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Thermochemical conversion processes are one of the possible solutions for the flexible production of electric and thermal power from biomass. The pyrolysis degradation process presents, among the others, the interesting features of biofuels and high energy density bio-oil production potential high conversion rate. In this paper, numerical results of a slow batch and continuous fast pyrolyzers, are presented, aiming at validating both a tridimensional computational fluid dynamics-discrete element method (CFD–DEM) and a monodimensional distributed activation energy model (DAEM) represents with data collected in dedicated experiments. The purpose of this paper is then to provide reliable models for industrial scale-up and direct design purposes.

The slow pyrolysis experimental system, a batch of small-scale constant-pressure bomb for allothermic conversion processes, is presented. A DEM numerical model has been implemented by means of a modified OpenFOAM solver. The fast pyrolysis experimental system and a lab scale screw reactor designed for biomass fast pyrolysis conversion are also presented along with a 1D numerical model to represent its operation. The model which is developed for continuous stationary feeding conditions and based on a four-parallel reaction chemical framework is presented in detail.

The slow pyrolysis numerical results are compared with experimental data in terms of both gaseous species production and reduction of the bed height showing good predictive capabilities. Fast pyrolysis numerical results have been compared to the experimental data obtained from the fast pyrolysis process of spruce wood pellet. The comparison shows that the chemical reaction modeling based on a Gaussian DAEM is capable of giving results in very good agreement with the bio-oil yield evaluated experimentally.

As general results of the proposed activities, a mixed experimental and numerical approach has demonstrated a very good potential in developing design tools for pyrolysis development.

The purpose of this paper is to investigate fast pyrolysis of maple fruit as an energy sources. This could serve as a solution to the energy sources problem.

Fast pyrolysis of maple fruit (samara) was achieved in a fixed bed reactor. The pyrolysis experiments have been conducted on the sample of maple seeds to particularly determine the effects of pyrolysis temperature, particle size and sweep gas flow rate on the pyrolysis product yields.

The oil of maple fruit from fast pyrolysis has good properties to be a potential candidate as a biofuel or as a source of chemicals. In addition to being environmentally desirable, it can reduce the energy cost, e.g. that Turkey imports a majority of its energy.

The use of maple fruit for fast pyrolysis and pyrolysis conditions impact on the yields of pyrolysis liquid can be considered as novel aspects of this paper.

In 2008, a number of Southern African countries cultivated about 900,000 ha of Jatropha, with a number of biodiesel plants ready for production; however, none of the projects succeeded. In 2014, KiOR advanced biofuel Energy Company in the USA announced bankruptcy due to incompetent technology. Studies disclose that the reasons for biofuel plants failure are not only due to lack of incentives and unclear policies but also due to lack of economic feasibility and low production yields. This paper aims to review the techno-economy assessment of second-generation biofuel technologies. The purpose of this paper is to summarize specific techno-economic indicators such as production cost, technology efficiency and process life cycle analysis for advanced biofuel technology and to narrate and illustrate a clear view of what requires assessment to deploy a feasible advanced biofuel technology. This study also reviews assessment of biomass supply chain, feedstock availability and site selection criteria. The review also elaborates on the use of different processes, forecasting and simulation-modeling tools used in different techno-economic analysis studies. The review provides guidance for conducting a technical and economic feasibility study for the advanced biofuels energy business.

The aim of this review is, therefore, to evaluate the techno-economic feasibility studies for the establishment of viable industrial scale production of second-generation biofuels. It does so by grouping studies based on technology selection, feedstock availability and suitability, process simulation and economies as well as technology environmental impact assessment.

In conclusion, techno-economic analysis tools offer researchers insight in terms of where their research and development should focus, to attain the most significant enhancement for the economics of a technology. The study patterns within the scope of techno-economics of advanced biofuel reveal that there is no generic answer as to which technology would be feasible at a commercial scale. It is therefore important to keep in mind that models can only simplify and give a simulation of reality to a certain extent. Nevertheless, reviewed studies do not reach the same results, but some results are logically similar.

The originality of this article specifically illustrates important technical and economic indicators that should be considered when conducting feasibility studies for advance biofuels.

