity of ZnFe2O4-cetyltrimethylammonium bromide…
Abstract
Purpose
The purpose of this research is to assess the removal of oil spills from the seawater surface as well as the antibacterial activity of ZnFe2O4-cetyltrimethylammonium bromide (CTAB, cationic surfactant) magnetic nanoparticles (ZFO-CTAB MNPs).
Design/methodology/approach
A CTAB-assisted sol–gel method was used to synthesize ZFO-CTAB MNPs. X-ray powder diffraction and Fourier transform infrared spectroscopy were used for ZFO-CTAB MNPs characterization. Also, the magnetic force and apparent density of ZFO-CTAB MNPs were determined. The oil spill cleanup was investigated by using the gravimetric oil removal (GOR) technique, which used ZFO-CTAB MNPs as oil absorbent material and four oil samples (crude, diesel, gasoline and used oil) as oil spill models. The antibacterial activity of ZFO-CTAB MNPs against Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli and Salmonella typhi) was investigated by using the optical density method.
Findings
The results revealed that, when the amount of ZFO-CTAB was 0.01 g, gasoline oil had the highest GOR (51.80 ± 0.88 g/g) and crude oil had the lowest (11.29 ± 0.82 g/g). Furthermore, for Escherichia coli, Salmonella typhi and Pseudomonas aeruginosa, ZFO-CTAB MNPs inhibited bacterial growth with a higher percentage (94.24%–95.63%).
Originality/value
The applications of ZFO-CTAB MNPs in the cleanup of oil spills from aqueous solutions, as well as their antibacterial activity. The results showed that ZFO-CTAB MNPs are a promising material for removing oil spills from bodies of water as well as an antibacterial agent against Gram-negative bacterial strains.
Details
Keywords
Mayya Ziganshina, Sergey Stepin, Sergey Karandashov and Veronika Mendelson
The purpose of this paper is to search for toxic anticorrosive pigments’ substitute in protective coatings is one of the important tasks that the specialists in the field of steel…
Abstract
Purpose
The purpose of this paper is to search for toxic anticorrosive pigments’ substitute in protective coatings is one of the important tasks that the specialists in the field of steel corrosion face.
Design/methodology/approach
One of the ways to solve the problem of metal corrosion is to use complex oxides as pigments, which are characterized as low-toxic compounds and possess the ability to inhibit corrosion.
Findings
In the production of ferrites, it is possible to use production waste as raw material, and that makes it possible to reduce the price of the resulting product and solve environmental problems simultaneously.
Originality/value
Permanent growth of world production is accompanied by the increasing environment corrosiveness, associated with the intensification of air, water basin and soil pollution by industrial waste. This, as well as the continuously increasing operated metal stock, has recently made the tendency of metals’ total loss from corrosion steadily increasing. All of this points to the importance of studying corrosion processes and the systematic and effective fight against metal corrosion.
Details
Keywords
Ibrahim A. Amar, Jawaher O. Asser, Amina S. Mady, Mabroukah S. Abdulqadir, Fatima A. Altohami, Abubaker A. Sharif and Ihssin A. Abdalsamed
The main purpose of this paper is to investigate the adsorption properties of CoFe1.9Mo0.1O4 magnetic nanoparticles (CFMo MNPs) using, anionic dye “congo red (CR)” as a model of…
Abstract
Purpose
The main purpose of this paper is to investigate the adsorption properties of CoFe1.9Mo0.1O4 magnetic nanoparticles (CFMo MNPs) using, anionic dye “congo red (CR)” as a model of water pollutants.
Design/methodology/approach
The magnetic nano-adsorbent was synthesized via sol-gel process. Different techniques including; Fourier transform infrared spectroscopy, point of zero charge, scanning electron microscope and X-ray powder diffraction were used to characterize the prepared adsorbent. Adsorption experiments were conducted in batch mode under various conditions (contact time, shaking speed, initial dye concentration, initial solution pH, solution temperature and adsorbent amount) to investigate the adsorption capability of CFMo MNPs for CR.
Findings
The results showed that, CFMo MNPs could successfully remove more than 90% of CR dye within 20 min. Adsorption kinetics and isotherms were better described using pseudo-second-order (PSO) and Langmuir models, respectively. The maximum adsorbed amount (qmax) of CR dye was 135.14 mg/g. The adsorption process was found to be endothermic and spontaneous in nature as demonstrated by the thermodynamics (
Practical implications
This study provided a good example of using an easily separated magnetic nano-adsorbent for fast removal of a very toxic organic pollutant, congo red, from the aquatic environment
Originality/value
The employment of Mo-doped cobalt ferrite for the first time for removing hazardous anionic dyes such as congo red from their aqueous solutions.
