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The purpose of this paper is to synthesize anticorrosion pigments ZnFe2O4 from diverse raw materials of various shapes and size of primary particles.
Abstract
Purpose
The purpose of this paper is to synthesize anticorrosion pigments ZnFe2O4 from diverse raw materials of various shapes and size of primary particles.
Design/methodology/approach
Anticorrosion pigments were synthesized through a high‐temperature process during a solid phase. Zinc ferrites were prepared from hematite (α‐Fe2O3), goethite (α‐FeO.OH), magnetite (Fe3O4), and specularite (Fe2O3) entering into reaction with zinc oxide at temperatures ranging from 600 up to 1,100°C. The nature of the initial raw material, primarily the shape of its particles, affects the shape of the particles of the synthesized zinc ferrite. The formulated zinc ferrites had a rod‐shape, lamellar, and/or isometric shape. The shape of the particles of synthesized zinc ferrites was studied with regard to its effects on the mechanical and corrosion resistance of organic coatings. The obtained pigments were characterized by means of X‐ray diffraction analysis and scanning electron microscopy. The synthesized anticorrosion pigments were used to prepare epoxy coatings and water‐borne styrene‐acrylate coatings that were subjected to post‐application tests for physical‐mechanical properties and anticorrosion properties.
Findings
The shape of the particles was identified in the synthesized pigments. X‐ray diffraction analysis revealed the degree of precipitation and lattice parameters. All of the synthesized pigments had good anticorrosion efficiency in an epoxy and in styrene‐acrylate coatings. Compared with a commercially used anticorrosion pigment, their protective power in coatings was demonstrably stronger.
Practical implications
The synthesized pigments can be used conveniently in coatings protecting metal bases against corrosion.
Originality/value
The synthesis of zinc ferrites with different particle shapes for applications in anticorrosion coatings provides a new way of protecting metals against corrosion. Of benefit is the fact that the synthesized pigments do not contain any environmentally harmful substances.
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This paper gives a bibliographical review of the finite element methods (FEMs) applied to the analysis of ceramics and glass materials. The bibliography at the end of the paper…
Abstract
This paper gives a bibliographical review of the finite element methods (FEMs) applied to the analysis of ceramics and glass materials. The bibliography at the end of the paper contains references to papers, conference proceedings and theses/dissertations on the subject that were published between 1977‐1998. The following topics are included: ceramics – material and mechanical properties in general, ceramic coatings and joining problems, ceramic composites, ferrites, piezoceramics, ceramic tools and machining, material processing simulations, fracture mechanics and damage, applications of ceramic/composites in engineering; glass – material and mechanical properties in general, glass fiber composites, material processing simulations, fracture mechanics and damage, and applications of glasses in engineering.
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Nivin M. Ahmed, Walaa M. Abd El-Gawad and Eglal M.R. Souaya
Core-shell is structured particles having several chemical compositions. The advantage of these particles arise from their specific design, to be used in decreasing costs by using…
Abstract
Purpose
Core-shell is structured particles having several chemical compositions. The advantage of these particles arise from their specific design, to be used in decreasing costs by using inexpensive material (natural ore or waste material) as carrier for thin shell of active material. This study aims to prepare ferrites/silica core-shell pigments and compare their inhibition efficiency to original ferrites. These pigments have shells of different ferrites that comprise 10-15 per cent of the prepared pigments on silica fume. Silica fume which is the core is a byproduct in the ferro–silicon industry; this core comprises 85-90 per cent of the prepared pigments.
Design/methodology/approach
The prepared core-shell pigments were characterized using transmission electron microscopy analysis, energy-dispersive X-ray analysis and sequential wavelength dispersive X-ray fluorescence. These pigments were integrated in epoxy-based paint formulations, and the physical, mechanical and corrosion properties of dry films were examined. The corrosion properties were studied by using immersion test in 3.5 per cent NaCl for 28 days.
Findings
This study showed that these new eco-friendly and inexpensive pigments are similar to ferrites in their inhibition performance, i.e. they exhibited high corrosion prevention.
Research limitations/implications
Domestic waste materials were reused in paints and only simple modification was used, and then, their effectiveness showed similar performance to that of the original pigments.
Originality/value
Ferrite and ferrite/silica pigments are environmentally friendly pigments that can replace other hazardous pigments (e.g. chromates) with almost the same quality in their performance; also, they can be used in industries other than paints (e.g. paper, rubber and plastics composites).
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Yaojie Zheng, Huili Sun, Luchun Yan, Huisheng Yang, Kewei Gao, Xiaolu Pang and Alex A. Volinsky
The purpose of this study is to investigate the effect of ferrite on hydrogen embrittlement (HE) of the 17-4PH stainless steels.
Abstract
Purpose
The purpose of this study is to investigate the effect of ferrite on hydrogen embrittlement (HE) of the 17-4PH stainless steels.