This study aims to investigate the effect of reactor temperature on softwood and hardwood pyrolysis. Experiments are performed at six temperature levels ranging from 300 to 800°C under N₂ atmosphere. The weights of char, tar and gas yields produced were measured and recorded in percentage of initial weight of the pyrolyzed samples. Results of the study showed that hardwood produces maximum char, tar and gas yields of 41.02 per cent at 300°C,44.10 per cent at 300°C and 56.86 per cent at 800°C, respectively, whereas softwood produces maximum yields of 30.10 per cent at 300°C, 28.25 per cent at 300°C and 68.73 per cent at 800°C, respectively. Proximate analysis shows that volatile matter, fixed carbon, ash content and moisture content of hardwood are 74.83, 14.28, 2.81 and 8.08 per cent, respectively, and that of softwood are 79.76, 12.65, 0.98 and 6.61 per cent, respectively. Result of the elemental analysis results shows that the carbon, hydrogen, nitrogen, oxygen and sulphur contents for hardwood are 52.20, 6.45, 0.68, 39.64 and 1.03 per cent, respectively, and that of softwood are 45.95, 4.57, 0.56, 48.13 and 0.79 per cent, respectively. The higher heating value of hardwood and softwood are 21.76 and 16.50 kJ/g respectively. This study shows that char and tar yields decrease with increase pyrolysis temperature, whereas gas yield increases as pyrolysis temperature increases for the wood samples considered. At all temperatures considered in this study, gas yields are higher than tar and char yields for softwood, whereas for hardwood, tar yield decreases with increase in temperature with accompanying increase in gas yield.

Experiments are performed at six temperature levels ranging from 300 to 800°C under N₂ atmosphere.

At all temperatures considered in this study, gas yields are higher than tar and char yields for softwood, whereas for hardwood, tar yield decreases with increase in temperature with accompanying increase in gas yield.

Results of the study showed that hardwood produces maximum char, tar and gas yields of 41.02 per cent at 300°C,44.10 per cent at 300°C and 56.86 per cent at 800°C, respectively, whereas softwood produces maximum yields of 30.10 per cent at 300°C, 28.25 per cent at 300°C and 68.73 per cent at 800°C, respectively.

The authors aim to investigate the use of pyrolysis for the processing of waste printed circuit boards (PCBs). The aim was to make the process of separating the organic, metallic, and glass fibre fractions of PCBs much easier and therefore make recycling of each PCB fraction more viable.

The PCBs were pyrolysed in a fixed bed reactor at 850°C. The organic fraction released by the boards was analysed by a variety of gas chromatography techniques. The residue that remained after pyrolysis was analysed by ICP‐MS to determine the type of metals that were present.

When PCBs were heated to 800°C in an oxygen free atmosphere, the organic fraction decomposed to form volatile oils and gases leaving behind the metal and glass fibre fraction of the boards. The pyrolysed boards were very friable and the different fractions (metal components, copper power boards, glass fibre, etc.) could be easily separated. The recovered metals could then be recycled by traditional routes with particular emphasis being placed on the recovery and recycling of rare and precious metals. The organic oils and gases which are produced during pyrolysis of PCBs can either be used as a chemical feedstock or as a fuel.

The research was only carried out on a very small scale so an investigation into scale‐up must be performed.

By using pyrolysis, the organic and metallic fraction of PCBs can be separated and recycled.

This paper presents a novel method for resource recovery from PCBs.

Purpose – This work aims to study the treatment of adsorbant on the increasing liquid hydrocarbon quality produced by pyrolysis low density polyethylene (LDPE) plastic waste at low temperature. The hydrocarbon distribution, physicochemical properties and emission test were also studied due to its application in internal combustion engine. This research uses pure Calcium carbonate (CaCO₃) and pure activated carbon as adsorbant, LDPE type clear plastic samples with control variable that is solar gas station.

Design/Methodology/Approach – LDPE plastic waste of 10 kg were vaporized in the thermal cracking batch reactor using LPG 12 kg as fuel at range temperature from 100 to 300°C and condensed into liquid hydrocarbon. Furthermore, this product was treated with the mixed CaCO₃ and activated carbon as adsorbants to decrease contaminant material.

Findings – GC-MS identified the presence of carbon chain in the range of C6–C44 with 24.24% of hydrocarbon compounds in the liquid. They are similar to diesel (C6–C14). The 30% of liquid yields were found at operating temperature of 300°C. The calorific value of liquid was 46.021 MJ/Kg. This value was 5.07% higher than diesel as control.