Details
Keywords
A.U. Chaudhry, Vikas Mittal, M.I. Hashmi and Brajendra Mishra
Inorganic oxide addition can be synergistically beneficial in organic coatings if it can impart anti-corrosion properties and also act as an additive to enhance physical and/or…
Abstract
Purpose
Inorganic oxide addition can be synergistically beneficial in organic coatings if it can impart anti-corrosion properties and also act as an additive to enhance physical and/or chemical properties. The aim of this study was to evaluate the anti-corrosion benefits of nano nickel zinc ferrite (NZF) in the polymer film.
Design/methodology/approach
The time-dependent anti-corrosion ability of NZF (0.12-1.0 per cent w/w NZF/binder), applied on API 5L X-80 carbon steel, was characterized by electrochemical techniques such as open circuit potential, electrochemical impedance spectroscopy, linear polarization resistance and potentiodynamic. Characterization of corrosion layer was done by removing coatings after 216 h of immersion in 3.5 per cent w/v NaCl. Optical microscopy, field emission scanning electron microscopy and X-ray diffraction techniques were used to characterize the corroded surface.
Findings
Corrosion measurements confirm the electrochemical activity by metallic cations on the steel surface during corrosion process which results in improvement of anti-corrosion properties of steel. Moreover, surface techniques show compact corrosion layer coatings and presence of different metallic oxide phases for nanocomposite coatings.
Originality/value
The suggested protection mechanism was explained by the leaching and precipitation of metallic ion on the corroded surface which in turn slowed down the corrosion activity. Furthermore, improvement in barrier properties of rubber-based coatings was confirmed by the enhanced pore resistance. This work indicates that along with a wide range of applications of NZF, anti-corrosion properties can be taken as an addition.
Details
Keywords
Ibrahim A. Amar and Mohammed M. Ahwidi
This paper aims to investigate the electrocatalytic activity of CoFe1.9Mo0.1O4-Ce0.8Gd0.18Ca0.02O2-δ composite (CFMo-CGDC) for the direct synthesis of ammonia from H2O and N2…
Abstract
Purpose
This paper aims to investigate the electrocatalytic activity of CoFe1.9Mo0.1O4-Ce0.8Gd0.18Ca0.02O2-δ composite (CFMo-CGDC) for the direct synthesis of ammonia from H2O and N2 under atmospheric pressure.
Designs
CoFe1.9Mo0.1O4 nanoparticles (CFMo NPs) were synthesized via a sol-gel method. CFMo NPs were characterized using X-ray diffraction (XRD), Brunauer–Emmet–Teller (BET) specific surface area measurement and scanning electron microscope (SEM). Double-chamber reactor was used to synthesize ammonia using H2O and N2 as precursors. The factors affecting the ammonia formation rate (applied voltage and temperature) were studied.
Findings
CoFe1.9Mo0.1O4 nanoparticles (CFMo NPs) were synthesized via a sol-gel method. CFMo NPs were characterized using XRD, Brunauer–Emmet–Teller (BET) specific surface area measurement and SEM. Double-chamber reactor was used to synthesize ammonia using H2O and N2 as precursors. The factors affecting the ammonia formation rate (applied voltage and temperature) were studied.
Originality/value
The usage of CFMo-CGDC composite as an electrocatalyst for the synthesis of ammonia directly from H2O and N2.
Details
Keywords
Iskandar Waini, Umair Khan, Aurang Zaib, Anuar Ishak and Ioan Pop
This study aims to investigate the micropolar fluid flow through a moving flat plate containing CoFe2O4-TiO2 hybrid nanoparticles with the substantial influence of thermophoresis…
Abstract
Purpose
This study aims to investigate the micropolar fluid flow through a moving flat plate containing CoFe2O4-TiO2 hybrid nanoparticles with the substantial influence of thermophoresis particle deposition and viscous dissipation.