Design/methodology/approach
The effects of ferrite on HE of the 17-4PH stainless steels were investigated by observing microstructure and conducting slow-strain-rate tensile tests and hydrogen permeability tests.
Findings
The microstructure of the ferrite-bearing sample is lath martensite and banded ferrite, and the ferrite-free sample is lath martensite. After hydrogen charging, the plasticity of the two steels is significantly reduced, along with the tensile strength of the ferrite-free sample. The HE susceptibility of the ferrite-bearing sample is significantly lower than the ferrite-free steel, and the primary fracture modes gradually evolved from typical dimple to quasi-cleavage and intergranular cracking. After aging at 480°C for 4 h and hydrogen charging for 12 h, the 40.9% HE susceptibility of ferrite-bearing samples was the lowest. In addition, the hydrogen permeation tests show that ferrite is a fast diffusion channel for hydrogen, and the ferrite-bearing samples have higher effective hydrogen diffusivity and lower hydrogen concentration.
Originality/value
There are a few studies of the ferrite effect on the HE properties of martensitic precipitation hardening stainless steel.
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Heike Bartsch, Sebastian Thiele, Jens Mueller, Dirk Schabbel, Beate Capraro, Timmy Reimann, Steffen Grund and Jörg Töpfer
This paper aims to investigate the usability of the nickel copper zinc ferrite with the composition Ni0.4Cu0.2Zn0.4Fe1.98O3.99 for the realization of high-temperature multilayer…
Abstract
Purpose
This paper aims to investigate the usability of the nickel copper zinc ferrite with the composition Ni0.4Cu0.2Zn0.4Fe1.98O3.99 for the realization of high-temperature multilayer coils as discrete components and integrated, buried function units in low temperature cofired ceramics (LTCC).
Design/methodology/approach
LTCC tapes were cast and test components were produced as multilayer coils and as embedded coils in a dielectric tape. Different metallization pastes are compared. The properties of the components were measured at room temperature and higher temperature up to 250°C. The results are compared with simulation data.
Findings
The silver palladium paste revealed the highest inductance values within the study. The measured characteristics over a frequency range from 1 MHz to 100 MHz agree qualitatively with the measurements obtained from toroidal test samples. The inductance increases with increasing temperature and this influence is lower than 10%. The characteristic of embedded coils is comparable with this of multilayer components. The effective permeability of the ferrite material reaches values around 130.
Research limitations/implications
The research results based on a limited number of experiments; therefore, the results should be verified considering higher sample sizes.
Practical implications
The results encourage the further investigation of the material Ni0.4Cu0.2Zn0.4Fe1.98O3.99 for the use as high-temperature ferrite for the design of multilayer coils with an operation frequency in the range of 5-10 MHz and operation temperatures up to 250°C.
Originality/value
It is demonstrated for the first time, that the material Ni0.4Cu0.2Zn0.4Fe1.98O3.99 is suitable for the realization of high-temperature multilayer coils and embedded coils in LTCC circuit carriers with high performance.
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Mayya Ziganshina, Sergey Stepin, Sergey Karandashov and Veronika Mendelson
The purpose of this paper is to search for toxic anticorrosive pigments’ substitute in protective coatings is one of the important tasks that the specialists in the field of steel…
Abstract
Purpose
The purpose of this paper is to search for toxic anticorrosive pigments’ substitute in protective coatings is one of the important tasks that the specialists in the field of steel corrosion face.
Design/methodology/approach
One of the ways to solve the problem of metal corrosion is to use complex oxides as pigments, which are characterized as low-toxic compounds and possess the ability to inhibit corrosion.
Findings
In the production of ferrites, it is possible to use production waste as raw material, and that makes it possible to reduce the price of the resulting product and solve environmental problems simultaneously.
Originality/value
Permanent growth of world production is accompanied by the increasing environment corrosiveness, associated with the intensification of air, water basin and soil pollution by industrial waste. This, as well as the continuously increasing operated metal stock, has recently made the tendency of metals’ total loss from corrosion steadily increasing. All of this points to the importance of studying corrosion processes and the systematic and effective fight against metal corrosion.
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Maruti K. Rendale, S.N. Mathad and Vijaya Puri
The present communication aims to investigate the influence of cobalt substitution on the structural, mechanical and elastic properties of nickel–zinc ferrite thick films. The…
Abstract
Purpose
The present communication aims to investigate the influence of cobalt substitution on the structural, mechanical and elastic properties of nickel–zinc ferrite thick films. The changes observed in the crystallite size (D), lattice constant (a), texture coefficient [TC(hkl)] and mechanical and elastic properties of the thick films due to cobalt substitution have been reported systematically.
Design/methodology/approach
Ni–Zn ferrites with the stoichiometric formula Ni0.7−xCoxZn0.3Fe2O4 (where, x = 0, 0.04, 0.08, 0.12, 0.16 and 0.20) were synthesized via solution combustion technique using sucrose as the fuel and poly-vinyl-alcohol as the matrix material. The thick films of the ferrites were fabricated on alumina substrates by the screen printing method. The thickness of the films was 25 μm, as measured by the gravimetric method. The thick films were subjected to X-ray diffraction and Fourier transform infrared spectroscopy.