Originality/Value – Hydrocarbon compounds in liquid produced by thermal cracking at a low temperature was similar to liquid from a catalytic process.

Purpose – The purpose of this research is to study the process conditions that give best yield and expected compositions of liquid smoke products that result during the pyrolisis process relying on predetermined variables.

Design/Methodology/Approach – Pyrolisis process running times are varied, that is, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, and 6 hourly. Condensing temperature maintained remained 25–30 °C. Products identification was applied by using gas chromotography mass spectroscopy.

Findings – Based on the research output, it was concluded that process conditions which give maximum yield were achieved when using double unit condenser (DUC) and time optional four hours, and it provides maximum volume liquid smoke product, and compositions of pyrolisis products. The process also created seven components, namely nepthalene, propanoic acid, 3,7 nanodiena, 2 metilguaiakol, 2-metoksi 4-methyl phenol, 4 ethyl-2 metoksil phenol, oxybanzene. Applying DUC during condensation phase may increase condensing force thereafter obtaining resulted products between 200% and 300% rather than using single unit condenser (SUC).

Research Limitations/Implications – This research was conducted on a fixed batch reactor made of a metal plate with a thickness of 3.0 mm. It carries 200 kg in capacity. In this phase, the moisture of candlenut shells might be kept in 10–12.5% wt. Process temperature applied ranged within 350–500 °C.

Originality/Value – In addition the study increased the theorical of understanding about pyrolisis process and Improving the production of liquid smoke from candlenut shell by pyrolisis process using the method of vapor condensation (Double unit condensor).

The energy demand of growing population is on rise despite the fact that conventional energy reserves are limited and exhaustive in nature. To quench the ever-needing demand of energy, there is an urgent need to find out new energy options. In this regard, role of bioenergy plantation has gained enormous attention of scientist community all over the world. Biochar, a black pyrolysed carbonaceous product, is used as soil amendment and is reported to provide several benefits such as retention of nutrients in soil, better cation exchange capacity, soil carbon sequestration with better biomass yield. The paper aims to discuss these issues.

The present study investigated the effect of domestic waste water (grey water) as well as biochar in combination for above-ground biomass of Eucalyptus hybrid (clone 413) and Anthocephalus cadamba plantations under flooded irrigation.

Height, girth and above-ground biomass of both plantations increased significantly from control. Above-ground biomass of A. cadamba was observed to be better than Eucalyptus hybrid during initial period of establishment. After application of biochar, treatment WW+BBm was found to produce maximum above-ground biomass followed by treatment WW and WW+ BBg in both plantations system.

The present study encompassed a real sustainable approach for environmental management by integrating the use of waste water (source of nutrients) as well as biochar (a solid waste pyrolysed material that act as soil fertilizer, an efficient adsorbent as well as a sink for carbon sequestration) for the better biomass yield of bioenergy plantations.

The purpose of the article is to identify relevant criteria for decision support in the implementation of waste-to-energy (WtE)-based systems.

The methodology is a simple case study with a qualitative approach. Five experts involved in the project of a thermoelectric power plant qualitatively evaluated, on a Likert scale, a decision model with 15 indicators derived from recent studies. The research object was the first stage of a project to implement a thermoelectric plant employing municipal solid waste (MSW) in southern Brazil.

The study identified 15 criteria supporting the decision-making process regarding WtE implementation for MSW in a mid-sized city in southern Brazil. The study identified that compliance with MSW legislation, compliance with energy legislation, initial investment and public health impact are the most influential criteria. The study offered two models for decision processes: a simplified one and a complete one, with ten and fifteen indicators, respectively.

The study concerns mid-sized municipalities in southern Brazil.

Municipal public managers have now a methodology based on qualitative evaluation that admits multiple perspectives, such as technical, economic, environmental and social, to support decision-making processes on WtE technologies for MSW.

MSW management initiatives can yield jobs and revenues for vulnerable populations and provide a correct destination for MSW, mainly in developing countries.

The main originality is that now municipal public decision-makers have a structured model based on four constructs (technical, economic, environmental and social) deployed in 15 indicators to support decision-making processes involving WtE and MSW management.