Design/methodology/approach
The partial differential equations are converted to the similarity equations of a particular form through the similarity variables. Numerical outcomes are computed by applying the built-in program bvp4c in MATLAB. The process of flow, heat and mass transfers phenomena are examined for several physical aspects such as the hybrid nanoparticles, micropolar parameter, the thermophoresis particle deposition and the viscous dissipation.
Findings
The friction factor, heat and mass transfer rates are higher with an increment of 1.4%, 2.2% and 1.4%, respectively, in the presence of the hybrid nanoparticles (with 2% volume fraction). However, they are declined because of the rise of the micropolar parameter. The imposition of viscous dissipation reduces the heat transfer rate, significantly. Meanwhile, thermophoresis particle deposition boosts the mass transfer. Multiple solutions are developed for a certain range of physical parameters. Lastly, the first solution is shown to be stable and reliable physically.
Originality/value
As far as the authors have concerned, no work on thermophoresis particle deposition of hybrid nanoparticles on micropolar flow through a moving flat plate with viscous dissipation effect has been reported in the literature. Most importantly, this current study reported the stability analysis of the non-unique solutions and, therefore, fills the gap of the study and contributes to new outcomes in this particular problem.
Details
Keywords
Ibrahim A. Amar, Aeshah Alzarouq, Wajdan Mohammed, Mengfei Zhang and Noarhan Matroed
This study aims to explore the possibility of using magnetic biochar composite (MBCC) derived from Heglig tree bark (HTB) powder (agricultural solid waste) and cobalt ferrite (CoFe…
Abstract
Purpose
This study aims to explore the possibility of using magnetic biochar composite (MBCC) derived from Heglig tree bark (HTB) powder (agricultural solid waste) and cobalt ferrite (CoFe2O4, CFO) for oil spill removal from seawater surface.
Design/methodology/approach
One-pot co-precipitation route was used to synthesize MBCC. The prepared materials were characterized by X-ray diffraction, scanning electron microscopy-energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy. The densities of the prepared materials were also estimated. Crude, diesel engine and gasoline engine oils were used as seawater pollutant models. The gravimetric oil removal (GOR) method was used for removing oil spills from seawater using MBCC as a sorbent material.
Findings
The obtained results revealed that the prepared materials (CFO and MBCC) were able to remove the crude oil and its derivatives from the seawater surface. Besides, when the absorbent amount was 0.01 g, the highest GOR values for crude oil (31.96 ± 1.02 g/g) and diesel engine oil (14.83 ± 0.83 g/g) were obtained using MBCC as an absorbent. For gasoline engine oil, the highest GOR (27.84 ± 0.46 g/g) was attained when CFO was used as an absorbent.
Originality/value
Oil spill removal using MBCC derived from cobalt ferrite and HTB. Using tree bark as biomass (eco-friendly, readily available and low-cost) for magnetic biochar preparation also is a promising method for minimizing agricultural solid wastes (e.g. HTB) and obtaining value-added-products.
Details
Keywords
Water is a vital natural resource without which life on earth would be impossible. Properties of synthetic dyes like high stability and noxious nature make it difficult to remove…
Abstract
Purpose
Water is a vital natural resource without which life on earth would be impossible. Properties of synthetic dyes like high stability and noxious nature make it difficult to remove them from the effluent. This review focuses on the removal of synthetic dyes using nanoparticles (NPs) based on the adsorption principle.
Design/methodology/approach
Adsorption technique is widely used to remove synthetic dyes from their aqueous solution for decades. Synthetic dye removal using NPs is promising, less energy-intensive and has become popular in recent years. NPs are in high demand for treating wastewater using the adsorption principle due to their tiny size and vast surface area. To maximise environmental sustainability, the utilisation of green-produced NPs as efficient catalysts for dye removal has sparked attention amongst scientists.
Findings
This review has prioritised research and development of optimal dye removal systems that can be used to efficiently remove a large quantity of dye in a short period while safeguarding the environment and producing fewer harmful by-products. The removal efficiency of synthetic dye using different NPs in wastewater treatment varies mostly between 75% to almost 100%. This review will aid in the scaling up of the wastewater treatment process.
Research limitations/implications
There is a lack of research emphasis on the safe disposal of NPs once the reuse efficiency significantly drops. The relevance of cost analysis is equally critical, yet only a few papers discuss cost-related information.
Originality/value
Comprehensive and planned research in this area can aid in the development of long-term wastewater treatment technology to meet the growing need for safe and reliable water emphasising reuse and desorption efficiency of the NPs.
Details