Findings
The detailed study of variation of lattice parameter (a), sintering density, micro-strain and elastic properties with cobalt (Co+2) substituted was carried out. The remarkable increase in lattice parameter (from 8.369 A° to 8.3825 A°), bulk density and average grain size (69-119 nm) with the cobalt content was due to larger ionic radius of Co2+ compared to Ni2+. Texture analysis [TC(hkl)] reveals all thick films have adequate grain growth in the (311) plane direction. The main absorption bands of spinel ferrite have appeared through infrared absorption spectra recorded in the range of 300-700 cm−1.
Originality/value
The variation in stiffness constants (for isotropic material, C11 = C12), longitudinal elastic wave (Vl), transverse elastic wave (Vt), mean elastic velocity (VMean), rigidity modulus (G), Poisson’s ratio(s) and Young’s modulus (E) with cobalt (Co+2) composition has been interpreted in terms of binding forces found.
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To study nonreciprocal effects in microstrip components due to ferrite thin film overlay.
Abstract
Purpose
To study nonreciprocal effects in microstrip components due to ferrite thin film overlay.
Design/methodology/approach
The possibility of obtaining non reciprocal characteristics in the X band microwave region in the absence of external magnetic field by a simple process of using Mg, Co, Zn ferrite thin films as in‐touch overlay over λ/2 microstrip rejection filter was investigated. Microstrip rejection filter is basically a reciprocal component. The ferrite thin films were deposited by electroless plating.
Findings
It was found that frequency, pH and ferrite overlay material dependent changes occurred and differences in forward and reverse loss also observed, in some cases greater than 30 dB. Owing to the overlay the rejection properties of the filter is lost and there is an increase in insertion loss. The best non reciprocal effects are seen at higher frequencies. The presence of permeability related effects like magnetostatic modes interfering with the normal propagation of the microstrip circuits might be causing the changes in the circuits.
Originality/value
There is scope for true planarisation of ferrite‐based components by using the ferrite in thin film form as in‐touch overlay.
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Halil Ibrahim Ünal, Hakan Atapek, Baran Gürkan Beleli, Seyda Polat, Serap Gümüs and Ersoy Erisir
The purpose of this paper is to investigate the fracture of grade X42 microalloyed steel used as pipe material after tensile test at room temperature and impact tests at 0, −20…
Abstract
Purpose
The purpose of this paper is to investigate the fracture of grade X42 microalloyed steel used as pipe material after tensile test at room temperature and impact tests at 0, −20 and −40°C, respectively.
Design/methodology/approach
In the first stage of the study, X42 steels in the form of sheet and pipe materials were selected and etched samples were characterized using light microscope. In the second stage, mechanical properties of steels were obtained by microhardness measurements, static tensile and impact tests and all the broken surfaces were examined by scanning electron microscope to determine the fracture type as a function of both microstructure and loading.
Findings
The examinations revealed that: first, the sheet material had a typical ferritic-pearlitic matrix, second, the transverse section of the sheet steel exhibited a matrix consisting of polygonal ferrite-aligned pearlite colonies and the longitudinal one had elongated ferrite phase and pearlite colonies in the direction of rolling, third, ferrite and pearlite distribution was different from the sheet material due to multiaxial deformation in the pipe material, fourth, tensile fracture surfaces of the steels had typical dimple fracture induced by microvoid coalescence, fifth, impact fracture surfaces of the steels changed as a function of the test temperature and cleavage fracture mode of ferritic-pearlitic matrix became more dominant as the temperature decreased, and sixth, grain morphology had an effect on the fracture behavior of the steels.
Originality/value
The paper explains the fracture behaviour of X42 microalloyed pipeline steel and its fractographical analysis.
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S.M. Jenei, O.S. Aleksić, L.D. Živanov and D.I. Raković
Ni‐ferrite powder average grain size less than 0.9µm was used for the ferrite paste preparation. Ferrite paste was printed on Al2O3 substrate and fired 850°C/10min. After Ni…
Abstract
Ni‐ferrite powder average grain size less than 0.9µm was used for the ferrite paste preparation. Ferrite paste was printed on Al2O3 substrate and fired 850°C/10min. After Ni‐ferrite thick film characterization had been done, simple planar inductor geometry, such as square spirals, were printed on it. Measurements were done, using an HP 4194A impedance analyser. The experimental results were summarized and compared with theoretical predictions given by the electromagnetic analysis using the method of current images for the reason of accounting the effect of magnetic substrate. The computer program, developed here, allows determination of the required thickness of the substrate which will produce inductance enhancement of the given permeability of the substrate material. The same results can also be used to determine the permeability of magnetic film or substrate quickly and are directly applicable to the design of the planar inductors.